• Title/Summary/Keyword: $CO_2$ 주입

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A Study on the Sheet Resistance Variation in Ion Implanted Poly-Si Thin Flim by CO2 Laser Annealing (CO2 레이저 열처리에 따른 이온 주입된 다결정 실리콘 박막의 판막저항 변화에 관한 연구)

  • Park, Pyeong-Whang;An, Chul
    • Proceedings of the KIEE Conference
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    • 1987.07a
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    • pp.539-541
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    • 1987
  • P+ ion implanted poly-Si flim with doses of 10E13-10E16 ions/$cm^2$ were annealed by CO2 laser and their sheet resistances were measured and compared with thoses of furnace annealed samples. In case of lightly doped samples, the measured sheet resistance of laser annealed samples were lower several orders of magnitude than those of furnace annealed samples. The origin of this reduction of sheet resistances is supposed to be the increase of the grain size to the extent of certain critical value.

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혐기성 슬러지를 이용한 디젤오염토양의 분해

  • 박현철;이태호;박태주
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.298-301
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    • 2003
  • 생물학적 토양오염 복원기술은 산소와 영양염류를 오염토양에 공급하여 호기성 미생물의 대사작용을 자극함으로써 유류를 생분해 하는 방법으로 널리 사용되고 있다. 유류에 오염된 토양은 혐기성 상태인 경우가 대부분이기 때문에, 호기성 미생물을 이용하기 위해서는 충분한 산소를 공급하여야 하므로 운전비가 많이 드는 단점이 있다. 최근에는 혐기성 미생물을 이용하여 유류오염 토양을 정화하는 방법이 보고되고 있다. 혐기성 생분해 방법은 다소 분해 속도는 느리지만 산소를 공급하지 않기 때문에 경제적인 유류오염토양 복원 방법으로 주목받고 있다. 본 연구에서는 디젤을 사용하여 인위적으로 10000 mg/kg.TPH soil의 농도로 오염시킨 토양 50g을 100$m\ell$ 용적의 vial에 주입하고 하수처리장의 혐기성 소화조 슬러지를 15$m\ell$, 30$m\ell$을 주입하여 배양하였으며 TPH의 분해량과 CH$_4$$CO_2$ 발생량을 측정하였다. vial의 기상을 $N_2$가스로 치환함으로써 혐기성 상태가 되도록 하였으며, 35$^{\circ}C$에서 90일간 배양하였다. 그 결과, 슬러지를 주입하지 않은 대조군의 경우에는 TPH의 분해가 거의 없었지만, 슬러지를 주입한 경우에는 TPH(Total Petroleum Hydrocarbon)농도가 55% 제거된 것으로 나타났다. TPH의 분해는 CH$_4$$CO_2$ 발생량과 밀접한 상관관계를 보였다. 본 연구의 결과로부터 하수처리장의 혐기성 소화조 슬러지를 이용한 유류오염 토양의 복원 가능성을 확인할 수 있었다.양에서 유동 가능성이 있는 중금속만을 추출하였다. 분석실험은 토양의 Cd2+ 와 Pb2+를 대상으로 행하여졌으며, 여러 토양에서 추출 분석한 결과를 EDTA분석결과와 비교하였다. 실험결과, 중금속은 매우 신속하게 고분자 자성체와 결합하였고, 그 후 자성체를 외부 자장으로 모은 후 산으로 용해시키고, 결합된 중금속은 Graphite furnace AAS로 분석함으로써 빠르고 효율적으로 분석실험을 수행할 수 있음을 알 수 있었다. 한편, 실험에서 나타난 수치들을 비교 검토한 결과 토양 분석시 sandy soil에서는 자성체를 이용한 분석이 EDTA에 의한 방법보다 더 높은 추출도를 보인 반면, silt 함량이 많은 토양의 경우에서 EDTA분석에서 더 높은 중금속 추출도를 보였다.s 중에서 490nm와 555nm의 복합밴드를 포함하는 OC2 알고리즘(ocean color chlorophyll 2 algorithm)을 사용하는 것이 OC2 series 및 OC4 알고리즘보다 좋은 추정 값을 도출할 수 있을 것으로 기대된다.환경에서는 5일에서 7월에 주로 이 충체의 유충이 발육되고 전파되는 것으로 추측되었다.러 가지 방법들을 적극 적용하여 금후 검토해볼 필요가 있을 것이다.잡은 전혀 삭과가 형성되지 않았다. 이 결과는 종간 교잡종을 자방친으로 하고 그 자방친의 화분친을 사용할 때만 교잡이 이루어지고 있음을 나타내고 있다. 따라서 여교잡을 통한 종간잡종 품종육성 활용방안을 금후 적극 확대 검토해야 할 것이다하였다.함을 보이고 있다.X> , ZnCl$_{3}$$^{-}$같은 이온과 MgCl$^{+}$, MgCl$_{2}$같은 이온종을 형성하기 때문인것 같다. 한편 어떠한 용리액에서

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Characteristic of Partial Oxidation of Methane and Ni Catalyst Reforming using GlidArc Plasma (GlidArc 플라즈마를 이용한 메탄 부분산화 및 Ni 촉매 개질 특성)

  • Kim, Seong-Cheon;Chun, Young-Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1268-1272
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    • 2008
  • Low temperature plasma applied with partial oxidation is a technique to produce synthesis gas from methane. Low temperature plasma reformer has superior miniaturization and start-up characteristics to reformers using steam reforming or CO$_2$ reforming. In this research, a low temperature plasma reformer using GlidArc discharge was proposed. Reforming characteristics for each of the following variables were studied: gas components ratio (O$_2$/CH$_4$), the amount of steam, comparison of reaction on nickle and iron catalysts and the amount of CO$_2$. The optimum conditions for hydrogen production from methane was found. The maximum Hydrogen concentration of 41.1% was obtained under the following in this condition: O$_2$/C ratio of 0.64, total gas flow of 14.2 L/min, catalyst reactor temperature of 672$^{\circ}C$, the amount of steam was 0.8, reformer energy density of 1.1 kJ/L with Ni catalyst in the catalyst reactor. At this point, the methane conversion rate, hydrogen selectivity and reformer thermal efficiency were 66%, 93% and 35.2%, respectively.

Study on the Productivity of Microalgae Nannochloropsis sp. Using the Highly Efficient Vertical Photobioractor (수직형 고효율 광배양기를 통한 미세조류 Nannochloropsis sp.의 생장성 연구)

  • Kim, Young-Nam;Chung, Myung-Hee;Kim, Eun-Joo;Karnadi, Vita;Kim, Young-Jun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.1
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    • pp.38-44
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    • 2015
  • We have investigated the productivity of microalgae, Nannochloropsis sp., using highly efficient vertical photobioreactor which has been developed by the company IMBiz. This experiment was performed in the field for one month with 2 sets of 2 tons of media under autotrophic cultural mode. In the culture with 0.1% of $CO_2$, the average daily productivity was shown to be up to 0.953g per liter, and 0.574g per liter in the culture with only ambient air. The temperature ranged from $20^{\circ}C$ to $31^{\circ}C$, and it didn't make any differences on the productivity. The light intensity ranged from 5,000 Lux to 40,000 Lux. The light has been appeared to have a very close relationship with the productivity of microalgae. Meanwhile, the harvesting method of pressurefloating attempted in this photobioreactor was found to be very effective.

Effects of Extrusion Process Parameters on Puffing of Extruded Pellets (압출성형 공정변수가 압출성형 펠릿의 팽화에 미치는 영향)

  • Kim, Jae-Hyun;Ryu, Gi-Hyung
    • Korean Journal of Food Science and Technology
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    • v.33 no.1
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    • pp.55-59
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    • 2001
  • Pressure-puffing system or extruder has been used to puff rice kernel or rice flour. Most of the study on rice puffing were the effect of process conditions such as moisture content and heating temperature on physical and chemical characteristics of popped rice. The study on mechanism and development of instant puffed rice like popcorn has been limited. Extruded waxy rice pellets were puffed in a microwave oven after drying and conditioning. Extruded pellets were formed with extrusion conditions of $20{\sim}27%$ moisture content, 2.76 MPa $CO_2$ gas injection pressure and 200 rpm screw speed. Under these conditions, puffed waxy rice pellets in microwave oven had low density and soft texture. Density and texture of puffed waxy rice pellet could be optimized by control of moisture content, $CO_2$ gas injection pressure and screw speed that affect significantly when puffing extruded waxy rice pellet.

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Characterization of CO2 Biomineralization Microorganisms and Its Mineralization Capability in Solidified Sludge Cover Soil in Landfill (매립지 복토용 슬러지 고화물내 이산화탄소 생광물화 고정균 분석 및 생광물화능 평가)

  • Ahn, Chang-Min;Bae, Young-Shin;Ham, Jong-Heon;Chun, Seung-Kyu;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.8
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    • pp.598-606
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    • 2013
  • This study was performed to determine whether biomineralization microbes were actively present underneath landfill cover soil producing biocalcification. From this, various types of microbes were observed. Among them, two species were dominantly found; Bacillus megaterium and Alkaliphilus metalliredigens that were known as biominerlization bacteria. With those microbes, $CO_2$ was more highly consumed than without bacteria. In response, the calcium carbonate mineral was produced at 30% (wt) greater than that of the control. At the same time, TG-DTA was successfully used for quantification of $CO_2$ consumed forming calcium carbonate minerals resulting from biocalcification. It was decided that the presence of solidified sewage sludge cake utilized as a cover soil in the landfill could efficiently contribute to possible media adaptably and naturally sequestering $CO_2$ producing from the landfill.

Online Capacitance Estimation of Supercapacitor Bank Using Current Injection (주입전류를 이용한 수퍼커패시터 뱅크의 실시간 커패시턴스 추정방법)

  • Lee, Junwon;Lee, Jaedo;Ryu, Jisu;Cha, Hanju
    • Proceedings of the KIPE Conference
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    • 2015.07a
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    • pp.395-396
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    • 2015
  • 본 논문에서는 수퍼커패시터 에너지 저장장치의 DC링크 커패시터뱅크 커패시턴스 추정에 관하여 기술한다. DC링크 커패시터뱅크에 임의의 주파수성분의 전류를 주입하여 생성되는 전압과 전류의 AC성분의 관계로 커패시턴스를 추정하였다. 제안한 방법은 온라인으로 실시간 추정이 가능하며, BPF(Band Pass Filter)를 구성하여 동일한 주파수 신호를 추출하여 커패시턴스를 추정한다. 100%, 110% 계통전압에서도 커패시턴스의 평균 값은 2.03F과 2F으로 나타났고, 분산은 0.0005와 0.0001로 나타나 동일한 추정 값이 연속해서 계산되어 타당성을 검증하였다.

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Evaluation of the Removal Properties of Mn(II) by Manganese-Coated Sand (망간사에 의한 망간제거 특성 평가)

  • Yu, Mok-Ryun;Yang, Jae-Kyu;Kim, Mu-Nui;Lee, Seung-Mok;Lee, Nam-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.571-576
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    • 2007
  • Manganese-Coated Sand(MCS) prepared with three different methods were applied in the treatment of soluble $Mn^{2+}$ in batch and column experiments. In the bench-scale MCS preparation, the coating efficiency of manganese on the surface of sand increased as the dosage of initial Mn(II) increased. The removed amount of the soluble $Mn^{2+}$ by MCS increased as the solution pH increased, following a typical anionic-type adsorption. The removed amounts of the soluble $Mn^{2+}$ through adsorption was quite similar over the entire pH range, without depending on the contents of Mn on the surface of sand as well as coating methods. When NaClO was used an oxidant, the removed amount of the soluble $Mn^{2+}$ by MCS increased as the concentration of NaClO increased, This trend might be explained by the increased removal efficiency through coating of manganese oxides produced from oxidation of the soluble $Mn^{2+}$ by NaClO on the surface of MCS. From the bench-scale column experiments, the breakthrough of $Mn^{2+}$ occurred after 4,100 bed volume without presence of NaClO while 1.6-times delayed breakthrough of $Mn^{2+}$ was observed in the presence of NaClO. This result also supports that the removal efficiency of the soluble $Mn^{2+}$ could be enhanced by using NaClO.

H2S Poisoning Effect and Recovery Methods of Polymer Electrolyte Membrane Fuel Cell (황화수소 피독이 고분자전해질 연료전지에 미치는 영향과 회복기법)

  • Chun, Byungdo;Kim, Junbom
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.107-114
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    • 2017
  • The performance of polymer electrolyte membrane fuel cell (PEMFC) could be deteriorated when fuel contains contaminants such as carbon monoxide (CO) or hydrogen sulfide ($H_2S$). Generally, $H_2S$ is introduced in hydrogen by steam reforming of hydrocarbon which has mercaptan as odorant. $H_2S$ poisoning effect on PEMFC performance was examined on this study. Pure hydrogen injection, voltage cycling and water circulation methods were compared as performance recovery methods. The PEMFC performance was analyzed using electrochemical methods such as polarization curve, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). Pure hydrogen injection and voltage cycling methods showed low recovery ratio, however, water circulation method showed high recovery ratio over 95%. Because anode was directly poisoned by $H_2S$, anode water circulation showed higher recovery ratio compared to the other methods. Water circulation method was developed to recover PEMFC performance from $H_2S$ poisoning. This method could contribute to PEMFC durability and commercialization.

The variation of chracteristics induced by $Co^60$-$\gamma$ray at the interface and oxide layer of MOS sructure ($Co^60$-$\gamma$선 조사에 따른 MOS구조의 계면 및 산화막내에서의 특성변화)

  • 김봉흡;류부형;이상돈
    • Electrical & Electronic Materials
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    • v.1 no.3
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    • pp.269-277
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    • 1988
  • P형 Si(100)로 제작한 MOS 커패시터에 $Co^{60}$-.gamma.선을 주사한 후 고주파 C-V특성 곡선으로 부터 방사선 조사에 의해 유발된 산화막안의 트랩전하의 거동 및 Si- $SiO_{2}$계면에서의 트랩밀도 분포의 변화를 검토하였다. 산화막 느랩전하는 .gamma.선 흡수선량 증가와 더불어 증가하다가 $10^{7}$ rad 부근에서부터 서서히 포화하는 경향이 나타났으며 게면트랩밀도의 분포모양은 흡수선량의 증가와 더불어 전형적인 이그러진 W자형에서 넓혀진 V자형 분포로 변화하였으나 최소값은 항상 진성페르미준위( $E_{i}$)부근에 있었으며 그 밀도는 1.0*$10^{11}$~7.5*$10^{11}$[개/$cm^{2}$/eV]로 계산되었다. 또한, 일정 바이어스전압하에서의 조사선량에 따른 $V_{fb}$ 의 변화는 현저하지는 않았으나 바이어스 전압을 +12V로 인가할 때 변화방향의 반전상태가 관측되었다. 그 이유로는 Si측의 계면 부근에서 일어난 눈사태 전자가 산화막내로 주입됨에 따라 도너형 양전하의 수가 감소되기 때문으로 추정되었다.되었다.

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