• Title/Summary/Keyword: $CO_2$ Transport

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Podand-Mediated Transport of $Ag^+$ in a Bulk Liquid Membrane System

  • 조문환;이상철;양승창;신송석;김경태
    • Bulletin of the Korean Chemical Society
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    • v.17 no.12
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    • pp.1109-1111
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    • 1996
  • The Podand Ⅰ (Figure 1) has been studied as cation carrier in a bulk liquid membrane system. Ag+ and some other transition metal ions (M2+=Cu, Ni, Co, Zn, and Cd) have been transported using the podand as carrier in a bulk liquid membrane system. Studies on the transport of equimolar mixtures of two or three competing components have also been carried out with the same system. Ag+ exhibited a higher transport rate than the other M2+ in the competitive experiments. Ligand structure and the equilibrium constant for complex formation are important parameters in the transport of the metal ions.

High efficiency and long lifetime green OLED with a new electron transport material and a three-component RGB white OLED for full-color display applications.

  • Tokairin, Hiroshi;Kuma, Hitoshi;Yamamoto, Hiroshi;Funahashi, Masakazu;Fukuoka, Kenichi;Hosokawa, Chishio
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1138-1142
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    • 2005
  • We achieved a highly efficient green OLED with an efficiency of 30cd/A by using a new electron transport material and optimizing the device structure. The luminous efficiency was 16.8lm/W at $3000cd/m^2$ and the lifetime was over 60,000hr at an initial luminance of $1000cd/m^2$. Furthermore, we obtained a threecomponent RGB white OLED by using the highly efficient green material. This RGB white OLED shows more excellent color reproducibility for full color displays with color filters, compared to a twocomponent white OLED.

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Studies on the Macrocycle-mediated Transport of Divalent Metal Ions in a Supported Liquid Membrane System

  • 조문환;신상철
    • Bulletin of the Korean Chemical Society
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    • v.16 no.1
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    • pp.33-36
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    • 1995
  • Macrocyclic ligands have been studied as cation carriers in a supported liquid membrane system. Cd2+ has been transported using nitrogen substituted macrocycles as carriers and several divalent metal ions (M2+=Zn, Co, Ni, Cu, Pb, Mg, Ca, and Sr) have been transported using DBN3O2, DBN2O2and PolyNtnoen as carriers in a supported liquid membrane system. Competitive Cd2+-M2+ transport studies have also been carried out with the same system. Ligand structure, stability constant, membrane solvent and carrier concentration are also important parameters in the transport of metal ions.

Process Design of Carbon Dioxide Storage in the Marine Geological Structure: II. Effect of Thermodynamic Equations of State on Compression and Transport Process (이산화탄소 해양지중저장 처리를 위한 공정 설계: II. 열역학 상태방정식이 압축 및 수송 공정에 미치는 영향 평가)

  • Huh, Cheol;Kang, Seong-Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.4
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    • pp.191-198
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    • 2008
  • To design a reliable $CO_2$ marine geological storage system, it is necessary to perform numerical process simulation using thermodynamic equation of state. $CO_2$ capture process from the major point sources such as power plants, transport process from the capture sites to storage sites and storage process to inject $CO_2$ into the deep marine geological structure can be simulate with numerical modeling. The purpose of this paper is to compare and analyse the relevant equations of state including ideal, BWRS, PR, PRBM and SRK equation of state. We also studied the effect of thermodynamic equation of state in designing the compression and transport process. As a results of comparison of numerical calculations, all relevant equation of state excluding ideal equation of state showed similar compression behavior in pure $CO_2$. On the other hand, calculation results of BWRS, PR and PRBM showed totally different behavior in compression and transport process of captured $CO_2$ mixture from the oxy-fuel combustion coal-fired plants. It is recommended to use PR or PRBM in designing of compression and transport process of $CO_2$ mixture containing NO, Ar and $O_2$.

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Prediction of Transport Properties for Transportation of Captured CO2. 1. Viscosity (수송조건 내 포집 이산화탄소의 전달물성 예측. 1.점성)

  • Lee, Won Jun;Yun, Rin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.4
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    • pp.195-201
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    • 2017
  • In this study, the viscosity of a $CO_2-gas$ mixture was investigated for the transportation of the captured $CO_2-gas$ in pipelines and for the designing of a thermal system, both of which involve the utilization of the $CO_2-gas$ mixture. The viscosities of the $CO_2-gas$ mixture, $CO_2+CH_4$, $CO_2+H_2S$, and $CO_2+N_2$ were predicted using three different models as follows : Chung, TRAPP, and REFPROP. The predictability values of the models were validated by comparing the estimated results with the experiment data for the $CO_2+CH_4$ and $CO_2+N_2$ under high-density conditions. The Chung model showed 2.41%, which is the lowest mean deviation of the prediction among the model. Based on the Chung model, the mixture mole fractions were changed from 0.9, 0.95, and 0.97, the mixture pressure was ranged from 80 bar to 120 bar by 10 bar, and the mixture temperature was varied from 310 K to 400 K by 10 K to observe the effects of the parameters on the mixture viscosity. Considering the high mole fraction of the $CO_2$ in the mixture, a significant variation of the mixture viscosity was observed close to the pseudo-critical temperature, and the viscosity for the $CO_2+H_2S$ mixture shows the highest values compared with those of the $CO_2+CH_4$ and $CO_2+N_2$.

A Preliminary Drop Test of a Type IP-2 Transport Package with a Bolted Lid Type (볼트체결방식의 IP-2형 운반용기의 낙하예비시험)

  • Kim Dong-Hak;Seo Ki-seog;Park Hong Yun;Lee Kyung Ho;Yoon Jeong-Hyoun;Lee Heung-Young
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11a
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    • pp.339-347
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    • 2005
  • A type IP-2 transport package should prevent a loss or dispersal of the radioactive contents and a more than $20\%$ increase in the maximum radiation level at any external surface of the package when it were subjected to the drop test under the normal conditions of transport. If a shielding thickness of IP-2 transport package is thick, a bolted lid type may prevent a loss or dispersal of the radioactive contents than the door type of ISO containers which are generally used as a type IP-2 transport package. In this paper, to evaluate the effect of drop directions on the bolt tension and the coherence of a bolt, the drop tests of preliminary small model are tested and evaluated for seven directions before the drop test of a type IP-2 transport package with a bolted lid type under the normal conditions of transport. Seven drop directions which are a bottom-vertical drop, a lid-vortical drop. a horizontal drop and four corner drops have been carried out. Using a force sensor, the bolt tension during the drop impact is measured. The coherence of bolt is evaluated by the difference between the fastening torque of bolt before a drop test and the unfastening torque of bolt after a drop impact.

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Measurements and Assessments on Shielding Performance of FCTC10 60Co Transport Container

  • Zhuang, Dajie;Zhang, Guoqing;Li, Guoqiang;Wang, Renze
    • Journal of Radiation Protection and Research
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    • v.41 no.3
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    • pp.310-314
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    • 2016
  • Background: FCTC10 container is designed to transport $^{60}Co$ radioactive sources used in irradiation industry. It belongs to Type B(U) Category III (yellow) package when being loaded with a $^{60}Co$ source of $1.8{\times}10^5$ Ci. Materials and Methods: The container is constituted of shielding container, basket, protective cover and bracket. Shielding ability is provided mainly by stainless steel shells, tungsten alloy and lead among steel shells. Radiation level around the container has been calculated with both Monte Carlo simulations and measurements. Results and Discussion: It is proven that the shielding performance of the container fulfills the requirements in GB11806-2004 (Regulations for the safe transport of radioactive material, China Standard Press). Exposure doses to workers and to critical groups of public were calculated based on hypothetical exposure scene according to transport practice experience. Conclusion: The results show that doses to workers and public are less than the constraint dose considered in design, and the radiation level would be increased less than a factor of 2 under design basis accidents.

Temperature Dependence of Energy Gap and Thermodynamic Function Properties of Undoped and Co-doped $Cd_{4}GeSe_{6}$ Sing1e Crystals by Chemical Transport Reaction Method (화학수송법으로 성장한 $Cd_4GeSe_{6}$$Cd_{4}GeSe_{6}$ : $CO^{2+}$ 단결정에서 에너지 띠 간격의 온도의존성 및 열역학함수 추정)

  • Kim, Nam-Oh;Kim, Hyung-Gon;Kim, Duck-Tae;Hyun, Seung-Cheol;Oh, Gum-Kon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.2
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    • pp.85-90
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    • 2003
  • In this work $Cd_{4}GeSe_{6}$ and $Cd_{4}GeSe_{6}$ : $Co^{2+}$ single crystals were grown by the chemical transport reaction method and the structure of $Cd_{4}GeSe_{6}$ and $Cd_{4}GeSe_{6}$ : $Co^{2+}$ single crystals were monoclinic structure. The temperature dependence of optical energy 9ap was fitted well to Varshni equation. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gap.

RADIATION SHIELDING EVALUATION OF IP-2 PACKAGES FOR LOW- AND INTERMEDIATE-LEVEL RADIOACTIVE WASTE

  • Kim, Min-Chul;Choi, Jong-Rak;Chung, Sung-Hwan;Ko, Jae-Hoon
    • Nuclear Engineering and Technology
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    • v.40 no.6
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    • pp.511-516
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    • 2008
  • Korea Hydro & Nuclear Power Co., Ltd. (KHNP) developed new IP-2 packages to transport low- and intermediate-level radioactive waste (LILW) steel drums from nuclear power plants to a disposal facility in accordance with IAEA and Korean transport regulations of radioactive material. Radiation shielding evaluation of the packages was carried out to demonstrate compliance with the regulatory requirements for IP-2 packages of radioactive material. Dose rate limits of LILW drums contained in the packages were determined.

Impurity optical absorption of $HgGa_2S_4:CO^{2+}$ single crystals ($HgGa_2S_4:CO^{2+}$ 단결정의 불순물 광흡수)

  • Kim, H.G.;Kim, N.O.;Kim, B.C.;Choi, Y.I.;Kim, D.T.;Hyun, S.C.;Bang, T.H.;Lee, K.S.;Gu, H.B.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05c
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    • pp.3-7
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    • 2004
  • $HgGa_2S_4:CO^{2+}$ single crystal were grown by the chemical transport reaction(CTR) method. 1n the optical absorption spectrum of the $HgGa_2S_4:CO^{2+}$ single crystal measured at 298K, three groups of impurity optical absorption peaks consisting of three peaks, respectively, were observed at 673nm, 734nm, and 760nm, 1621nm, 1654nm, and 1734nm, and 2544nm, 2650nm, and 2678nm. At 10K, the three peaks(673nm, 734nm, and 760nm) of the first group were split to be twelve peaks. These impurity optical absorption peaks are assigned to be due to the electronic transitions between the split energy levels of $Co^{2+}$ sited in the $S_4$ symmetry point.

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