• Title/Summary/Keyword: $CO_2$ fluxes

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Effects of controlled environmental changes on the mineralization of soil organic matter

  • Choi, In-Young;Nguyen, Hang Vo-Minh;Choi, Jung Hyun
    • Environmental Engineering Research
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    • v.22 no.4
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    • pp.347-355
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    • 2017
  • This study investigated how the combined changes in environmental conditions and nitrogen (N) deposition influence the mineralization processes and carbon (C) dynamics of wetland soil. For this objective, we conducted a growth chamber experiment to examine the effects of combined changes in environmental conditions and N deposition on the anaerobic decomposition of organic carbon and the emission of greenhouse gases from wetland soil. A chamber with elevated $CO_2$ and temperature showed almost twice the reduction of total decomposition rate compared to the chamber with ambient atmospheric conditions. In addition, $CO_2$ fluxes decreased during the incubation under the conditions of ambient $CO_2$ and temperature. The decrease in anaerobic microbial metabolism resulted from the presence of vegetation, which influences the litter quality of soils. This can be supported by the increase in C/N ratio over the experimental duration. Principle component analysis results demonstrated the opposite locations of loadings for the cases at the initial time and after three months of incubation, which indicates a reduction in the decomposition rate and an increasing C/N ratio during the incubation. From the distribution between the decomposition rate and gas fluxes, we concluded that anaerobic decomposition rates do not have a significantly positive relationship with the fluxes of greenhouse gas emissions from the soil.

Application of Carbon Tracking System based on Ensemble Kalman Filter on the Diagnosis of Carbon Cycle in Asia (앙상블 칼만 필터 기반 탄소추적시스템의 아시아 지역 탄소 순환 진단에의 적용)

  • Kim, JinWoong;Kim, Hyun Mee;Cho, Chun-Ho
    • Atmosphere
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    • v.22 no.4
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    • pp.415-427
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    • 2012
  • $CO_2$ is the most important trace gas related to climate change. Therefore, understanding surface carbon sources and sinks is important when seeking to estimate the impact of $CO_2$ on the environment and climate. CarbonTracker, developed by NOAA, is an inverse modeling system that estimates surface carbon fluxes using an ensemble Kalman filter with atmospheric $CO_2$ measurements as a constraint. In this study, to investigate the capability of CarbonTracker as an analysis tool for estimating surface carbon fluxes in Asia, an experiment with a nesting domain centered in Asia is performed. In general, the results show that setting a nesting domain centered in Asia region enables detailed estimations of surface carbon fluxes in Asia. From a rank histogram, the prior ensemble spread verified at observational sites located in Asia is well represented with a relatively flat rank histogram. The posterior flux in the Eurasian Boreal and Eurasian Temperate regions is well analyzed with proper seasonal cycles and amplitudes. On the other hand, in tropical regions of Asia, the posterior flux does not differ greatly from the prior flux due to fewer $CO_2$ observations. The root mean square error of the model $CO_2$ calculated by the posterior flux is less than the model $CO_2$ calculated by the prior flux, implying that CarbonTracker based on the ensemble Kalman filter works appropriately for the Asia region.

Spatio-Temporal Monitoring of Soil CO2 Fluxes and Concentrations after Artificial CO2 Release (인위적 CO2 누출에 따른 토양 CO2 플럭스와 농도의 시공간적 모니터링)

  • Kim, Hyun-Jun;Han, Seung Hyun;Kim, Seongjun;Yun, Hyeon Min;Jun, Seong-Chun;Son, Yowhan
    • Journal of Environmental Impact Assessment
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    • v.26 no.2
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    • pp.93-104
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    • 2017
  • CCS (Carbon Capture and Storage) is a technical process to capture $CO_2$ from industrial and energy-based sources, to transfer and sequestrate impressed $CO_2$ in geological formations, oceans, or mineral carbonates. However, potential $CO_2$ leakage exists and causes environmental problems. Thus, this study was conducted to analyze the spatial and temporal variations of $CO_2$ fluxes and concentrations after artificial $CO_2$ release. The Environmental Impact Evaluation Test Facility (EIT) was built in Eumseong, Korea in 2015. Approximately 34kg $CO_2$ /day/zone were injected at Zones 2, 3, and 4 among the total of 5 zones from October 26 to 30, 2015. $CO_2$ fluxes were measured every 30 minutes at the surface at 0m, 1.5m, 2.5m, and 10m from the $CO_2$ releasing well using LI-8100A until November 13, 2015, and $CO_2$ concentrations were measured once a day at 15cm, 30cm, and 60cm depths at every 0m, 1.5m, 2.5m, 5m, and 10m from the well using GA5000 until November 28, 2015. $CO_2$ flux at 0m from the well started increasing on the fifth day after $CO_2$ release started, and continued to increase until November 13 even though the artificial $CO_2$ release stopped. $CO_2$ fluxes measured at 2.5m, 5.0m, and 10m from the well were not significantly different with each other. On the other hand, soil $CO_2$ concentration was shown as 38.4% at 60cm depth at 0m from the well in Zone 3 on the next day after $CO_2$ release started. Soil $CO_2$ was horizontally spreaded overtime, and detected up to 5m away from the well in all zones until $CO_2$ release stopped. Also, soil $CO_2$ concentrations at 30cm and 60cm depths at 0m from the well were measured similarly as $50.6{\pm}25.4%$ and $55.3{\pm}25.6%$, respectively, followed by 30cm depth ($31.3{\pm}17.2%$) which was significantly lower than those measured at the other depths on the final day of $CO_2$ release period. Soil $CO_2$ concentrations at all depths in all zones were gradually decreased for about 1 month after $CO_2$ release stopped, but still higher than those of the first day after $CO_2$ release stared. In conclusion, the closer the distance from the well and the deeper the depth, the higher $CO_2$ fluxes and concentrations occurred. Also, long-term monitoring should be required because the leaked $CO_2$ gas can remains in the soil for a long time even if the leakage stopped.

Experimental Study on Effects of PAG Oil for $CO_2$ Evaporation Heat Transfer (PAG 오일이 $CO_2$ 증발열전달에 미치는 영향에 관한 실험적 연구)

  • Lee, Sang-Jae;Kim, Dae-Hoon;Choi, Jun-Young;Lee, Jae-Heon;Kwon, Young-Chul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.5
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    • pp.357-363
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    • 2008
  • In order to investigate $CO_2$ heat transfer coefficient and pressure drop by PAG oil concentration during $CO_2$ evaporation, the experiment on evaporation heat transfer characteristics in a horizontal micro-fin tube was performed. The experimental apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiment was conducted for various mass fluxes($400{\sim}1200\;kg/m^2s$), heat fluxes($10{\sim}30\;kW/m^2$) and saturation temperatures ($-5{\sim}5^{\circ}C$), and PAG oil concentration($0{\sim}5\;wt%$). The variation of the heat transfer coefficient was different in accordance with the oil concentration. With the increase of the oil concentration, the evaporation heat transfer coefficient decreased and the delay of dryout by oil addition was found. Pressure drop increased with the increase of the oil concentration and heat flux, and the decrease of saturation temperature.

An Experimental Study on the Evaporative Heat Transfer Characteristics of $CO_2$/Propane Mixtures Flowing Upward in Vertical Smooth and Micro-fin Tubes with an Outer Diameter of 5 mm (외경 5mm 수직 평활관 및 마이크로핀관 내의 이산화탄소/프로판 혼합냉매의 증발열전달 특성에 관한 실험적 연구)

  • Cho, Jin-Min;Kim, Min-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.4
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    • pp.243-251
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    • 2009
  • Refrigerant mixtures provide an opportunity to adjust their properties to fit design criteria and a possibility to create new blends that can improve heat transfer characteristics. Therefore, mixture of $CO_2$ and propane is chosen which may be a promising refrigerant and has good environmental compatibility. This paper presents measured heat transfer coefficient data during evaporation process of $CO_2$/propane mixtures flowing upward in vertical smooth and. micro-fin tubes. Smooth and micro-fin tubes with outer diameters of 5 mm and length of 1.44in were selected as test tubes. The tests were conducted at mass fluxes of 212 to $656kg/m^{2}s$, inlet temperatures of -10 to $30^{\circ}C$, heat fluxes of 15 to $60\;kW/m^2$ and for several compositions (75/25, 50/50, 25/75 wt%). Among $CO_2$/propane refrigerant mixtures, the heat transfer characteristics are much better than that of any compositions when the composition is 75/25 (wt%).

Effects of Different Averaging Operators on the Urban Turbulent Fluxes (평균 방법이 도시 난류 플럭스에 미치는 영향)

  • Kwon, Tae Heon;Park, Moon-Soo;Yi, Chaeyeon;Choi, Young Jean
    • Atmosphere
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    • v.24 no.2
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    • pp.197-206
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    • 2014
  • The effects of different averaging operators and atmospheric stability on the turbulent fluxes are investigated using the vertical velocity, air temperature, carbon dioxide concentration, and absolute humidity data measured at 10 Hz by a 3-dimensional sonic anemometer and an open-path $CO_2/H_2O$ infrared gas analyzer installed at a height of 18.5 m on the rooftop of the Jungnang KT building located at a typical residential area in Seoul, Korea. For this purpose, 7 different averaging operators including block average, linear regression, and moving averages during 100 s, 300 s, 600 s, 900 s, and 1800 s are considered and the data quality control procedure such as physical limit check and spike removal is also applied. It is found that as the averaging interval becomes shorter, turbulent fluxes computed by the moving average become smaller and the ratios of turbulent fluxes computed by the 100 s moving average to the fluxes by the 1800 s moving average under unstable stability are smaller than those under neutral stability. The turbulent fluxes computed by the linear regression are 85~92% of those computed by the 1800 s moving average and nearly the same as those computed by 900 s moving average, implying that the adequate selection of an averaging operator and its interval will be very important to estimate more accurate turbulent fluxes at urban area.

Development of $Al_2O_3-SiC-C$ Refractory for Hot Metal Pretreatment (용선예비처리용 $Al_2O_3-SiC-C$계 내화물 개발)

  • 김의호;이석한;이석향;서병길;박정민;이재옥
    • Journal of the Korean Ceramic Society
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    • v.23 no.5
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    • pp.86-92
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    • 1986
  • As there is a growing trend to make high quality steel improving production efficiency and utilizing slag as resources the technologies of hot metal pretreatment have been progressed to meet these demands. Although mill scale $Na_2CO_3$ and CaO used as fluxes proved to be excellent agents then can severely corrode refractories such as chamotte and high alumina for torpedo or open ladle car. Thus it was considered necessary to develop new refractories which can endure suchy conditions. Desulfurization fluxes vastly used in POSCO are $CaCO_3$ and CaO Recent trials have been made by testing phenol resin bonded $Al_2O_3-SiC-C$ bricks in torpedo ladle car for hot metal pretreatment. The results showed that the life of this brick became about 1.2 times longer than that of foreign products. And the crushing strength M.O.R corrosion resistance and oxidation resistance were tested.

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PDR Model : Test and fit observed data Obtained by Herschel PACS

  • Yun, Hyeong-Sik;Lee, Jeong-Eun;Lee, Seokho
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.81.1-81.1
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    • 2014
  • We utilized a 2-D PDR code developed by Lee et al. (2014) to explore the observed OH line fluxes toward embedded protostars. This 2-D PDR code combines self-consistently the FUV radiative transfer, gas-energetics, chemistry, and line radiative transfer. We modeled two sources, GSS30-IRS1 and Elias29, which show conspicuous line emission in the Herschel/PACS wavelength range. The physical and chemical structure for a given embedded source was derived by fitting the PACS CO line fluxes. After exploring various parameter spaces, we conclude that IR-pumping effect either by the central IR source and dust in-situ is insignificant for OH emission, unlike previous studies. We here present a possible solution for the observed OH fluxes, which require a high OH abundance and temperature at the inner-part of the UV heated cavity wall.

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Experimental Study on Evaporation Heat Transfer and Oil Effect in Micro-fin Tube Using $CO_2$ (마이크로핀관 내 $CO_2$의 증발 열전달과 오일 영향에 관한 실험적 연구)

  • Lee, Sang-Jae;Choi, Jun-Young;Lee, Jae-Heon;Kwon, Young-Chul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.2
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    • pp.106-112
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    • 2008
  • In this paper, the experimental results on evaporation heat transfer characteristics were reported for a micro-fin tube using $CO_2$. An experimental refrigerant loop had been established to measure the evaporation heat transfer coefficient and pressure drop of $CO_2$. Experiments were conducted for mass fluxes, heat fluxes, saturation temperatures and PAG oil concentrations. With increasing the heat flux and the saturation temperature, the evaporation heat transfer coefficient increased. At the higher mass flux, however, the exit vapor quality of the micro-fin tube was to be lower. The peak of the heat transfer coefficient was shifted toward low quality region. The evaporation pressure drop increased as the mass flux increased and the saturation temperature decreased. As PAG oil concentration increased, the evaporation heat transfer coefficient decreased and the dryout was delayed by oil addition.

Development and Validation of Hourly Based Sim-CYCLE Fine in a Temperate C3//C4 Coexisting Grassland

  • Lee, G.Z.;Lee, P.Z.;Kim, W.S;Oikawa, T.
    • The Korean Journal of Ecology
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    • v.28 no.6
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    • pp.353-363
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    • 2005
  • We developed a local-scale ecophysiological model, Sim-CYCLE Fine by modifying Sim-CYCLE which was developed for a global scale simulation. Sim-CYCLE fine is able to simulate not only carbon fluxes but also plant growth with various time-steps from an hour to a month. The model outputs of $CO_2$ flux and biomass/LAI were highly reliable; we validated the model results with measurements from the eddy covariance technique and the harvest method ($R^2$ values of around 0.9 for both). The results suggested that the phonology and the seasonal dynamics of the $C_3/C4$ plant communities affected significantly the carbon fluxes and the plant growth during the plant growing season.