• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.4
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• pp.288-292
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• 1998

In this paper, we fabricated $SnO_2$ composite ceramics doped with 0~20mol% $SnO_2$ of bulk type to investigate the CO and $H_2$ gas sensitivity in various composition, temperature, and concentration of CO and $H_2$ gas. At the temperature range from $100^{\circ}C\sim425^{\circ}C$, the measured 1000ppm and 250ppm CO gas sensitivities of $SiO_2-SnO_2$composite ceramics were about 1.0~7.6 and 1.0~5.6, respectively. These values were about 1.0~1.5 times larger than pure $SnO_2$. The maximum 1000ppm CO gas sensitivity of $SiO_2-SnO_2$composites were measured around $325^{\circ}C$. At the temperature range from $270^{\circ}C\sim380^{\circ}C$, the 1000ppm and 500ppm $H_2$gas sensitivities of $SiO_2-SnO_2$ composites were about 2.9~21.2 and 2.1~11.3, respectively. Also the maximum 1000, 500 ppm $H_2$ gas sensitivities of samples were measured around.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.9
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• pp.1163-1169
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• 2014

As a preliminary study for detection techniques of $CO_2$ gas bubble plumes, we have conducted a comparative experiment on artificially generated $CO_2$ gas bubbles plume by using multibeam echosounder (MBES), single beam echosounder (SBES), and sub-bottom profiler (SBP). The rising speed of artificial gas bubbles is higher than references because of compulsory release of compressed gas in the tank. Compared to single beam acoustic equipments, the MBES detects wide swath coverage. It provides exact determination of the source position and 3D information on the gas bubble plumes in the water column. Therefore, it is shown that MBES can distinctly detect gas bubble plumes compared to single beam acoustic equipments. We can establish more effective complementary detection technique by simultaneous operation of MBES and SBES. Consequently, it contributes to improve qualitative and quantitative detection techniques by understanding the acoustic characteristics of the specific gas bubbles.

• International Journal of Air-Conditioning and Refrigeration
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• v.15 no.1
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• pp.34-45
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• 2007

In order to reduce the compression power and to use the overall energy contained in LNG effectively, a combined cycle is devised and simulated. The combined cycle is composed of two cycles; one is an open cycle of liquid/solid carbon dioxide production cycle utilizing LNG cold energy in $CO_2$ condenser and the other is a closed cycle gas turbine which supplies power to the $CO_2$ cycle, utilizes LNG cold energy for lowering the compressor inlet temperature, and uses the heating value of LNG at the burner. The power consumed for the $CO_2$ cycle is investigated in terms of a solid $CO_2$ production ratio. The present study shows that much reduction in both $CO_2$ compression power (only 35% of the power used in conventional dry ice production cycle) and $CO_2$ condenser pressure could be achieved by utilizing LNG cold energy and that high cycle efficiency (55.3% at maximum power condition) in the gas turbine could be accomplished with the adoption of compressor inlet cooling and regenerator. Exergy analysis shows that irreversibility in the combined cycle increases linearly as a solid $CO_2$ production ratio increases and most of the irreversibility occurs in the condenser and the heat exchanger for compressor inlet cooling. Hence, incoming LNG cold energy to the above components should be used more effectively.

• Journal of the Korean Institute of Telematics and Electronics
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• v.23 no.6
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• pp.766-772
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• 1986

SnO2/Pt CO gas sensors operating at relatively low temperature were fabricated, and their performance characteristics were measured. When the mixing weight ratio of SnO2/Pt was 99.5/0.5, a good sensitivity to CO gas was obtained. And the experimental results were in consistent with the gas sensing model. The optimum operating, temperature range of the fabricated devices was 50-80\ulcorner and the response time was 15 sec. at 80\ulcorner in 1000 ppm CO ambient. The humidity dependence of sensitibity to CO gas could be reduced by adding hydrophokbic silica to the mixture of SnO2 and Pt. For the practical application of the fabricated devices, a CO gas alarming system has been developed.

• Korean Journal of Materials Research
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• v.20 no.8
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• pp.408-411
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• 2010

Indium doped $SnO_2$ thick films for gas sensors were fabricated by a screen printing method on alumina substrates. The effects of indium concentration on the structural and morphological properties of the $SnO_2$ were investigated by X-ray diffraction and Scanning Electron Microscope. The structural properties of the $SnO_2$:In by X-ray diffraction showed a (110) dominant $SnO_2$ peak. The size of $SnO_2$ particles ranged from 0.05 to $0.1\;{\mu}m$, and $SnO_2$ particles were found to contain many pores, according to the SEM analysis. The thickness of the indium-doped $SnO_2$ thick films for gas sensors was about $20\;{\mu}m$, as confirmed by cross sectional SEM image. Sensitivity of the $SnO_2$:In gas sensor to 2000 ppm of $CO_2$ gas and 50 ppm of H2S gas was investigated for various indium concentrations. The highest sensitivity to $CO_2$ gas and H2S gas of the indium-doped $SnO_2$ thick films was observed at the 8 wt% and 4 wt% indium concentration, respectively. The good sensing performances of indium-doped $SnO_2$ gas sensors to $CO_2$ gas were attributed to the increase of oxygen vacancies and surface area in the $SnO_2$:In. The $SnO_2$:In gas sensors showed good selectivity to $CO_2$ gas.

• Corrosion Science and Technology
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• v.7 no.2
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• pp.69-76
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• 2008

Common methods for large scale hydrogen production, such as steam reforming and coal gasification, also involve production of carbonaceous gases. It is therefore necessary to handle process gas streams involving various mixtures of hydrocarbons, $H_2$, $H_2O$, CO and $CO_2$ at moderate to high temperatures. These gases pose a variety of corrosion threats to the alloys used in plant construction. Carbon is a particularly aggressive corrodent, leading to carburisation and, at high carbon activities, to metal dusting. The behaviour of commercial heat resisting alloys 602CA and 800, together with that of 304 stainless steel, was studied during thermal cycling in $CO/CO_2$ at $650-750^{\circ}C$, and also in $CO/H_2/H_2O$ at $680^{\circ}C$. Thermal cycling caused repeated scale separation, which accelerated chromium depletion from the alloy subsurface regions. The $CO/H_2/H_2O$ gas, with $a_C=2.9$ and $p(O_2)=5\times10^{-23}$ atm, caused relatively rapid metal dusting, accompanied by some internal carburisation. In contrast, the $CO/CO_2$ gas, with $a_C=7$ and $p(O_2)=10^{-23}-10^{-24}$ atm caused internal precipitation in all three alloys, but no dusting. Inward diffusion of oxygen led to in situ oxidation of internal carbides. The very different reaction morphologies produced by the two gas mixtures are discussed in terms of competing gas-alloy reaction steps.

• Journal of Climate Change Research
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• v.5 no.3
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• pp.209-218
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• 2014

In this study, the researchers have developed the greenhouse gas emission coefficients targeted at sewage sludge incineration plants that treat sewage sludge by incineration. Among the gases emitted from the sewage sludge incineration plants, the greenhouse gases showed concentrations of 6.84% for $CO_2$, 4.51 ppm for $CH_4$, and 86.34 ppm for $N_2O$; calculated into greenhouse gas emission coefficients, these gave $276.06kg\;CO_2/ton$, $0.0066kg\;CH_4/ton$, and $0.35kg\;N_2O/ton$. As the result of calculating the greenhouse gas emission quantity in sewage sludge incineration plants using the greenhouse gas emission coefficients, the gross greenhouse gas emission was $84.63ton\;CO_2\;eq./day$, and the net emission was $23.90ton\;CO_2\;eq./day$; this was $37.52ton\;CO_2\;eq./day$ less than the net greenhouse gas emission that was calculated using the standard values of IPCC, which was $61.42ton\;CO_2\;eq./day$. This difference is probably because unlike the standard values of IPCC, the greenhouse gas emission coefficients of this study reflected the special properties of subject facilities. Thus, it is thought that emission coefficient research on the facilities that deviated from the standard values of IPCC should continue to achieve the development of national greenhouse gas coefficient that reflects the special properties of Korea.

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.253-258
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• 2010

In the field of the $CO_2$ absorption process using aqueous ammonia, the effects of regeneration pressure and temperature on $CO_2$ absorption performances of the aqueous ammonia were investigated. The absorbents were prepared by dissolving ammonium carbonate solid in water to grant the resulted solution 0.5 $CO_2$ loading ($mol\;CO_2/mol\;NH_3$) and various ammonia concentration (14, 20, 26 and 32 wt%). As-prepared absorbents were regenerated at high pressure and temperature (over $120^{\circ}C$ and 6 bar) before the absorption test. The absorption test was carried out by injecting the simulated gas that contains 12 vol% of $CO_2$ into a bubbling reactor. The introduction of 26 wt% of the ammonia concentration for $CO_2$ absorption test resulted in the higher absorption capacities than other experimental conditions. In particular, when the absorbents with 26 wt% of the ammonia were regenerated at $150^{\circ}C$ and 14 bar, the highest absorption capacity, $45ml\;CO_2/g$, was obtained. According to the analysis of absorbents using acid-base titration, the ammonia loss during the regeneration of the absorbents with a fixed ammonia concentration decreased as the regeneration pressure increased, while it increased as the regeneration temperature increased. In the condition of fixed regeneration pressure and temperature, as expected, the ammonia loss increased as the ammonia concentration increased. The measured $CO_2$ loadings and ammonia concentrations of absorbents were compared to the values calculated by Electrolyte NRTL model in Aspen Plus.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.2
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• pp.114-121
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• 2014

The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt catalyst was prepared Co/alumina, Co/silica and Co/titania by the incipient wetness impregnation of the nitrates of cobalt with supports. Co-based catalysts was calcined at $400^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has carried out under $450^{\circ}C$, FT reaction of the catalyst has carried out at GHSV of 4,000 under $200^{\circ}C$ and 20atm. From test results, the order of increasing activity for the catalyst was Co/alumina > Co/silica > Co/titania. When the content of Co metal such as 5, 12, 20 and 30wt% was changed, an CO conversion increased as the content of Co metal increased. The activity of catalyst has obtained the best value at 12wt% Co content.

• Journal of Sensor Science and Technology
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• v.25 no.2
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• pp.124-130
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• 2016

NDIR $CO_2$ gas sensor was built with ASIC implemented thermopile sensor which included temperature sensor and unique elliptical waveguide structures in this paper. The temperature dependency of dual infrared sensor module ($CO_2$ and reference IR sensors) has been characterized and its output voltage characteristics according to the temperature and gas concentration were proposed for the first time. NDIR $CO_2$ gas and reference IR sensors showed linear output voltages according to the variation of ambient temperatures from 243 K to 333 K and their slopes were 14.2 mV/K and 8.8 mV/K, respectively. The output voltages of temperature sensor also presented a linear dependency according to the ambient temperature and could be described with V(T)=-3.191+0.0148T(V). The output voltage ratio between $CO_2$ and reference IR sensors revealed irrelevant to the changes of ambient temperatures and gave a constant value around 1.6255 with standard deviation 0.008 at 0 ppm. The output voltage of $CO_2$ gas sensor at zero ppm $CO_2$ gas consisted of two components; one is caused by the HPB (half pass-band) of IR filter and the other is attributed to the part of $CO_2$ absorption wavelength. The characteristics of output voltages of $CO_2$ gas sensor could be accurately modeled with three parameters which are dependent upon the ambient temperatures and represented small average error less than 1.5% with 5% standard deviation.