• 제목/요약/키워드: $CO_2$ Evolution

검색결과 421건 처리시간 0.026초

기상응축법으로 제조한 나노 WC및 WC-Co분말의 후속 열처리에 의한 상 및 협상 변화 (Change of Particle Morphology and Ingredient Phase of WC and WC-Co Nanopowders Fabricated by Chemical Vapor Condensation during Subsequent Heat-Treatment)

  • 김진천;하국현;김병기
    • 한국분말재료학회지
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    • 제11권2호
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    • pp.124-129
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    • 2004
  • Nanosized WC and WC-Co powders were synthesised by chemical vapor condensation(CVC) process using the pyrolysis of tungsten hexacarbonyl(W(CO)$_6$) and cobalt octacarbonyl(Co$_2$(CO)$_8$). The microstructural changes and phase evolution of the CVC powders during post heat-treatment were studied using the XRD, FE-SEM, TEM, and ICP-MS. CVC powders were consisted of the loosely agglomerated sub-stoichimetric WC$_{1-x}$ and the long-chain Co nanopowders. The sub-stochiometric CVC WC and WC-Co powders were carburized using the mixture gas of CH$_4$-H$_2$ in the temperature range of 730-85$0^{\circ}C$. Carbon content of CVC powder controlled by the gas phase carburization at 85$0^{\circ}C$ was well matched with the theoretical carbon sioichiometry of WC, 6.13 wt%. During the gas phase carburization, the particle size of WC increased from 20 nm to 40 nm and the long chain structure of Co powders disappeared.

Al-6.2wt.%Si 합금의 등온교반시간에 따른 미세조직변화 (Microstructural evolution of rheocast Al-6.2wt.%Si alloy with isothermal stirring)

  • 이정일;박지호;김긍호;이호인
    • 한국주조공학회지
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    • 제15권5호
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    • pp.514-522
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    • 1995
  • The microstructural evolution with isothermal stirring during semi-solid state processing of hypoeutectic Al-6.2wt%Si alloy was studied. Substructure of the individual primary solid particle in the slurry was investigated through transmission electron microscopy(TEM). Formation of subgrain boundaries on the rheocast Al-6.2wt%Si alloy is observed and the misorientation between the grains is shown typically under 2 degrees by analyzing selected area diffraction (SAD) and convergent beam electron diffraction (CBED) patterns. The existence of high angle grain boundaries are also observed in the alloy. Based upon these observations, mechanisms for the primary particles fragmentation are considered. With isothermal stirring, the dislocation density increases, and the evolution of dislocation cell structure takes place, which is interpreted as a process of achieving uniform deformation by dynamic recovery under applied shear stress.

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($^{14}C$ 표지 Imazapyr의 토양중 무기화와 흡착 (Mineralization and Adsorption of $^{14}C$-Lablled Imazapyr in Soil)

  • 권정욱;이재구
    • 한국환경농학회지
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    • 제16권4호
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    • pp.320-326
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    • 1997
  • 제초제 imazapyr의 토양환경중 행동을 구명하기 위하여 물리화학적 특성이 상이한 8종의 토양을 이용하여 $^{14}CO_2$로의 무기화 및 흡착 시험을 수행하여 얻은 결과를 요약하면 다음과 같다. 1. 물리화학적 특성이 상이한 8종의 토양중 배양기간 동안 발생된 $^{14}CO_2$의 양은 총 처리 방사능의 약 1.5${\sim}$4.9%로써 토양에 따라 상이한 방출율을 보였다. pH가 낮고 유기물이 많은 토양 C, G 및 H에서는 낮은 $^{14}CO_2$ 방출량을 보인 반면 pH가 높고 유기물이 적은 토양 B와 D에서는 높은 $^{14}CO_2$ 방출율을 보였다. 2. Imazapyr의 흡착실험에서 평형농도 도달시간은 네 토양 모두에서 약 3시간 이었다. 물리화학적 성질이 상이한 토양에서 0.25${\sim}$28.32%의 흡착율을 보였으며, 토양구성 요소중에서, 유기물 함량이 토양에 의한 imazapyr의 흡착에 가장 큰 영향을 미쳤다. Freundlich 흡착상수$(K_f)$는 유기물의 함량이 2.0${\sim}$21.3배 증가함에 따라 5.5${\sim}$25.6배 증가하였다. 그러므로 토양 유기물이 imazapyr의 흡착에 미치는 범위는 점토가 미치는 것보다 더 큼이 분명하다. $K_f$값은 토양 C, D, G 및 H에서 각각 0.44, 0.08, 0.65 및 2.05이었으며, 모든 토양에서 $K_d$와 유사한 값을 보였다.

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Effects of Soil Types on the Biodegradation of Crude Oil by Nocardia sp. H17-1

  • Yoon, Byung-Dae;Baek, Kyung-Hwa;Kim, Hee-Sik;Moon, Seong-Hoon;Lee, In-Sook;Oh, Hee-Mock
    • Journal of Microbiology and Biotechnology
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    • 제14권5호
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    • pp.901-905
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    • 2004
  • The degradation and mineralization of crude oil were investigated over 50-days in three soils, loamy sand, sand, and combusted loamy, which were artificially contaminated with crude oil (50 g $kg^{-1}$) and inoculated with Nocardia sp. H17-1. The degradation efficiency of total petroleum hydrocarbon (TPH) in sand was the highest at 76% among the three soils. The TPH degradation rate constants $(k_{TPH})$ in loamy sand, sand, and combusted loamy sand were 0.027 $d^{-1}$, 0.063 $d^{-1}$, and 0.016 $d^{-1}$, respectively. In contrast, the total amount of $CO_2$ evolved was the highest at 146.1 mmol in loamy sand. The $CO_2$ evolution rate constants (k_{CO2})$ in loamy sand, sand, and combusted loamy sand were 0.057 $d^{-1}$, 0.066 $d^{-1}$, and 0.037 $d^{-1}$, respectively. Therefore, it seems that the degradation of crude oil in soils can be proportional to the soil pore space and that mineralization can be accelerated with the increase of organic substance.

COCOA: The CO-evolution of cluster COres and the AGNs of central galaxies

  • Baek, Junhyun;Chung, Aeree;Tremou, Evangelia;Sohn, Bongwon;Jung, Taehyun;Ro, Hyunwook
    • 천문학회보
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    • 제39권2호
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    • pp.58.2-58.2
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    • 2014
  • We present the results of the KVN observations of central galaxies in cool-core and non cool-core clusters. The goal is to study how cooling environments affect the AGN activities in the core where their host galaxies are embedded. From the HIghest FLUx Galaxy Cluster Sample (HIFLUGCS), we have selected 19 radio bright AGNs located in the center of clusters with various cooling timescale. In our pilot study, we have obtained 22 and 43 GHz fluxes and morphologies of the sample using the Korean VLBI network. We find that 22/43 GHz fluxes do not strongly depend on the presence of a cool gas flow. However, an intriguing fact is that most AGNs in the cool-core clusters show the hint of a pc-scale jet component while the ones in the non cool-core clusters do not. Based on these results, we discuss the role of cooling flows in the central cluster AGNs and their co-evolution.

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Research Trends and Its Determinants in Mobile Commerce Research (1999-2012)

  • Ko, Chang-Ryong
    • Asian Journal of Innovation and Policy
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    • 제2권2호
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    • pp.150-172
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    • 2013
  • This paper wanted to find out research trends and its determinants on mobile commerce research reviewing 439 articles from 1999, the starting year of this field to 2012. Our analytical framework has 4 categories such as general, technology, consumer and firm, and 14 sub-categories. The results are as follows: First, studies on mobile commerce can be divided into 5 stages. Second, trends of mobile commerce are closely related to the evolution of mobile technologies such as communication technologies and devices (2G, 3G, 3G+, 4G LTE, LTE-A). Third, this field was led by USA until 2005 and has been led by Taiwan after 2006. Fourth, China, Korea, UK and Canada are also leading countries, all of which have mobile device manufacturers. Research trends of non-manufacturing countries and manufacturing countries are different from each other. In addition, the trends of leading countries are different from each other reflecting each country's business needs.

산소발생용 Cobalt-phosphate (Co-pi) 촉매를 이용한 Gallium Nitride (GaN) 광전극의 광전기화학적 특성 (Photoelectrochemical Properties of Gallium Nitride (GaN) Photoelectrode Using Cobalt-phosphate (Co-pi) as Oxygen Evolution Catalyst)

  • 성채원;배효정;;하준석
    • 마이크로전자및패키징학회지
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    • 제27권2호
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    • pp.33-38
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    • 2020
  • 광전기화학적 물분해에서 광전극으로 이용되는 GaN은 전해질에 대해 높은 안정성을 가지고 있으며 물의 산화 환원준위를 포함하고 있어 외부전압 없이 물분해가 가능하다. 그러나 GaN 광전극의 경우, 재료 자체의 효율이 낮아 상용화하기에는 부족한 실정이다. 본 연구에서는 광효율을 향상시키기 위해 Cobalt phosphate(Co-pi) 촉매를 광전기증착(Photoelectro-deposition)방법을 통하여 GaN 광전극에 도입하였다. Co-pi 촉매 증착 후 SEM, EDS, XPS분석을 진행하여 Co-pi의 증착 여부 및 증착 정도를 확인하고, Potentiostat를 이용해 PEC 특성을 분석하였다. SEM 이미지를 통해 Co-pi가 GaN 표면 위에 20~25 nm 사이즈의 클러스터 형태로 고르게 증착되어 있는 것을 확인하였다. EDS 및 XPS 분석을 통해 GaN 표면의 입자가 Co-pi임을 확인하였다. 이 후 측정된 PEC 특성에서 Co-pi를 증착 시킨 후 0.5 mA/㎠에서 0.75 mA/㎠로 향상된 광전류밀도 값을 얻을 수 있었다. 향상된 원인을 밝히기 위하여, 임피던스 및 Mott-Schottky 측정을 진행하였고, 측정 결과, 50.35 Ω에서 34.16 Ω으로 감소한 분극저항(Rp)과 증가된 donor 농도(ND) 값을 확인하였다. 물분해 전 후, 표면 성분을 분석한 결과 물분해 후에도 Co-pi가 남아있음으로써 Co-pi 촉매가 안정적이라는 것을 확인하였다. 이를 통해, Co-pi가 GaN의 효율 향상을 위한 촉매로서 효과가 있음을 확인하였고, 다른 광전극에 촉매로써 적용시켰을 경우, PEC 시스템의 효율을 향상시킬 수 있을 것으로 판단된다.

IAn Automatic Measurement Method for the Galaxy Disk Warp and its Application to SDSS Stripe 82 Galaxies

  • Moon, Jun-Sung;Kim, Jeonghwan H.;Jee, Woongbae;Yoon, Suk-Jin
    • 천문학회보
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    • 제39권2호
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    • pp.63.1-63.1
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    • 2014
  • The galaxy disk warp is a common phenomenon, yet their properties and formation mechanism(s) are still unclear. Here, we introduce a new automatic measurement method for the warp properties of stellar disks in nearby edge-on galaxies, including warp's angle, shape, and asymmetry. We obtain isophotal maps of edge-on galaxies and express each of isophote contours in polar coordinates (${\Phi}$, R) centered on the galaxy centers. Two peaks in the ${\Phi}$-R diagram correspond to the outermost tips of each isophote. The locations of peaks, in turn, inform us of the misalignment between their inner and outer galactic planes, i.e., the warp. We apply this method to SDSS Stripe 82 co-added data and discuss its reliability and validity. Based on the measurement of warp properties, we also investigate their correlations with both intrinsic and environmental properties of warped galaxies.

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Tricalcium Silicate의 초기수화반응(III) (Early Hydration of Tricalcium Silicate(III))

  • 오희갑;최상흘
    • 한국세라믹학회지
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    • 제24권4호
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    • pp.385-391
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    • 1987
  • Zeta potential according to the hydration time was studied during the early hydration of C3S with and without CO2 atmosphere. Zeta potential was low as a level of 20mV at the first and second exothermic peaks of heat evolution, but it was rapidly increased up to a level of 300mV. In the CO2 atmosphere, zeta potential was level of 60mV at 10 minutes hydration and it's value became a low gradually according to the hydration time. Zeta potential was also proportioned to the Ca2+ concentration in the liquid phase, i.e., there was positive correlation between zeta potential and Ca2+ concentration. The existence of silicate layer was not found out on the hydrated C3S in the CO2 atmosphere by SEM-EDAX.

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