• Title/Summary/Keyword: $CO_2$ 흡착

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The Effects Influencing Soil Adsorption by various Chemical Compounds (다양한 화합물이 토양의 흡착 거동에 미치는 영향)

  • Ahn, Jong-Pil;Park, Sang-Bum;Ahn, Ki-Mun;Heo, Hong-Kyun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1098-1108
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    • 2008
  • Batch type and column type experiments were performed in order to predict adsorption and movement within soil. Clay minerals montmorillonite and kaolinite were respectively added to paraquat which is a cationic compound with long residual time, 2,4-D which is an anionic compound with relatively short residual time and napropamide which is an amphoteric compound. Therefore, it is very important to determine the movements of toxic pollutants in the ground soil to establish measures to prevent soil grounds contamination and to restore contaminated soils effectively, because contamination of soil is getting severe due to these toxic wastes, industrial waste water, and agricultural chemicals, etc. Therefore, in this study, we have carried out column and batch experiments by using general toxic organic compounds as test samples in order to restore contaminated soils effectively as well as to prepare a basic data to develop absorbents that will remove various toxic organic compounds, with a grandiose purpose to prevent contaminations of soil and grounds due to various toxic organic compounds.

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The method to reduce the travel time of the gentry in (sLb-Camera-pLb) type ((sLb-Camera-pLb)타입의 겐트리 이동시간 단축 방법)

  • Kim, Soon-Ho;Kim, Chi-Su
    • Journal of the Korea Convergence Society
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    • v.10 no.4
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    • pp.39-43
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    • 2019
  • The gantry of surface mount equipment (SMD) is responsible for transferring parts from the feeder to the PCB. At this time, the moving time of the gantry affects the yield. Therefore, in this paper, we propose the fastest path from the suction to the mounting to reduce the gantry travel time. This path is a case where the velocity in front of the camera is 2m/sec due to the nature of the gantry. Therefore, the trajectory graph of this case was created through simulation and the travel time was calculated. As a result, we can see that the moving time of the moving-motion method proposed in this paper is 20% shorter than the current stop-motion method.

Synthesis and Characterization of Zeolite 4A on Activated Carbon Supports (활성탄 지지체상에서 제올라이트 4A 합성 및 특성)

  • Park, Jeong-Hwan;Suh, Jeong-Kwon;Jeong, Soon-Yong;Lee, Jung-Min;Doh, Myung-Ki
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.204-210
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    • 1997
  • Zeolite 4A-impregnated complex molecular sieve was prepared by hydrothermal reaction after aluminosilicate gel was penetrated into the pore of activated carbon granule. The crystals of zeolite 4A mainly were formed in the macropore of activated carbon, and their average diameter is $0.8{\mu}m$. The pore volume of activated carbon granule is $0.67m{\ell}/g$, and the pore volume of the sample including 21.6wt% of zeolite 4A crystal is $0.41m{\ell}/g$ decreasing the pore volume by 40% due to the crystallization of zeolite 4A crystals on the internal surface of activated carbon. The calcium ion exchange capacity of zeolite 4A-impregnated sample is 320mg $CaCO_3/g$ zeolite, and this value is almost the same as that of zeolite 4A powder. The crystal of zeolite 4A was not separated from the support of activated carbon granule in the course of ultrasonic dispersion. The adsorption isotherm of water on zeolite 4A-impregnated sample shows the intermediate shape between types, I and III. In addition, zeolite 4A-impregnated sample shows the hydrophilic and hydrophobic properties simultaneously.

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A Study on the Propane Dehydrogenation activity of Pt-Sn catalyst using MgAl2O4 support (MgAl2O4 지지체를 이용한 Pt-Sn/MgAl2O4의 프로판 탈수소 활성 연구)

  • Byun, Hyun-Joon;Koh, Hyounglim
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.757-767
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    • 2018
  • In the propane dehydrogenation reaction proceeding at high temperature, the main cause of deactivation of the catalyst is coke deposition and sintering. In order to investigate the catalysts for reducing such inactivation, we have investigated the applicability of $MgAl_2O_4$ as a carrier for the catalytic dehydrogenation reaction. $MgAl_2O_4$ was prepared by Alcohthermal method at calcination temperature of 800, 900, $1000^{\circ}C$, and $Pt-Sn/MgAl_2O_4$ catalyst was prepared by supporting Pt and Sn by co-impregnation method. The reaction temperature was conducted at a high temperature of 650, $600^{\circ}C$ to confirm the thermal stability. As a result of the reaction experiment, it was confirmed that the conversion rate and yield of propane dehydrogenation reaction test were higher than that of the carrier-applied catalyst having a carrier calcination temperature of 900 and $1000^{\circ}C$, when the carrier-applied catalyst having a calcination temperature of $800^{\circ}C$ was used, It was found that the yield was higher than that of $Pt-Sn/{\theta}-Al_2O_3$ at $650^{\circ}C$. TGA, BET, XRD, CO-chemisorption, and SEM-EDS analyzes were performed for characterization. $MgAl_2O_4-800^{\circ}C$ was correlated with the relationship between good yield, Pt dispersion and low deactivation rate.

Effects of Process Variables on the Microstructure and Gas Sensing Characteristics of Magnetron Sputtered $\textrm{SnO}_2$Thin Films (마그네트론 스퍼터링 증착 조건에 따른 $\textrm{SnO}_2$ 박막의 미세구조와 가스검지특성 변화)

  • Kim, Jong-Min;Moon, Jong-Ha;Lee, Byung-Teak
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1083-1087
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    • 1999
  • Microstructures and the gas-sensing characteristics of the $\textrm{SnO}_2$ thin films were studied, which were deposited at various conditions (rf power, sample temperature, $\textrm{O}_2$/Ar ratio) by the rf magnetron sputtering. As a result, six typical microstructures were derived, such as amorphous(A), amorphous mixed with polycrystalline grains (A+P), polycrystalline with random crystalographic orientation (P), fine columnar (FC), coarse columnar (CC) and Zone T (T) with dense fiberous structure. Typically, A, A+ P, and P structures were formed when no $\textrm{O}_2$ was added to the sputter gas, whereas FC, CC, and T structures were obtained when $\textrm{O}_2$ was added. The A structure formed at low rf power and low temperature, the A+P at high rf power and low temperature, and the P at high rf power and high temperature. The FC structure was obtained at low rf power and low temperature. the CC at low rf power and high temperature, and the T at high rf power and low temperature. Results of the gas-sensing test of the sensor chips fabricated from the typical films indicated that the fine columnar microstructure shows the highest sensitivity both at $300^{\circ}C$ and $400^{\circ}C$. It was proposed that this is due to the high specific surface area of the micro-columns.

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Bioavailability Soil-aged Residues of the Herbicide Bentazon to Rice Plants (토양중(土壤中) 신생(新生) 및 숙성(熟成) Bentazon 잔유물(殘油物)의 벼에 의(依)한 흡수(吸收))

  • Lee, Jae-Koo;Kyung, Kee-Sung;Fuhr, F.
    • Applied Biological Chemistry
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    • v.32 no.4
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    • pp.393-400
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    • 1989
  • The amounts of $^{14}CO_2$ evolved during the $^{14}C-bentazon$ aging in soil for 3 and 6 months were 6.1 and 14.8% of the original radioactivity, respectively. The presence of earthworms in soil tended to increase the uptake of $^{14}C-bentazon$ by the roots of rice plants, even if it was not statistically significant. The evolution of $^{14}CO_2$ from $^{14}C-bentazon$ in soil increased in the presence of rice plants and earthworms compared with in the absence of them. The uptake of $^{14}C-bentazon$ residues by rice plants decreased remarkably with increasing the aging period within the limit of 3 months both in the absence and presence of earthworms, but there is not much difference between 3-month-aging and 6-month-aging. Much larger amounts of $^{14}C-labelled$ compounds were translocated to the shoots, compared with the data from a previous investigation using maize plants. The amount of non-extractable bound residue increased remarkably with the aging period up to 3 months. The polarity of the compounds extracted from soil increased with the aging and the growing of rice plants, indicating the formation of some polar metabolites.

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Studies on the Recovery of Triglyceride from Used Shortening by Supercritical Fluid Extraction (초임계유체 추출에 의한 폐식용유의 재활용에 대한 기초연구)

  • Han, Byung-Seok;Yoon, Jung-Ro;Kwon, Young-An;Jung, Mun-Yhung;Kim, Kong-Hwan
    • Korean Journal of Food Science and Technology
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    • v.31 no.5
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    • pp.1300-1307
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    • 1999
  • Supercritical fluid extraction was applied to recycling triglyceride from used shortening. Used shortening and its fractions were analyzed with high performance size exclusion chromatography for their composition in triglycerides, polymer and low molecular weight compounds. Conjugated diene value and color of the fractions were also measured with a UV spectrophotometer and a colorimeter, respectively. Pressure and temperature ranges employed were $15{\sim}30$ MPa and $40{\sim}60^{\circ}C$, respectively. Concentration of fat in supercritical (SC) $CO_2$ ranged from $0.3\;X\;10^{-3}{\sim}7.4\;X10^{-3}(g\;fat/g\;CO_2)$. An exponential relation between concentration of fat in SC $CO_2$ and density was observed. Color of the extracts was light yellow which was very close to that of the fresh shortening. Low molecular weight compounds were preferentially concentrated in the initial fraction, while polymer was extracted in the final fraction. Conjugated diene value of the initial fractions was clearly lower than that of feed. It increased sharply as the polymer content in the fraction became significantly large.

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The Importance of Monitoring Wells Maintenance in Improving Groundwater Quality (지하수 관측정의 시설개선에 따른 수질변화와 유지관리에 대한 연구)

  • Kim, Jeong-Woo;Seo, Yongkyo;Kim, Rak-Hyeon;Cheon, Jeong-Yong
    • The Journal of Engineering Geology
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    • v.24 no.2
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    • pp.283-295
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    • 2014
  • Groundwater monitoring wells are important to maintain their performance for long term monitoring. The monitoring wells with extensive internal incrustation by clay adsorption were selected for this study. The performance of these monitoring wells was improved by pump washing, tube replacements for dedicated samplers, and well surging. After each improvement, the Mg, Mn, and Zn concentrations were increased. The results show that under these conditions, the monitoring wells must be carefully inspected at least once a year. Even in the case of no abnormal phenomenon like as internal incrustation, the monitoring wells need to be serviced at least once every four to five years to guarantee that they are effectively monitoring groundwater quality.

An Study on Development of Water Systems Damage Management Standard Caused by Mt. Baekdu Eruption (백두산 분화로 인한 상수도 시설 피해 관리 기준 설정 연구)

  • Choi, Jung-Ryel;Kim, Min Gyu;Lee, Gyeng-Bin;Chung, Il-Moon
    • The Journal of Engineering Geology
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    • v.28 no.2
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    • pp.259-266
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    • 2018
  • The purpose of this study is to establish the management standards of water systems in Korea. The damage factors of the water systems were classified by accumulation, adsorption, and abrasion. According to the thickness of volcanic ash, the management stage of the water systems was derived in four steps; VAD (Volcanic Ash Degree) I (0~1 mm), II (1~3 mm), III (3~5 mm), IV (over 5 mm). Finally, the management standards for water systems which consist of alarm levels, impacts of volcanic ashes, procedures and action plan to deal with the damage, are presented.

Estimation of Carbon Absorption Distribution by Land Use Changes using RS/GIS Method in Green Land (RS/GIS를 이용한 토지이용변화에 의한 녹지의 이산화탄소 (CO2) 흡착량 분포 추정)

  • Na, Sang-Il;Park, Jong-Hwa;Park, Jin-Ki
    • Journal of The Korean Society of Agricultural Engineers
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    • v.52 no.3
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    • pp.39-45
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    • 2010
  • Quantification of carbon absorption and understanding the human induced land use changes (LUC) forms one of the major study with respect to global climatic changes. An attempt study has been made to quantify the carbon absorption by LUC through remote sensing technology. The Landsat imagery four time periods was classified with the hybrid classification method in order to quantify carbon absorption by LUC. Thereafter, for estimating the amount of carbon absorption, the stand biomass of forest was estimated with the total weight, which was the sum of individual tree weight. Individual tree volumes could be estimated with the crown width extracted from digital forest cover type map. In particular, the carbon conversion index and the ratio of the $CO_2$ molecular weight to the C atomic weight, reported in the IPCC guideline, was used to convert the stand biomass into the amount of carbon absorption. Total carbon absorption has been modeled by taking areal estimates of LUC of four time periods and carbon factors for land use type and standing biomass. Results of this study, through LUC suggests that over a period of construction, 7.10 % of forest and 9.43 % of barren were converted into urban. In the conversion process, there has been a loss of 6.66 t/ha/y (7.94 %) of carbon absorption from the study area.