• Title/Summary/Keyword: $CO_2$ utilization

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The Production of Metal-biochar through Co-pyrolysis of Lignin and Red Mud and Utilization for the Removal of Contaminants in the Water (리그닌과 적니의 공동 열분해를 통한 금속-바이오차 생산 및 수중 오염물질 제거를 위한 활용)

  • Kim Eunji;Kim Naeun;Park Juyeong;Lee Heuiyun;Yoon Kwangsuk
    • Journal of Soil and Groundwater Environment
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    • v.29 no.2
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    • pp.1-10
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    • 2024
  • With industrial development, the inevitable increase in both organic and inorganic waste necessitates the exploration of waste treatment and utilization methods. This study focuses on co-pyrolyzing lignin and red mud to generate metalbiochar, aiming to demonstrate their potential as effective adsorbents for water pollutant removal. Thermogravimetric analysis revealed mass loss of lignin below 660℃, with additional mass loss occurring (>660℃) due to the phase change of metals (i.e., Fe) in red mud. Characterization of the metal-biochar indicated porous structure embedded with zero-valent iron/magnetite and specific functional groups. The adsorption experiments with 2,4-dichlorophenol and Cd(II) revealed the removal efficiency of the two pollutants reached its maximum at the initial pH of 2.8. These findings suggest that copyrolysis of lignin and red mud can transform waste into valuable materials, serving as effective adsorbents for diverse water pollutants.

Eco-Friendly Synthesis of Rod-Like Potassium Hexatitanate Particles (친환경 공정에 의한 봉상형 육티탄산칼륨 입자의 제조)

  • Lee, Chongmin;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.13 no.4
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    • pp.183-189
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    • 2017
  • Potassium hexatitanate ($K_2Ti_6O_{13}$) with high thermal insulating capacity, good mechanical properties, and excellent chemical stability are promising functional materials in the field of reinforcing material, heat insulating paints and automotive brake linings. In this study, we successfully synthesized rod-shaped potassium hexatitanate ($K_2Ti_6O_{13}$) by aerosol spray drying and post heat treatment as an eco-friendly process. The $KHCO_3-TiO_2$ porous particles were firstly synthesized from a colloidal mixture of $K_2CO_3$ and $TiO_2$ via aerosol spray drying. Size of $KHCO_3-TiO_2$ porous particles was ranged from $1{\mu}m$ to $5{\mu}m$. The porous particles were then heated to fabricate rod-type $K_2Ti_6O_{13}$. The length and width of rod-type composites were affected by temperature and heating time. The length and width of $K_2Ti_6O_{13}$ were increased by 830 nm and 500 nm, respectively, as the reaction temperature and time increased.

Fabrication of Cr$_2$O$_3$powder from waste MgO-Cr refractory

  • Lee, Hoon-Ha;Sohn, Jin-Gun;Lee, Jae-Young;Kim, Dae-Young
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.357-361
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    • 2001
  • The possibility of producing Cr$_2$O$_3$powder from waste magnesia-chromium refractory was investigated by sulfuric acid reaction, alkali fusion, water leaching & purification and heat treatment. The effects of temperature, the amount of NaOH added and the flow rate of air on chromium extraction efficiency in an alkali fusion step were investigated. The fusion product was leached with methanol to solve free-NaOH, and then leached with water to produce a Na$_2$CrO$_4$solution. The purity of chrome(Ⅵ) oxides, prepared both from monochromate with an impurity content and monochromate purified with $CO_2$were also examined. The purified monochromate solution was reduced from Cr(Ⅵ) to Cr(III) with NaHSO$_3$solution. The reduced solution was neutralized with NaOH to produce Cr(OH)$_3$. Water washing was treated to eliminate Na$_2$SO$_4$from neutralized Cr(OH)$_3$slurry. The washed Cr(OH)$_3$was dried and thermally treated to produce Cr$_2$O$_3$powder. The properties like lightness and hue of Cr$_2$O$_3$fabricated in this study were L=47.47, a=-14.40 and b=17.21.

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The trend of Korean Medicine utilization in 2008-2013 (비급여를 포함한 한의 외래의료이용의 최근(2008-2013) 변화추이)

  • Kim, Dongsu;Lim, Byungmook
    • Journal of Society of Preventive Korean Medicine
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    • v.21 no.1
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    • pp.57-66
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    • 2017
  • Objectives : This study aimed to analyze the structure and the trend of utilization and expenditure for Korean Medicine (KM) in Korea. Methods : Data were drawn from the 2008-2013 annual Korea Health Panel (Version 1.2.2), a national representative sample. We combined the data of household members with the data of outpatient KM service use. The volume of KM use was estimated based on the frequency of use and co-payment. Results : The KM utilization rate slightly increased in recent years, and it is presumed to be resulted from the increase of elderly population. Most KM outpatient visits were being concentrated in treating musculoskeletal diseases, and the procedures used frequently were acupuncture, moxibustion, cupping, and physical therapy. The imbalance of KM use between lower income group and higher income group was deepening. Conclusions : To expand restricted disease areas KM covered, the more herbal prescriptions should be insured and the insured form of herbal medicines need to be diversified.

Brief Review on Carbon Dioxide Capture and Utilization Technology (CCU 기술 국내외 연구동향)

  • Kim, Hak Min;Nah, In Wook
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.589-595
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    • 2019
  • The policies and researches for the reduction of greenhouses gases have been performed according to"Paris Agreement". Because South Korea is the $6^{th}$ biggest greenhouses gas emitter in the world, the Korea government has prepared the strategies for the reduction of greenhouse gases. The development of CCUS (Carbon Capture Utilization and Storage) technology is necessary to reduce greenhouse gases. Therefore, the CCUS has been studied by many contries in the world. In this work, the trends of CCUS technologies R&D has been shortly investigated.

Studies on storing Chest - nut(Castanea crenata var. dulcis Nakai) Sealing with Polyethylene Film (밤의 Polyethylene Film 밀봉 저장 효과)

  • Lee, B.Y.;Yoon, I.H.;Kim, Y.B.;Han, P.J.;Lee, Ch.M.
    • Korean Journal of Food Science and Technology
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    • v.17 no.5
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    • pp.331-335
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    • 1985
  • Series of study were conducted to develop a method for longterm storage of chest-nut with preserving it's taste and freshness. Experiments were carried out with Korean chest-nut (Castanea crenata var. Okkwang) sealed in polyethylene (P.E) film stored under the ambient and low temperature. Summarized results are as follow: After the harvest, $CO_2$ produced by chest-nut at the early storage was increased with temperature increase. Q10 mg/kg/day, the temperature index of $CO_2$production, by chest-nut ranged 2.4-2.7. It was available to store chest-nut in good condition with 8-15% total loss upto the following may at the ambient temperature sealed in 0.03 mm P.E. film, and upto the following july at the low temperature if sealed in 0.03 or 0.05 mm P.E. film. Throughout the period from one month after the innitiation upto the end of the storage, the rate of $CO_2$and $O_2$ was maintained near the optimum condition for the CA storage of chest-nut. The taste of chest-nut was improved during the storage due to increased reducing-sugar and decreased wate soluble tannin. However, the taste become bitter and unacceptable from the early stage of the storage when used the thicker P.E. film (than above mentioned) for the sealing.

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A Study on the Reaction Optimization for the Utilization of CO2 and CH4 from Bio-gas (바이오가스에서 CO2/CH4 활용에 관한 반응최적화 연구)

  • KHO, DONGHYUN;CHO, WOOKSANG;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.554-561
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    • 2016
  • Depending on the Bio-gas sources, main component gases of $CH_4$ and $CO_2$ are shown to be variously present in amounts. For the anaerobic digester, The concentration of $CH_4$ and $CO_2$ in the gases are 60~70 and 30~35 vol%. For the landfill gas, $CH_4$ and $CO_2$ are 40~60 and 40~60 vol%. For the food wastes, $CH_4$ and $CO_2$ are 60~80 and 20~40 vol%, respectively. In this study, maximum conversion rates of $CO_2$ were obtained from the variety of concentrations of $CH_4$ and $CO_2$ by the catalysts of reforming reactions. Moreover, in order to get maximum producing amount of synthetic gas, experimental studies were performed to optimize the reaction variables. On the basis of $CH_4$, 243 ml, R [$CH_4/(O2+CO_2)$] value were varied from 0.8 to 1.35, in the study of $CH_4$ and $CO_2$ reforming reactions. It was shown that the optimal results were obtained for 1.35 of R value. And also, at $850^{\circ}C$ and 1 atm, the production rate of synthetic gas was 90% and the conversion rates of $CH_4$ and $CO_2$ were higher than 99% and 90%, respectively.

Biogas Production and Utilization Technologies from Organic waste (유기성폐기물을 이용한 바이오가스 생산 및 활용기술)

  • Heo, Nam-Hyo;Lee, Seung-Heon;Kim, Byeong-Ki
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.202-205
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    • 2008
  • Anaerobic digestion(AD) is the most promising method of treating and recycling of different organic wastes, such as OFMSW, household wastes, animal manure, agro-industrial wastes, industrial organic wastes and sewage sludge. During AD, i.e. degradation in the absence of oxygen, organic material is decomposed by anaerobes forming degestates such as an excellent fertilizer and biogas, a mixture of carbon dioxide and methane. AD has been one of the leading technologies that can make a large contribution to producing renewable energy and to reducing $CO_2$ and other GHG emission, it is becoming a key method for both waste treatment and recovery of a renewable fuel and other valuable co-products. A classification of the basic AD technologies for the production of biogas can be made according to the dry matter of biowaste and digestion temperature, which divide the AD process in wet and dry, mesophilic and thermophilic. The biogas produced from AD plant can be utilized as an alternative energy source, for lighting and cooking in case of small-scale, for CHP and vehicle fuel or fuel in industrials in case of large-scale. This paper provides an overview of the status of biogas production and utilization technologies.

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Experiment Investigation on Fluid Transportation Performance of Propellant Acquisition Vanes in Microgravity Environment

  • Zhuang, Baotang;Li, Yong;Luo, Xianwu;Pan, Halin;Ji, Jingjing
    • International Journal of Fluid Machinery and Systems
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    • v.7 no.1
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    • pp.1-6
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    • 2014
  • The propellant acquisition vane (PAV) is a key part of a vane type surface tension propellant management device (PMD), which can manage the propellant effectively. In the present paper, the fluid transportation behaviors for five PAVs with different sections were investigated by using microgravity drop tower test. Further, numerical simulation for the propellant flow in a PMD under microgravity condition was also carried out based on VOF model, and showed the similar flow pattern for PAVs to the experiment. It is noted that the section geometry of PAVs is one of the main factors affecting the fluid transportation behavior of PMD. PAVs with bottom length ratio of 5/6 and 1/2 have larger propellant transportation velocity. Based on the experiments, there were two stages during the process of propellant transportation under microgravity environment: liquid relocation and steady transportation stage. It is also recognized that there is a linear correlation between liquid transportation velocity and relative time's square root. Those results can not only provide a guideline for optimization of new vane type PMDs, but also are helpful for fluid control applications in space environment.

Limitation of Light Energy Utilization in the Fallen Stems of Opunttia bigelovii without CO2 and Water Absorption (지상에 떨어진 Opunttia bigelovii 선인장의 줄기에 있어서 광에너지의 이용한계)

  • Chang, Nam-Kee
    • The Korean Journal of Ecology
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    • v.3 no.1_2
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    • pp.31-39
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    • 1980
  • Light energy utilization was investigated in the fallen stems of Opuntia bigelovii. Threshold time for the decreasing steady state of acid accumulation in the palisade tissue of Opuntia stems was 4 hours under 1,000 $\mu Em^{-2}sec^{-1}$ of PAR at $75^{\circ}C$, while stomatal closing throughout the stem stage was illustrated by 256.0-310.4 sec $\textrm{cm}^{-1}$ of stem diffusive resistance and 0.20g $day^{-1}$ of the water loss rate as cuticular resistance. The acid loss rate in the stems per 4 hours was related to tissue water contents and a few acid loss rate could be recognized at the water content rage of 56.4%~46.8%. Endogenous oscillation of tissue acidity due to the diurnal rhythmic phenomena depended on the tissue water content was found in the Opuntia stems with stomatal closing during the normal day/night cycle. The survival rate of 1 segment to survive 2 years old cactus was 22.7% in desert environments. Such a compensation photosynthesis which utilizes light energy and maintains the reassimilation of endogenous gases was interpreted as conceptual model.

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