• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.577-580
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• 2008

Concrete absorbs $CO_2$ in the air because of carbonation. according to rising concern for lasting earth environment efforts of reducing greenhouse gas, especially co2, are occurred whole industry throughout the world. In this paper selected one building and computed amount of production and absorbtion of co2 during its lifecycle at concrete. In computing amount of absorbtion of co2 considered amount of absorbtion according to the area of concrete changing senarioes of servicelife(40,60,80 years) and deconstruct preiod(60,40,20 years). As a result, size of concrete and maintenance period of disused concrete work increasement of $CO_2$ as main factors. We came to the conclusion that maintenance period is more important than recycle of unused concrete as a method for reducing environmental load in architectural industry.

• Clean Technology
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• v.30 no.1
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• pp.62-67
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• 2024

In this study, an alkali metal Na was introduced into iron-based catalysts used in the carbon dioxide-based Fischer-Tropsch process by wet impregnation and physical mixing methods to compare their performance. The as-prepared catalysts were evaluated for reactivity at 3.5 MPa, 330 ℃, feed ratio of H₂/CO₂ = 3 with a space velocity of 4,000 mL h^-1 g_cat^-1. Comparing the two catalysts, it was found that Na was uniformly distributed throughout the catalyst when wet-impregnated, but Na for physically mixed catalyst was relatively located on the surface of the catalyst. In addition, the wet-impregnated catalyst showed higher liquid hydrocarbon (C₅₊) yield and lower CO selectivity. In conclusion, the effect of Na distribution in the catalyst on the reaction was identified and can be controlled by the introduction method.

• Resources Recycling
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• v.19 no.5
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• pp.31-43
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• 2010

To fabricate porous SiC candle filter for filtration facility of the IGCC system, the candle type filter preforms were fabricated by ramming and vacuum extrusion process. A commercially available ${\alpha}$-SiC powders with various particle size were used as starting raw materials, and $44\;{\mu}m$ mullite, $CaCO_3$ powder were used as non-clay based inorganic sintering additive. The candle typed preforms by ramming process and vacuum extrusion were sintered at $1400^{\circ}C$ for 2h in air atmosphere. The effect of forming method and particle size of filter matrix on porosity, density, strength (flexural and compressive strength) and microstructure of the sintered porous SiC candle tilters were investigated. The sintered porous SiC filters which were fabricated by ramming process have more higher density and strength than extruded filter in same particle size of the matrix, and its maximum density and 3-point bending strength were $2.00\;g/cm^3$ and 45 MPa, respectively. Also, corrosion test of the sintered candle filter specimens by different forming method was performed at $600^{\circ}C$ for 2400h using IGCC syngas atmosphere for estimation of long-term reliability of the candle filter matrix.

• Applied Chemistry for Engineering
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• v.9 no.6
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• pp.829-834
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• 1998

Concerned with environmental issue, a new decomposition method for CFCs that caused the destruction of ozone layer was proposed. Using thermal plasma process, CFC113 decomposed completely. In order to quantify the tendency in decomposition and recombination of CFC113, thermodynamic equilibrium calculations were performed. The calculation was conducted with CFC113, $H_2$, $O_2$ at 1 atm and 300 K~5000 K. In the experiment, products which are generated after decomposition in the plasma were examined by varying reacting gases($H_2$, $O_2$) flow rates and the changes of inside diameters of quenching tubes. Decomposition products were analyzed using Gas Chromatograph. The results are very promising with a decomposition efficiency greater than 99.99%. As to CFC113/$H_2$=1/3, conversion to CO decreased with increasing $O_2$ ratio. When CFC113/$O_2$=1/1, 1/1.5 and 1/2, conversion to CO increases above $H_2$ ratio of 3. The change of CO conversion is not sensitive to power changes. As total flow rate increased, CO conversion was slightly decreased. When the inside diameter of the quenching tube was changed from 8mm into 4mm, CO conversion was increased due to enhanced quenching rate.

• Journal of Animal Environmental Science
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• v.17 no.3
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• pp.163-170
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• 2011

This study was carried out to investigate greenhouse gas (GHG), $CH_4$ and $N_2O$, emission from liquid swine manure according to aeration levels in summer. To evaluate the influence of operation methods on GHG emissions, liquid swine manure were applied with different rates of aeration (store without aeration, $1m^3/ton/h$, $2.5m^3/ton/h$, and $5m^3/ton/h$). Following are the results of this study. The liquid swine manure applied no aeration, $1m^3/ton/h$, $2.5m^3/ton/h$, and $5m^3/ton/h$ aeration rates released 315.6, 13.9, 17.9 and $9.6{\mu}g/m^2/s$ of $CH_4$ and 0.173, 0.157, 0.131, and $0.241{\mu}g/m^2/s$ of $N_2O$, respectively. Liquid swine manure applied no aeration released the most amount of GHG ($6,681.4{\mu}g/m^2/s$ $CO_2$-Eq.) and followed by $5m^3/ton/h$ ($276.4{\mu}g/m^2/s$ $CO_2$-Eq.), $2.5m^3/ton/h$ ($416.0{\mu}g/m^2/s$ $CO_2$-Eq.), and $1m^3/ton/h$ ($340.8{\mu}g/m^2/s$ $CO_2$-Eq.). Our results reveal that the aerated system may reduce GHG emissions compared to no aeration. Consequently, aeration and mixing were effective at reducing GHG emissions during liquid swine manure storage.

• Clean Technology
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• v.13 no.4
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• pp.266-273
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• 2007

The adsorption properties of the activated carbon-based adsorbents were studied to remove COS emitted from $SO_2$ catalytic reduction process on the integrated gasification combined cycle (IGCC) system in this work. Transition metal supported catalysts and mixed metal oxide catalysts were used for the $SO_2$ catalytic reduction. The mechanism of COS produced from the $SO_2$ reduction and the COS concentration s according to the reaction temperature were investigated. In this study, an activated carbon and a modified activated carbon doped with KOH were used to remove the very low concentration of COS effectively. The adsorption rate and the breakthrough time of COS were measured by a thermo gravity analyzer (TGA, Cahn Balance) and a fixed bed flow reactor equipped with GC-pulsed flammable photometric detector (PFPD), respectively. It was confirmed that the COS breakthrough time of the activated carbon doped with KOH was longer than that of an activated carbon. In conclusion, the modified-activated carbon having a high surface area showed a high adsorption rate of COS produced from the $SO_2$ reduction.

• Korean Journal of Environment and Ecology
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• v.25 no.1
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• pp.91-101
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• 2011

The purpose of this study is to demonstrate the positive effects of artificial ground greening on the reduction of carbon dioxide ($CO_2$) which can help improve ecological functions in cities and mitigation of climate change, through quantifying $CO_2$ uptake and evapotranspiration by the process of photosynthesis of some plants. Experiment of $CO_2$ uptake and evapotranspiration was conducted by measurement of $CO_2$ exchange rate using the infrared gas analyzer, for 7 month, growing season from May to November 2009, 2 times a month. The result was as follows; The $CO_2$ uptake quantity per $cm^2$ of Chrysanthemum zawadskii was the highest rate at $21.47{\times}10^{-6}g/cm^2/s$ and Poa pratensis was $16.20g{\times}10^{-6}g/cm^2/s$. The stronger was light of intensity, the higher were $CO_2$ uptake rate of most plants. In quantity of evapotranspiration, Poa pratensis was the highest rate at $8.75{\times}10^{-5}g/cm^2/s$ and Aquilegia buergariana was $8.66{\times}10^{-5}g/cm^2/s$. From this study, it is confirmed that artificial ground greening has capacity of absorption $CO_2$ and effects on improving urban microclimate.

• Proceedings of the KIEE Conference
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• 2004.07c
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• pp.1591-1593
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• 2004

압력센서는 몇 가지 센싱 메카니즘을 가지고 있으므로 종류가 다양하고 크기 변에서도 여러 가지가 이용되고 있다. 최근에는 센싱 부분이 작으며 제어부분도 포함되는 ASIC화된 센서 시스템이 개발되고 있다. 여기에 이용되는 대부분의 탄성물질은 힘을 받았을 때 물질 내부의 벌크에서 저항 값이 변화하는 특성을 갖고 있다. 이러한 특성은 피에조 저항률(piezoresistivity)로 언급되며 스트레인 게이지의 감도에 영향을 주는 중요한 요소로 작용한다. 다이어프램으로 금속대선 세라믹을 사용하면 안정성이 우수한 특정을 가칠 수 있으며, 부식성 가스 류 및 화학성분에 대해서 내성이 강하고 환경변화에 따른 변형과 공정의 단순화 등 우수한 특성을 갖고 있는 것이 큰 장점이다. 센싱부는 산화 루세니움($RuO_2$)을 주 성분으로 하는 분말을 Paste화 하여 다이어프램 위에 스크린 프린팅을 하여 기본성능을 나타내었으며 특히, 상품화에서 중요한 일반성능에서는 온도 특성에 대한 Span 과 Offset 그리고 공정의 단순화에 대해서 고찰을 하였다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.10
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• pp.1294-1299
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• 2000

The combustion characteristics have been investigated to develop the 50 kW-class gas turbine combustor. The combustor design program was developed and applied to design this combustor. The combustion air which has the temperature of 45, 200, $300^{\circ}C$ were supplied to combustor for elucidating the effect of inlet air temperature on CO, NOx emissions and flame temperature. The exit temperature and NO were increased and CO was decreased with increasing inlet air temperature. Also, the effect of equivalence ratio was considered to verify the combustor performance. The emissions of CO and NO with inlet air temperature can be analyzed qualitatively by measuring the temperature inside the combustor. The combustion performance with fuel schedule was evaluated to get the informations of the starting and part loading process of gas turbine. The combustion was stable above the equivalence ratio of 0.18. The pattern factor which is the important parameter of combustor performance was satisfied with the design criterion. Consequently the combustor was proved to meet the performance goal required for the target gas turbine system.

• Applied Chemistry for Engineering
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• v.32 no.2
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• pp.149-156
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• 2021

A kraft recovery boiler produces steam for power generation by the combustion of black liquor from the kraft pulping process. Since saturated steam became superheated in a superheater above the furnace, it is important to increase the heat exchange efficiency for the superheated steam production and power generation. A nose arch at the bottom of the superheater is important for blocking radiation from the furnace which causes corrosion of the superheater. But the nose arch is the main reason for creating a recirculation region and then decreasing the heat exchange efficiency by holding cold flue gas after the heat transfer to saturated steam. In this study, the size of recirculation region and the temperature of flue gas at the outlet were analyzed by the nose arch structure using computational fluid dynamics (CFD). As a result, when the nose arch angle changed from 106.5° (case 1) to 150° (case4), the recirculation region of flue gas decreased and the heat exchange efficiency between the flue gas and the steam increased by 10.3%.