• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.690-695
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• 2012

Gas hydrate is an inclusion compound consisting of water and low molecular weight gases, which are incorporated into the lattice structure of water. Owing to its promising aspect to application technologies, gas hydrate has been widely studied recently, especially $CO_2$ hydrate for the CCS (Carbon Capture and Storage) issue. The key point of $CO_2$ hydrate technology for the CCS is how to produce gas hydrate in an efficient and economic way. In this study, we have tried to study the characteristic of gas hydrate formation using micro-sized ice through an ultrasonic nozzle which generate 2.4 MHz frequency wave. $CO_2$ as a carrier gas brings micro-sized mist into low-temperature reactor, where the mist and carrier gas forms $CO_2$ hydrate under $-55^{\circ}C$ and atmospheric pressure condition and some part of the mist also remains unreacted micro-sized ice. Formed gas hydrate was average 10.7 of diameter at average. The starting ice particle was set to constant pressure to form $CO_2$ hydrate and the consumed amount of $CO_2$ gas was simultaneously measured to calculate the conversion of ice into gas hydrate. Results showed that the gas hydrate formation was highly suitable because of its extremely high gas-solid contact area, and the formation rate was also very high. Self-preservation effect of $CO_2$ hydrate was confirmed by the measurement of $CO_2$ hydrate powder at normal and at pressed state, which resulted that this kind of gas storage and transport could be feasible using $CO_2$ hydrate formation.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.1
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• pp.30-36
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• 2010

The heat flowrate and pressure drop of $CO_2$ in a multi-tube-in-tube helical coil type gas cooler were investigated experimentally. The mass flowrate of $CO_2$ and coolant were varied from 0.06 to 0.075 [kg/s], respectively and the cooling pressure of gas cooler were from 8 to 10 [MPa]. The heat flowrate of $CO_2$ in the test section is increased with the increase in mass flowrate of coolant, the cooling pressure and mass flowrate of $CO_2$. The pressure drop of $CO_2$ is decreased with the decrease in mass flowrate of coolant and $CO_2$, but decreased with increase in cooling pressure of $CO_2$. The heat flowrate of $CO_2$ in the multi-tube-in-tube helical coil type gas cooler is greatly higher than that of $CO_2$ in the double pipe type gas cooler, while the pressure drop of $CO_2$ in the multi-tube-in-tube helical coil type gas cooler is greatly lower than that of $CO_2$ in the double pipe type gas cooler. Therefore, in case of the application of $CO_2$ at the multi-tube-in-tube helical coil type gas cooler, it is expected to carry out the high-efficiency, high-performance and compactness of gas cooler.

• Journal of Welding and Joining
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• v.33 no.4
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• pp.17-23
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• 2015

Laser-gas metal arc hybrid welding has been considered as an alternative process of gas metal arc welding for offshore pipe laying. Fiber delivered high power lasers which enable deep penetration welding were recently developed but high power welding characteristics were not fully understood yet. In this study, the influence of shielding gas composition on welding phenomena in high power laser welding was investigated. Bead shapes, melt ejection and dropping were observed after autogenous laser welding with 100% Ar, Ar-20% $CO_2$, Ar-50% $CO_2$, and 100% $CO_2$ shielding gas. Process parameter window was widest with Ar-50% $CO_2$ shielding gas and the penetration was deepest with 100% $CO_2$ shielding gas. The melt dropping was not observed when Ar-50% $CO_2$ or 100% $CO_2$ shielding gas was supplied.

• Journal of the Korean Institute of Gas
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• v.14 no.4
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• pp.51-55
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• 2010

The global activities to reduce the $CO_2$ emission as a greenhouse gas have been various efforts. Under this circumstance, small and medium sized gas field containing $CO_2$ to develop as LNG is not economic feasibility. Particularly, for the separation of $CO_2$ in gas field, separation facilities should be installed to add. This is and increase in plant construction cost and separated $CO_2$ emission into the atmosphere is not the result of greenhouse gas reduction. When the uneconomic gas field apply the KOGAS DME process, the gas field containing $CO_2$ can be increase economic feasibility because of natural gas and $CO_2$ can be use to resource gas. The Tri-reformer produced syngas as H2 and CO in KOGAS DME process and the resource gases are natural gas, steam, oxygen and $CO_2$. The $CO_2$ is used as raw material gases from recover $CO_2$ in DME process. In this study, we investigated range of application of $CO_2$ in gas field.

• Journal of Environmental Science International
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• v.17 no.6
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• pp.689-698
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• 2008

Numerical study is conducted to predict effects of radiative heat loss and fuel composition in synthetic gas diffusion flame diluted with $CO_2$. The existing reaction models in synthetic gas flames diluted with $CO_2$ are evaluated. Numerical simulations with and without gas radiation, based on an optical thin model, are also performed to concrete impacts on effects of radiative heat loss in flame characteristics. Importantly contributing reaction steps to heat release rate are compared for synthetic gas flames with and without $CO_2$ dilution. It is also addressed that the composition of synthetic gas mixtures and their radiative heat losses through the addition of $CO_2$ modify the reaction pathways of oxidation diluted with $CO_2$.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.1
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• pp.12-19
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• 2013

A gasification process with pre-combustion $CO_2$ capture process, which converts coal into environment-friendly synthetic gas, might be promising option for sustainable energy conversion. In the coal gasification for power generation, coal is converted into $H_2$, CO and $CO_2$. To reduce the cost of $CO_2$ capture and to maximize hydrogen production, the removal of CO and the additional production of hydrogen might be needed. In this study, a 2l/min water gas shift system for a coal gasifier has been studied. To control the concentration of major components such as $H_2$, CO, and $CO_2$, MFCs were used in experimental apparatus. The gas concentration in these experiments was equal with syngas concentration from dry coal gasifiers ($H_2$: 25-35, CO: 60-65, $CO_2$: 5-15 vol%). The operation conditions of the WGS system were $200-400^{\circ}C$, 1-10bar. Steam/Carbon ratios were between 2.0 and 5.0. The commercial catalysts were used in the high temperature shift reactor and the low temperature shift reactor. As steam/carbon ratio increased, the conversion (1-$CO_{out}/CO_{in}$) increased from 93% to 97% at the condition of CO: 65, $H_2$: 30, $CO_2$: 5%. However the conversion decreased with increasing of gas flow and temperature. The gas concentration from LTS was $H_2$: 54.7-60.0, $CO_2$: 38.8-44.9, CO: 0.3-1%.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.90-95
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• 2003

Chemical management of annulus gas system is carried out for the purpose of ensuring the safety and reliability of the system via securing the integrity of the system, detecting the D$_2$O in-leakage of coolant and/or moderator, and reducing the radiation dose. Since the quality of CO_2$ gas, which is used as a filling gas for annulus gas system at CANDU plants, has a propound effect on the integrity of the system material and the radiation dose, CO_2$ gas of high quality is needed. If the quality of CO_2$ gas does not meet the specification, it may give rise to undesirable effect not only on the annulus gas system, but also on the environment due to the production of radioactive nuclei. Therefore, it is very important to check the impurities of CO_2$ gas. Based on this background, the inventories of C-14 and Ar-41 in CO_2$ gas that is supplied as annulus gas were estimated using the data on concentrations of the impurities of $CO_2$ such as C, N_2$ and Ar. The results of this study is expect to give useful information on optimization of CO_2$ impurities maintenance and management of gaseous radioactive wastes produced at CANDU plants.

• Membrane Journal
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• v.23 no.5
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• pp.384-391
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• 2013

We prepared composite membrane which was made with polysulfone supported hollow fiber membrane coated with Hyflon AD to eliminate $CO_2$ gas from mixed-gases which were generated in DME manufacturing processes. The performance of module about simulated flaring gas was measured by using manufactured composite membrane. 1-stage evaluation result shows $CO_2$ concentration was below 3% at 1.2 MPa and at Stage cut 0.24 above. In addition $CO_2$ removal rate and $CH_4$ recovery rate was 80% respectively at the same condition. 2-stage evaluation result shows, when the $CO_2$ concentration of product gas was fixed at 5%, recycled $CO_2$ at stage cut 0.074 had the same concentration as the feed gas and the recovery rate of $CH_4$ was 99% at the moment.

• Transactions of the Korean hydrogen and new energy society
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• v.19 no.5
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• pp.439-444
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• 2008

The heat capacity and pressure drop of $CO_2$ and coolant in a multi-tube type gas cooler were investigated experimentally. The main components of the refrigerant loop are a receiver, a $CO_2$ compressor, a mass flow meter, an evaporator and a multi-tube type gas cooler as a test section. The mass flowrate of $CO_2$ and coolant were varied from 0.06 to 0.075 [kg/s], respectively and the cooling pressure of gas cooler were from 8 to 10 [MPa]. The heat capacity of $CO_2$ in the test section is increased with the increment in mass flowrate of coolant, the cooling pressure and mass flowrate of $CO_2$. The pressure drop of $CO_2$ is decreased with the decrease in mass flowrate of coolant and $CO_2$, but decreased with increase in cooling pressure of $CO_2$. The heat capacity of $CO_2$ per unit heat transfer area of gas cooler is greatly high. Therefore, in case of the application of $CO_2$ at the multi-tube type gas cooler, it is expected to carry out the high-efficiency, high-performance and compactness of gas cooler.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.116-120
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• 2013

Characteristics of photocatalytic CO removal process conducting CO conversion by using Pt loaded $TiO_2$ photocatalyst were investigated in a photocatalytic tubular reactor. Effects of Pt loading method onto $TiO_2$, linear velocity of gas stream containing CO gas, CO concentration and moisture content in the gas stream on the conversion of CO to $CO_2$ were examined. It was found that the CO gas could be removed almost 100% by using photocatalytic tubular reactor internally coated with Pt/$TiO_2$ photocatalyst under UV irradiation, when the linear velocity of gas stream was in the range of 0.01~0.25 m/s and CO concentration in the gas stream was ranged from 20 to 100 ppm and the relative humidity of the gas stream was in the range of 20~40%. The conversion of CO gas decreased gradually with increasing linear velocity of gas stream and CO concentration in the gas stream. The moisture in the gas stream could promote the removal of CO gas by means of the generation of OHradicals.