• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2005.11b
• /
• pp.92-106
• /
• 2005

The head-end processes of spent TRISO fuel have been reviewed to understand the current status and the limitations of the reported processes. The main concerns in the TRISO treatment are to effectively breach and separate the carbon and SiC layers composing the TRISO particles. The crush-bum scheme which was considered in the early stages of the development has been replaced by the crush-leach or $CO_2$ burning and the succeeding CO decomposition process because of a sequestration problem of $CO_2$ containing $^{14}C$. However there are still many obstacles to overcome in the reported processes. Hence, innovative thermomechanical and pyrochemical concepts to breach the coating layers of the TRISO particle with a minimized amount of second waste are proposed in this paper and their principles are described in detail.

• Journal of Soil and Groundwater Environment
• /
• v.20 no.1
• /
• pp.19-27
• /
• 2015

If $CO_2$ stored for geological sequestration escapes from deep formations and is introduced to shallow aquifers, it dissolves into groundwater, creates acidic environments, and enhance mineral dissolution from rocks and soils. Among these minerals, dissolution and spread of hazardous trace metals can cause environmental problems with detrimental impacts on groundwater quality. This study aims to investigate geochemical effects of $CO_2$ in groundwater on dissolution of galena, the main mineral controlling the mobility of lead. A series of batch experiments are performed with granulated galena in $CO_2$ solutions under various experimental conditions for $CO_2$ concentration and reaction temperature. Results show that dissolution of galena is significantly enhanced under acidic environments so that both of equilibrium concentrations and dissolution rates of lead increase. For thermodynamic analysis on galena dissolution, the apparent rate constants and the activation energy for galena dissolution are calculated by applying rate law to experimental results. The apparent rate constants are $6.71{\times}10^{-8}mol/l{\cdot}sec$ at $15^{\circ}C$, $1.77{\times}10^{-7}mol/l{\cdot}sec$ at $25^{\circ}C$, $3.97{\times}10^{-7}mol/l{\cdot}sec$ at $35^{\circ}C$ and the activation energy is 63.68 kJ/mol. The galena dissolution is suggested to be a chemically controlled surface reaction, and the rate determining step is the dissociation of Pb-S bond of surface complex.

• Geophysics and Geophysical Exploration
• /
• v.9 no.1
• /
• pp.10-18
• /
• 2006

We measured the changes in P-wave velocity that occur when injecting $CO_2$ in gaseous, liquid, and supercritical phases into water-saturated anisotropic sandstones. P-wave velocities were measured in two cylindrical samples of Tako Sandstone, drilled along directions normal and parallel to the bedding plane, using a piezo-electric transducer array system. The velocity changes caused by $CO_2$ injection are typically -6% on average, with maximum values about -16% for the case of supercritical $CO_2$ injection. P-wave velocity tomograms obtained by the differential arrival-time method clearly show that $CO_2$ migration behaviour is more complex when $CO_2$ flows normal to the bedding plane than when it flows parallel to bedding. We also found that the differences in P-wave velocity images were associated both with the $CO_2$ phases and with heterogeneity of pore distribution in the rocks. Seismic images showed that the highest velocity reduction occurred for supercritical $CO_2$ injection, compared with gaseous or liquid $CO_$ injection. This result may justify the use of the seismic method for $CO_2$ monitoring in geological sequestration.

• Geophysics and Geophysical Exploration
• /
• v.9 no.1
• /
• pp.37-43
• /
• 2006

In 2006, the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) plans to undertake (subject to receiving the necessary approvals) a Pilot program for $CO_2$ storage within a depleted gas reservoir. The Otway Basin Pilot Program (OBPP) aims to demonstrate that subsurface $CO_2$ storage is both economically and environmentally sustainable in Australia. This will be the first $CO_2$ storage program in the world to utilise a depleted gas reservoir and, hence, the experience gained will be a valuable addition to the range of international $CO_2$ storage programs that are underway or being planned. A key component of the OBPP is the design of an appropriate geophysical monitoring strategy that will allow the subsurface migration of the $CO_2$ plume to be tracked and to verify that containment has been successful. This paper presents the results from modelling the predicted gravity response to $CO_2$ injection into the Otway Basin reservoir, where the goal was to determine minimum volumes of $CO_2$ that may be detectable using non-seismic geophysical techniques. Modelling results indicate that gravity measurements at 10 m spacing within the existing observation well and the planned $CO_2$ injection well would provide excellent vertical resolution, even for the smallest $CO_2$ volume modelled (10000 tonnes), but resolving the lateral extent of the plume would not be possible without additional wells at closer spacing.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.228.2-228.2
• /
• 2010

In this work, the hydrogen production costs of the nuclear energy sources are estimated in the necessary input data on a Korean specific basis. G4-ECONS was appropriately modified to calculate the cost for hydrogen production of HTE process with Very High Temperature nuclear Reactor (VHTR) as a thermal energy source rather than the LUEC (Levelized Unit Electricity Cost). The general ground rules and assumptions follow G4-ECONS. Through a preliminary study of cost estimates, we wished to evaluate the economic potential for hydrogen produced from nuclear energy, and, in addition, to promptly estimate the hydrogen production costs for an updated input data for capital costs. The estimated costs presented in this paper show that hydrogen production by the VHTR could be competitive with current techniques of hydrogen production from fossil fuels if $CO_2$ capture and sequestration is required. Nuclear production of hydrogen would allow large-scale production of hydrogen at economic prices while avoiding the release of $CO_2$. Nuclear production of hydrogen could thus become the enabling technology for the hydrogen economy. The major factors that would affect the cost of hydrogen were also discussed.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.15 no.1
• /
• pp.11-15
• /
• 2009

The proposal of the $CO_2$ ocean sequestration necessitates a thorough understanding of its consequences to aquatic organisms. This paper describes acute toxic responses to high $CO_2$ environment of a cephalopod, Octopus vulgaris. O. vulgaris was chronically cannulated in the abdominal aorta and recovered in a restrained chamber. Acid base variables as well as ion concentrations were estimated in samples of the blood collected from recovered O. vulgaris. 100% mortality occurred within 72h during exposure to 3%-$CO_2$ environment. Hemolymph pH significantly decreased after 30 min during exposure to 1%-$CO_2$ environment without any compensation thereafter. $[HCO_3^-]$ significantly increased from 2.2 mM at 0h to 7.8 mM at 8h, but gradually decreased thereafter. Hemolymph ions $([Cl^-],\;[Na^+],\;[K^+])$ showed no significant changes. O. vulgaris may be more sensitive than teleost, yellowtail, flounder and dogfish.

• Journal of Forest and Environmental Science
• /
• v.36 no.1
• /
• pp.37-46
• /
• 2020

Vegetation carbon sequestration and regeneration are the two major parameters of forest research. In this study, we analyzed the vegetation carbon stock and regeneration of community-managed pine plantation of Kathmandu, central Nepal. Vegetation data were collected from 40 circular plots of 10 m radius (for the tree) and 1m radius (for seedling) applying a stratified random sampling and nested quadrat method. The carbon stock was estimated by Chave allometric model and estimated carbon stock was converted into CO₂ equivalents. Density-diameter (d-d) curve was also prepared to check the regeneration status and stability of the plantation. A d-d curve indicates the good regeneration status of the forest with a stable population in each size class. Diversity of trees was very low, only two tree species Pinus roxburghii and Eucalyptus citriodora occurred in the sample plots. Pine was the dominant tree in terms of density, basal area, biomass, carbon stock and CO₂ stock than the eucalyptus. The basal area, carbon stock and CO₂ stock of forest was 33±1.0 ㎡ ha^-1, 108±5.0 Mg ha^-1 and 394±18 Mg ha^-1, respectively. Seedling and tree density of the plantation was 4,965 ha^-1 and 339 ha^-1 respectively. The forest carbon stock showed a positive relationship with biomass, tree diameter, height and basal area but no relationship with tree density. Canopy cover and tree diameter have a negative effect on seedling density and regeneration. In conclusion, the community forest has a stable population in each size class, sequestering a significant amount of carbon and CO₂ emitted from densely populated Kathmandu metro city as the forest biomass hence have a potentiality to mitigate the global climate change.

• Korean Chemical Engineering Research
• /
• v.45 no.6
• /
• pp.573-581
• /
• 2007

The present study deals with removal of $CO_2$ using various mesoporous materials impregnated with MEA (monoethanolamine). The mesoporous materials such as MCM-41, MCM-48 and SBA-15 were synthesised and then impregnated with 30, 50 and 70 wt% of MEA, respectively. XRD, FT-IR and SEM were used to evaluate the characterization of those. From the adsorption/desorption experiments for various materials, the adsorption capacity of these materials were found in the order of MCM-41> MCM-48> SBA-15. MCM-41 impregnated with 50 wt% of MEA showed the maximum adsorption capacity of $57.1mg-CO_2/gr-sorbent$ at $40^{\circ}C$. It is nearly 8 times higher than MCM-41 without impregnation of MEA. In the multiple cycle test of 20 times, MCM-41 impregnated with 50 wt% of MEA showed a constant adsorption capacity.

• Journal of Climate Change Research
• /
• v.5 no.4
• /
• pp.339-348
• /
• 2014

Agro-ecosystem plays an important role in the mitigation of atmospheric $CO_2$ concentration through photosynthesis and soil carbon fixation. The perennial crops have capacity of carbon accumulation because they have lived for years in the same position. Carbon dioxide fixation occurs in the fruit orchard by photosynthesis and soil carbon sequestration. The objectives of this review are to introduce the fruit orchard as a carbon dioxide sink and to summarize the methods that measure $CO_2$ flux in the orchard. There are three difference methods (chamber, biomass, and eddy covariance method) to measure $CO_2$ exchanges on sites. However, there is no standard method suitable for fruit cultivation condition in Korea. Thus the standard method have to be developed in order to exactly estimate the carbon accumulation. In foreign studies, the carbon assessments were conducted in apple, peach, olive, grape orchard and so on. On the other hand the estimation of $CO_2$ exchange was carried out for apple and mandarine orchard in Korea. According to these results, fruit orchard is a $CO_2$ sink even though amount of carbon accumulation is smaller than the forest. To introduce certainly fruit orchard as greenhouse gas sink, long-term monitoring and further study have to be conducted under each planting condition.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.11 no.4
• /
• pp.416-424
• /
• 2023

Concrete emits a large amount of carbon dioxide throughout its life cycle, and due to the societal demand for carbon dioxide reduction, research on storing carbon dioxide in concrete in the form of minerals is ongoing. In this study, cyanobacteria, which absorb carbon dioxide through photosynthesis and fix it as calcium carbonate, were applied to a porous concrete substrate, and the changes in the properties of the concrete substrate due to their special environmental curing condition were analyzed. The results showed that the calcium carbonate precipitation by the microorganisms was concentrated in the light-exposed surface area, and most of the precipitation occurred in the cement paste part, not in the aggregate. This microbially induced calcium carbonate precipitation enhanced the mechanical performance of the paste and improved the overall compressive strength as the curing age progressed. In addition, the increase in microbial biofilm and calcium carbonate improved the pore structure, which influenced the reduction in water permeability.