• Title/Summary/Keyword: $CO_2$ supply

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Catalytic Reduction of Oxidized Mercury to Elemental Form by Transition Metals for Hg CEMS (수은 연속측정시스템에서 전이금속에 의한 산화수은의 원소수은으로의 촉매환원)

  • Ham, Sung-Won
    • Clean Technology
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    • v.20 no.3
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    • pp.269-276
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    • 2014
  • This study was aimed to develop catalytic system for the dry-based reduction of oxidized mercury ($Hg^{2+}$) to elemental mercury ($Hg^0$) which is one of the most important components comprising mercury continuous emission monitoring system (Hg-CEMS). Based on the standard potential in oxidation-reduction reaction, transition metals including Fe, Cu, Ni and Co were selected as possible candidates for catalyst proceeding spontaneous reduction of $Hg^{2+}$ into $Hg^0$. These transition metal catalysts revealed high activity for reduction of $Hg^{2+}$ into $Hg^0$ in the absence of oxygen in reactant gases. However, their activities were greatly decreased in the presence of oxygen, which was attributed to the transformation of transition metals by oxygen to the corresponding transition metal oxides with less catalytic activity for the reduction of oxidized mercury. Hydrogen supplied to the reactant gases significantly enhanced $Hg^{2+}$ reduction activity even in the presence of oxygen. It might be due to occurrence of combustion reaction between $H_2$ and $O_2$ causing the consumption of $O_2$ at such high reaction temperature at which oxidized mercury reduction reaction took place. Because the system showed high activity for $Hg^{2+}$ reduction to $Hg^0$, which was compatible to that of wet-chemistry technology using $SnCl_2$ solution, the catalytic reduction system of Fe catalyst with the supply of $H_2$ could be employed as a commercial system for the reduction of oxidized mercury to elemental mercury.

A Study on the Energy Consumption Characteristics for Use and Operation Period in Office Buildings (업무용 건물의 용도 및 운전 기간별 에너지 소비 특성 연구)

  • Park, Byung Hun;Kim, Si Heon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.11
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    • pp.605-611
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    • 2017
  • The purpose of this study is to calculate the energy consumption rate based on data regarding energy use in office buildings, and to confirm the general characteristics of energy consumption. The energy consumption rate of the building is calculated by dividing the energy consumption by the floor area. The energy consumption rate of small-sized office buildings was calculated as $101.48{\sim}201.55kWh/m^2{\cdot}year$ and in the case of medium-sized buildings, the range was $92.77{\sim}177.89kWh/m^2{\cdot}year$. In the case of small buildings, it was found that the energy consumption was $73.24kWh/m^2{\cdot}year$ in electronic device, $34.31kWh/m^2{\cdot}year$ in hot water supply, and $18.37kWh/m^2{\cdot}year$ in heating. In the case of medium-sized buildings, electronic devices was $73.08kWh/m^2{\cdot}year$, lighting was $18.35kWh/m^2{\cdot}year$ and heating, $15.37kWh/m^2{\cdot}year$. In all of the study buildings, the peak heating energy use was observed from 8:00 a.m. to 10:00 a.m during the winter, and the peak power management was required. Energy use at and around the midnight hour is confirmed to be 40~60% of weekly working hours, so it is necessary to manage power use at night time as well as during the day. In order to improve the accuracy of future studies, it is necessary to make efforts to secure the data with standardized energy measuring units for the various type of buildings.

Technical Trends of Rare Metal Recycling in the Next Generation Automobile (차세대 자동차용 희소금속 리싸이클링 기술동향)

  • Hwang, Young-Gil;Kil, Sang-Cheol;Kim, Jong-Heon
    • Resources Recycling
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    • v.23 no.2
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    • pp.3-16
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    • 2014
  • Car exhaust $CO_2$ gas reduction and fuel efficiency of the car lighter for the current era is a big challenge. The developments of high-performance Nd magnets, Li-ion secondary battery and exhaust gas purification performance of PGM catalysts used in the lightweight EV and HEV are activated. Country in order to improve the car lighter and function that use the resources of rare metals are ubiquitous imported from China because of export supply control, as soaring prices have unstable supply and demand. Compared to the emissions from the next-generation automotive recycling, waste scarce resources need to be. This study investigated the recycling technology analysis and development of the information technology, or delivered to the researchers by giving national car industry aims to contribute to the development. Findings, pulmonary high-performance motor vehicle emissions in the exhaust gas purification PGM Catalysts, Li-ion battery and Nd magnets recycling technology, such as pre- and post-processing techniques to classify technology, pre-urban mining technology mechanical separation by screening techniques under development, the study and post-processing technology has, pyro and hydro metallurgical smelting technology is established. Waste Recycling in terms of economic efficiency of mechanical components for the intensive study of screening techniques is needed.

The Comparative Study on the Characteristics of Thermoacoustic Laser According to Shapes of Resonance Tube (공명 튜브의 기하학적 형상에 따른 열음향 레이저의 특성 비교 연구)

  • Kim, Nam-Jin;An, Eoung-Jin;Oh, Won-Jong;Oh, Seung-Jin;Chun, Wongee
    • Journal of Energy Engineering
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    • v.21 no.2
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    • pp.133-137
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    • 2012
  • Among various clean energy technologies, the solar energy technology has been widely used in various fields such as photovoltaic power generation and solar water/space heating. These days, special attention is drawn on its conversion into acoustic energy along with waste heat as a means to promote clean energy utilization. This work was carried out to investigate the possibility of converting solar energy into acoustic waves, especially, its performance characteristics for a single resonance tube (20.2 mm in ID). Variations are made for the stack length and its position as well as power supply. For a resonance tube of 200mm, an average sound pressure of 114.5 dB was measured with a stack length of 25.6mm at 5cm from the closed end. When the power supply was increased to 35W, an average sound pressure of 117.29 dB was detected with a frequency of 500Hz. There was an increase in frequency, 630 Hz (115.7dB), with a shorter resonance tube of 150mm.

Influence of Sputtering Conditions on Properties of Copper Oxide Thin Films (스퍼터링 공정 조건이 산화 구리 박막 특성에 미치는 영향)

  • Cho, Jae Yu;Heo, Jaeyeong
    • Current Photovoltaic Research
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    • v.5 no.1
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    • pp.15-19
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    • 2017
  • The fossil fuel power consumption generates $CO_2$, which causes the problems such as global warming. Also, the increase in energy consumption has accelerated the depletion of the fossil fuels, and renewable energy is attracting attention. Among the renewable energies, the solar energy gets a lot of attention as the infinite clean energy source. But, the supply level of solar cell is insignificant due to high cost of generation of electric power in comparison with fossil fuels. Thus several researchers are recently doing the research on ultra-low-cost solar cells. Also, $Cu_2O$ is one of the applied materials as an absorption layer in ultra-low-cost solar cells. Cuprous oxide ($Cu_2O$) is highly desirable semiconductor oxide for use in solar energy conversion due to its direct band gap ($E_g={\sim}2.1eV$) and a high absorption coefficient that absorbs visible light of wavelengths up to 650 nm. In addition, $Cu_2O$ has several advantages such as non-toxicity, low cost and can be prepared with simple and cheap methods on large scale. In this work, we fabricated the $Cu_2O$ thin films by reactive sputtering method. The films were deposited with a Cu target with variable parameters such as substrate temperature, rf-power, and annealing condition. Finally, we confirmed the structural properties of thin films by XRD and SEM.

A Study on the Pro-Environmental Energy Supply Program of Urban Enterprises on the concept of BAT(Best Available Technology): Application of Air Environmental Indices and Benefit-Cost Analysis Based (한 도시 사업체 에너지 수급의 최적화 방안 연구 - 대기오염지수와 경제성 평가를 중심으로 -)

  • Kwon, Yong-Sik;Kim, Yong-Bum;Chung, Yong
    • Journal of Environmental Impact Assessment
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    • v.7 no.2
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    • pp.89-102
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    • 1998
  • The purpose of this study is to seek AEI(Air Environmental Indices), PSI(Pollutant Standard Index) and the urban air quality control goal(the best available alternative energy program) by assessing the best ratio of energy types used in urban enterprises, based on harmful health effect and air quality standard and costs. This study is focused on an urban area(Puchun), where area sourcees are associated with heavy traffic, large population, and its industrial sources with large emissions. In the first step, air modeling, estimation of AEI and PSI, and benefit-cost analysis were carried out. In the second step, we assessed that 660 scenarios about the ratio of B-C oil, light oil and LNG used in urban enterprises with regard to air quality and cost. In the third step, the best available alternative energy program was selected for the ratio of energy species(B-C oil, light oil and LNG) by using the lexicographic method. From the emission analysis, main source of $NO_2$ is identified as industries and air quality is evaluated according to the ratio of B-C oil, light oil and LNG used in urban enterprise. The modeling data of TSP, $SO_2$, $NO_2$, CO, $O_3$, by ISC3 and PBM are respectively $118{\mu}g/m^3$, 0.027ppm, 0.025ppm, 2.0ppm, 0.55ppm in indurstrial area. That data are close to Environmental Air Quality Standard. By means of sensitivity analysis, we obtained the difference in concentration between the areas(Nae-dong, Joong-dong) according to the ratio of B-C oil, light oil and LNG used in the industries. From the result of alternatives assessment the lowest AEI value and cost, the ratio of B-C oil, light oil and LNG are 2.5%, 20%, 77.5%, respectively.

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Ka-band CMOS 2-Channel Image-Reject Receiver (Ka-대역 CMOS 2채널 이미지 제거 수신기)

  • Dongju Lee;Se-Hwan An;Ji-Han Joo;Jun-Beom Kwon;Younghoon Kim;Sanghun Lee
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.23 no.5
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    • pp.109-114
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    • 2023
  • In this paper, a 2-channel Image-Reject receiver using a 65-nm CMOS process is presented for Ka-band compact radars. The designed receiver consists of Low-Noise Amplifier (LNA), IQ mixer, and Analog Baseband (ABB). ABB includes a complex filter in order to suppress unwanted images, and the variable gain amplifiers (VGAs) in RF block and ABB have gain tuning range from 4.5-56 dB for wide dynamic range. The gain of the receiver is controlled by on-chip SPI controllers. The receiver has noise figure of <15 dB, OP1dB of >4 dBm, image rejection ratio of >30 dB, and channel isolation of >45 dB at the voltage gain of 36 dB, in the Ka-band target frequency. The receiver consumes 420 mA at 1.2 V supply with die area of 4000×1600 ㎛.

Characteristics of Gasification for a Refused Plastic Fuel (플라스틱 고형 연료의 가스화 특성)

  • Chun, Young Nam;Lim, Mun Sup;Jo, Dae Young
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.11
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    • pp.636-641
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    • 2015
  • Waste energy conversion to SRF (Solid Refuse Fuel) has the effects not alternative fossil fuel usage but also the reduction of greenhouse gas. But the direct burning of the SRF including a plastic waste generates air pollution problem like soot, dioxin, etc. so that an application of pyrolysis and gasification treatment should be needed. The purpose of this study is to supply a basic thermal data of the pyrolysis gasification characteristics in the plastic-rich SRF which are needed for developing the novel pyrolyser or gasifier. To do so, a bench-scale test rig was newly engineered, and then experiments were achieved for the production characteristics of gas, tar, and char. While SRF sample, gasification air ratio, holding time changed as 2 g, 0.691, 32 min respectively, the $H_2$ 1.36%, $CH_4$ 2.18%, CO 1.88%, $Cl_2$ 15.9 ppm, HCl 6.4 ppm were composed. Also light tar benzene $4.03g/m^3$, naphthalene $0.39g/m^3$, anthracene $0.11g/m^3$, pyrene $0.06g/m^3$, gravimetric tar $18g/m^3$, and char 0.29 g was formed.

Trends in Production and Application Technology of Nano-platinum Group Particles for PEFC (고분자고체형연료전지용 나노백금족입자의 제조와 응용기술 동향)

  • Kil, Sang-Cheol;Hwang, Young-Gil
    • Resources Recycling
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    • v.26 no.3
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    • pp.79-91
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    • 2017
  • The core of Hydrogen Fuel Cell Vehicles (FCV) is polymer solid fuel cell (PEFC), and the core material that generates electrochemical electricity in the cell is platinum catalyst. Platinum is localized in South Africa and Russia, and the world production of Pt is about 178 tons per year, which is expensive and recycled. At present, the amount of Pt used in PEFC is $0.2{\sim}0.1mg/cm^2$. In order to reduce the price of the battery and increase the FCV supply, the target is to reduce the amount of Pt used to $0.05{\sim}0.03mg/cm^2$. $Pt-Pd/Al_2O_3$, Pt/C, Pt/GCB, Pt/Au/C, PtCo/C, PtPd/C, etc. by using polyol method using nano Pt, improved Cu-UPD/Pt substitution method and nano-capsule method, Have been researched and developed, and there have been reported techniques for improving the activity of Pt catalysts and stabilizing them. This paper investigates the production technology of nano-Pt and nano-Pt catalysts, recycling of spent Pt catalysts and application trends of Pt catalysts.

Effect of Acetylene Mixing Rate on Synthesis of Carbon Nanotube (탄소나노튜브의 합성에 대한 아세틸렌 혼합 비율의 영향)

  • Kim, Jae-Hyun;Lee, Joo-Hee;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.6
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    • pp.768-773
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    • 2014
  • In this study, experimental and numerical studies for the synthesis of carbon nanotube(CNT) in methane counterflow diffusion flame have been performed. Methane mixed with acetylene($C_2H_2$) was used as a fuel gas and ferrocene was used as a catalyst for synthesis of CNT. The major parameters was $C_2H_2$ mixing rate and mixing rates were 2 %, 6 %, and 10 %. Characteristics of CNT formation on grid were analyzed from SEM images. the chemical reaction mechanism adopted is GRI-MECH 3.0. Numerical results showed that flame temperature and CO mole fraction were increased with increasing acetylene mixing rate. Experimental results showed that the CNT synthesis in 2% acetylene mixture flame better than that of 6% and 10% acetylene mixture flames. It can be considered that 6% and 10% acetylene mixture flames generated the excessive carbon source and then it interrupted the supplement of the carbon source into ferrocene catalyst. It can be found that the supply of appropriate quantity of carbon source can make effect to synthesis of high purity of CNT.