• Title/Summary/Keyword: $CO_2$ Storage

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Influence of oxyfluorination on activated carbon nanofibers for CO2 storage

  • Bai, Byong-Chol;Kim, Jong-Gu;Im, Ji-Sun;Jung, Sang-Chul;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.4
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    • pp.236-242
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    • 2011
  • The oxyfluorination effects of activated carbon nanofibers (OFACFs) were investigated for $CO_2$ storage. Electrospun CFs were prepared from a polyacrylonitrile/N,N-dimethylformamide solution via electrospinning and heat treatment. The electrospun CFs were chemically activated in order to generate the pore structure, and then oxyfluorination was used to modify the surface. The samples were labeled CF (electrospun CF), ACF (activated CF), OFACF-1 ($O_2:F_2$ = 7:3), OFACF-2 ($O_2:F_2$ = 5:5) and OFACF-3 ($O_2:F_2$ = 3:7). The functional group of OFACFs was investigated using X-ray photoelectron spectroscopy analysis. The C-F bonds formed on surface of ACFs. The intensities of the C-O peaks increased after oxyfluorination and increased the oxygen content in the reaction gas. The specific surface area, pore volume and pore size of OFACFs were calculated by the Brunauer-Emmett-Teller and density functional theory equation. Through the $N_2$ adsorption isotherm, the specific surface area and pore volume slightly decreased as a result of oxyfluorination treatment. Nevertheless, the $CO_2$ adsorption efficiency of oxyfluorinated ACF improved around 16 wt% due to the semi-ionic interaction effect of surface modificated oxygen functional groups and $CO_2$ molecules.

Case Study on Stability Assessment of Pre-existing Fault at CO2 Geologic Storage (CO2 지중저장 시 단층 안정성 평가)

  • Kim, Hyunwoo;Cheon, Dae-Sung;Choi, Byung-Hee;Choi, Hun-Soo;Park, Eui-Seob
    • Tunnel and Underground Space
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    • v.23 no.1
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    • pp.13-30
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    • 2013
  • Increase of pore fluid pressure resulting from injection of $CO_2$ may reactivate pre-existing faults, and the induced seismic activities can raise the safety issues such as seal integrity, restoration of storage capacity, and, in the worst case, removal of previously injected $CO_2$. Thus, fault stability and potential for $CO_2$ leakage need to be assessed at the stage of site selection and planning of injection pressure, based on the results of large-scale site investigations and numerical modeling for various scenarios. In this report, studies on the assessment of fault stability during injection of $CO_2$ were reviewed. The seismic activities associated with an artificial injection of fluids or a release of naturally trapped high-pressure fluids were first examined, and then site investigation methods for the magnitude and orientation of in situ stresses, the distribution and change of pore fluid pressure, and the location of faults were generally summarized. Recent research cases on possibility estimation of fault reactivation, prediction of seismic magnitude, and modeling of $CO_2$ leakage through a reactivated fault were presented.

Changes of Physico-Characteristics in Green Pumpkin during Storage by Packaging Material and Method (포장재질 및 방법에 따른 애호박의 저장 중 품질변화)

  • Lee, Jin-Won;Shin, Hye-Seoung;Lee, Kyung-Hee;Park, Jang-Woo
    • Korean Journal of Food Science and Technology
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    • v.41 no.4
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    • pp.374-379
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    • 2009
  • In this study, we investigated effects of different packaging materials and methods on physico-characteristics of green pumpkin during storage at $10^{\circ}C$. Whole green pumpkin samples were packaged with polyvinyl chloride film (PVCF), orange coating film (OCF), paraffin film (PF), or paper with paraffin film (PWPF) and stored at $10^{\circ}C$. Weight loss, pH, firmness, browning, and gas composition ($O_2$ and $CO_2$) inside the film packages were evaluated. All characteristics of the unpackaged group (control group, CON) changed rapidly and lost marketability as compared with the packed pumpkin group. The pH values in all of the green pumpkin samples were between 6.38 and 6.67, and decreased with increased storage time. Over the storage time, all packaged pumpkin groups evidenced prevented or retarded deterioration of the green pumpkin samples in terms of appearance, texture, and discoloration. Firmness decreased slightly with increased storage time. Brown color difference were much higher in the controls than in the film-packaged green pumpkin samples, and increased rapidly in the early stages of storage. These results were attributed to reduce respiration rates as a result of elevated carbon dioxide and reduced oxygen levels in the packages. The results of this study demonstrated that the green pumpkin packaged with PWPF and PVCF showed retarded deterioration as compared to the CON, OCF and PF samples in a controlled atmosphere, and thus significant differences were noted according to the packaging material and methods used.

CO2 Capture & Separation in Microporous Materials: A Comparison Between Porous Carbon and Flexible MOFs (다공성 물질을 이용한 CO2 포집 및 분리: 다공성 탄소와 유연한 MOF 비교 연구)

  • Jung, Minji;Park, Seoha;Oh, Hyunchul;Park, Kwi-il
    • Korean Journal of Materials Research
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    • v.28 no.7
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    • pp.417-422
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    • 2018
  • The stereotype of flexible MOFs(Amino-MIL-53) and carbonized porous carbon prepared from renewable resources is successfully synthesized for $CO_2$ reduction application. The textural properties of these microporous materials are investigated, and their $CO_2$ storage capacity and separation performance are evaluated. Owing to the combined effects of $CO_2-Amino$ interaction and its flexibility, a $CO_2$ uptake of $2.5mmol\;g^{-1}$ is observed in Amino-MIL-53 at 20 bar 298 K. In contrast, $CH_4$ uptake in Amino-MIL-53 is very low up to 20 bar, implying potential sorbent for $CO_2/CH_4$ separation. Carbonized samples contain a small quantity of metal residues(K, Ca, Mg, S), resulting in naturally doped porous carbon. Due to the trace metal, even higher $CO_2$ uptake of $4.7mmol\;g^{-1}$ is also observed at 20 bar 298 K. Furthermore, the $CH_4$ storage capacity is $2.9mmol\;g^{-1}$ at 298 K and 20 bar. To evaluate the $CO_2$ separation performance, the selectivity based on ideal adsorption solution theory for $CO_2/CH_4$ binary mixtures on the presented porous materials is investigated.

Carbon Uptake and Emissions in Urban Landscape, and the Role of Urban Greenspace for several Cities in Kangwon Province (강원도 일부도시의 경관내 탄소흡수 및 배출과 도시녹지의 역할)

  • 조현길
    • Journal of the Korean Institute of Landscape Architecture
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    • v.27 no.1
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    • pp.39-53
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    • 1999
  • This study quantified carbon uptake and emissions in urban landscape, and the role of urban greenspace in atmospheric carbon reduction for several cities of Chuncheon and Kangleung in Kangwon province. Mean carbon storage by trees and shrubs was 26.0 t (mertric tons)/ha in Chuncheon and 46.7 t/ha in Kangleung for natural lands, and ranged from 4.7 to 6.3 t/ha for urban lands (all land use types except natural and agricultural lands) in both cities. Mean annual carbon uptake by trees and shrubs ranged from 1.60 to 1.71 t/ha/yr for natural lands, and from 0.56 to 0.71 t/ha/yr for urban lands. There was no significant difference (95% confidence level) between the two cities in the carbon storage and annual carbon uptake per ha, except the carbon storage for natural lands. Organic carbon storage in soils (to a depth of 60 cm) of Chuncheon average 24.8 t/ha for urban lands and 31.6 t/ha for natural lands, 1.3 times greater than for urban lands. Annual carbon accumulation in soils was 1.3 t/hr/yr for natural lands of the study cities. Annual per capita carbon emissions from fossil fuel consumption were 1.3 t/yr in Chunceon and 1.8 t/yr in Kangleung. The principal carbon release in urban landscapes was from transport and industry. Total carbon storage by urban greenspace (trees, shrubs, and soils) equaled 66% of total carbon emissions in Chuncheon and 101% in Kangleung. Carbon uptake by urban greenspace annually offset total carbon emissions by approximately 4% in the study cities. Thus, urban greenspace played a partial important role in reducing atmospheric $CO_2$ concentrations. To increase $CO_2$ uptake and storage by urban greenspace, suggested are conservation of natural lands, minimization of hard surfaces and more plantings, selection of tree species with high growth rate, and proper management for longer healthy tree growth.

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Greenhouse Gas Mitigation Effect Analysis by Establishing Additional Heat Storage System for Combined Heat and Power Plant (열병합발전소에서의 축열조 증설에 의한 온실가스 감축 효과 분석)

  • Kim, Shang Mork;Yoon, Joong Hwan;Lim, Kyoung Mi
    • Journal of Climate Change Research
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    • v.2 no.3
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    • pp.175-189
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    • 2011
  • In this research, we describe the methodology and the quantification about GHG reduction effects, expected by optimization of operation mode according to establishing additional heat storage system of Bundang Combined Cycle Power Plant. As an intermediate form of General Combined Cycle Power Plant and Heat supply only district heating plant, Bundang Combined Cycle Power Plant(and Ilsan, Anyang, Bucheon) is possible to satisfy demand for the electrical load and thermal load capacity at the same time through changes to the operation mode itself. Therefore, through the operating transition of high-efficiency mode that the condenser cooling water is recovered and supplied to district heat and cooling, establishing additional heat storage system have flexible supply ability at the power and heat market. In this research, We calculated using the operating performance for the last three years(2008~2010) and efficiency of each mode-specific values. As a result, GHG reduction effects were calculated as $97.95kg_{-}CO_2/Gcal$ per heat energy 1 Gcal supplied at the heat storage system and we expected emmision reduction effect about $13,500Ton_{-}CO_2/yr$.

Physico-chemical Changes of Commercial Ssamjang during Storage (공장식 쌈장의 저장기간에 따른 이화학적 성분변화)

  • Kim, Yong-Kook;Kim, Seong-Ju;Han, Min-Soo;Chang, Young-Il;Chang, Kyu-Seob
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.389-396
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    • 2005
  • Physico-chemical properties of ssamjang prepared by industrial process were investigated. Overall experiments were planned by central composite design for five independent variables, kochujang mash aging period $(X_{1})$, doenjang aging period $(X_{2})$, doenjang content $(X_{3})$, sterilization temperature $(X_{4})$, and storage temperature $(X_{5})$. Storage period had no consistent effect on moisture content of ssamjang. Doenjang having longer aging period showed lower moisture content than that having shorter aging period. Titratable acidity and pH of ssamjang gradually increased and decreased with storage period, respectively, with pH of ssamjang significantly affected by aging period of doenjang and kochujang mashes, and sterilization and storage temperatures. Amino nitrogen contents of ssamjang increased during storage and were more affected by sterilization temperature than by aging period and content of doenjang, and storage temperature. Crude protein content of ssamjang irregularly changed during storage, and was slightly affected by content of doenjang.

Evaluation of Gamma Irradiation for Extending the Shelf Life of Kimchi (김치의 저장성 연장을 위한 Gamma선 조사)

  • Cha, Bo-Sook;Kim, Woo-Jung;Byun, Myung-Woo;Kwon, Joong-Ho;Cho, Han-Ok
    • Korean Journal of Food Science and Technology
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    • v.21 no.1
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    • pp.109-119
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    • 1989
  • To improve the storage method of Kimchi, optimum ripening Kimchi for an irradiation treatment(the time of around 0.3% in total acidity of Kimchi) was irradiated by doses of 1, 2, 3 kGy with Co-60 ${\gamma}-radiation$ and stored at $10^{\circ}C$. Total aerobic bacteria increased in the beginning of storage and then decrease slowly as the number of total lactic acid bacteria increased. Total lactic acid bacteria initially loaded by $10^8\;cells/ml$ in Kimchi shortly after irradiation reduced to $10^4-10^6\;cells/ml$ with 1-3 kGy doses and decreased gradually through the whole storage period. The initial load of yeast, $10^3\;cells/ml$, increased steadily during Kimchi storage and led to more than $10^4\;cells/ml$ after 30 days of storage. While it maintained tha the load in 2-3 kGy irradiated groups after 30 days of storage was less than that at the beginning of storage. pH, acidity and volatile acid in the nonirradiated group were 4.0, 0.7% and 0.06%, respectively at the 15th day after storage, but at the 30th day after storage, 2-3 kGy irradiated groups showed different values, 4.1, 0.58-0.63%, and 0.04-0.05%, respectively. The texture(firmness) of Kimchi reduced along with storage time, and 2 kGy irradiated group proved most favourable in its texture during storage. In the sensory evaluation of Kimchi, nonirradiated group was inedible after 15 days of storage, whereas 2-3 kGy irradiated groups could proling the storage-life of Kimchi over 2 times compared with the nonirradiated Kimchi, showing the good sensory quality even after 30 days of storage.

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Estimated Gas Concentrations of MA(Modified Atmosphere) and Changes of Quality Characteristics during the MA Storage on the Oyster Mushrooms (느타리버섯의 환경기체조성 농도 예측 및 MA 저장 중 품질특성 변화)

  • Lee, Hyun-Dong;Yoon, Hong-Sun;Lee, Won-Og;Jung, Hoon;Cho, Kwang-Hwan;Park, Won-Kyu
    • Food Science and Preservation
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    • v.10 no.1
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    • pp.16-22
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    • 2003
  • This study was conducted to find out effective MA (Modified Atmosphere) gas compositions on the oyster mushroom through statistical analysis of the respiration rate and MA storage for the various packaging materials. Under the various gas compositions, the oxygen consumption rate of oyster mushroom was from 28.9 to 161.4mgO$_2$/kg$.$hr and the carbon dioxide evolution rate was from 53.4 to 166.9 mgCO$_2$/kg$.$hr at 20$^{\circ}C$. The estimated MA condition of oyster mushroom were 2.5∼4.5%O$_2$and 11.5∼l3%CO$_2$by the RSREG(Response Surface Regression). The gas compositions of MA packaging are following that 0.03mm LDPE were 1.6∼3.0%O$_2$and 3.9∼5.3%CO$_2$,0.05mm LDPE were 1.2∼1.3%O$_2$and 9.0∼11.1%CO$_2$and Nylon+PE were 0.9∼1.2%O$_2$and 33.5∼39.6%CO$_2$. The weight loss increased at 0.03mm LDPE but has the lowest value at Nylon+PE. The hardness of pileus and stipe was decreased with storage periods. The $\Delta$E-value increased with storage period and seriously changed in early storage period at 12 and 20$^{\circ}C$. In the 0.05mm LDPE, the gas compositions of packaging were similar to estimated gas compositions from the RSREG and the storage quality was superior to the other packaging materials in weight loss, hardness, and color difference at 4, 12 and 20 $^{\circ}C$.

Effect of Packaging Method and Storage Time on Physicochemical Characteristics of Dry-Cured Pork Neck Products at 10℃

  • Kim, Il-Suk;Jin, Sang-Keun;Yang, Mi-Ra;Ahn, Dong Uk;Park, Jae-Hong;Kang, Suk-Nam
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.11
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    • pp.1623-1629
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    • 2014
  • Dry-cured pork neck samples were stored at $10^{\circ}C$ for 90 days under vacuum packaging (VP) or modified atmosphere packaging (MAP; 25% $CO_2$+75% $N_2$) conditions. The pH, moisture, water activity, total aerobic bacteria, and Enterobacteriaceae counts of dry-cured pork neck products with MAP were significantly lower than those with VP (p<0.05) after 90 days of storage. However, CIE $b^*$ and 2-thiobarbituric acid reacted substance (TBARS) values of the pork product with MAP were significantly higher (p<0.05) than those with VP. Total aerobic bacterial counts and Enterobacteriaceae counts of samples with MAP were lower than those with VP after 30 days of storage. Sensory results indicated that aroma, flavor and tenderness scores of the samples with both VP and MAP decreased during storage and the scores after >60 days of storage were lower than those at Day 1. In conclusion, despite presenting higher lipid oxidation, the samples stored in packages containing 25% $CO_2$ for 90 days at $10^{\circ}C$ have lower bacterial counts than vacuum-packed samples. Therefore, further studies should be performed on the packaging of dry-cured meat at adjusted concentrations of $CO_2$.