• Title/Summary/Keyword: $CO_2$ 흡수

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Synergistic Effects of N-methyl-2-pyrrolidone on Skin Permeation of a Hydrophobic Active Ingredient (N-methyl-2-pyrrolidone 제제의 경피흡수촉진효과)

  • Lee, Geun-Soo;Lee, Dong-Hwan;Kim, Kyoung-Bum;Ko, Hyun-Joo;Pyo, Hyeong-Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.2
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    • pp.115-120
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    • 2010
  • The formidable barrier property of the stratum cornemum and the high hydrophilicity of active ingredient make it difficult to permeate through the skin and reach to its site of action. The aim of this study was to investigate the effect of chemical penetration enhancers on the skin permeation of a hydrophilic cosmetic active ingredient, such as arbutin. The enhancing effects of N-methyl-2-pyrrolidone (NMP) on the permeation of a hydrophilic cosmetic active ingredient were evaluated by using Franz diffusion cell. The study indicated that NMP has considerable influence on the skin permeability. NMP was not only the most effective enhancer but also increased the skin permeability of arbutin approximately 1.3~1.5 fold compared with control without penetration enhancer. The lag time did not change with NMP, which suggested no effect of NMP on skin lipid fluidity. This suggest that arbutin co-permeated with NMP. The results indicate NMP is effective enhancer of a hydrophilic cosmetic active ingredient in penetration, with potential applications for drug delivery system.

Study of continuous regeneration of carbon dioxide sorbent using amino acid salt (아미노산염을 이용한 이산화탄소 흡수제 연속 재생에 관한 연구)

  • Choi, Jin-Sik;Kim, Jae Gang;Lee, Jun Hyung;Chu, Yeon Jin;Lee, Ju-Yeol;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.947-953
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    • 2017
  • In this study, the regeneration efficiency of the amino acid salt absorbent which can be applied to carbon dioxide absorption / regeneration process was confirmed. The regeneration efficiency has a great influence on the economical judgment of the process. so, continuous regeneration experiment was conducted to establish economical process. The amino acid salts used in the experiments are Potassium L-lysinate and Potassium L-alaninate. Each amino acid and potassium hydroxide(KOH) were mixed at a 1: 2 molar ratio. In order to confirm the regeneration efficiency of the absorbent, carbon dioxide was absorbed in the two materials, and the carbon dioxide desorption experiment was carried out by heating. The initial reaction rate was L-alanine was faster. Over time, L-lysine, desorption higher concentrations of carbon dioxide. L-lysine showed higher regeneration efficiency than L-alanine, (L-alanine 47.26% and L-lysine 62.11%). As a result of the continuous regeneration experiment using the L-lysine having good absorption and regeneration efficiency, it was confirmed that the regeneration efficiency decreases as the number of regeneration increases.

Study of CO2 Carbonation-Regeneration Characteristics of Potassium-Based Dry Sorbents According to Water Vapor Contents of Inlet Gas and Regeneration Temperature in the Cycle Experiments of Bubbling Fluidized-Bed Reactor (회분식 기포유동층 반응기에서 K-계열 건식흡수제의 주입수분농도 및 재생반응온도에 따른 CO2 흡수-재생 반응특성 연구)

  • Park, Keun-Woo;Park, Yeong Seong;Park, Young Cheol;Jo, Sung-Ho;Yi, Chang-Keun
    • Korean Chemical Engineering Research
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    • v.47 no.3
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    • pp.349-354
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    • 2009
  • In this study, a bubbling fluidized-bed reactor was used to study $CO_2$ capture from flue gas using a potassium-based dry sorbent. A dry sorbent, manufactured by the Korea Electric Power Research Institute, consists of 35% of $K_2CO_3$ for $CO_2$ absorption and 65% of supporters for mechanical strength. $H_2O$, a reactant of the carbonation reaction, was supplied in the reactor as a form of saturated water vapor at a given temperature. The experiment of the regeneration reaction was performed by raising up to a given temperature using $N_2$ as a fluidization gas. It was indicated that sorption capacity and regenerability of dry sorbents showed high-efficiency at $1.97\;mol\;H_2O/mol\;CO_2$ and $400^{\circ}C$, respectively. The regenerated sorbent samples were analyzed by TGA to confirm the extent of the reaction. When the regeneration temperature was $150^{\circ}C$, the regenerability of dry sorbents was about 60%, which was capable of applying those sorbents to a two-interconnected fluidized-bed reactor system with continuous solid circulation. The results obtained in this study can be used as basic data for designing and operating a large scale $CO_2$ capture process with two fluidized-bed reactors.

Development of a Methanol Absorption System for the Removal of $H_2S$, COS, $CO_2$ in Syngas from Biomass Gasifier (바이오매스 가스화 내의 $H_2S$, COS, $CO_2$ 복합 제거를 위한 메탄올 흡수탑 개발)

  • Eom, Won Hyun;Kim, Jae Ho;Lee, See Hoon
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.23-27
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    • 2012
  • To make synthetic liquid fuel from biomass such as wood pellet, energy crop and so on, a biomass to liquid (BTL) process by using a biomass gasifier with Fisher-Tropsch (FT) reaction was developed. However $H_2S$, COS and $CO_2$ in syngas from biomass gasifiers resulted in a decrease of the conversion efficiency and the deactivation of the catalyst. To remove acid gases in syngas, a lab-scale methanol absorption tower was developed and the removal characteristics of acid gases were investigated. The methanol absorption tower efficiently removed $H_2S$ and COS with a removal of $CO_2$, so it could be useful process for the BTL process.

Comparing Net CO2 Uptake of Schlumbergera truncata 'Pink Dew' Phylloclades in a Growth Chamber and a Greenhouse (생육상과 온실에서 게발선인장 '핑크듀'의 엽상경별 CO2 흡수율 비교)

  • Seo Hee Jung;Ah Ram Cho;Yoon Jin Kim
    • Journal of Bio-Environment Control
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    • v.32 no.1
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    • pp.64-71
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    • 2023
  • Crassulacean acid metabolism (CAM) plants use surplus CO2 generated by cooling and heating at night when ventilation is not needed in a greenhouse. Schlumbergera truncata 'Pink Dew' is a multi-flowering cactus that needs more phylloclades for high-quality production. This study examined photosynthetic characteristics by the phylloclade levels of S. truncata in a growth chamber and a greenhouse for use of night CO2 enrichment. The CO2 uptake rate of the S. truncata's top phylloclade in a growth chamber exhibited a C3 pattern, and the second phylloclade exhibited a C3-CAM pattern. The CO2 uptake rate of the top phylloclade in a greenhouse showed a negative value both day and night, but those of the second phylloclade exhibited a CAM pattern. The stomatal conductance and water-use efficiency (WUE) of S. truncata at both the top and second phylloclades were higher in a growth chamber than in a greenhouse. The WUE of S. truncata in a growth chamber and a greenhouse was higher at the second phylloclade, which is a CAM pattern compared with those of the top phylloclade. The daily total net CO2 uptake of S. truncata was higher in a growth chamber than in a greenhouse. The daily total net CO2 uptake of S. truncata at the second phylloclade had the highest value of 155 mmol·m-2·d-1 in a growth chamber. The night total CO2 uptake of S. truncate at the second phylloclade was 3-fold higher in a growth chamber than in a greenhouse. S. truncata's second phylloclade exhibited a CAM pattern that uptake CO2 at night, and the second phylloclade, was more mature than the top phylloclade. A multi-flowering cactus S. truncata 'Pink Dew' efficiently uptake night surplus CO2 in the proper environmental condition with matured phylloclade.

Development of High-Durability Ceramic Hollow Fiber and Performance Evaluation of Contact Membrane Process according to Pressure Conditions (고내구성 세라믹 중공사 개발과 압력 조건에 따른 접촉막 공정의 특성 평가)

  • Lee, Seung Hwan;Jeong, Byeong Jun;Shin, Min Chang;Zhuang, Xuelong;Jung, Jiwon;Lee, Yeon Jun;Won, Dongyeon;Park, Jung Hoon
    • Membrane Journal
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    • v.30 no.6
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    • pp.443-449
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    • 2020
  • In this study, CO2 separation experiment was performed on a CH4/CO2 mixed gas using a ceramic hollow fiber membrane contactor module (HFMC). In order to fabricate high-durability HFMC, a high-durability hollow fiber membrane was prepared and evaluated. HFMC was fabricated using the prepared hollow fiber membrane, and the experiment used a mixture of CH4/CO2 (30% CO2, CH4 balance) and monoethanolamine (MEA). During HFMC operation, the effect of gas and absorbent pressure on the CO2 removal efficiency was evaluated. The CO2 removal efficiency increased as the gas pressure increased, and the CO2 absorption flux also showed a tendency to increase with the liquid flow rate. In addition, when the CO2 absorption rate was less than 40%, LTS-1, a counter-current form where the absorbent enters from the bottom, has higher CO2 removal performance than LTS-2, a countercurrent form in which the absorbent enters from the top. and when the absorption rate was 40% or higher, LTS-2 had higher performance than LTS-1.

LiF(Mg, Cu, Na, Si) Thermoluminescent Dosimeters for In-phantom Dosimetry of $^{60}Co\;{\gamma}$-rays (LiF(Mg, Cu, Na, Si) 열형광선량계를 사용한 $^{60}Co\;{\gamma}^-$선의 수중 흡수선량 측정)

  • Kim, Hyun-Ja;Chung, Woon-Hyuk;Lee, Woo-Gyo;Doh, Sih-Hong
    • Journal of Radiation Protection and Research
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    • v.15 no.2
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    • pp.57-65
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    • 1990
  • Newly developed LiF(Mg, Cu, Na, Si) thermoluminescence phosphors sealed in a plastic capsules (32mm dia., 0.9mm wall thickness) were used for in-phantom dosimetry of $^{60}Co$ $\gamma$-irradiation. The absorbed doses in water were determined by applying the general cavity theory to the absorbed dose in TLD cavity, which was computed from exposure. The absorbed doses at various sites in the water-phantom were measured by LiF(Mg, Cu, Na, Si) TLD and compared with doses obtained by the ionization method. Both results were consistent within the experimental fluctuation$({\pm}3%)$ Central axis percentage depth doses and phantom-air ratios measured by LiF(Mg. Cu, Na, Si) TLD showed good agreement with the published values[Br. J. Radiology, Suppl. 17(1983)].

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The evaluation of absorbed dose of rectum for the patient of intracavitary treatment $^{60}$ Co by MgB$_4$O$_{7}$ (Mn) TLD (MgB$_4$O$_{7}$ (Mn) TLD에 의한 $^{60}$ Co 강내 치료 환자의 직장의 흡수선량 평가)

  • 유명진;신병철;문창우;정태식;염하용;도시홍
    • Progress in Medical Physics
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    • v.5 no.2
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    • pp.21-26
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    • 1994
  • By measuring with TLD, absorbed dose of rectum will be determined more accurately than calculated value. MgB$_4$O$\sub$7/(Mn) TLD phosphor was prepared and its characteristic was studied. To measure the absorbed dose of rectum with TLD, 33 patients who had intracavitary treatment with $\^$60/Co from April 1994 to September 1994 at Kosin Medical center. There were 10-59% differecne in most cases between the calculation and the measurement for the absorbed dose of rectum. The difference was less the case with tandem and ovoid than the case with only ovoid.

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Ionic Liquids as a SO2 Absorption Media (이온성액체 기반 SO2 흡수제 개발 동향)

  • Choi, Ji-Shik;Johari, Suzaimi;Lee, Sang-Deuk;Lee, Hyun-Joo
    • Clean Technology
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    • v.18 no.1
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    • pp.22-30
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    • 2012
  • Separation of $SO_2$ from the flue gases of fossil fuel power plants are important issue because of its strong environmental impact. Industrially, $SO_2$ is being removed with a slurry of limestone, lime or aqueous caustic soda. However, these scrubbing processes possess several drawbacks such as the generation of huge amount of wastewater and the production of metal salts. Recently, ionic liquids have gained increasing interest as an absorbent for acid gas, $CO_2$ and $SO_2$. In this review, we have introduced the recent progress of ionic liquids as a $SO_2$ absorbent.

Optical Properties of $I^B-AI-VI^B_2$$I^B-AI-VI^B_2 :Co^{2+}$ Crystals ($I^B-AI-VI^B_2$$I^B-AI-VI^B_2 :Co^{2+}$결정의 광학적 특성연구)

  • 김화택;김창대;윤창선;진문석;최성휴
    • Journal of the Korean Vacuum Society
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    • v.4 no.3
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    • pp.334-341
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    • 1995
  • IB-AI-VIB2 및 IB-AI-VIB2 :Co2+ 결정을 고순도 원소를 출발 물질로 하고 iodine을 수송 매체로 사용하여 chemical transport reaction method로 성장시켰다. 성장된 결정의 결정구조는 chalcopyrite 구조였으며, energy gap은 direct band gap으로 3.514~1.814 eV 정도로 주어졌으며, cobalt를 불순물로 첨가할 때 energy gap은 감소하였다. IB-AI-VIB2 :Co2+ 결정에서 첨가된 cobalt가 모체결정의 Td symmetry site에 Co2+ ion으로 위치하여, Co2+ ion의 energy 준위 사이의 전자전이에 기인하는 불순물 광흡수 peaks가 나타났다. 이 불순물 광흡수 peaks에 결정장 이론을 적용하여 구산 1st-order spin-orbit coupling parameter(λ)는 -183~ -189cm-1정도였고, 2nd-order spin-orbit coupling parameter(P)는 225~239 cm-1정도였으며, crystal field parameter(Dq)는 328~395cm-1, Racah parameter(B)는 531~552cm-1정도였다.

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