• Title/Summary/Keyword: $CO_2$ Evolution

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Effect of Co-Substitution on the Crystallization and Magnetic Properties of a Mechanically Milled Nd15(Fe1-xCox)77B8 (x=0-0.6) Alloy

  • Kwon, H.W.;Yang, C.J.
    • Journal of Magnetics
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    • v.7 no.4
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    • pp.143-146
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    • 2002
  • Mechanical milling technique is considered to be a useful way of processing the fine Nd-Fe-B-type powder with high coercivity. In the present study, phase evolution of the $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ (x=0-0.6) alloys during the high energy mechanical milling and annealing was investigated. The effect of Co-substitution on the crystallization of the mechanically milled $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ amorphous material was examined. The Nd-Fe-B-type alloys can be amorphized completely by a high-energy mechanical milling. On annealing of the amorphous material, fine $\alpha$-Fe crystallites form first from the amorphous. These fine $\alpha$-Fe crystallites reacts with the remaining amorphous afterwards, leading to crystallization to $Nd_2Fe_{14}$B phase. The Co-substitution for Fe in $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ ($\mu$x=0∼0.6) alloys lower significantly the crystallization temperature of the amorphous phase to the $Nd_2Fe_{14}$B phase. The mechanically milled and annealed $Nd_{15}Fe_{77}B_8$ alloy without Co-substitution exhibits consistently better magnetic properties with respect to the alloys with Co-substitution.

Gas Composition within Kimchi Package as Influenced by Temperature and Seasonal Factor (온도 및 계절요인에 따른 포장 김치의 기체조성 변화)

  • Hong, Seok-In;Lee, Myung-Ki;Park, Wan-Soo
    • Korean Journal of Food Science and Technology
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    • v.32 no.6
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    • pp.1326-1330
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    • 2000
  • Kimchi, made from seasonal baechu (Chinese cabbage), was sealed in PP trays with a Nylon/CPP lid film and stored at various temperatures (0, 10, $20^{\circ}C$) to investigate the feasibility of detecting its fermentation degree by measuring gas composition inside the packages. The gas composition inside the kimchi package continuously changed due to $CO_2$ evolution during fermentation. Regardless of temperature, the fermentative gas accumulation in the package caused $CO_2$ concentration to increase by two-stepwise pattern, but $O_2$ concentration to decrease exponentially. As $CO_2$ concentration increased secondarily, the pH values of kimchi decreased proportionally (r>0.968). The production of $CO_2$ during kimchi fermentation was stimulated at higher temperatures and affected by seasonal factor. Kimchi made from winter baechu produced more fermentative gas than that from summer baechu. It was suggested that the changes in $CO_2$ concentration could be used as a characteristic index for indicating the fermentation course of packaged kimchi products.

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A Study on the Optimum Design of Cargo Tank for the LPG Carriers Considering Fabrication Cost (건조비를 고려한 LPG 운반선 화물창의 최적설계에 관한 연구)

  • Shin, Sang-Hoon;Hwang, Sun-Bok;Ko, Dae-Eun
    • Journal of the Society of Naval Architects of Korea
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    • v.48 no.2
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    • pp.178-182
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    • 2011
  • Generally in order to reduce the steel weight of stiffened plate, stiffener spaces tend to be narrow and the plate gets thin. However, it will involve more fabrication cost because it can lead to the increase of welding length and the number of structural members. In the yard, the design which is able to reduce the total fabrication cost is needed, although it requires more steel weight. The purpose of this study is to find optimum stiffener spaces to minimize the fabrication cost for the cargo tank of LPG Carriers. Global optimization methods such as ES(Evolution Strategy) and GA(Genetic Algorithm) are introduced to find a global optimum solution and the sum of steel material cost and labor cost is selected as main objective function. Convergence degree of both methods in according to the size of searching population is examined and an efficient size is investigated. In order to verify the necessity of the optimum design based on the cost, minimum weight design and minimum cost design are carried out.

Fabrication and Characterization of NiCo2O4/Ni Foam Electrode for Oxygen Evolution Reaction in Alkaline Water Splitting (알칼라인 수전해 산소 발생 반응을 위한 NiCo2O4/Ni foam 전극 제조 및 특성 평가)

  • Kwon, Minsol;Go, Jaeseong;Lee, Yesol;Lee, Sungmin;Yu, Jisu;Lee, Hyowon;Song, Sung Ho;Lee, Dongju
    • Journal of Powder Materials
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    • v.29 no.5
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    • pp.411-417
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    • 2022
  • Environmental issues such as global warming due to fossil fuel use are now major worldwide concerns, and interest in renewable and clean energy is growing. Of the various types of renewable energy, green hydrogen energy has recently attracted attention because of its eco-friendly and high-energy density. Electrochemical water splitting is considered a pollution-free means of producing clean hydrogen and oxygen and in large quantities. The development of non-noble electrocatalysts with low cost and high performance in water splitting has also attracted considerable attention. In this study, we successfully synthesized a NiCo2O4/NF electrode for an oxygen evolution reaction in alkaline water splitting using a hydrothermal method, which was followed by post-heat treatment. The effects of heat treatment on the electrochemical performance of the electrodes were evaluated under different heat-treatment conditions. The optimized NCO/NF-300 electrode showed an overpotential of 416 mV at a high current density of 50 mA/cm2 and a low Tafel slope (49.06 mV dec-1). It also showed excellent stability (due to the large surface area) and the lowest charge transfer resistance (12.59 Ω). The results suggested that our noble-metal free electrodes have great potential for use in developing alkaline electrolysis systems.

MOLECULAR GAS PROPERTIES UNDER ICM PRESSURE IN THE CLUSTER ENVIRONMENT

  • LEE, BUMHYUN;CHUNG, AEREE
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.491-494
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    • 2015
  • We present 12CO (2-1) data for four spiral galaxies (NGC 4330, NGC 4402, NGC 4522, NGC 4569) in the Virgo cluster that are undergoing different ram pressure stages. The goal is to probe the detailed molecular gas properties under strong intra-cluster medium (ICM) pressure using high-resolution millimeter data taken with the Submillimeter Array (SMA). Combining this with Institut de RadioAstronomie $Millim{\acute{e}}trique$ (IRAM) data, we also study spatially resolved temperature and density distributions of the molecular gas. Comparing with multi-wavelength data (optical, $H\small{I}$, UV, $H{\alpha}$), we discuss how molecular gas properties and star formation activity change when a galaxy experiences $H\small{I}$ stripping. This study suggests that ICM pressure can modify the physical and chemical properties of the molecular gas significantly even if stripping does not take place. We discuss how this affects the star formation rate and galaxy evolution in the cluster environment.

Chemistry of Carbonate-Sulfur Flux

  • Q. Won Choi;Choi Han;Chang So-Young;Pyun Chong-Hong;Kim Chang-Hong
    • Bulletin of the Korean Chemical Society
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    • v.15 no.12
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    • pp.1118-1121
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    • 1994
  • Reactions of alkaline metal carbonates with sulfur are investigated in detail. The evolution of CO and a trace of $SO_2$ were observed in the course of reaction with major component of polysulfides. Some evidences that the reaction proceeds with breaking of terminal sulfur-sulfur bond in the sulfur polymer, and forming CO, $SO_2$ and polysulfide are presented. Polysulfides have the role of keeping free sulfur and allow it to react with other chemicals to rather high temperatures.plexes, whereas the binuclear and mononuclear complexes of Mn$^{2+}$ and Co$^{2+}$

QUANTIFYING DARK GAS

  • LI, DI;XU, DUO;HEILES, CARL;PAN, ZHICHEN;TANG, NINGYU
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.75-78
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    • 2015
  • A growing body of evidence has been supporting the existence of so-called "dark molecular gas" (DMG), which is invisible in the most common tracer of molecular gas, i.e., CO rotational emission. DMG is believed to be the main gas component of the intermediate extinction region from Av~0.05-2, roughly corresponding to the self-shielding threshold of $H_2$ and $^{13}CO$. To quantify DMG relative to $H{\small{I}}$ and CO, we are pursuing three observational techniques; $H{\small{I}}$ self-absorption, OH absorption, and THz $C^+$ emission. In this paper, we focus on preliminary results from a CO and OH absorption survey of DMG candidates. Our analysis shows that the OH excitation temperature is close to that of the Galactic continuum background and that OH is a good DMG tracer co-existing with molecular hydrogen in regions without CO. Through systematic "absorption mapping" by the Square Kilometer Array (SKA) and ALMA, we will have unprecedented, comprehensive knowledge of the ISM components including DMG in terms of their temperature and density, which will impact our understanding of galaxy evolution and star formation profoundly.

Fabrication of Metal-biochar Composite through CO2 Assisted Co-pyrolysis of Chlorella and Red Mud and Its Application for Persulfate Activation (녹조류와 적니의 이산화탄소환경 공동열분해를 통한 탄소-철 복합체 생성 및 과황산염 활성화를 통한 수중 염료 제거)

  • Jang, Hee-Jin;Kwon, Gihoon;Yoon, Kwangsuk;Song, Hocheol
    • Journal of Soil and Groundwater Environment
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    • v.27 no.1
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    • pp.31-38
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    • 2022
  • The common algae and industrial waste, chlorella and red mud, were co-pyrolyzed in carbon dioxide condition to fabricate iron-biochar composite. In order to investigate the direct effect of chlorella and red mud in the syngas generation and the property of biochar, experiments were performed using mixture samples of chlorella and red mud. The evolution of flammable gasses (H2, CH4, CO) was monitored during pyrolysis. The produced biochar composite was employed as a catalyst for persulfate activation for methylene blue removal. BET analysis indicated that the iron-biochar composite mainly possessed meso- and macropores. The XRD analysis revealed that hematite (Fe2O3) contained in red mud was transformed to Fe3O4 during co-pyrolysis. The composite effectively activated persulfate and removed methylene blue. Among the composite samples, the composite fabricated from the mixture composed of 1:2 chlorella:red mud showed the best performance in syngas generation and methylene blue removal.

DNA Barcoding for Diophrys quadrinucleata (Ciliophora: Euplotia) from South Korea

  • Chae, Kyu-Seok;Min, Gi-Sik
    • Animal Systematics, Evolution and Diversity
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    • v.38 no.4
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    • pp.274-278
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    • 2022
  • One marine ciliate, Diophrys quadrinucleata Zhang et al., 2020 was newly recorded from South Korea in this study. We provided morphological diagnosis and images of the Korean D. quadrinucleata population. We determined the small subunit ribosomal DNA (SSU rDNA) and cytochrome oxidase subunit I (CO1) sequence data of D. quadrinucleata, and then the sequences were compared with other Diophrys species. Intra-specific variation between the Korean and type (Chinese) populations was identical in the SSU rDNA, while the inter-specific variations between seven Diophrys species were 0.3-3.8% in the SSU rDNA and 12.6-18.2% in the CO1. In this study, we obtained 18S and CO1 data from species with identified morphology. As the importance of securing 18S and CO1 based on morphology increases in current studies, this study will contribute to ciliate studies.

The Effect of Addition of Ti and Co Elements on Microstructural control and Characteristics of Vacuum-casted Cu-25 wt%Cr Electrical Contact Material (Ti과 Co 첨가가 진공주조법으로 제조된 Cu-25 wt%Cr 난가공성 중고압용 전기접점 소재의 미세구조 제어 및 물성에 미치는 영향)

  • Hye Sung Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.37 no.4
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    • pp.172-181
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    • 2024
  • In this study, the effect of addition of Ti and Co elements on microstructural evolution and characteristics of vacuum-casted Cu-25%Cr electrical contact material was investigated. The coarse and insoluble Cr phases with an average size of 300 ㎛ in commercial Cu-25%Cr alloy were reduced to tens of micrometers in vacuum casted Cu-25%Cr-X(X=Ti, Co) alloy, which can be interpreted as result controlling coarsening and the work-frame structure of the insoluble Cr phase by the formation of intermetallic compounds such as Cr2Ti or Cr0.5Co1.5Ti around the Cr phase As a result, the electrical properties such as weight loss and fusion resistance against the repeated arc generation of the electrical contact material as well as the mechanical properties were greatly improved.