• Title/Summary/Keyword: $CO_2$ Evolution

검색결과 429건 처리시간 0.032초

역원추형 발효조에서의 동시당화발효에 의한 전분으로 부터의 연속 에탄올 발효 (Continuous Ethanol Production from Starch by Simultaneous Saccharification and Fermentation in a Tapered Column Fermentor)

  • 김철호;유연우김철이상기
    • KSBB Journal
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    • 제5권4호
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    • pp.329-334
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    • 1990
  • In an attempt to develop a novel process for ethanol production from starch, a simultaneous saccharification and fermentation (SSF) process using Zymomonas mobilis and amyloglucosidase (AMG) was studied in continuous modes. Compared with a conventional cylindrical column type of fermentor, the tapered column type of fermentor was found to be superior in terms of reactor performance for ethanol fermentation. The tapered columm fermentor packed with coimmobilized Z. mobilis and AMG alleviated the problems which were associated with CO2 evolution and provided a significantly better flow pattern for both liquid and gas phases in the fermentor without channelling. However, the fluidized bed type of tapered column fermentor using flocculent strain of Z. mobiles and immobilized AMG showed lower productivity (5.2g/1/h) than that of packed bed type of tapered column fermentor(9.2g/l/h).

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Mechanical and acoustic behaviors of brine-saturated sandstone at elevated temperature

  • Huang, Yan-Hua;Yang, Sheng-Qi
    • Geomechanics and Engineering
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    • 제17권2호
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    • pp.215-225
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    • 2019
  • The mechanical behavior of rock is essential to estimate the capacity and long-term stability of $CO_2$ storage in deep saline aquifers. As the depth of reservoir increases, the pressure and temperature that applied on the rock increase. To answer the question of how the confining pressure and temperature influence the mechanical behavior of reservoir rock, triaxial compression experiments were carried out on brine-saturated sandstone at elevated temperature. The triaxial compressive strength of brine-saturated sandstone was observed to decrease with increasing testing temperature, and the temperature weakening effect in strength enhanced with the increase of confining pressure. Sandstone specimens showed single fracture failures under triaxial compression. Three typical regions around the main fracture were identified: fracture band, damaged zone and undamaged zone. A function was proposed to describe the evolution of acoustic emission count under loading. Finally, the mechanism of elevated temperature causing the reduction of strength of brine-saturated sandstone was discussed.

Supermassive Black Hole Masses of ~500k QSOs from the Sloan Digital Sky Survey

  • Taak, Yoon Chan;Im, Myungshin
    • 천문학회보
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    • 제44권2호
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    • pp.77.2-77.2
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    • 2019
  • Measurements of supermassive black hole (SMBH) masses are crucial in studying the co-evolution of SMBHs and their host galaxies. Although reverberation mapping is the most accurate method known to date, this requires spectroscopic monitoring over long periods. Thus, the current sample barely reaches three digits. The virial method, on the other hand, uses emission-line and continuum properties from a single spectrum to estimate the SMBH mass; hence the name single-epoch method. The Sloan Digital Sky Survey (SDSS) has observed spectra of almost all quasi-stellar objects (QSOs) discovered so far. Building on previous studies, using the single-epoch method, we estimate the SMBH masses of more than 500,000 QSOs from the SDSS DR14 Quasar Catalog. This increases the mass-estimated SMBH sample almost by a factor of two, and especially more for the low-mass regime, which was the main target of SDSS-IV (eBOSS).

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소실모형이 탄소강 및 회주철 주물의 표면층 조직에 미치는 영향 (Effect of Evaporative Pattern on the Surface Layer Structures of Carbon Steel and Gray Iron Castings.)

  • 김지윤;조남돈
    • 한국주조공학회지
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    • 제12권4호
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    • pp.305-316
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    • 1992
  • Steel and iron castings made with expandable polystylene (referred to hereafter as EPS) patterns are often affected by distinctive defects associated with incomplete decomposition of the EPS as the molds are filled with metal. The effects of practical factors on carbon pick-up were investigated on the specimens, by taking successive layers of swarf and analysis, whereas the lustrous carbon is determined by using combustion analysis. The quality of the castings, with particular reference to carbon pick-up in low carbon steel and lustrous carbon on gray iron, is further influenced to a significant extent by such practical factors as reduced pressure, the pouring temperature, the density of EPS pattern, the additive in coating and in pattern and the casting thickness. The rate at which carbon pick-up and lustrous carbon deposites are formed can be reduced by reducing the density of the pattern and also reducing pressure, especially by adding $Na_2CO_3$ in coating and in pattern to promote $CO_2$ evolution. The upper parts of castings obtained using EPS patterns are slightly higher in carbon pick-up and in lustrous carbon than other parts.

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Effect of Substrate Rotation on the Phase Evolution and Microstructure of 8YSZ Coatings Fabricated by EB-PVD

  • Park, Chanyoung;Choi, Seona;Chae, Jungmin;Kim, Seongwon;Kim, Hyungtae;Oh, Yoon-Suk
    • 한국세라믹학회지
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    • 제53권1호
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    • pp.81-86
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    • 2016
  • The effect of substrate rotation speed on the phase forming behavior and microstructural variation of 8 wt% yttria ($Y_2O_3$) stabilized $ZrO_2$ (8YSZ) coatings as a thermal barrier coating has been investigated. 8YSZ coatings with $100{\sim}200{\mu}m$ thickness were deposited by electron beam-physical vapor deposition onto a super alloy (Ni-Cr-Co-Al) substrate with a bond coating (NiCo-CrAlY). The width of the columnar grains of the 8YSZ coatings increased with increasing substrate rotation speed from 1 to 30 rpm at a substrate temperature range of $900{\sim}950^{\circ}C$. In spite of the different growth behaviors of coatings with different substrate rotation speeds, the phases of each coating were not changed remarkably. Even after post heat treatments with various conditions of the coated specimens fabricated at 20 rpm, only a change of color was noticeable, without any remarkable change in the phase or microstructure.

부평 은광산 지역의 유문암질암과 화강암류의 가스 및 유체포유물 연구 (Gas and Fluid Inclusion Studies of the Granitic and Rhyolitic Rocks From the Bupyeong Silver Mine Area)

  • 김규한;하우영
    • 자원환경지질
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    • 제30권6호
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    • pp.519-529
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    • 1997
  • Volcanic rocks including rhyolitic tuff, rhyolite and welded tuff in the Bupyeong silver mine area form a topographic circular structure which is interpreted as a resurgent caldera. Granitic rocks are emplaced inside and outside area of the circular structure. Pervasive silver mineralization took place in the rhyolitic rock of the southwestern margin of the caldera. Gas and fluid incluson studies were carried out to investigate the petrogenetic evolution and post-magmatic alteration for the rhyolitic and granitic rocks. Gas compositions are characterized by a low $CH_4/CO_2$ ratio (0.004-0.005) for rhyolitic and inside granitic rocks and a high $CH_4/CO_2$ ratio (0.01~0.29) for outside granitic rocks such as the Kimpo and Incheon granites. Homogenization temperature of solid daughter mineral bearing fluid inclusion (III and IV types) and two phase fluid inclusion (I and II types) for quartz in the Bupyeong granites range from 400 to $500^{\circ}C$ and 121 to $514^{\circ}C$, respectively. Salinties vary from 20 to 30 wt% NaCl for type III and IV inclusions and less than 20 wt % NaCl for type I and II inclusions. The fluid inclusion data shows a considerable influx of the meteoric water toward post magmatic alteration stage.

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디지털 프린팅용 글래스-세라믹 복합 잉크 제조 및 특성 평가 (Formulation and Evaluation of Glass-Ceramic Ink for Digital Ink-jet Printing)

  • 권종우;이종흔;황광택;김진호;한규성
    • 한국재료학회지
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    • 제27권11호
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    • pp.583-589
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    • 2017
  • Ceramic ink-jet printing has become a widespread technology in ceramic tile and ceramicware industries, due to its capability of manufacturing products on demand with various designs. Generally, thermally stable ceramic inks of digital primary colors(cyan, magenta, yellow, black) are required for ink-jet printing of full color image on ceramic tile. Here, we synthesized an aqueous glass-ceramic ink, which is free of Volatile organic compound(VOC) evolution, and investigated its inkjet printability. $CoAl_2O_4$ inorganic pigment and glass frit were dispersed in aqueous solution, and rheological behavior was optimized. The formulated glass-ceramic ink was suitably jetted as single sphere-shaped droplets without satellite drops. After ink-jet printing and firing processes, the printed glass-ceramic ink pattern on glazed ceramic tile was stably maintained without ink spreading phenomena and showed an improved scratch resistance.

초초임계압 발전용 소재의 표면처리층의 고온 안정성 평가 (High-Temperature Stability Evaluation of Various Surface Treated Layers of Materials for Ultra-Super Critical Power Plants)

  • 류경환;송태권;이재현;김길수;이선호;엄기원
    • 한국재료학회지
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    • 제16권5호
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    • pp.329-335
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    • 2006
  • In order to improve thermal efficiency of the fossil fuel power plants, we need to develop advanced materials with superior durability in the ultra-super critical state, which requires surface modifications for superior surface properties. In this study, we coated the Incoloy 901 and 12-17Cr steels for turbine buckets and valves with nitriding, boriding, and $Cr_3C_2-NiCr$ HVOF(high velocity oxygen flow) method. Then the samples were heat treated at $650^{\circ}C$ for 100 hours in vacuum. We analyzed the evolution behaviors of nitrides such as $Fe_3N,\;Fe_4N$, and CrN and borides such as FeB and $Fe_2B$ with XRD and SEM/EDS by comparing hardnesses and compositions of the coated layers before and after the heat treatments.

가스하이드레이트 형성 과정의 비저항 모니터링 (Electrical Resistivity Monitoring of Gas Hydrate Formation)

  • 이주용;이재형;이대성;이원석;김세준;허대기;김현태
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 추계학술대회 논문집
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    • pp.186-187
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    • 2008
  • Electrical resistivity in hydrate-bearing sediments is sensitive to porosity, gas hydrate saturation, gas content, pore fluid composition, and temperature, so electrical measurements such as well logs and electromagnetic surveys have been used to explore gas hydrate-bearing formation. The high pressure tomography cell is designed considering the effect of electrode configuration and electrical shielding on tomography measurements and the safety. The evolution of electrical conductivity during $CO_2$ hydrate formation and dissociation reflects the combined effects of concurrent changes that include ionization of dissolved $CO_2$, temperature-dependent ionic mobility, changes in the degree of saturation, ion exclusion, surface conduction, and porosity changes. Measurements during hydrate formation and dissociation require careful analysis to properly interpret signatures, in particular when out-of plane conductivity anomalies prevail.

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층상계 하이니켈 양극재의 잔류 리튬 생성 및 저감 메커니즘 연구 (A Mechanism Study on Formation and Reduction of Residual Li of High Nickel Cathode for Lithium-ion Batteries)

  • 빈민욱;나범탁;홍태은;김영진
    • 산업기술연구
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    • 제42권1호
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    • pp.7-12
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    • 2022
  • High nickel layered oxide cathodes are gaining increasing attention for lithium-ion batteries due to their higher energy density and lower cost compared to LiCoO2. However, they suffer from the formation of residual lithium on the surface in the form of LiOH and Li2CO3 on exposure to ambient air. The residual lithium causes notorious issues, such as slurry gelation during electrode preparation and gas evolution during cell cycling. In this review, we investigate the residual lithium issues through its impact on cathode slurry instability based on deformed polyvinylidene fluoride (PVdF) as well as its formation and reduction mechanism in terms of inherently off-stoichiometric synthesis of high nickel cathodes. Additionally, new analysis method with anhydrous methanol was introduced to exclude Li+/H+ exchange effect during sample preparation with distilled water. We hope that this review would contribute to encouraging the academic efforts to consider practical aspects and mitigation in global high-energy-density lithium-ion battery manufacturers.