• Title/Summary/Keyword: $CO_2$ conversion

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Two-stage Enzymatic Conversion of Lactose to Galactooligosaccharides by Two-type ${\beta}-galactosidases$ (두 종류 ${\beta}-galactosidases$ 의 이단 반응을 이용한 갈락토올리고당의 제조)

  • In, Man-Jin;Kim, Min-Hong;Chae, Hee-Jeong
    • Korean Journal of Food Science and Technology
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    • v.29 no.2
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    • pp.376-378
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    • 1997
  • In an attempt to increase the conversion of lactose to galactoligosaccharides, two types of ${\beta}-galactosidases$ originated from Thermus caldophilus and Bacillus sp. A4442 reacted with 60% (w/w) lactose consecutively. Concentration of galactooligosaccharides reached up to 60% at the 85% conversion of the initial lactose maintaining transgalactosylation ratio ca. 90%.

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Effect of Titanium Dioxide in BaO-ZnO-B2O3-SiO2 Glasses on the Optical Properties of Color Conversion Glass (BaO-ZnO-B2O3-SiO2계 유리에서 TiO2의 첨가가 색변환 유리의 광특성에 미치는 영향)

  • Jeong, HyeonJin;Lim, Tae-Young;Kim, Jin-Ho;Lee, MiJai;Hwang, Jonghee;Hwang, Pyeong Ha;Park, Tae-Ho;Shin, Dongwook
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.710-714
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    • 2014
  • The effect of titanium dioxide ($TiO_2$) on the properties of color conversion glasses was examined for glasses based on $BaO-ZnO-B_2O_3-SiO_2$. One glass sample, containing 25 mol% of each component, was used as a reference; the other three glass samples contained 1, 3, and 5 mol% $TiO_2$, respectively. The four color conversion glass samples were prepared by sintering a mixture of glass frits and a $YAG:Ce^+$ phosphor. The characteristics of the color conversion glass samples, such as luminous efficacy, luminance, CIE (Commission International de I'Eclairage) chromaticity, CCT (Correlated Color Temperature), and CRI (Color Rendering Index) were analyzed according to the PL spectrum. The refractive index of the glass samples was found to increase with the titanium dioxide content. In conclusion, luminous efficacy of color conversion glasses increased as the content of $TiO_2$ was raised in the glass matrix.

Ergonomic evaluation of stereoscopic contents for a museum exhibition

  • Abe, N.;Ohta, K.;Kawai, T.;Ando, K.;Kakinuma, T.;Fujita, K.;Kudo, N.
    • Journal of Information Display
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    • v.12 no.3
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    • pp.159-165
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    • 2011
  • This research entailed the production of stereoscopic 3D (S3D) contents using 2D-to-S3D conversion for exhibition at a museum and subjective evaluation. Hybrid production combining S3D images of existing live-action videos using the 2D-to-S3D conversion technology and computer graphic ones created via stereo rendering was conducted. Design and control of the chronological analysis of the parallactic angle was conducted on the produced contents, using binocular information as well as subjective evaluations, with the intent of conducting an investigation on the characteristics of such contents from the perspectives of the producers and viewers. An investigation was also conducted on the effects of the viewing position on the impressions of the S3D images.

Performance Evaluation of Diesel Oxidation Catalysts for Diesel Vehicles (디젤자동차용 산화촉매의 성능 평가)

  • 최병철;박희주;정명근
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.6
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    • pp.59-64
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    • 2003
  • Recently, as people pay attention to the environmental pollution, the emissions of diesel engine have been a serious problem. We carried out the performance evaluation test of Diesel Oxidation Catalysts (DOC) for HSDI diesel engine equipped vehicles. The DOC, basically coated with Pt catalyst, was manufactured with various washcoat materials. It was found that CO conversion efficiency depends on temperature, but THC conversion efficiency is dominated by temperature and space velocity. The THC and CO conversion efficiencies of aged catalysts were increased with additions of $ZrO_2$ and zeolite B in the washcoat. We found that DOC performance changes with coating techniques, even through it has same washcoat materials. The DOC coated by high temperature washcoat coating technology showed good conversion efficiency than low temperature washcoat coated DOC.

Improvement of $\lambda$--window Range of the Three-Way Catalyst for Natural Gas Vehicles (천연가스 자동차용 삼원촉매의 $\lambda$-윈도우 영역 개선)

  • 최병철;정필수
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.1
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    • pp.92-100
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    • 2000
  • The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

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Operation Characteristics of Coal Syngas Production and DME Conversion Facilities (석탄 합성가스 제조 및 화학원료(DME) 전환설비의 운전 특성)

  • Chung, Seok-Woo;Kim, Mun-Hyun;Lee, Seung-Jong;Yun, Yong-Seung
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.83-86
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    • 2006
  • In this study, the syngas producing facility that consists of pulverized coal feeding/gasification and hot gas clean-up system was tested for Indonesian subbituminous coal. And the DME conversion facilities have been developed and tested for converting syngas to DME by reactions with catalysts. So, the entrained-bed slagging type pi lot scale coal gasifier was operated normally in the temperature range of $1,400{\sim}1,450^{\circ}C,\;7{\sim}8kg/cm^2$ pressure. And Roto middle coal produced syngas that has a composition of $36{\sim}38%$ CO, $14{\sim}16%\;H_2,\;and\;5{\sim}8%\;CO_2$. Particulates in syngas were 99.8% removed by metal filters. $H_2S$ composition in syngas was also desulfurized by the Fe chelate system to yield less than 0.1 ppm level. When the clean syngas $70{\sim}100 Nm^3/h$ was provided to DME conversion rector, normally operated in the temperature range of $230{\sim}250^{\circ}C$ and $60kg/cm^2$ pressure, 4.5% DME was yielded.

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Hydrogen Gas Production from Biogas Reforming using Plasmatron (플라즈마트론을 이용한 바이오가스 개질로부터 수소생산)

  • Kim, Seong Cheon;Chun, Young Nam
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.528-534
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    • 2006
  • The purpose of this paper is to investigate the optimal operating condition for the hydrogen production by biogas reforming using the plasmatron induced thermal plasma. The component ratio of biogas($CH_4/CO_2$) produced by anaerobic digestion reactor were 1.03, 1.28, 2.12, respectively. And the reforming experiment was performed. To improve hydrogen production and methane conversion rates, parametric screening studies were conducted, in which there are the variations of biogas flow ratio(biogas/TFR: total flow rate), vapor flow ratio($H_2O/TFR$: total flow rate) and input power. When the variations of biogas flow ratio, vapor flow ratio and input power were 0.32~0.37, 0.36~0.42, and 8 kW, respectively, the methance conversion reached its optimal operating condition, or 81.3~89.6%. Under the condition mentioned above, the wet basis concentrations of the synthetic gas were H2 27.11~40.23%, CO 14.31~18.61%. The hydrogen yield and the conversion rate of energy were 40.6~61%, 30.5~54.4%, respectively, the ratio of hydrogen to carbon monoxide($H_2/CO$) was 1.89~2.16.

Effect of Additives for Prevention of NaBO2 Precipitation on Hydrogen Generation Properties of NaBH4 Hydrolysis (NaBO2의 석출 방지를 위한 첨가제가 NaBH4 가수분해의 수소발생특성에 미치는 영향)

  • Oh, Taekyun;Kwon, Sejin
    • Journal of Hydrogen and New Energy
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    • v.24 no.1
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    • pp.1-11
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    • 2013
  • Additives such as glycerol, methanol, acetone, and ethanol were used to prevent $NaBO_2$ from precipitation, and their effects on hydrogen generation properties of $NaBH_4$ hydrolysis were investigated. When the concentration of additives was 5 wt%, the additives such as methanol, acetone, and ethanol could not prevent $NaBO_2$ precipitation. Although glycerol prevented $NaBO_2$ precipitation, conversion efficiency decreased to 78.0% due to its viscosity. Based on test results, hydrogen generation tests were also performed at various concentration of glycerol and methanol to investigate the concentration effects on hydrogen generation properties. As the concentration of glycerol increased from 1 wt% to 3 wt%, conversion efficiency increased owing to additive effect. When its concentration increased to 5 wt%, conversion efficiency decreased due to its viscosity. As the concentration of methanol increased from 5 wt% to 10 wt%, conversion efficiency increased owing to additive effect. When its concentration increased to 15 wt%, conversion efficiency decreased due to $NaB(OCH_3)_4$ precipitate. Although conversion efficiency decreased about 1% when 3 wt% glycerol was added, $NaBO_2$ precipitation was prevented. Consequently, addition of 3 wt% glycerol to $NaBH_4$ solution improves stability of hydrogen generation system.

Impact of conversion at time of minimally invasive pancreaticoduodenectomy on perioperative and long-term outcomes: Review of the National Cancer Database

  • Jennifer Palacio;Daisy Sanchez;Shenae Samuels;Bar Y. Ainuz;Raelynn M. Vigue;Waleem E. Hernandez;Christopher J. Gannon;Omar H. Llaguna
    • Annals of Hepato-Biliary-Pancreatic Surgery
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    • v.27 no.3
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    • pp.292-300
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    • 2023
  • Backgrounds/Aims: Current literature presents limited data regarding outcomes following conversion at the time of minimally invasive pancreaticoduodenectomy (MI-PD). Methods: The National Cancer Database was queried for patients who underwent pancreaticoduodenectomy. Patients were stratified into three groups: MI-PD, converted to open pancreaticoduodenectomy (CO-PD), and open pancreaticoduodenectomy (O-PD). Multivariable modeling was applied to compare outcomes of MI-PD and CO-PD to those of O-PD. Results: Of 17,570 patients identified, 12.5%, 4.2%, and 83.4% underwent MI-PD, CO-PD, and O-PD, respectively. Robotic pancreaticoduodenectomy (R-PD) resulted in a higher lymph node yield (n = 23.2 ± 12.2) even when requiring conversion (n = 22.4 ± 13.2, p < 0.001). Margin positivity was higher in the CO-PD group (26.6%) than in the MI-PD group (21.3%) and the O-PD (22.6%) group (p = 0.017). Length of stay was shorter in the MI-PD group (laparoscopic pancreaticoduodenectomy 10.4 ± 8.6, R-PD 10.6 ± 8.8) and the robotic converted to open group (10.7 ± 6.4) than in the laparoscopic converted to open group (11.2 ± 9) and the O-PD group (11.5 ± 8.9) (p < 0.001). After adjusting for patient and tumor characteristics, both MI-PD (odds ratio = 1.40; p < 0.001) and CO-PD (odds ratio = 1.24; p = 0.020) were significantly associated with an increased likelihood of long-term survival. Conclusions: CO-PD does not negatively impact perioperative or oncologic outcomes.

CO oxidation Reaction over copper metal oxide catalysts (구리복합산화물 촉매상에서 일산화탄소의 산화반응)

  • Lee, Hak Beum;Koh, Hyoung Lim
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.129-135
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    • 2016
  • CO oxidation was performed with Cu-Mn and Cu-Zn co-precipitated catalysts as differential precipitant, metal ratio and calcination temperature. The effects of differential metal mole ratio and calcination temperature in mixed metal oxide catalyst were investigated with CO oxidation reaction. Physiochemical properties were studied by XRD, $N_2$ sorption and SEM. 2Cu-1Mn with $Na_2CO_3$ catalyst calcined at $270^{\circ}C$ has a large surface area $43m^2/g$ and the best activity for CO oxidation. $Cu_{0.5}Mn_{2.5}O_4$ in XRD peak shows the lower activity than others. The catalytic activity over the catalyst calcined $270^{\circ}C$ displayed the highest conversion, and it was better activity comparing with Pt catalysts CO conversion.