• Title/Summary/Keyword: $CO_2$ thermal system

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Experimental Study of Transition to Secondary Acoustic Instability at Downward-Propagating Premixed Flame in a Tube (튜브 내 하향 전파하는 예혼합 화염의 이차 열음향 불안정성 천이에 관한 실험적 연구)

  • Park, Juwon;Kim, Daehae;Park, Dae Geun;Yoon, Sung Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.7
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    • pp.915-921
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    • 2020
  • Thermoacoustic instability caused by air conditioning in a combustion chamber has emerged as a problem that must be solved to establish a stable combustion system. Thermoacoustic instability is largely divided into primary and secondary acoustic instability. In this study, an experimental study of the effects of heat losses was conducted to investigate the mechanism of secondary acoustic instability. To generate the secondary acoustic instability, a quarter-wavelength resonator with one open end and one closed end was used, and the inside of the resonator was filled with premixed gases. Subsequently, secondary acoustic instability with downward-propagating flames could be realized via thermal expansion on the burnt side. To control heat losses qualitatively, an additional co-axial tube was installed in the resonator with air or nitrogen supply. Therefore, additional diffusion flames can be formed at the top of the resonator depending on the injection of the oxidizer into the co-axial tube when rich premixed flames are used. Consequently, secondary acoustic instability could not be achieved by increasing heat losses to the ambient when the additional diffusion flame was not formed, and the opposite result was obtained with the additional diffusion flame.

Synthesis and Biocompatibility Study of Hydrogel for Patch Sensor in Non-invasive Glucose Monitoring System (무채혈 혈당 측정시스템의 Patch Sensor용 수화젤의 합성 및 생체적합성에 관한 연구)

  • Kwon, Jeong-Woo;Kim, Dong-Chul;Yoon, In-Joon;Jeong, Yoon-Na;Jeong, Ji-Young;Hwang, In-Sik
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.111-117
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    • 2009
  • This study aims to verify for humans the suitability of the enzyme-fixed hydrogel used for the patch sensor of the blood sugar testing system without blood sampling, which utilizes reverse iontophoresis. Using acrylate monomers, hydrogel was synthesized to which a certain unit of enzyme is fixed. In order to analyze the material property of the synthesized hydrogel, a structural analysis was performed using FT-IR spectroscopy, while the DSC was used to verify the thermal stability. In addition, with the UV-Vis spectrophotometer, it was verified that the degree of active enzyme is at least 50% greater than the standard product. The SEM was used to verify secure fixation of the enzyme onto the surface. As a result, it was observed that the enzyme is successfully fixed to the surface. Since the hydrogel makes direct contact with a patient's skin, it is essential to evaluate the toxicity when making direct contact with the skin. For that purpose, various sets of tests were undertaken according to the ISO 10993-cytotoxicity, intracutaneous reactivity, skin irritation test and maximization sensitization. Consequently, it was successfully verified that the enzyme-fixed hydrogel have bioavailability.

Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2016 (설비공학 분야의 최근 연구 동향 : 2016년 학회지 논문에 대한 종합적 고찰)

  • Lee, Dae-Young;Kim, Sa Ryang;Kim, Hyun-Jung;Kim, Dong-Seon;Park, Jun-Seok;Ihm, Pyeong Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.6
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    • pp.327-340
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    • 2017
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2016. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering have been reviewed as groups of flow, heat and mass transfer, the reduction of pollutant exhaust gas, cooling and heating, the renewable energy system and the flow around buildings. CFD schemes were used more for all research areas. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the results of the long-term performance variation of the plate-type enthalpy exchange element made of paper, design optimization of an extruded-type cooling structure for reducing the weight of LED street lights, and hot plate welding of thermoplastic elastomer packing. In the area of pool boiling and condensing, the heat transfer characteristics of a finned-tube heat exchanger in a PCM (phase change material) thermal energy storage system, influence of flow boiling heat transfer on fouling phenomenon in nanofluids, and PCM at the simultaneous charging and discharging condition were studied. In the area of industrial heat exchangers, one-dimensional flow network model and porous-media model, and R245fa in a plate-shell heat exchanger were studied. (3) Various studies were published in the categories of refrigeration cycle, alternative refrigeration/energy system, system control. In the refrigeration cycle category, subjects include mobile cold storage heat exchanger, compressor reliability, indirect refrigeration system with $CO_2$ as secondary fluid, heat pump for fuel-cell vehicle, heat recovery from hybrid drier and heat exchangers with two-port and flat tubes. In the alternative refrigeration/energy system category, subjects include membrane module for dehumidification refrigeration, desiccant-assisted low-temperature drying, regenerative evaporative cooler and ejector-assisted multi-stage evaporation. In the system control category, subjects include multi-refrigeration system control, emergency cooling of data center and variable-speed compressor control. (4) In building mechanical system research fields, fifteenth studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, renewable energies, etc. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which could be help for improving the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the analyses of indoor thermal environments controlled by portable cooler, the effects of outdoor wind pressure in airflow at high-rise buildings, window air tightness related to the filling piece shapes, stack effect in core type's office building and the development of a movable drawer-type light shelf with adjustable depth of the reflector. The subjects of building energy were worked on the energy consumption analysis in office building, the prediction of exit air temperature of horizontal geothermal heat exchanger, LS-SVM based modeling of hot water supply load for district heating system, the energy saving effect of ERV system using night purge control method and the effect of strengthened insulation level to the building heating and cooling load.

Optical imaging methods for qualification of superconducting wires

  • Kim, Gracia;Jin, Hye-Jin;Jo, William
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.4
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    • pp.21-25
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    • 2014
  • In order to develop 2nd generation (2G) high-temperature superconducting (HTS) wires as commercial products, it is necessary to perform a high speed investigation of their superconducting performance. Room-temperature and non-contact optical scanning tools are necessary to verify the microstructure of the superconducting materials, the current flow below the critical temperature, and the critical current density. In this paper, we report our results of an inspection of the electrical transport properties of coated conductors. The samples that we used in our study were highly qualified rare-earth based coated conductors produced via co-evaporation, and $SmBa_2Cu_3O_{7-y}$ (SmBCO) was the superconducting materials used in our studies. A film grown on IBAD-MgO templates shows larger than 400 A/cm at 77 K and a self-field. The local transport properties of the films were investigated by room-temperature imaging by thermal heating. The room-temperature images show structural inhomogeneities on the surface of the films. Bolometric response imaging via low-temperature bolometric microscopy was used to construct the local current mapping at the surface. These results indicate that the non-uniform regions on the surface disturb the current flow, and laser scanning images at room-temperature and at a low-temperature suggest a correlation between the structural properties and transport properties. Thus this method can be effective to evaluate the quality of the coated conductors.

Preparation and Characterization of Fire-Resistant Silicone Polymer Composites Containing Inorganic Flame Retardants (무기계 난연제를 첨가한 실리콘 고분자 내화재료의 제조 및 특성분석)

  • Yoon, Chang-Rok;Lee, Jong-Hyeok;Bang, Dae-Suk;Won, Jong-Pil;Jang, Il-Young;Park, Woo-Young
    • Elastomers and Composites
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    • v.45 no.2
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    • pp.87-93
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    • 2010
  • The fire resistive materials are used to resist from fire accidents in the building. In this study silicone rubber/inorganic flame retardant composites were prepared by mechanical stirring method, using aluminium trihydroxide(ATH, $Al(OH)_3$) and magnesium dihydroxide(MDH, $Mg(OH)_2$) as synergistic fire-resistant additives. The thermal properties of the fire resistant composites were characterized by thermogravimetric analysis(TGA). In addition, rheological properties were observed by rheometer and fire-resistant properties were tested by gas torch. Through this study, we realized that the silicone rubber containing ATH, MDH increased the performance of fire-resistance.

A Study on Performance Characteristics of Heat Pump System on Cooling Mode for Light-duty Commercial Electric Vehicles (EV 상용차용 히트펌프 시스템 냉방 운전 특성에 관한 연구)

  • Jeon, Hanbyeol;Kim, Jung-Il;Won, Hun-Joo;Lee, Ho-Seong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.69-75
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    • 2019
  • The cooling performance of heat pump system for light-duty commercial electric vehicle was evaluated experimentally. The cooling performance characteristics of the heat pump for light-duty commercial electric vehicles were evaluated by varying the temperature, flow rate of chiller coolant, and electric compressor speed, under the exterior air temperature of 35 ℃ and interior air temperature of 25 ℃. Increasing the compressor speeds decreased the cooling system efficiency by 16.4 % on average with the cooling capacity increasing by 8.0 % on average and the compressor work increasing by 27% on average. To use waste heat from the coolant to chill power electronic components, such as the motor and inverter, a chiller was installed to transfer heat between the coolant and refrigerant. Increasing the temperature of the chiller coolant from 35 ℃ to 55 ℃ decreased the efficiency by 18.2 % on average due to higher condensing heat source. Increasing the coolant flow rate from 10 liter/min to 20 liter/min did not affect the cooling capacity of the system due to a similar total condensing heat transfer rate at the chiller and the exterior heat exchanger. In future works, heating performance will be investigated by varying the operating conditions to use the chiller's waste heat with an improvement of heating capacity.

Performance Evaluation of FDS for Predicting the Unsteady Fire Characteristics in a Semi-Closed ISO 9705 Room (반밀폐된 ISO 9705 화재실에서 비정상 화재특성 예측을 위한 FDS의 성능평가)

  • Mun, Sun-Yeo;Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.21-28
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    • 2012
  • The objective of this study is to evaluate the prediction accuracy of FDS(Fire Dynamic Simulator) for the thermal and chemical characteristics of under-ventilated fire with unsteady fire growth in a semi-closed compartment. To this end, a standard doorway width of the full-scale ISO 9705 room was modified to 0.1 m and the flow rate of heptane fuel was increased linearly with time (until maximum 2.0 MW based on ideal heat release rate) using a spray nozzle located at the center of enclosure. To verify the capability of FDS, the predicted results were compared with a previous experimental data under the identical fire conditions. It was observed that with an appropriate grid system, the numerically predicted temperature and heat flux inside the compartment showed reasonable agreement with the experimental data. On the other hand, there were considerable limitations to predict accurately the unsteady behaviors of CO and $CO_2$ concentration under the condition of continuous fire growth. These results leaded to a discrepancy between the present evaluation of FDS and the previous evaluation conducted for steady-state under-ventilated fires. It was important to note that the prediction of transient CO production characteristics using FDS was approached carefully for the under-ventilated fire in a semi-closed compartment.

Phase Change of Precipitates and Age Hardening in Rapidly Solidified Mg-Zn-Ca Base Alloys

  • Park Won-Wook;You Bong-Sun
    • Journal of Powder Materials
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    • v.12 no.4 s.51
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    • pp.303-308
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    • 2005
  • Various kinds of Mg-Zn-Ca base alloys were rapidly quenched via melt spinning process. The meltspun ternary and quaternary alloy ribbons were heat-treated, and then the effects of additional elements on age hardening behavior and phase change of precipitates were investigated using Vickers hardness tester, XRD, and TEM equipped with EDS system. In ternary alloys, age hardening was mostly due to the distribution of $Mg_6Ca_2Zn_3$ and $Mg_2Ca$. The stable phases of precipitates were varied according to the aging temperature and the alloy composition. With the increase of Ca content, $Mg_2Ca$ precipitates were detected more than $Mg_6Ca_2Zn_3$ precipitates. In quaternary alloys, the precipitates taken from Mg-Zn-Ca-Co were identified as new quaternary phase, whereas those taken from Mg-Zn-Ca-Zr as MgZnCa containing Zr. In general, the ternary alloy showed higher peak hardness and thermal stability than the quaternary considering the total amounts of the solutes. It implies that the structure of precipitate should be controlled to have the coherent interface with the Mg matrix.

Experimental Study on Thermal Characteristics of Heat Exchanger Modules for Multi Burner Boiler (자트로파 유(Crude Jatropha Oil)에 대한 보일러 직접 연소 특성)

  • Kang, Sae-Byul;Kim, Jong-Jin
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2934-2939
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    • 2008
  • We conducted a test of a direct burning of crude Jatropha oil (CJO) in a commercial boiler system. The fuel, crude Jatropha oil is not biodiesel which comes from transeterification process of bio oil, but it is pure plant oil. The higher heating value (HHV) of the CJO is 39.3 MJ/kg (9,380 kcal/kg) and is higher than that of a commercial heating oil, 37.9 MJ/kg. The kinematic viscosity of CJO is 36.2 mm2/s at $40^{\circ}C$ and 8.0 mm2/s at $100^{\circ}C$. The burner used in the test is a commercial burner for a commercial heatingoil and its capacity is 140 kW (120,000 kcal/h). We did a preliminary test whether the combustion is stable or not. The preliminary test was a kind of open air combustion test using the commercial burner with crude Jatropha oil. We found that the combustion can be stable if the crude Jatrophaoil temperature is higher than $90^{\circ}C$. We measured the flue gas concentration by using a gas analyzer. The NOx concentration is $80{\sim}100\;ppm$ and CO concentration is nearly 0 ppm at flue gas O2 concentration of 3.0 and 4.5%.

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Artificial Photosynthesis Using Zeolites

  • Castagnola, Norma B.;Dutta, Prabir K.
    • Journal of Photoscience
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    • v.6 no.3
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    • pp.91-96
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    • 1999
  • Zeolites and microporouos materials continue to attract attention as novel hosts for photochemical reactions. Zeolities are attractive because of their ability to selectivity exchange and incorporate species within the void spaces and interconnecting channels, providing a spatial arrangement of molecules. Our research has primarily focused on intrazeolitic electron transfer from excited Ru(bpy)32+ in supercages of zeolite Y to a series of bipyridinium ions. In the Ru(bpy)32+ viologen-zeolite Y samples, the slowing of the back electron transfer from the bipyridinium radical cation to Ru(bpy)32+ allows for charge propagation via self exchange between diquat molecules. This provides an opportunity for permanent charge separation. When the migrating charge on the diquat radical within the zeolite reaches the surface, it can be transferred to a neutral viologen (PVS) in solution, resulting in permanent charge separation. The advantage of long-lived charge separation can be exploited for useful chemistry if suitable catablysts can be assembled on the zeolities. We have studied Ru(bpy)2 as water oxdiation catalysts. We have demonstrated that synthesis of RuO2 fibers on a zeolite via thermal decomposition of Ru3(CO)12 leads to the most active water decomposition catalyst reported to date. Because of the extensive interest of photochemical water reduction to H2, much is known about catalytic systems usin gone electron catalyst, and even more importantly, that no reaction of viologen occurred with H2 over this catalyst. The present challenge is to incorporate all these elements of the system into an architecture and we are examining zeolite membranes for this purpose.

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