• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2012.05a
• /
• pp.71-72
• /
• 2012

The purpose of this study is not only fixation of carbon dioxide using the cement-Paste solution's calcium ion by wet carbonating reaction but also quantitatively evaluate the possibility of storage technology of Carbon dioxide. wet carbonation is reaction of CO₂ injection by CO₂ reactor. As a result of experiment, the carbon dioxide is fixed, and high-purity Calcium Carbonate is eluted.

• Journal of the Korean Ceramic Society
• /
• v.55 no.1
• /
• pp.44-49
• /
• 2018

The use of fossil fuels is steadily increasing. The thermal power generation industry uses a lot of energy and emits a large amount of greenhouse gases. On the other hand, a desulfurization facility can be installed to remove sulfur content during boiler combustion process of the power plant. Dry desulfurized gypsum generated from dry desulfurization facilities is suitable as a $CO_2$ absorbing material due to the presence of CaO. In this study, the carbonation properties of dry desulfurized gypsum were investigated by carbonizing dry desulfurized gypsum via mixing with water and stirring. As a result of microstructural, XRD and thermal analyses of the carbonized dry desulfurized gypsum, the carbonation age was found to be suitable for 16 h. Dry desulfurized gypsum absorbs about 16% of $CO_2$ per unit weight.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.33 no.6
• /
• pp.226-233
• /
• 2023

In this study, the basic physical properties and microstructure of concrete interlocking blocks with amount of different CO₂ gas injection were analyzed according to determine the applicability of In-situ carbonation technology to construction secondary products. The amount of carbon dioxide gas injection was selected as 0, 0.1, 0.3, 0.5, 0.7 wt.% compared to cement amount. A lab-scale press equipment was designed to apply developed carbonation technology to real construction site. And mixer for stable CO₂ gas injection was designed. Using the designed devices, CO₂ gas injected samples were created and physical property of samples were performed. As a result of the physical property test, as the CO₂ injection amount increased to 0.3 %, it showed higher strength behavior compared to the original mix. And more than 0.5 % samples showed lower strength behavior than original sample, but they satisfied the standard of concrete interlocking block. This results were determined that CO₂ injection contributed to the creation of hydrates such as C-S-H. Therefore, the possibility of applying carbonation technology, which injects CO₂ during mixing, to various secondary construction products was confirmed.

• Proceedings of the IEEK Conference
• /
• 2001.10a
• /
• pp.586-591
• /
• 2001

This research investigated the feasibility of the accelerated carbonation of cement waste forms with carbon dioxide in a supercritical state. Hydraulic cement has been used as a main solidification matrix for the immobilization of radioactive and/or hazardous wastes. As a result of the hydration reaction for major compounds of portland cement, portlandite (Ca(OH)$_2$) is present in the hydrated cement waste form. The chemical durability of a cement form is expected to increase by converting portlandite to the less soluble calcite (CaCO$_3$). For a faster reaction of portlandite with carbon dioxide, SCCD (supercritical carbon dioxide) rather than gaseous $CO_2$, in ambient pressure is used. The cement forms fabricated with an addition of slated lime or Na-bentonite were cured under ambient conditions for 28days and then treated with SCCD in an autoclave maintained at 34$^{\circ}C$ and 80atm. After SCCD treatment, the physicochemical properties of cement matrices were analyzed to evaluate the effectiveness of accelerated carbonation reaction. Conversion of parts of portlandite to calcite by the carbonation reaction with SCCD was verified by XRD (X-ray diffraction) analysis and the composition of portlandite and calcite was estimated using thermogravimetric (TG) data. After SCCD treatment, tile cement density slightly increased by about 1.5% regardless of the SCCD treatment time. The leaching behavior of cement, tested in accordance with an ISO leach test method at 7$0^{\circ}C$ for over 300 days, showed a proportional relationship to the square root of the leaching time, so the major leaching mechanism of cement matrix was diffusion controlled. The cumulative fraction leached (CFL) of calcium decreased by more than 50% after SCCD treatment. It might be concluded that the enhancement of the characteristics of a cement matrix by an accelerated carbonation reaction with SCCD is possible to some extent.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.11 no.4
• /
• pp.307-315
• /
• 2023

In this study, mortar test specimens were produced by varying the mixing ratio of CO₂ reaction hardening cement (CSC) and general cement (OPC), and the mechanical and carbonation characteristics were evaluated by controlling the primary curing temperature and secondary curing CO₂ pressure. Under all curing conditions, it was observed that the higher the CSC ratio in the binder, the lower the mechanical properties. Specifically, a first curing temperature of 60 ℃ yielded higher mechanical properties compared to the case of 20 ℃, and a greater carbonation penetration depth was also observed. At a first curing temperature of 60 ℃, it was noted that the curing pressure and bending strength during the second CO₂ curing were inversely proportional, while the compressive strength showed a proportional relationship. This phenomenon is believed to be due to excessive carbonation, which reduces mechanical properties, and the fact that flexural strength is more sensitive to these properties compared to compressive strength. However, based on the evaluation of the limited curing conditions, it is evident that future test conditions need to be expanded and reviewed more thoroughly.

• Korean Chemical Engineering Research
• /
• v.55 no.2
• /
• pp.141-155
• /
• 2017

In the present paper, we investigated the development status of precipitated calcium carbonate (PCC) production using steel slag, which is one of mineral carbonation (MC) technologies, from the standpoint of $CO_2$ utilization. Principle, feature, and global and domestic development status of the mineral carbonation technology were discussed together with the overview of the production method and market of PCC. Mineral carbonation is known as stable and environmentally-friendly technology enabling economical treatment of industrials wastes. Typically, PCC is produced by the reaction of $CO_2$ with supernatant solution after Ca extraction from steel slag followed by the separation of solid and liquid. The development status of MC using steel slag is at the pilot stage (Slag2PCC at Aalto University), and there remains the process economics improvement for commercialization. Key technologies for the further development are efficient extraction of Ca ions from steel slag including impurities removal, valorization of PCC via shape and size control, usage development and value-addition of residual slag, and optimization of reaction conditions for continuous process setup, etc.

• Journal of the Korea Concrete Institute
• /
• v.24 no.5
• /
• pp.577-584
• /
• 2012

Carbonation resistance is one of the most influencing factors on durability of concrete. Alkali activated slag (AAS) is known to have weaker resistance for carbonation than OPC due to the low calcium contents. In this paper, the carbonation characteristic of AAS mortar which is related to the basicity (CaO/$SiO_2$) was investigated. In order to give the various basicity conditions, SM (source material) was blended with quicklime (CaO) and silicon dioxide ($SiO_2$) by adopting mechano-chemical treatment method. Experiments including flow test, compressive strength test, carbonation depth test, together with XRD, FTIR and TGA were employed to evaluate the effects of basicity of SM on the carbonation characteristics. The test results showed that the carbonation resistance effectively increased with the increase of the basicity of SM.

• Corrosion Science and Technology
• /
• v.4 no.2
• /
• pp.69-74
• /
• 2005

The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady state within about five hours after exposure. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2017.05a
• /
• pp.165-166
• /
• 2017

Corrosion of reinforcement is the main factors affecting the durability of reinforced concrete in the world which lead to the failure of structures of reinforced concrete buildings. In this research, mixed brucite(Mg(OH)₂) into ordinary portland cement paste in ratio of 5, 10 and 15% as a kind of CO₂ fixation material. Samples were exposed to an accelerated carbonation enslavement of 20% CO₂ concentration, 60% relative humidity, and a temperature of 20℃ until tested at 3d, 7d, 14d and 28d. After 28d CO₂ accelerated curing, in the paste containing MH megnesian calcite was found by XRD and SEM-EDX. Meanwhile, paste containing Mg(OH)₂ exhibit the better pore distribution than ordinary portland cement paste and relatively good compressive strength.

• Journal of the Mineralogical Society of Korea
• /
• v.28 no.1
• /
• pp.39-49
• /
• 2015

Recently, carbon capture and storage (CCS) techniques have been globally studied. This study was conducted to use waste cement powder as an efficient raw material of mineral carbonation for $CO_2$ sequestration. Direct aqueous carbonation experiment was conducted with injecting pure $CO_2$ gas (99.9%) to a reactor containing $200m{\ell}$ reacting solution and the pulverized cement paste (W:C = 6:4) having particle size less than 0.15 mm. The effects of two additives (NaCl, $MgCl_2$) in carbonation were analyzed. The characteristics of carbonate minerals and carbonation process according to the type of additives and pH change were carefully evaluated. pH of reacting solution was gradually decreased with injecting $CO_2$ gas. $Ca^{2+}$ ion concentration in $MgCl_2$ containing solution was continuously decreased. In none $MgCl_2$ solution, however, $Ca^{2+}$ ion concentration was increased again as pH decreased. This is probably due to the dissolution of newly formed carbonate mineral in low pH solution. XRD analysis indicates that calcite is dominant carbonate mineral in none $MgCl_2$ solution whereas aragonite is dominant in $MgCl_2$ containing solution. Unstable vaterite formed in early stage of experiment was transformed to well crystallized calcite with decreasing pH in the absence of $MgCl_2$ additives. In the presence of $MgCl_2$ additives, the content of aragonite was increased with decreasing pH whereas the content of calite was decreased.