• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.61-62
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• 2023

In this study, the steel slag was immersed in CO₂ nano-bubble water by Electric arc funace it was accelerated aging was reviewed through XRD analysis. The main minerals of the electric furnace oxidized slag were spinel and gehlenite, and there was no change with the number of CO₂ nano-bubbles. Minerals such as larnite, calcio-olivine, agnetite, calcite, and spinel were distributed in electrically reduced slag, and the content of calcite more than doubled with CO₂ nano-bubble immersion. Therefore, it is judged that the acceleration aging of Electric arc funace reduced slag is effective according to the immersion of CO₂ nano-bubble.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.145-146
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• 2020

This study investigated the performance evaluation of polymer cement mortar for repairing concrete structures using calcium nitrite(Ca(NO₂)₂) and CO₂ nano-bubble mixing water to develop section-restoration methods for the repair and reinforcement of cracks. The evaluation items were strength and microstructure analysis at 28 days of age according to the change in the amount of calcium nitrite and the use of CO₂ nano-bubble water. As a result of the experiment, it was confirmed that the performance of polymer cement mortar for repairing concrete structures was improved by the generation of nitrite-based hydration products when calcium nitrite and CO₂ nano-bubble water were used.

• Clean Technology
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• v.17 no.1
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• pp.19-24
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• 2011

The bubble point pressures of binary mixtures of carbon dioxide ($CO_2$) and N,N-dimethylformamide (DMF) were measured by using a high-pressure experimental apparatus equipped with a variable-volume view cell, at various $CO_2$ compositions in the range of temperatures above the critical temperature of $CO_2$ and below the critical temperature of DMF. The experimental bubble point pressure data were correlated with the Peng-Robinson equation of state (PR-EOS) to estimate the corresponding dew point compositions at equilibrium with the bubble point compositions. The experimentally measured bubble point pressures gave good agreement with those calculated by the PR-EOS. The variable-volume view cell equipment was verified to be an easy and quick way to measure the bubble point pressures of high-pressure compressible fluid mixtures.

• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.94-98
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• 2009

The bubble point pressures of dimethyl carbonate and carbon dioxide mixtures were measured by using a high-pressure experimental apparatus equipped with a variable-volume view cell, at various $CO_2$ compositions in the range of temperatures above the critical temperature of $CO_2$ and below the critical temperature of dimethyl carbonate. The experimental bubble point pressure data were correlated with the Peng-Robinson equation of state (PR-EOS) to estimate the corresponding dew point compositions at equilibrium with the bubble point compositions. The experimentally measured bubble point pressures gave good agreement with those calculated by the PR-EOS. The variable-volume view cell equipment was verified to be an easy and quick way to measure the bubble point pressures of high-pressure compressible fluid mixtures.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.91-92
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• 2023

In this study, the chemical composition of converter slag according to CO₂ nanobubble promotion aging time was examined. The CO₂ nanobubble water immersion time was 0, 12, 24, 36, 48 hours, and then dried and pulverized to perform XRD analysis. As a result, the longer the sample was immersed in CO₂ nanobubble water, the higher the amount of calcite produced, and the change after 36 hours was minimal.

• Analytical Science and Technology
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• v.24 no.6
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• pp.467-476
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• 2011

Solubility data of carbon dioxide ($CO_2$) in the imidazolium-based ionic liquids with methylsulfate anion are presented at pressures up to about 45 MPa and at temperatures between 303.15 K and 343.15 K. The ionic liquids studied in this work were 1-ethyl-3-methylimidazolium methylsulfate ([emim][$mSO_4$]), 1-butyl-3-methylimidazolium methylsulfate ([bmim][$mSO_4$]). The solubilities of $CO_2$ were determined by measuring the bubble point or cloud point pressures of the binary mixtures using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. The equilibrium pressure increased very steeply at high $CO_2$ compositions. The $CO_2$ solubility in ionic liquids increased with increase of the total length of alkyl chains attached to the imidazolium cation of the ionic liquids. The phase equilibrium data for the $CO_2$ + ionic liquid systems have been correlated using the Peng-Robinson equation of state.

• Journal of Environmental Science International
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• v.20 no.10
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• pp.1329-1336
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• 2011

The objectives of this study are to examine the processing of oils contamination soil by means of using a micronano-bubble soil washing system, to investigate the various factors such as washing periods, the amount of micro-nano bubbles generated depending on the quantity of acid injection and quantity of air injection, to examine the features involved in the elimination of total petroleum hydrocarbons (TPHs) contained in the soil, and thus to evaluate the possibility of practical application on the field for the economic feasibility. The oils contaminated soil used in this study was collected from the 0~15 cm surface layer of an automobile junkyard located in U City. The collected soil was air-dried for 24 hours, and then the large particles and other substances contained in the soil were eliminated and filtered through sieve No.10 (2 mm) to secure consistency in the samples. The TPH concentration of the contaminated soil was found to be 4,914~5,998 mg/kg. The micronano-bubble soil washing system consists of the reactor, the flow equalization tank, the micronano- bubble generator, the pump and the strainer, and was manufactured with stainless material for withstanding acidic phase. When the injected air flow rate was fixed at 2 L/min, for each hydrogen peroxide concentrations (5, 10, 15%) the removal percents for TPH within the contaminated soil with retention times of 30 minutes were respectively identified as 4,931 mg/kg (18.9%), 4,678 mg/kg (18.9%) and, 4,513 mg/kg (17.7%). And when the injected air flow rate was fixed at 2 L/min, for each hydrogen peroxide concentrations (5, 10, 15%) the removal percents for TPH within the contaminated soil with retention times of 120 minutes were respectively identified as4,256 mg/kg (22.3%), 4,621 mg/kg (19.7%) and 4,268 mg/kg (25.9%).

• Journal of Environmental Science International
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• v.26 no.1
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• pp.23-28
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• 2017

This study was aimed at determining the changes in heavy metal removal efficiency at different acid concentrations in a micro-nanobubble soil washing system and pickling process that is used to dispose of heavy metals. For this purpose, the initial and final heavy metal concentrations were measured to calculate the heavy metal removal efficiency 5, 10, 20, 30, 60, and 120 min into the experiment. Soil contaminated by heavy metals and extracted from 0~15 cm below the surface of a vehicle junkyard in the city of U was used in the experiment. The extracted soil was air-dried for 24 h, after which a No. 10 (2 mm) was used as a filter to remove large particles and other substances from the soil as well as to even out the samples. As for the operating conditions, the air inflow rate in the micro-nano bubble soil washing system was fixed at 2 L/min,; with the concentration of hydrogen peroxide being adjusted to 5%, 10%, or 15%. The treatment lasted 120 min. The results showed that when the concentration of hydrogen peroxide was 5%, the efficiency of Zn removal was 27.4%, whereas those of Ni and Pb were 28.7% and 22.8%, respectively. When the concentration of hydrogen peroxide was 10%, the efficiency of Zn removal was 38.7%, whereas those of Ni and Pb were 42.6% and 28.6%, respectively. When the concentration of hydrogen peroxide was 15%, the efficiency of Zn removal was 49.7%, whereas those of Ni and Pb were 57.1% and 42.6%, respectively. Therefore, the efficiency of removal of all three heavy metals was the highest when the hydrogen peroxide concentration was 15%.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.464-464
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• 2023

최근 이산화탄소(Carbon Dioxode, CO₂) 배출량 증가로 인하여 지구온난화와 같은 기후변화 문제가 심각한 사회 문제로 대두되고 있다. 이에 따라 2015년 12월 12일 프랑스 파리에서 열린 제21차 유엔기후변화협약에서 교토의정서를 대체하는 파리협정(Paris Agreement)을 채택하였으며, 국내에서는 이러한 국제사회의 기후변화 대응에 동참하고 온실가스 감축을 이행하기 위한 2050 탄소중립 정책을 추진하였다. 이산화탄소를 다량으로 발생시키는 철강·산업·건설·에너지 분야 중건설 분야에서 배출되는 이산화탄소는 전체 배출량의 19.9%로 특히 시멘트를 제조하는 과정에서 많은 양의 이산화탄소가 배출되고 있다. 기존의 건설 분야 에서는 이산화탄소를 저감하기 위해 콘크리트 배합 또는 양생과정에서 챔버 내 이산화탄소를 가스 형태로 주입하여 탄산화 반응을 통해 콘크리트 내부에 이산화탄소를 영구히 저장시키고자 하였다. 그러나 이는 챔버 사용, 양생조건 등 적용 조건이 제한적이며, 콘크리트 내 이산화탄소 흡수 효율이 높지 않아 이를 개선할 수 있는 기술이 필요하다. 이를 개선하기 위해 최근에는 콘크리트 배합수 내 이산화탄소를 용해시켜 배합과정에서 콘크리트 내부로 이산화탄소를 강제로 인입시키는 연구들이 진행되고 있다. 그러나 콘크리트 배합수로 사용되고 있는 일반물이나 지하수의 경우 가압을 하여도 약 1,400mg/L의 이산화탄소를 용해시키며, 가압을 통해 용해된 이산화탄소는 쉽게 대기 중으로 방출되는 한계점을 지니고 있어 현장에서 사용하기 어려운 문제가 있다. 이러한 한계점을 극복하기 위해서 본 연구에서는 200nm 이하의 크기를 가지는 나노버블기술을 이용해 압력을 가하지 않은 상태에서 수중에 이산화탄소를 용해시킬 수 있는 시스템을 개발하고자 한다. 나노버블기술을 이용한 수중 이산화탄소용해 시스템을 통해 수중에 이산화탄소를 용해시켜 콘크리트 배합수로 활용하기 위한 기초 연구가 될 것으로 판단된다.