• Title/Summary/Keyword: $CO_2$ agent

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A Study on Clean Agents for Halon Replacement in the Portable Extinguisher with CO2 as an Expellant Gas (이산화탄소를 가압원으로 하는 할론대체 소화기용 청정소화약제에 대한 연구)

  • Jeong, Keesin
    • Fire Science and Engineering
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    • v.33 no.3
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    • pp.51-55
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    • 2019
  • To prevent ozone depletion caused by CFCs, the replacement of Halon with clean agents has been developed in the fire protection field along with refrigerants, detergents, and foaming agents. The alternatives for Halon 1211 have been developed in the portable fire extinguisher area and HCFC-123 is used widely as a clean fire extinguishing agent. The type of expellant gas is important because their own vapor pressure is low. In this study, HCFC-123, HCFC-124, HFC-125, and Novec-1230 were selected as fire extinguishing agents and CO2, which is expected to improve the fire extinguishing ability, was chosen as the expellant gas. For each agent, experiments changing the agent and CO2 amount were carried out and HCFC-123 showed a good result, as expected. The extinguisher, HCFC-123 of 1.5 kg, showed the same ability to suppress a class A and B fire as the extinguisher, HCFC-123 of 2.5 kg, which is currently sold on the market. According to this result, the expellant gas has a subsidiary fire extinguish effect. This can reduce the amount of HCFC fire extinguishing agent, which is categorized in the phase-out alternatives, and is a more eco-friendly and economical fire extinguisher than the previous one. This study can also help solve the problems of CO2 fire extinguishers for class B and C fires, and can be used to extinguish electric and electron facilities fire, which contains large amounts of class A fire combustibles.

CO2 Suppression Characteristics of the Nitrogen-diluted Methane Counterflow Non-premixed Flame (질소로 희석된 대향류 메탄 비예혼합화염에서 CO2에 의한 소화특성)

  • Lee, Ho-Hyun;Oh, Chang Bo;Hwang, Cheol Hong
    • Journal of the Korean Society of Safety
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    • v.28 no.2
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    • pp.42-48
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    • 2013
  • The $CO_2$ suppression characteristics and flame structure of nitrogen-diluted methane counterflow non-premixed flame were studied experimentally and numerically. To mimic a situation where combustion product gases are entrained into a compartment fire, fuel stream was diluted with $N_2$. A gas-phase suppression agent, $CO_2$, was diluted in the air-stream to investigate the suppression characteristics by the agent. For numerical simulation, an one-dimensional OPPDIF code was used for comparison with experimental results. An optically-thin radiation model(OTM) was adopted to consider radiation effects on the suppression characteristics. It was confirmed experimentally and numerically that suppression limit decreased with increasing nitrogen mole fraction in the fuel stream. A turning point was found only when a radiation heat loss was considered and the extinguishing concentration for turning point was differently predicted compared to the experiment result. Critical extinguishing concentration when neglecting radiation heat loss was also differently predicted compared with the experimental result.

Sulfuric Acid Leaching of Valuable Metals from Spent Petrochemical Catalyst using Hydrogen Peroxide as a Reducing Agent (石油化學 廢觸媒로부터 過酸化水素를 還元劑로이용한 有價金屬의 황산침출)

  • 박경호;손정수;김종석
    • Resources Recycling
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    • v.10 no.2
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    • pp.20-26
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    • 2001
  • Sulfuric acid leaching of Mn, Co and Fe from spent petrochemical catalyst was performed using hydrogen peroxide as a reducing agent. Low extraction of Mn, Co and Fe was obtained by only sulfuric acid. When hydrogen peroxide were added as a reducing agent, the high extraction of these metals could be obtained. Different from ordinary leaching, the extraction per-centages of metal components decreased with elevating leaching temperature in this process. Under the optimum condition, the extraction percentages of Mn, Co and Fe were 93.0% , 87.0% and 100% respectively.

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A Study on the Hydrolyzed Ginseng Saponin-Quaternary and its Application in Cosmetics (가수분해된 인삼사포닌 4급 암모늄엽과 화장품으로의 응용에 관한 연구)

  • 김영대;김창규;이정남;하병조
    • Journal of Ginseng Research
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    • v.13 no.2
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    • pp.189-197
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    • 1989
  • A new quaternary ammonium compound, hydrolyzed ginseng-saponin quaternary (HGSQ), from Korean ginseng saponin and 2,3-epoxypropyltrimethylammonium chloride has been developed as a conditioning agent in cosmetics. This structure has a hydrophobic group from the aglycone of ginseng saponin which is biologically active and considered to be the most important component of the Korean ginseng. Its properties : surface tension, critical micelle concentration (CMC), eye irritation, sorption onto hair, force reduction(%) and moisture retention effect were studied. Its cationic character allows the molecule to be more substantive than ginseng saponin. HGSQ had good physical properties and was safe. enough as a cosmetic raw material. Also half-head tests of HGSQ-containing shampoo were carried out to compare the conditioning effects in shampoos. HGSQ was an excellent conditioning agent in shampoo..

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Fabrication of Magnesium Alloy Foam Through $TiH_2$ and $CaCO_3$ ($TiH_2$$CaCO_3$를 이용한 마그네슘 합금의 제조)

  • Seo, Chang-Hwan;Seong, Hwan-Goo;Yang, Dong-Hui;Park, Soo-Han;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.26 no.6
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    • pp.267-271
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    • 2006
  • Metal foam is a class of attractive materials, which exhibits unique combinations of physical, mechanical, thermal, electrical and acoustic properties. In particular, it is light and good at absorbing energy, which makes it attractive in automotive and aerospace applications weight is critical. In this paper, the Mg alloy foam was prepared by melt foaming method by addition of calcium as thickening agent, and $TiH_2$ or $CaCO_3$ powder as blowing agent. The macrostructural observation of foamed Mg showed that the pore structures of Mg alloy foam made by $CaCO_3$ as blowing agent were much better than that of foams made by $TiH_2$ as blowing agent. In addition, this paper showed the possible reason of fabrication magnesium alloy foam in proportion to blowing agent and the porosity range was about 40 to 76% as results value.

3D-QSAR Study of Competitive Inhibitor for Acethylcholine Esterase (AChE) Nerve Agent Toxicity

  • San Juan, Amor A.;Cho, Seung-Joo
    • Molecular & Cellular Toxicology
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    • v.2 no.3
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    • pp.216-221
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    • 2006
  • The cholinesterase-inhibiting organophosphorous (OP) compounds known as nerve agents are highly toxic. The principal toxic mechanism of OP compounds is the inhibition of acethylcholine esterase (AChE) by phosphorylation of its catalytic site. The reversible competitive inhibition of AChE may prevent the subsequent OP intoxication. In this study, three-dimensional quantitative structure-activity relationship (3D-QSAR) was performed to investigate the relationship between the 29 compounds with structural diversity and their bioactivities against AChE. In particular, predictive models were constructed using the comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA). The results indicate reasonable model for CoMFA ($q^{2}=0.453,\;r^{2}=0.697$) and CoMSIA ($q^{2}=0.518,\;r^{2}=0.696$). The presence of steric and hydophobic group at naphtyl moiety of the model may lead to the design of improved competitive inhibitors for organophosphorous intoxication.

DW1350, a Newly Synthetic Anti-osteoporotic Agent: 2. Effect on Ovariectomized Osteoporosis Rat Model, a Histomorphometrical Aspect

  • Lee, Jin-Soo;Ku, Sae-Kwang;Jung, Da-Hee;Jin, Youn-Goo;Park, Jae-Hoon;Yang, Hee-Bok;Jung, Yong-Ho;Ryu, Jei-Man
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.155.1-155.1
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    • 2003
  • In the present study, the effect of DW-1350, a newly synthesized anti-osteoporotic agent, was evaluated in ovariectomized Rat. Female SD Rat mice underwent bilateral ovariectomy for prevention study that test article was administered from 2 days after ovariectomy for 6 weeks, for therapeutic study it was conducted from 6 weeks after ovariectomy for three months. (omitted)

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Preparation of the Nano Cobalt Powder by Wet Chemical Reduction Method (액상환원공정을 이용한 나노 코발트 분말의 합성)

  • Hong, Hyun-Seon;Ko, Young-Dae;Kang, Lee-Seung;Kim, Geon-Hong;Jung, Hang-Chul
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.244-249
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    • 2011
  • Spherical nanosized cobalt powder with an average size of 150-400 nm was successfully prepared at room temperature from cobalt sulfate heptahydrate ($CoSO_4{\cdot}7H_2O$). Wet chemical reduction method was adopted to synthesize nano cobalt powder and hypophosphorous acid ($H_3PO_2$) was used as reduction agent. Both the HCP and the FCC Co phase were developed while $CoSO_4{\cdot}7H_2O$ concentration ranged from 0.7 M to 1.1 M. Secondary phase such as $Co(OH)_2$ and $CO_3O_4$ were also observed. Peaks for the crystalline Co phase having HCP and FCC structure crystallized as increasing the concentration of $H_3PO_2$, indicating that the amount of reduction agent was enough to reduce $Co(OH)_2$. Consequently, a homogeneous Co phase could be developed without second phase when the $H_3PO_2/CoSO_4{\cdot}7H_2O$ ratio exceeded 7.

Human Chorionic Gonadotropin (hCG) Regression Curve for Predicting Response to EMA/CO (Etoposide, Methotrexate, Actinomycin D, Cyclophosphamide and Vincristine) Regimen in Gestational Trophoblastic Neoplasia

  • Rattanaburi, Athithan;Boonyapipat, Sathana;Supasinth, Yuthasak
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.12
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    • pp.5037-5041
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    • 2015
  • Background: An hCG regression curve has been used to predict the natural history and response to chemotherapy in gestational trophoblastic disease. We constructed hCG regression curves in high-risk gestational trophoblastic neoplasia (GTN) treated with EMA/CO and identified an optimal hCG level to detect EMA/CO resistance in GTN. Materials and Methods: Eighty-one women with GTN treated with EMA/CO were classified as primary high-risk GTN (n = 65) and single agent-resistance GTN (n = 16). The hCG levels prior to each course of chemotherapy were plotted in the 10th, 50th, and 90th percentiles to construct the hCG regression curves. Diagnostic performance was evaluated for an optimal cut-off value. Results: The median hCG levels were 264,482 mIU/mL mIU/mL and 495.5 mIU/mL mIU/mL for primary high-risk GTN and single agent-resistance GTN, respectively. The 50th percentile of the hCG level in primary high-risk GTN and single agent-resistance turned to normal before the 4th and the 2nd course of chemotherapy, respectively. The 90th percentile of the hCG level in primary high-risk GTN and single agent-resistance turned to normal before the 9th and the 2nd course of chemotherapy, respectively. The hCG level of ${\geq}118.6mIU/mL$ mIU/mL at the 5thcourse of EMA/CO predicted the EMA/CO resistance in primary high-risk GTN patients with a sensitivity of 85.7% and a specificity of 100%. Conclusion: EMA/CO resistance in primary high-risk GTN can be predicted by using an hCG regression curve in combination with the cut-off value of 118.6 mIU/mL at the 5thcourse of chemotherapy.

The Effect of the Mixture of Nonionic Surfactant and Bioactive Agent for Surfactant-enhanced Soil Flushing (SESF) of TCB Contaminated Soil

  • Lee, Dal-Heui;Cho, Heuy Nam;Chung, Sung-Lae
    • Journal of Soil and Groundwater Environment
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    • v.19 no.2
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    • pp.1-6
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    • 2014
  • The objective of this study was to find the effect of the mixture of the nonionic surfactant and bioactive agent that solubilizes trichlorobenzene (TCB) present as a contaminant for surfactant-enhanced soil flushing (SESF). Three different nonionic surfactants and two different bioactive agents were obtained from four companies. Separate funnel experiments and shaker table agitation / centrifugation experiments were used for the test. Based on the separate funnel experimental results, three suitable mixture agents (APG + OSE, Brij 35 + MOSE, T-Maz 60 + MOSE) were selected. In the shaker table agitation / centrifugation experiments, these three different mixture agents were reduced to one (T-Maz 60 +MOSE). The maximum removal (95%) of TCB was obtained using a mixture of the nonionic surfactant and bioactive agent. Therefore, the used test methods and results can be used for SESF.