• Title/Summary/Keyword: $CO_2$ 주입

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Thermal and Mechanical Properties of Poly(lactic acid) Specimens Fabricated by Various Equal-channel Angular Extrusion Processes (다양한 방식의 등통로각압축공정으로 가공된 Poly(lactic acid) 시편들의 열 및 기계적 물성)

  • Liu, Xu-Yan;Jung, Si-In;Choi, Ho-Suk;Oh, Jun-Taek;Kim, Jong-Kuk
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.206-210
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    • 2011
  • We fabricated rod-like poly(lactic acid)(PLA) specimens through applying various methods of equal-channel angular extrusion(ECAE) process and investigated the change of thermal and mechanical properties of specimens before and after each ECAE process. Combining three re-injection routes(A, BC, and C) and three pass counts(1, 2 and 4) allowed us to fabricate 7 different PLA specimens. Thermal properties of each specimen were measured by both differential scanning calorimeter and thermo-gravimetric analyzer. Shear strains of each specimen with respect to applied loads were measured by indentation hardness tester. Field emmision scanning electron microscopy was used to observe internal microstructure of cross-section of each specimen. The observed microstructures qualitatively supported the explanation of hardness test results. Among 7 specimens, PLA-P2A showed the biggest shear strain probably due to its dense microstructure.

A Study on the Reinforcement Effect Analysis of Aging Agricultural Reservoir using Surface Stabilizer (표층안정재를 사용한 노후 농업용 저수지의 보강효과 분석에 관한 연구)

  • Kim, Jae-Hong;Kim, You-Seong;Cho, Dae-sung
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.2
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    • pp.13-21
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    • 2020
  • In Korea, small reservoirs have been constructed for the supply of agricultural water, but most of them have been over 50 years from the year of construction. Aging agricultural reservoirs are being investigated for serious defects such as leaks and movements in slope, which are very vulnerable to safety. Accordingly, grouting methods are used to reinforce aging agricultural reservoirs in Korea. However, cement used as a grouting injection material consumes natural resources and generates a large amount of greenhouse gases during production. In addition, there is a problem that sufficient reinforcement is not made due to various factors such as the injection amount, the compounding ratio, the injection pressure, and etc. Therefore, due to these problems, the development of new materials and methods that can replace the grouting method and cement is required. In order to solve these problems, this study conducted an laboratory test on the surface stabilizer used to secure the stability of road and rail slopes. In addition, the program was analyzed and the reinforcing effect was examined when the surface stabilizer was used as reinforcement material for aging agricultural reservoir. As a result of the laboratory test, when the surface stabilizer is mixed, the increase of cohesion is possible up to 9% and there is no change in the friction angle. The results of the program analysis showed that the 1.0m reinforcement of slopes increased the factor of safety by 1.4 times, making it possible to reinforce the aging agricultural reservoir using surface stabilizers. And as a reinforcement method, it was analyzed that it is most appropriate to reinforce the slope and the bottom of slope simultaneously.

P Element-Mediated Transformation with the rosy Gene in Drosophila melanogaster (D. melanogaster에 있어서 P Element를 이용한 rosy 유전자의 형질전환)

  • Kim, Wook;Kidwell, Margaret G.
    • The Korean Journal of Zoology
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    • v.38 no.3
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    • pp.340-347
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    • 1995
  • We have used two kinds of P element constructs, Pc[(ry+)B] and p[(ry+)$\Delta$SX9], for genetic transformation by microinjection of D. melanogaster. Pc[(ry+)B] construct carrying the rosy gene within an autonomous P element was injected into a true M strain caring the ry506. mutation. The source of transposase for microinjection and transformation was provided by a P element helper plasmid designated p-$\Delta$2-3hs$\pi$, which was co-injected with nonautonomous P[(ry+)$\Delta$SX9] construct into same ry506 M strains. A dechorination method was adopted and 35 independent transformed lines were obtained froin 1143 G0 Injected (35/1143). About 20% of the injected embryos eclosed as adults. Among G0 eclosed flies, approximately 40% exhibited eye color that was similar to wild-type (ry+), but about 60% of fertile G0 transformed lines appeared to have no G1 transformants. Therefore it is unlikely that G0 expression requires integration of the rosy transposon into chromosomes. Pc[(ry+)B] and P[(ry+)$\Delta$SX9] constructs were found to be nearly same in the frequency of element-mediated transformation. On the basis of these results, nonautonomous P elements constructs could he used as same effective vectors in P element-mediated transformation for introducing and fixing genes in insect populations.

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Liquid Velocity and Local Fouling in Coagulation-submerged Microfiltration Module for Drinking Water Treatment (정수처리를 위한 응집-침지식 정밀여과 모듈의 유체유속 및 국부오염)

  • Choi, Youngkeun;Kim, Hyun-Chul;Noh, Soohong
    • Membrane Journal
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    • v.25 no.3
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    • pp.268-275
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    • 2015
  • Effects of aeration intensity on local fouling were investigated in submerged membrane modules. Higher liquid velocities were observed at the section with the lower fiber packing density. The liquid velocity is increased with increasing the gas-liquid injection factor. The high shear stress coincided with the high liquid velocity. The shear stress increases with the increasing of gas-liquid injection factor and the liquid velocity improves with the increasing of gas-liquid injection factor. Irreversible fouling resistance ($R_{ir}$) of the fiber position is significant in a local region of high suction pressure near the suction point of the fiber (position 1). The ratio of $R_{ir}/R_m$ and $R_{ir}/R_r$ of position 1 was highest compared to the position 2 and 3. Irreversible fouling resistances results confirmed the preferential deposition of foulants near the suction part of the fiber where the local suction pressure is the highest and correspondingly, more particles are accumulated to the membrane surface. The effects of local fouling along the fiber length are significant factors to optimize the design of submerged modules.

Studies of Pretreatment Mehtods for Additional Reduction of Sewage Sludge (최종 하수처리장 슬러지의 추가감량을 위한 슬러지 전처리 연구)

  • Kim, Seogku;Kim, Jahyun;Lim, Junhyuk;Lee, Jeakun;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.10
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    • pp.15-21
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    • 2014
  • In this study, biochemical methane potential test was conducted to estimate ultimate methane and carbon dioxide yield for anaerobic digestion and pretreatment with sewage sludge cake. Two of 0.2 % TS of sewage sludge cakes were treated with 5M NaOH or sonication of 0.51 W/mL during 30 min respectively. Another sample was treated simultaneously with NaOH and sonication in same condition. Then, initial soluble COD increased from 33.1 mg/L to 494 mg/L. After BMP test, methane production ranged from 3.12 and 84.2 mL $CH_4$ per g of Volatile Solid (VS) and 9.2 and 13.5 mL $CO_2$ per g of Volatile Solid (VS) for carbon dioxide. In other tests, injection of nutrient media or sludge supernatant produced 73.1 and 73.8 mL $CH_4$ per g of Volatile Solid (VS) and 11.2 and 13.6 mL $CO_2$ per g of Volatile Solid (VS) respectively. When BMP test finished, 62 % of initial volatile solids decreased to 33.8~45.4 %. Simultaneous pretreatment increased soluble COD, reduction rate of volatile solids and digestion efficiency than those for alkaline and ultrasonic pretreatment.

Study on Destruction of Chlorinated Organic Compounds in a Two Stage Molten Carbonate Oxidation System (2단 용융탄산염산화시스템에서 염소유기화합물 분해에 관한 연구)

  • Eun, Hee-Chul;Yang, Hee-Chul;Cho, Yung-Zun;Lee, Han-Soo
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1148-1152
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    • 2008
  • Molten carbonate oxidation (MCO) is one of the promising alternative technologies for the treatment of the chlorinated organic compounds because it is capable of trapping chlorine during a destruction of them. In this study, destructions of chlorinated organic compounds ($C_6H_5Cl$, $C_2HCl_3$ and $CCl_4$) and an insulated oil containing PCBs were performed by using the two stage molten carbonate oxidation system. MCO reactor temperature largely affected the destruction of the chlorinated organic compounds. Destruction of the chlorinated organics very efficient in the primary MCO reactor however a significant amount of CO was emitted from the MCO system. This CO emission was gradually decreased by an increase in the primary reactor temperature and oxidizing air feed rate. The HCl emission from the MCO system was below 7 ppm regardless of tested conditions. The chlorine collection efficiencies were in the range of 99.95-99.99%. The destruction of PCBs in the insulated oil was efficient at a temperature above $900^{\circ}C$ and overall destruction efficiency of them was determined as over 99.9999%.

Changes of Physico-chemical Characteristic on Swine Manure Using Different Suction Strength in Composting System (돈분 퇴비화 시 공기 흡입 강도에 따른 이화학적 특성변화)

  • Lee, Dong-Jun;Kim, Jung Kon;Jeong, Kwang-Hwa;Kawg, Jung-Hoon;Ravindran, B.;Lee, Ji-Woong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.2
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    • pp.59-67
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    • 2017
  • The aim of this experiment was to investigate the effect of air suction rate (SR) during the composting process of swine manure mixed with sawdust used as a bulking agent. In the 25 L composting reactors, the suction rate (SR) was at four different treatment levels (100%, 200%, 300%, 400%), and were fixed on the based on constant aeration rate into the composting mixtures. The temperature reached to thermophilic phase within 2 days and it was maintained up to the $5^{th}$ day of the composting process in all reactors and then gradually decreased to room temperature at the end of the composting process. The moisture content (MC, %) of the initial mixtures was 64.27%, and it was reduced to 38.4, 33.08, 14.59 and 11.93 in the different suction rate of 100%, 200%, 300%, 400%, respectively in the end process. During the composting, the level of pH was increased from 6.83 to 8.67 and it gradually decreased to 7.56 in 100% and 200%(SR). At the same time, the pH values were reduced only up to 8.19 at 300%, and 8.08 at 400%(SR), showing that suction strengths of 100% and 200% were the better option for composting than those of 300% and 400%. The total Kjeldahl nitrogen (TKN) of initial composts mixtures was 2.3% and were changed in 3.3, 3.1, 2.5, and 2.3% at the end of the composting period from the 100%-400% (SR) variations respectively. These results also indicated that 100% and 200% (SR) were more affected by the dry mass loss as $CO_2$ and water evaporation. The initial value of C/N ratio was 25.17 and were significantly reduced to 11.88, 11.97, 14.31, and 14.72 at the end of the experiment, respectively from the 100%-400% (SR) variations. These results suggest that the suction rate (SR) of 100% and 200% relative to constant air supply would be the optimal conditions to produce high-quality compost.

Maturity Evaluation and Determination of Aeration Time Using Germination Index of Co-Digestates (발아지수를 이용한 혼합 혐기소화액의 부숙도 평가 및 폭기기간 설정)

  • Byeon, Ji-Eun;Lee, Hong-Ju;Hwang, Sun-Goo;Rhim, Tae-Jin;Ryoo, Jong-Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.2
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    • pp.5-13
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    • 2020
  • This study was conducted to evaluate the effect of optimal aeration time of livestock manure slurry with fruits pomace on germination index. Six co-digestates of livestock manure slurry with fruits was aerated with 0.1 ㎥ air/㎥·min for 54 days. The maturity of digestates was evaluated using the germination method. The germination index(GI) of co-digestate of SS + CS + MP was more than 70 at the 30th day of aeration. The GI of co-digestate of SS + CS was more than 70 at the 36th day of aeration. The GI of digestate of swine manure slurry alone was 70 at the 54th day of aeration. The co-digestate of SS + MP caused to shorten 24 days of aeration period to reach GI of 70, compared to swine manure digestate. These results suggest that the germination index of seed could be used to establish the optimal aeration time for co-digestate of liquid fertilizer.

The Neutralization Treatment of Waste Mortar and Recycled Aggregate by Using the scCO2-Water-Aggregate Reaction (초임계이산화탄소-물-골재 반응을 이용한 폐모르타르와 순환골재의 중성화 처리)

  • Kim, Taehyoung;Lee, Jinkyun;Chung, Chul-woo;Kim, Jihyun;Lee, Minhee;Kim, Seon-ok
    • Economic and Environmental Geology
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    • v.51 no.4
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    • pp.359-370
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    • 2018
  • The batch and column experiments were performed to overcome the limitation of the neutralization process using the $scCO_2$-water-recycled aggregate, reducing its treatment time to 3 hour. The waste cement mortar and two kinds of recycled aggregate were used for the experiment. In the extraction batch experiment, three different types of waste mortar were reacted with water and $scCO_2$ for 1 ~ 24 hour and the pH of extracted solution from the treated waste mortar was measured to determine the minimum reaction time maintaining below 9.8 of pH. The continuous column experiment was also performed to identify the pH reduction effect of the neutralization process for the massive recycled aggregate, considering the non-equilibrium reaction in the field. Thirty five gram of waste mortar was mixed with 70 mL of distilled water in a high pressurized stainless steel cell at 100 bar and $50^{\circ}C$ for 1 ~ 24 hour as the neutralization process. The dried waste mortar was mixed with water at 150 rpm for 10 min. and the pH of water was measured for 15 days. The XRD and TG/DTA analyses for the waste mortar before and after the reaction were performed to identify the mineralogical change during the neutralization process. The acryl column (16 cm in diameter, 1 m in length) was packed with 3 hour treated (or untreated) recycled aggregate and 220 liter of distilled water was flushed down into the column. The pH and $Ca^{2+}$ concentration of the effluent from the column were measured at the certain time interval. The pH of extracted water from 3 hour treated waste mortar (10 ~ 13 mm in diameter) maintained below 9.8 (the legal limit). From XRD and TG/DTA analyses, the amount of portlandite in the waste mortar decreased after the neutralization process but the calcite was created as the secondary mineral. From the column experiment, the pH of the effluent from the column packed with 3 hour treated recycled aggregate kept below 9.8 regardless of their sizes, identifying that the recycled aggregate with 3 hour $scCO_2$ treatment can be reused in real construction sites.

Physicochemical Treatment of Waste Water Containing Organic Materials (유기물을 함유한 폐수의 물리화학적 처리에 관한 연구)

  • Lee, Han-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.1
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    • pp.493-498
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    • 2013
  • The production of synthetic polymer compounds and ethanolamine (ETA, a pH control agent used in nuclear power plants) generates effluent that pollutes water. This study focused on the development of chemicals for the treatment of effluent and processes to reduce the COD level due to the presence of organic materials via physicochemical treatment. It was found that a mixed coagulant of $FeCl_2$ and $MgCl_2$ (1:1) was the most effective in treating effluent and reducing the COD level. When the mixed coagulant was injected into effluent including organic materials, the COD level was reduced by more than 80%.