• 제목/요약/키워드: $CO_2$ standard gas

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Zeolites: Their Features as Pressure Swing Adsorbents and CO2 Adsorption Capacity (제올라이트: 압력순환형 흡착제로서의 특성과 CO2 흡착성능)

  • Kim, Moon-Hyeon;Cho, Il-Hum;Choi, Sang-Ok;Choo, Soo-Tae
    • Journal of Environmental Science International
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    • v.23 no.5
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    • pp.943-962
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    • 2014
  • Industrial gas drying, dilute gas mixtures purification, air fractionation, hydrogen production from steam reformers and petroleum refinery off-gases, etc are conducted by using adsorptive separation technology. The pressure swing adsorption (PSA) has certain advantages over the other methods, such as absorption and membrane, that are a low energy requirement and cost-effectiveness. A key component of PSA systems is adsorbents that should be highly selective to a gas being separated from its mixture streams and have isotherms suitable for the operation principle. The six standard types of isotherms have been examined in this review, and among them the best behavior in the adsorption of $CO_2$ as a function of pressure was proposed in aspects of maximizing a working capacity upon excursion between adsorption and desorption cycles. Zeolites and molecular sieves are historically typical adsorbents for such PSA applications in gas and related industries, and their physicochemical features, e.g., framework, channel structure, pore size, Si-to-Al ratio (SAR), and specific surface area, are strongly associated with the extent of $CO_2$ adsorption at given conditions and those points have been extensively described with literature data. A great body of data of $CO_2$ adsorption on the nanoporous zeolitic materials have been collected according to pressure ranges adsorbed, and these isotherms have been discussed to get an insight into a better $CO_2$ adsorbent for PSA processes.

Source Emission Rate on Air Pollutants from Portable Gas Range and Optimal Ventilation Rate in Indoor Environment (휴대용 가스렌지 연소에 의한 공기오염물질의 발생량 및 실내환경의 필요 환기량)

  • Yim, Sung-Kuk;Kim, Young-Hee;Yang, Won-Ho
    • Journal of Environmental Health Sciences
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    • v.33 no.2 s.95
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    • pp.92-97
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    • 2007
  • A series of source tests were conducted to characterize emissions of nitrogen oxide(NOx, NO, $NO_2$), carbon mon oxide(CO), carbon dioxide$(CO_2)$ and total VOCs from portable combustion devices in steady-state using well-mixed chamber. Since use of portable gas range is widespread in houses and restaurants in Korea, it is important to characterize the emission of air pollutants and suggest optimum ventilation rate. Ranges of emission rates of air pollutants from portable gas ranges were $NO \;0.551\sim0.939mg/hr,\;NO_2\;0.354\sim1.080mg/hr,\;NO_x\;1.207\sim1.631mg/hr,\;CO\;1.389\sim4.21mg/hr,\;CO_2\;2426.823\sim2973.495mg/hr$, and VOCs $0\sim0.119mg/h$. Mean of personal exposure and indoor environment level of $NO_2$ by combustion of portable gas range were 74.7 ppb and 65.4 ppb, respectively, suggesting persons using portable gas range in houses and restaurants might be highly exposed. Required ventilation rate to control the air pollutants emitted from portable gas range was maximumly $3.131m^3/hr$ on the basis of $NO_2$ indoor air quality standard.

A Study on Realization Method of Low Carbon School Building (저 탄소 학교건축물 구현 방안에 관한 연구)

  • Tae, Sung-Ho;Cho, Young-Sang;Shin, Sung-Woo;Lee, Seung-Min;Meang, Joon-Ho
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.9 no.2
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    • pp.30-37
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    • 2010
  • This study purposed realization and a phase reduction of school building $CO_2$ emissions. Accordingly selected standard school buildings and evaluated life cycle environmental load($CO_2$). This study proposed Green building technology which separated design sector, energy sector, afforestation sector for carbon-neutral city school buildings realization of M-city. As a result, elementary, middle and high schools of M-city built in the year 2013 were required that design sector was Energy Performance Index(EPI) 75 point and energy sector was solar installations more than 25% of the power usage, Solar systems installed more than 10% of total gas consumption and the area of afforesting more than 35% of the ecological area to achieve 30% $CO_2$ reduction compared to the Respectively standard school buildings.

Carbon Monoxide Sensor Based on a B2HDDT-doped PEDOT:PSS Layer

  • Memarzadeh, R.;Noh, Hui-Bog;Javadpour, S.;Panahi, F.;Feizpour, A.;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2291-2296
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    • 2013
  • An efficient carbon monoxide (CO) sensor was developed based on poly(3,4-ethylenedioxy)thiophenepoly(styrenesulfonate) (PEDOT:PSS) modified with a new pyrimidine-fused heterocyclic compound, bis(2-hydroxyphenyl)dihydropyrido[2,3-d:6,5-d]dipyrimidine-tetraone (B2HDDT). B2HDDT remains stable in the polymer matrix through interactions with functional groups of the polymer. It created prominent sites that captured CO gas, and the experimental parameters, including the amount of doped B2HDDT in the PEDOT:PSS film, were optimized. The sensor probe was also examined to verify its reliability for detecting CO in the presence of atmospheric gases in a discriminating manner. NMR, AFM, and FT-IR spectra were obtained to evaluate the structure and morphology of the B2HDDT-doped PEDOT:PSS (PEDOT:PSS/B2HDDT) film. The content of 35 vol % B2HDDT (7.0 mM) in PEDOT:PSS provided the largest response factor (${\Delta}R/R_o$) for the CO gas. The sensor response was reproducible, with a relative standard deviation < 5% (n = 5). The detection limit was determined to be $0.44{\pm}0.05$ vol %.

Development of Controlled Gas Nitriding Furnace(II) : Controlled Gas Nitriding System and its Hardware (질화포텐셜 제어 가스질화로 개발(II) : 제어시스템 및 하드웨어)

  • Won-Beom Lee;Won-Beom Lee;YuJin Moon;BongSoo Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.2
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    • pp.86-95
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    • 2023
  • This paper explained the equipment and process development to secure the source technology of controlled nitrification technology. The nitriding potential in the furnace was controlled only by adjusting the flow rate of ammonia gas introduced into the furnace. In addition, a control system was introduced to automate the nitriding process. The equipment's hardware was designed to enable controlled nitriding based on the conventional gas nitriding furnace, and an automation device was attached. As a result of measuring the temperature and quality uniformity for the equipment, the temperature and compound uniformity were ±1.2℃ and 14.3 ± 0.2 ㎛, respectively. And, it was confirmed that nitriding potential was controlled within the tolerance range of AMS2759-10B standard. In addition to parts for controlled nitriding, it was applied to products produced in existing conventional nitriding furnaces, and as a result, gas consumption was reduced by up to 80%.

Real-time Air Quality Monitoring System Based on Wireless Network (무선네트워크기반 공기질 실시간 모니터링 시스템)

  • Paik, Seung Hyun;Lee, Jun Yeong;Jung, Sang Woo;Park, Hong Bae
    • IEMEK Journal of Embedded Systems and Applications
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    • v.11 no.3
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    • pp.143-151
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    • 2016
  • In this paper, a real-time air quality monitoring system based on wireless network is designed and implemented for industrial park or multiuse facilities. The existing gas detector is high price and hard to apply the remote monitoring system. On the other hand, demand for air quality monitoring is increasing because of industrial gas accident, air pollution, and so on. In Korea, indoor air regulation was established by law. According to indoor air regulation, CO2, CO, and NO2 are important gases as the air quality standard. So we study the gas detector for indoor air quality and the wireless network system. The wireless network consist of sensor network and WCDMA to apply various place. To verify the performance of the implemented gas detector, the gas measurement experiment is performed in laboratory environment by using the realized gas detecting wireless sensor node. And we evaluate the experiment results.

Investigation of the Supercritical Fluids as an Insulating Medium for High Speed Switching

  • Shon, Chae-Hwa;Song, Ki-Dong;Oh, Yeon-Ho;Oh, Ho-Seok
    • Journal of Electrical Engineering and Technology
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    • v.11 no.6
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    • pp.1783-1786
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    • 2016
  • The paper investigates the insulation properties of the supercritical $CO_2$ ($SCCO_2$) fluid as an insulating medium for electrical apparatuses. The insulating material is crucial for electrical apparatuses and $SF_6$ gas has been widely used for high power electrical apparatuses. There have been many research efforts to develop substituents for $SF_6$ gas because of high global warming potential. We obtained above 350 kV/mm insulation strength with 12.0 MPa $SCCO_2$. The positive and negative IEC standard pulses are applied between two 10 mm diameter spherical electrodes. The insulation strength of $SCCO_2$ is at least 2.5 times higher than that of $CO_2$ gas at 6.0MPa. The insulation strength of $SCCO_2$ fluid is about 10 times higher than that of $SF_6$ at 0.5MPa which is the ordinary operating pressure of electrical switchgears. Using the result, we expect that the time for switching and dielectric recovery could be reduced using $SCCO_2$ fluid as an insulating medium.

Comparison of Formaldehyde Emission of Wood-based Panels with Different Adhesive-hardener Combinations by Gas Chromatography and Standard Methods

  • Eom, Young Geun;Kim, Sumin;Baek, In-Chan;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.2 s.130
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    • pp.29-39
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    • 2005
  • Formaldehyde emissions from wood-based panels bonded with pine and wattle tannin-based adhesives, urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), and co-polycondensed resin of urea-melamine-formaldehyde (UMF) were measured by the Japanese standard method using a desiccator (JIS A 1460) and the EN 120 (European Committee For Standardization, 1991) method using the perforator value. In formaldehyde emission, all particleboards made using the wattle tannin-based adhesive with three different hardeners, paraformaldehyde, hexamethylenetetramine, and tris(hydroxyl)nitromethan (TN), satisfied the requirements of grade $E_1$. But only those made using the pine tannin-based adhesive with the hexamine as hardener met the grade $E_1$ requirements. Hexamine was effective in reducing formaldehyde emission in tannin-based adhesives when used as the hardener. While the UF resin showed a desiccator value of $7.1mg/{\ell}$ and a perforator value of 12.1 mg/100 g, the MF resin exhibited a desiccator value of $0.6mg/{\ell}$ and a perforator value of 2.9 mg/100 g. According to the Japanese Industrial Standard and the European Standard, the formaldehyde emission level of the MDF panels made with UF resin in this study came under grade $E_2$. The formaldehyde emission level was dramatically reduced by the addition of MF resin. The desiccator and perforator methods produced proportionally equivalent results. Gas chromatography, a more sensitive and advanced method, was also used. The samples for gas chromatography were gathered during the experiment involving the perforator method. The formaldehyde contents measured by gas chromatography were directly proportional to the perforator values.

SEPARATION AND PURIFICATION PROCESS OF DEMO PLANT FOR 10TON PER DAY DME PRODUCTION (일일 10톤 DME 생산 Demo Plant에서의 분리정제 공정)

  • Ra Young Jin;Cho Wonihl;Shin Dong Geun;Lim Gye Gue
    • 한국가스학회:학술대회논문집
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    • 2005.10a
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    • pp.141-145
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    • 2005
  • DME (Di-Methyl Ether) is a new clean fuel and an environmental-friendly energy resource, also is recently increasing with an alternative interest because of the industrial use. DME has been shown to have excellent properties as a diesel fuel giving emission level better than ULEV standard. So it has been attracting considerable as an alternative diesel fuel. In this study, we carried out simulation of separation and purification process of demo plant for 101on per day DME production, which cause the effect that is important in productivity, from operation results of pilot plant for 50kg per day DME production. The liquefied stream, which was separated by gas-liquid separator after DME reactor, includes $CO_2$, DME, Methanol and $H_2O$. We established three distillation columns for separation and purification of the stream. $CO_2$ was extracted from the stream by first distillation column, DME was extracted by second column and Methanol was extracted by third column. We investigated and analyzed the effect which the actual operation variables cause in efficiency of process and optimized process, finally we got the DME of purity $100\%$.

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New Requirements of Environmental Standard for Aircraft Engine Exhaust Emissions (환경규제 강화에 따른 항공기 배기가스 배출기준 개정 방안 연구)

  • Noh, Ji-Sub;Kim, Kyeong-Su;Nam, Young-Woo
    • Journal of Aerospace System Engineering
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    • v.14 no.spc
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    • pp.7-12
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    • 2020
  • In this paper the new revision of Korean Airworthiness Standards (KAS) - Emissions was proposed for enforced environmental standards. The Aircraft Engine Fuel Venting and Exhaust Emissions Requirements have been only defined for smoke, HC, CO and NOx as management items in previous KAS. However, this standard has not covered the current situation that International Civil Aviation Organization (ICAO) and United States Environmental Protection Agency (EPA) enforced environmental regulations, such as emissions trading system, limitation of CO2 emissions and restriction of exhaust gas. In order to overcome these outdated situations, we presented the new requirements for aircraft exhaust gas emissions standard of Korea based on the latest standards of United States, Europe and other countries.