• Title/Summary/Keyword: $CO_2$fixation

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Propylene Carbonate Synthesis using Supercritical $CO_2$ and Ionic Liquid (초임계 이산화탄소와 이온성 액체를 이용한 Propylene Carbonate 합성)

  • Kim, Byeong-Heon;Jang, Sung-Hyeon;Min, Se-Ryeon;Kim, Hwa-Yong
    • Clean Technology
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    • v.17 no.1
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    • pp.37-40
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    • 2011
  • Some ionic liquids are suitable for catalysts and solvents which are applicable to $CO_2$ fixation reaction converting $CO_2$ to carbonate. Using the ionic liquids, the synthesis process will become greener and simpler because of easy catalyst recycling and unnecessary use of volatile and harmful organic solvents. In this work, the synthesis of propylene carbonate from propylene oxide using carbon dioxide and ionic liquids were measured at high pressures up to ~140 bar and at temperatures between $60^{\circ}C$ and $80^{\circ}C$. As a results, we found the optimum condition and obtained the maximum yield under that condition.

An Experimental Study on the Resistance to Penetration of Harmful Ions in Surface Coatings Material Containing Organic Corrosion inhibitor (유기계 방청제를 혼입한 표면피복재의 유해이온 침투저항에 관한 실험적 연구)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.157-166
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    • 2017
  • In general, carbonation and chlorine ions are the most harmful causes of deterioration of concrete structures. Recently, a method has been developed to control the corrosion of rebar in concrete containing chloride by impregnating a Surface coating material with a inhibitor. In this study, accelerated carbonation and differential thermogravimetric analysis (TG-DTA) and CASS tests were carried out to evaluate the characteristics of Surface coatings containing Organic Corrosion inhibitors which are excellent in corrosion inhibition and fix degradation causes $CO_2$ and $Cl^-$. As a result of the experiment, TG-DTA analysis and accelerated carbonation showed that $CO_2$ was directly reacted with amine derivative in concrete by the incorporation of Organic Corrosion inhibitor. In other words, $CO_2$ was immobilized and carbonation inhibition effect was confirmed. In addition, in the CASS test, the specimen coated with the Surface coating material containing the Organic Corrosion inhibitor with $Cl^-$ fixing property showed no corrosion until the 28th day and had excellent performance in preventing corrosion of a rebar by the chloride ion.

Characteristics Related to Photosynthesis and Grain Yield of $F_1$ Hybrid Rice (벼 1대잡종의 광합성 및 수량 관련 특성)

  • Lee, Deog-Bae;Kwon, Tae-Oh;Lee, Jae-Kil;Park, Keon-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.4
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    • pp.420-427
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    • 1995
  • This study was carried out to investigate heterosis in photosynthetic characteristics and yield of F$_1$ hybrid rice using genetic cytoplasmic male sterile lines. Two F$_1$ hybrid rices, HR7028A/Yongmoonbyeo and IR54756A/Yongmoonbyeo, showed heterobeltiosis in dry weight and leaf area at the heading date and at the 20 day after heading. HR7028A/Yongmoonbyeo showed heterobeltiosis and IR54756A/Yongmoonbyeo showed heterosis in chlorophyll content and RuDPCase activity in flag leaf, T-sugar and starch content in stem, and $CO_2$ fixation at the 20 day after heading as well as at the heading date. HR7028A/Yongmoonbyeo showed heterobeltiosis in number of panicles and grains per panicle, and IR54756A/Yongmoonbyeo had heterobeltiosis in number of panicles per plant. As results, heterobeltiosis of HR7028A/Yongmoonbyeo in yield was 11% and that of IR54756A/Yongmoonbyeo was 4%.

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Effect of $SO_2$ on Leaf Tip Blight of Ginkgo biloba caused by Coniothyrium sp. (은행나무의 잎끝마름병에 미치는 $SO_2$ 의 영향)

  • Kang, Yun-Jie;Park, So-Hong;Lee, Du-Hyung;Bae, Gong-Young
    • Korean Journal of Environmental Agriculture
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    • v.18 no.2
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    • pp.179-184
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    • 1999
  • To examine the relationship between air pollution and occurrence of disease in plants, we investigated the alteration of physiology and biochemistry of Ginkgo biloba by inoculating with Coniothyrium sp. and fumigating with 0.1 ${\mu}l/l\;SO_{2-}$ Visual damage did not appear but photosynthesis, $CO_2$ use efficiency(CUE) and water use efficiency(WUE) were reduced when G. biloba was exposed to $SO_{2-}$for 7days (8 hours a day). When inoculated with Coniothyrium sp., the seventies of damage in G. biloba showed a threefold difference between $SO_{2-}$ treatment (SI) and $SO_{2-}$ free treatment (SFI) at day 42 from initial inoculation. Little difference was observed in sugar contents that may be used pathogens feed, among control, SFI and SI. In spite of the reduction in photosynthetic rate, sugar contents and CUE were maintained. WUE was enhanced 13% more at SI than SFI. The $CO_2$fixation boosted because of enhanced WUE, and thus sugar synthesis was not affected. In addition, sugar transport seems to be retarded for some internal alteration. Consequently, the severity of SI was more serious than that of SFI because Coniothyrium sp. easily invades into the physical texture of G. biloba weakened by $SO_2$ fumigation and because sugar was accumulated in leaves of G. biloba.

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External Fixation with Acrylic Frame in Forelimb Fracture of Korean Native Two Calves (한우송아지의 전지골절에서 아크릴릭 프레임을 이용한 외부고정)

  • Shin, Sang-Min;Lee, Dong-Bin;Lee, Hae-Beom;Kim, Min-Su;Ji, Joong-Ryong;Kim, Nam-Soo
    • Journal of Veterinary Clinics
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    • v.28 no.1
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    • pp.179-182
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    • 2011
  • Two day-old male and 1 month-old female Hanwoo calves presented to Chonbuk Animal Medical Center in Chonbuk National University. Two calves were stepped by mother cow and had right (2 day-old male) and left (1 month-old female) forelimb lameness. The male calf was diagnosed as right radius-ulnar fracture through physical and radiographic examination. The other female calf was diagnosed as left third and fourth metacarpal bone fracture by the same examinations as male calf. Acrylic frame external fixator was used to reduce the fractures. Arcrylic frame external fixator in two calves lasted for 5~6 weeks. After removing the acrylic frame external fixator, radiographic evaluation and physical examination were performed. Fractured radius-ulnar and metacarpal bones were unionized and the calves were able to stand and bear weight. In these two calves, application of acrylic frame external fixator in calf fracture was effective. Acrylic frame external fixator should be considered for the repair of radius-ulnar and metacarpal bone fracture in calf.

Preparation and Characterization of Doped $Fe_2O_3$ and GaAs Photosemiconductive Electrodes for $CO_2$ Fixation

  • Kim, Il Kwang;Lee, Seong Jae;Kim, Min Su;Jeong, Seung Il;Park, Byung Sun;Kim, Youn Geun
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.669-674
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    • 1995
  • The preparation and characterization of photosemiconductive electrodes of GaAs and of $Fe_2O_3$ doped with MgO or CaO were investigated. The doped $Fe_2O_3$ photosemiconductive electrodes were prepared from thin films sintered at temperatures from 1,100 to $1,450^{\circ}C$, and rapidly quenched in distilled water. The surfaces of the electrodes containing both corundum structure of $Fe_2O_3$ and spinel structure of $Mg_xFe_{3-x}O_4$ or $Ca_xFe_{3-x}O_4$ were analyzed by X-ray diffraction and scanning electron microscopy. The cathodic and anodic photocurrents on these electrodes indicated a critical doping amount of 5-11 wt. %. The photocurrents were enhanced when GaAs electrodes were treated with methylene violet the anodic photo-currents were temporarial enhanced and changed to the cathodic ptotocurrents after the surface was dryed.

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Services of Algae to the Environment

  • Rai, Lal-Chand;Har Darshan Kumar;Frieder Helmut Mohn;Carl Johannas Soeder
    • Journal of Microbiology and Biotechnology
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    • v.10 no.2
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    • pp.119-136
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    • 2000
  • Being autotrophic, algae occupy a trategic place in the biosphere. They produce oxygen both directly and indirectly through the chloroplasts of all green plants. The chloroplasts are believed to have originated from archaic prokaryotic algae through endosymbiosis with primitive eukaryotic cells. Phytoplankton and other algae regulate the global environment not only by releasing oxygen but also by fixing carbon dioxide. They affect water quality, help in the treatment of sewage, and produce biomass. They can be used to produce hydrogen which is a clean fuel, and biodiesel, and fix $N_2$ for use as a biofertilizer. Some other services of algae to the environment include restoration of metal damaged ecosystems, reducing the atmospheric $CO_2$ load and citigating global warming, reclamation of saline-alkaline unfertile lands, and production of dimethyl sulphide (DMS) and oxides of nitrogen (NOx) involved in the regulation of UV radiation. ozone concentration, and global warming. Algae can be valuable in understanding and resolving certain environmental issues.

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Growth, Photosynthesis and Chlorophyll Fluorescence of Chinese Cabbage in Response to High Temperature (고온 스트레스에 대한 배추의 생장과 광합성 및 엽록소형광 반응)

  • Oh, Soonja;Moon, Kyung Hwan;Son, In-Chang;Song, Eun Young;Moon, Young Eel;Koh, Seok Chan
    • Horticultural Science & Technology
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    • v.32 no.3
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    • pp.318-329
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    • 2014
  • In order to gain insight into the physiological responses of plants to high temperature stress, the effects of temperature on Chinese cabbage (Brassica campestris subsp. napus var. pekinensis cv. Detong) were investigated through analyses of photosynthesis and chlorophyll fluorescence under 3 different temperatures in the temperature gradient tunnel. Growth (leaf length and number of leaves) during the rosette stage was greater at ambient $+4^{\circ}C$ and ambient $+7^{\circ}C$ temperatures than at ambient temperature. Photosynthetic $CO_2$ fixation rates of Chinese cabbage grown under the different temperatures did not differ significantly. However, dark respiration rate was significantly higher in the cabbage that developed under ambient temperature relative to elevated temperature. Furthermore, elevated growth temperature increased transpiration rate and stomatal conductance resulting in an overall decrease of water use efficiency. The chlorophyll a fluorescence transient was also considerably affected by high temperature stress; the fluorescence yield $F_J$, $F_I$, and $F_P$ decreased considerably at ambient $+4^{\circ}C$ and ambient $+7^{\circ}C$ temperatures, with induction of $F_K$ and decrease of $F_V/F_O$. The values of RC/CS, ABS/CS, TRo/CS, and ETo/CS decreased considerably, while DIo/CS increased with increased growth temperature. The symptoms of soft-rot disease were observed in the inner part of the cabbage heads after 7, 9, and/or 10 weeks of cultivation at ambient $+4^{\circ}C$ and ambient $+7^{\circ}C$ temperatures, but not in the cabbage heads growing at ambient temperature. These results show that Chinese cabbage could be negatively affected by high temperature under a future climate change scenario. Therefore, to maintain the high productivity and quality of Chinese cabbage, it may be necessary to develop new high temperature tolerant cultivars or to markedly improve cropping systems. In addition, it would be possible to use the non-invasive fluorescence parameters $F_O$, $F_V/F_M$, and $F_V/F_O$, as well as $F_K$, $M_O$, $S_M$, RC/CS, ETo/CS, $PI_{abs}$, and $SFI_{abs}$ (which were selected in this study), to quantitatively determine the physiological status of plants in response to high temperature stresses.

Development of MRI Phantom for Assessing MR Image Quality (자기공명영상 화질 평가용 팬텀 개발에 관한 연구)

  • Ahn, Chang-Beom;Na, Dong-Gyu;Kim, Kwang-Gi;Kim, Dong-Sung;Kim, In-Su;Lee, Jung-Whee;Hong, Suk-Joo;Byun, Jae-Ho;Khang, Hyun-Soo;Jang, Gi-Won;Song, In-Chan
    • Investigative Magnetic Resonance Imaging
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    • v.10 no.2
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    • pp.89-97
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    • 2006
  • Purpose : To evaluate MR image qualities we developed a new MRI phantom with the fixation structures necessary to position it into coil firmly. Materials and methods : We designed MRI phantom for eight evaluation items such as slice thickness accuracy, high contrast spatial resolution, low contrast object detectability, geometry accuracy, slice position accuracy, image intensity uniformity, percent signal ghosting and signal to noise ratio. For the positioning of phantom at coils, the fixation structures were set up on the surface of phantom. Six different MRI units were used for test the possibility for the clinical application and their image qualities were evaluated. Results : We acquired appropriate MR image qualities enough for the evaluation on all used MR units and confirmed that their evaluations were within reliable values compared to real ones for some items. The positioning of our phantom into head coils with fixation structures worked well for proper imaging. Conclusion : We found that our prototype of MRI phantom had the possibility of clinical application for MR image quality assessment.

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Property enhancement of lightweight aggregate by carbonation processing (인공경량골재의 탄산화 반응에 따른 물성향상에 관한 연구)

  • Park, Junyoung;Kim, Yootaek;Choi, Yunjae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.5
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    • pp.254-259
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    • 2012
  • The mechanical property enhancement was studied using fly ash produced from fluidized bed type boiler in power plant, which contains a lot of Ca component being used to carbonate for $CO_2$ fixation in the lightweight aggregates made of cement and some portion of fly ash as a cement substitution under the supercritical condition. Specimens having various fly ash substitution rates and curing periods were carbonated under the supercritical condition at $40^{\circ}C$. The weight change rate, carbonation rate by TG/DTA analysis, 1% Phenolphthalein test, specific gravity and mechanical compression strength test were performed to observe the mechanical property enhancement of the cemented materials after carbonation under the supercritical condition and to make sure those could be classified as lightweight aggregates having specific gravity under 2.0.