• Title/Summary/Keyword: $CO_2$ fluxes

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A Preliminary Flux Study for CO2 and Biogenic VOCs in a Forest (산림지역 이산화탄소 및 자연적휘발성유기화합물의 교환량 관측기법 기초연구)

  • Kim, So-Young;Kim, Su-Yeon;Choi, Soon-Ho;Kim, Sae-Wung
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.5
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    • pp.485-494
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    • 2012
  • The purpose of this study is to monitor the flux of $CO_2$ and BVOCs (biogenic volatile organic compounds) between the atmosphere and forest. The main research activities are conducted at Taehwa Research Forest (TRF), managed by the College of Agriculture and Life Sciences at Seoul National University. The TRF site is located 60 km north-east from the center of Seoul Metropolitan Area. The TRF flux tower is in the middle of a Korean Pine (Pinus Koraiensis) plantation ($400m{\times}400m$), surrounded by a mixed forest. Eddy covariance method was used for $CO_2$ flux above the forest and REA (Relaxed eddy accumulation) method applying eddy covariance was used for BVOCs flux. BVOCs flux that was measured in spring (from May 16 to 18) had distribution of 84 to $2917{\mu}g/m^2{\cdot}h$. Especially, it showed that d-limonene being strong reactivity composed the largest fraction of monoterpene. Ambient $CO_2$ concentration measured in Mt. Taehwa was 399 ppm and observed $CO_2$ fluxes between the atmosphere and forest suggested that during the day, $CO_2$ is absorbed by plants through photosynthesis and released during the night.

Pressure Drop Characteristics of Supercritical $CO_2$ in a Helically Coiled Tube (헬리컬 코일관 내 초임계 $CO_2$의 압력강하 특성)

  • Yu, Tae-Geun;Kim, Dae-Hui;Roh, Geon-Sang;Ku, Hak-Geun;Oh, Hoo-Kyu
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.216-221
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    • 2005
  • The heat transfer coefficient and pressure drop during gas cooling process of carbon dioxide in a helically coiled tube were investigated experimentally. The experiments were conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable speed pump, a mass flowmeter, a pre-heater, a gas cooler(test section) and an isothermal tank. The test section is a double pipe type heat exchanger with refrigerant flowing in the inner tube and water flowing in the annulus. It was made of a copper tube with the inner diameter of 4.85 [mm], the outer diameter of 6.35 [mm] and length of 10000 [mm]. The refrigerant mass fluxes were 200${\sim}$600 [kg/$m^2$s] and the average pressure varied from 7.5 [MPa] to 10.0 [MPa]. The main results were summarized as follows: The heat transfer coefficient of supercritical $CO_2$ increases, as the cooling pressure of gas cooler decreases. And the heat transfer coefficient increases with the increase of the refrigerant mass flux. The pressure drop decreases in increase of the gas cooler pressure and increases with increase the refrigerant mass flux.

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Behaviors of Metals in the Settling Particles in the Bransfield Strait, Antarctica (남극 브랜스필드 해협에서 침강입자의 금속원소 특성)

  • Kim, Dong-Seon;Kim, Dong-Yup;Kim, Young-June;Kang, Young-Chul;Shim, Jeong-Hee
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.41-52
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    • 2003
  • Sediment trap samples were collected to find out characteristic behaviors of metals in the settling particles by using time-series sediment traps at 678m and 1678m water depths in the Bransfield Strait from December 27th, 1999 to December 26th, 2000. Total mass fluxes at the intermediate water depth (678m water depth) were high in the austral summer and low in the austral winter, whereas at the deep water depth (1678m water depth) they showed high values in both the summer and winter. Total mass fluxes were generally higher in the deep water depth than in the intermediate water depth, which indicates that a substantial amount of sediments are laterally transported by strong currents into the deep basin from the shallow water depths. Aluminium contents also showed large seasonal variations with high values in the winter and low values in the summer. On the contrary, organic carbon contents were high in the summer and low in the winter. Al contents were negatively correlated with organic carbon contents, which may be ascribed that detrital particles are diluted by organic matter produced by phytoplankton in the surface waters. Metals measured in this study exhibited three characteristic behaviors; 1) a positive correlation with Al-Ti, Fe, Mn, V, Co, and Ba, 2) a negative correlation with Al-Cd and Zn, 3) no relationship with Al-Sr, Cu, Cr, Ni. Terrestrial materials may act as a major source fer metals that are positively correlated with Al, and organic matter may be a major source for metals that are negatively correlated with Al. Enrichment factor (EF) of Fe, Mn, Ba, Vi Co, Sr, Cr, and Ni ranged from 0.5 to 1.5, whereas EF of Zn, Cu, and Cd showed much higher values than 1.

Analysis of Heat Transfer and Pressure Drop During Gas Cooling Process of Carbon Dioxide in Transcritical Region (초임계 영역내 $CO_2$ 냉각 열전달과 압력강하 분석)

  • 손창효;이동건;정시영;김영률;오후규
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.1
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    • pp.65-74
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    • 2004
  • The heat transfer coefficient and pressure drop of $CO_2$(R-744) during gas cooling Process of carbon dioxide in a horizontal tube were investigated experimentally and theoretically. The experiments were conducted without oil in the refrigerant loop. The main components of the refrigerant loop consist of a receiver. a variable-speed pump. a mass flowmeter, an evaporator. and a gas cooler(test section). The main components of the water loop consist of a variable-speed Pump. an constant temperature bath. and a flowmeter. The gas cooler is a counterflow heat exchanger with refrigerant flowing in the inner tube and water flowing in the annulus The test section consists of smooth, horizontal stainless steel tube of 9.53 mm outer diameter and 7.75 mm inner diameter. The length of test section is 6 m. The refrigerant mass fluxes were 200 ~ 300 kg/($m^2{\cdot}s$) and the inlet pressure of the gas cooler varied from 7.5 MPa to 8.5 MPa. The main results were summarized as follows : The predicted correlation can evaluated the R-744 exit temperature from the gas cooler within ${\pm}10%$ for most of the experimental data, given only the inlet conditions. The predicted gas cooley capacity using log mean temperature difference showed relatively food agreement with gas cooler capacity within ${\pm}5%$. The pressure drop predicted by Blasius estimated the pressure drop on the $CO_2$ side within ${\pm}4.3%$. The predicted heat transfer coefficients using Gnielinski's correlation evaluated the heat transfer coefficients on the $CO_2$ side well within the range of experimental error. The predicted heat transfer coefficients using Gao and Honda's correlation estimated the heat transfer coefficients on the coolant side well within ${\pm}10\;%$. Therefore. The predicted equation's usefulness is demonstrated by analyzing data obtained in experiments.

An Experimental Study on Heat Transfer and Pressure Drop Characteristics of Carbon Dioxide During Gas Cooling Process in a Hellically Coiled Tube

  • Oh, Hoo-Kyu;Son, Chang-Hyo;Yu, Tae-Geun;Kim, Dae-Hui
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.3
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    • pp.263-271
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    • 2007
  • The heat transfer coefficient and pressure drop during 9as cooling process of $CO_2$ (R744) in a helically coiled copper tube with the inner diameter of 4.55 mm and outer diameter of 6.35 mm were investigated experimentally. The main components of the refrigerant loop are a receiver, a variable-speed pump. a mass flow meter a pre-heater and a helically coiled type gas cooler (test section). The refrigerant mass fluxes are varied from 200 to $800kg/m^2s$ and the inlet pressures of gas cooler are 7.5 to 10.0 MPa. The heat transfer coefficients of $CO_2$ in a helically coiled tube are higher than those in a horizontal tube. The Pressure drop of $CO_2$ in the gas cooler shows a relatively good agreement with those predicted by Ito's correlation developed for single-phase in a helically coiled tube. The local heat transfer coefficient of $CO_2$ agrees well with the correlation by Pitla et al. However. at the region near pseudo-critical temperature. the experiments indicate higher values than the Pitla et al correlation. Therefore, various experiments in helically coiled tubes have to be conducted and it is necessary to develop the reliable and accurate prediction determining the heat transfer and pressure drop of $CO_2$ in a helically coiled tube.

Combustion characteristics of rice-husk according to the change of heat flux (왕겨의 heat flux별 연소특성에 관한 연구)

  • Park Eun-young;Park Duckshin;Cho Youngmin;Park Byunghyun;Lee Cheulkyu
    • Proceedings of the KSR Conference
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    • 2005.11a
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    • pp.1190-1195
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    • 2005
  • Biomass burning is a source of greenhouse gases, carbon dioxide, methane, and nitrous oxide. Under the ideal conditions of complete combustion, the burning of biomass produces carbon dioxide and water vapor. Since complete combustion is not achieved under any conditions of biomass burning, other carbon species, including carbon monoxide, methane, non-methane hydrocarbons and particulate carbon are produced. In this study, we analyze the combustion characteristics of rice-husk, such as heat release rate, smoke production rate, the percentage variation of CO and $CO_2$, oxygen consumption rate, and mass loss under different heat fluxes (20, 50 and 70kW). As a result, at 20kW incomplete combustion is occurred so that the percentage of CO is high in initial burning and total smoke release is higher than the others. At 50kW and 70kW, the combustion behaviors is very similar except the variation of CO percentage.

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Preparation and Permeation of La2Ce2O7 Membrane

  • Park, Jihye;Jung, Miewon
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.269-272
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    • 2015
  • $La_2Ce_2O_7$ and $CeO_2$ membranes were fabricated from the corresponding powders derived from sol-gel process with polyvinyl alcohol binder. These powders and membranes were characterized by XRD, BET, and FE-SEM analysis. Hydrogen and CO gas permeation experiments were performed using Sievert's type equipment. Both fluxes on these membranes were found to decrease with increase of the temperature. This phenomenon was followed by the surface and Knudsen diffusion mechanism. The hydrogen permeability of the $La_2Ce_2O_7$ membrane was found to be $7.27{\times}10^{-5}mol/m^2sPa$, with perm-selectivity of 7.24 at 303 K.

Outflow properties of 24 DIGITembedded soruces

  • Kang, Seonmi;Lee, Jeong-Eun;Choi, Minho;Evans, Neal J.;Dunham, Michael M.
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.65.2-65.2
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    • 2013
  • We present a study of outflows on 24 embedded young stellar objects (YSOs), which are selected from the sources of the Dust, Ice, and Gas in Time (DIGIT) Herschel key program. Molecular outflow activity, which is believed to have strong dependence on accretion process, is the most powerful in the early embedded phase of star formation and declines as the central protostars evolve to the main sequence stage. In order to study the relation between the CO outflow observed in low J transitions and the properties of protostars, we mapped the CO outows of the selected targets in J = 1-0 and J = 2-1 lines with the 14-m TRAO telescope and the 6-m SRAO telescope, respectively. We estimate CO outflow momentum fluxes (Fco) and compare with bolometric luminosity, Lbol, bolometric temperature, Tbol, and the FIR molecular line luminosities of CO, $H_2O$, OH and [O I], which were detected by the Herschel-PACS observations. We found that $Fco_{1-0}$ is greater than $Fco_{2-1}$, and the mean ratio is about 2. L1455-IRS3 and IRAM04191 have high Fco in spite of low $L_{bol}$. The well known correlation between Fco and $L_{bol}$. is not very evident from all our samples. However, Fco and $L_{bol}$. show a rather strong correlation if L1455-IRS3 and IRAM04191 are excluded. Fco shows little correlation with FIR line luminosities of individual species, while the total FIR line luminosity summed over CO, $H_2O$, OH, and [OI] lines seems to have some correlation. In addition, we report 22 GHz $H_2O$, and 44 GHz CH3OH maser line detections in four sources out of the 24 YSOs.

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Mechanism of Energy Transfer and Improvement Moist Stability of BaMg$Al_{10}O_{17}$:$Eu^{2+}$, $Mn^{2+}$ Phosphor

  • Liu, Ru-Shi;Ke, Wei-Chih
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.235-238
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    • 2009
  • BaMg$Al_{10}O_{17}$ (BAM) co-doped with $Eu^{2+}$ and $Mn^{2+}$ was synthesized in a solid-state reaction and their luminescence properties were investigated as functions of the concentrations of the sensitizer and activator. BAM:$Eu^{2+}$ had a broad blue emission band at 450 nm and BAM:$Mn^{2+}$ exhibited green emission at 514 nm. The energy transfer from $Eu^{2+}$ to $Mn^{2+}$ was mainly of the resonance-type via an electric dipole-quadrupole interaction. Additionally, the addition of various fluxes such as $AlF_3$ and $BaF_2$ in the synthesis improves the moist and thermal stability. This is particularly important for the phosphor in white light emitting diodes (LEDs).

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Heat Transfer Characteristics of Carbon Dioxide in a Inclined Helical Coil Type Heat Exchanger with Inner Diameter Tube of 4.55 mm (내경 4.55 mm의 경사진 헬리컬 코일형 열교환기내 이산화탄소의 열전달 특성에 관한 연구)

  • Son, Chang-Hyo
    • Journal of the Korean Institute of Gas
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    • v.11 no.3
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    • pp.1-6
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    • 2007
  • The heat transfer coefficient and pressure drop during gas cooling process of $CO_2$ (R-744) in inclined helical coil copper tubes were investigated experimentally. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and a inclined helical coil type gas cooler (test section). The test section consists of a smooth copper tube, which is specified as the inner diameter of 4.55 mm. The refrigerant mass fluxes were varied from 200 to $600kg/m^2s$ and the inlet pressures of gas cooler were done 7.5 to 10.0 (MPa). The heat transfer coefficients of $CO_2$ in the inclined helical coil tubes increase with the increase of mass flux and gas cooling pressure of $CO_2$. The pressure drop of $CO_2$ in the gas cooler shows relatively good coincidence with those predicted by Ito's correlation developed for single-phase in a helical coil tube. The local heat transfer coefficient of $CO_2$ is well coincident with the correlation by Pitla et al. However, at the region near pseudo-critical temperature, the experiments indicate higher values than the Pitla et al. correlation.

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