• Title/Summary/Keyword: $CH{_5}^+$

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Multichannel Audio Reproduction Technology based on 10.2ch for UHDTV (UHDTV를 위한 10.2 채널 기반 다채널 오디오 재현 기술)

  • Lee, Tae-Jin;Yoo, Jae-Hyoun;Seo, Jeong-Il;Kang, Kyeong-Ok;Kim, Whan-Woo
    • Journal of Broadcast Engineering
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    • v.17 no.5
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    • pp.827-837
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    • 2012
  • As broadcasting environments change rapidly to digital, user requirements for next-generation broadcasting service which surpass current HDTV service become bigger and bigger. The next-generation broadcasting service progress from 2D to 3D, from HD to UHD and from 5.1ch audio to more than 10ch audio for high quality realistic broadcasting service. In this paper, we propose 10.2ch based multichannel audio reproduction system for UHDTV. The 10.2ch-based audio reproduction system add two side loudspeakers to enhance the surround sound localization effect and add two height and one ceiling loudspeakers to enhance the elevation localization effect. To evaluate the proposed system, we used APM(Auditory Process Model) for objective localization test and conducted subjective localization test. As a result of objective/subjective localization test, the proposed system shows the statistically same performance compare with 22.2ch audio system and shows the significantly better performance compared with 5.1ch audio system.

Synthesis and Characterization on Acetonitrile and DMAP Complexes of Indium(III) compounds (Indium(III) 화합물의 Acetonitrile 과 DMAP 착물의 합성 및 특성)

  • Choi, Zel Ho
    • Journal of the Korean Chemical Society
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    • v.42 no.2
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    • pp.184-189
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    • 1998
  • Tris(pentafluorophenyl)indium acetonitrile complexes have been prepared from the reaction of Indium trihalides (halogen=Cl, Br) and bis(pentafluorophenyl)cadmium in acetonitrile, and characterized by elementary analysis, $^13C{^1H}-,\; ^1H-\;and\; ^{19}F-NMR$ spectroscopy and mass spectrometry. The Indium (III) compounds were formed stable 1:1 adducts with acetonitrile. $In(C_6F_5)_3{\cdot}DMAP$ has been prepared from the ligand exchange reaction of In$(C_6F_5)_3 {\cdot} CH_3CN$ with DMAP in $CH_2Cl_2 {\cdot} DMAP$ has higher donating character and replaced the $CH_3CN$ through the ligand transfer reaction.

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Establishment of Baseline Emission Factor of Methane in Korean Rice Paddy Soil (국내 벼 논에서 메탄 기본배출계수 개발)

  • Kim, Gun-Yeob;Jeong, Hyun-Cheol;Ju, Ok-Jung;Kim, Hee-Kwon;Park, Jun-Hong;Gwon, Hyo-Suk;Kim, Pil-Joo
    • Korean Journal of Environmental Agriculture
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    • v.32 no.4
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    • pp.359-365
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    • 2013
  • BACKGROUND: Methane ($CH_4$) emission is calculated using the default $CH_4$ emission factor as recommended by the International Panel on Climate Change(IPCC guidelines). However, the default emission factor has been derived using including the data from other countries having different soil and environmental conditions and may not reflect the real $CH_4$ emission rates in Korea. The objective of this study was to estimate the baseline emission factor of $CH_4$ in Korean paddy soils during rice cultivation. METHODS AND RESULTS: Methane emission patterns were characterized in four different paddy soils across country for a consecutive 3 years during the rice cultivation period. Rice plants were cultivated under continuous flooding and fertilized using the recommended chemical fertilization in Korea ($N-P_2O_5-K_2O$=90-45-57kg/ha). The mean $CH_4$ emission rate was 2.32 kg $CH_4$/ha/day and the uncertainty of the investigated data was 21.7%, with a valuable error range at 1.82-2.82 kg $CH_4$/ha/day with a 95% confidence interval. CONCLUSION(S): Conclusively, the Korean paddy soils' baseline emission factor of $CH_4$ is approximately 2.32 kg $CH_4$/ha/day and can be used to estimate the $CH_4$ emissions more exactly.

Characterization of physiochemical and nutrient profiles in canola feedstocks and co-products from bio-oil processing: impacted by source origin

  • Alessandra M. R. C. B. de Oliveira;Peiqiang Yu
    • Animal Bioscience
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    • v.36 no.7
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    • pp.1044-1058
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    • 2023
  • Objective: The objective of this study was to characterize physiochemical and nutrient profiles of feedstock and co-products from canola bio-oil processing that were impacted by source origin. The feedstocks and co-products (mash, pellet) were randomly collected from five different bio-oil processing plants with five different batches of samples in each bio-processing plant in Canada (CA) and China (CH). Methods: The detailed chemical composition, energy profile, total digestible nutrient (TDN), protein and carbohydrate subfractions, and their degradation and digestion (CNCPS6.5) were determined. Results: The results showed that TDN1x was similar in meals between CA and CH. CH meals and feedstock had higher, truly digestible crude protein (tdCP) and neutral detergent fiber (tdNDF) than CA while CA had higher truly digestible non-fiber carbohydrate (tdNFC). The metabolizable energy (ME3x), net energy (NELp3x, NEm3x, and NEg3x) were similar in meals between CA and CH. No differences were observed in energy profile of seeds between CA and CH. The protein and carbohydrate subfractions of seeds within CH were similar. The results also showed that pelleting of meals affected protein sub-fractionation of CA meals, except rapidly degradable fractions (PB1), rumen degradable (RDPB1) and undegrdable PB1 (RUPB1), and intestinal digestible PB1 (DIGPB1). Canola meals were different in the soluble (PA2) and slowly degradable fractions (PB2) between CA and CH. The carbohydrate fractions of intermediately degradable fraction (CB2), slowly degradable fraction (CB3), and undegradable fraction (CC) were different among CH meals. CH presented higher soluble carbohydrate (CA4) and lower CB2, and CC than CA meals. Conclusion: The results indicated that although the seeds were similar within and between CA and CH, either oil-extraction process or meal pelleting seemed to have generated significantly different aspects in physiochemical and nutrient profiles in the meals. Nutritionists and producers need to regularly check nutritional value of meal mash and pellets for precision feeding.

The Complexes of Aromatic Amines with Iodine or Iodine Monochloride in Carbon Tetrachloride (방향족아민과 요오드 또는 일염화요오드 사이의 錯物에 관한 연구)

  • Choi, Sang-Up;Lee, Bu-Yong
    • Journal of the Korean Chemical Society
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    • v.11 no.3
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    • pp.100-104
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    • 1967
  • The systems of aromatic amines such as aniline, N,N-dimethylaniline and N,N-diethylaniline with iodine or iodine monochloride in carbon tetrachloride have been examined spectrophotometrically. The results indicate the formation of one to one molecular complexes. The equilibrium constants obtained at room temperature for formation of the complexes are as follows: $C_6H_5NH_2{\cdot}I_2\;2.05$, $C_6H_5N(CH_3)_2{\cdot}I_2\;15.2$, $C_6H_5N(C_2H_5)_2{\cdot}I_2\;35.5$, $C_6H_5NH_2{\cdot}ICl\;18.5$, $C_6H_5N(CH_3)_2{\cdot}ICl\;25.6$, and $C_6H_5N(C_2H_5)_2\;42.0$ l $mole^{-1}$.

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The Etch Characteristics of TiN Thin Film Surface in the CH4 Plasma (CH4 플라즈마에 따른 TiN 박막 표면의 식각특성 연구)

  • Woo, Jong-Chang;Um, Doo-Seung;Kim, Gwan-Ha;Kim, Dong-Pyo;Kim, Chang-Il
    • Journal of the Korean institute of surface engineering
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    • v.41 no.5
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    • pp.189-193
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    • 2008
  • In this study, we carried out an investigation of the etching characteristics (etch rate, selectivity to $SiO_2$ and $HfO_2$) of TiN thin films in the $CH_4$/Ar inductively coupled plasma. The maximum etch rate of $274\;{\AA}/min$ for TiN thin films was obtained at $CH_4$(80%)/Ar(20%) gas mixing ratio. At the same time, the etch rate was measured as function of the etching parameters such as RF power, Bias power, and process pressure. The X-ray photoelectron spectroscopy analysis showed an efficient destruction of the oxide bonds by the ion bombardment as well as showed an accumulation of low volatile reaction products on the etched surface. Based on these data, the ion-assisted chemical reaction was proposed as the main etch mechanism for the $CH_4$ containing plasmas.

pH Dependence of CH3Hg+-binding Sites in Humic Acid: An X-ray Absorption Study (pH에 따른 부식유기산의 메틸수은 결합 리간드 변화: X-선 흡수분석)

  • Yoon, Soh-Joung;Bleam, William F.
    • Journal of Soil and Groundwater Environment
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    • v.16 no.6
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    • pp.122-132
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    • 2011
  • Mercury accumulates in biota mainly as methylmercury. In nature, methylmercury shows high affinity to organic matter and $CH_3Hg^+$-organic matter complexation affects the mobility and bioavailabiity of methylmercury. In this study, we examined the methylmercury binding sites in an aquatic humic acid as affected by the pH condition using Hg $L_{III}$-edge extended X-ray absorption fine structure (EXAFS). We evaluated methylmercury binding humic ligands using methylmercury-thiol, methylmerury-carboxyl, and methylmercury-amine complexation models. When $CH_3Hg^+$-to-humic reduced sulfur ratio is 0.3, we found that most of $CH_3Hg^+$ binds to thiol ligands at pH 5 and 7. At pH 7, however, some carboxyl or amine ligand contribution is observed, unlike at pH 5 where $CH_3Hg^+$ almost exclusively binds to thiol ligands. The carboxyl or amine ligand contribution may indicate that some types of thiol ligands in the natural organic matter have relatively low complexation constants or acid dissociation constants compared to those of some carboxyl or amine ligands. Analysis results indicate that ~0.2 fraction of methylmercury binds to amine or carboxyl ligands and ~0.8 to thiol ligands at pH 7.

Partial Oxidation of Methane in Palladium-silver Alloy Membrane Reactor (팔라듐-은 막반응기를 이용한 메탄의 부분산화반응)

  • Choi, Tae-Ho;Kim, Kwang-Je;Moon, Sang-Jin;Suh, Jung-Chul;Baek, Young-Soon
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.641-647
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    • 2005
  • The partial oxidation of methane is one of important processes for hydrogen production. As a membrane reactor, palladium-silver (Pd-Ag) alloy membrane prepared by electroless plating technique was employed for partial oxidation of methane. The experimental variables were reaction temperature, $O_2/CH_4$ mole ratio, $CH_4$ feed rate, and $N_2$ sweep gas flow rate. The methane conversions increased with the reaction temperatures in the range of 350 to $730^{\circ}C$. The highest methane conversion and CO selectivity were obtained at the condition of $O_2/CH_4$ mole ratio of 0.5 and $730^{\circ}C$ using commercially available nickel/alumina catalyst. The Pd-Ag membrane reactor showed higher methane conversions, 10~40% higher, compared to those in a traditional reactor.

Arthrobacter subterraneus sp. nov., Isolated from Deep Subsurface Water of the South Coast of Korea

  • Chang, Ho-Won;Bae, Jin-Woo;Nam, Young-Do;Kwon, Hyuk-Yong;Park, Ja-Ryeong;Shin, Kee-Sun;Kim, Kyoung-Ho;Quan, Zhe-Xue;Rhee, Sung-Keun;An, Kwang-Guk;Park, Yong-Ha
    • Journal of Microbiology and Biotechnology
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    • v.17 no.11
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    • pp.1875-1879
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    • 2007
  • Strain $CH7^T$, a pale yellow-pigmented bacterium and new isolate from deep subsurface water of the South Coast of Korea, was subjected to a polyphasic taxonomic study. $CH7^T$ grew between 5 and $37^{\circ}C$, pH 5.3-10.5, and tolerated up to 13% NaCl. A phylogenetic analysis based on 16S rRNA gene sequences showed that strain $CH7^T$ was associated with the genus Arthrobacter and phylogenetically closely related to the type strains Arthrobacter tumbae (99.4%) and Arthrobacter parietis (99.1%). However, DNA-DNA hybridization experiments revealed 2.1% and 12% between strain $CH7^T$ and Arthrobacter tumbae and Arthrobacter parietis, respectively. Thus, the phenotypic and phylogenetic differences suggested that $CH7^T$ should be placed in the genus Arthrobacter as a novel species, for which the name Arthrobacter subterraneus sp. novo is proposed. In addition, the type strain for the new species is $CH7^T$ ($=KCTC\;9997^T=DSM\;17585^T$).

Comparative Study of Extracellular Proteomes for Bacillus subtilis and Bacillus amyloliquefaciens

  • Lauan, Maria Claret;Santos, IlynLyzette;Lim, Jinkyu
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.1
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    • pp.30-37
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    • 2013
  • Bacillus subtilis and Bacillus amyloliquefaciens are closely related species that share a similar genomic background, and are both known to secrete large amounts of proteins directly into a medium. The extracellular proteomes of two strains of Bacillus subtilis and two strains of Bacillus amyloliquefaciens were compared by 2-D gel electrophoresis during the late exponential growth phase. The relative abundance of some minor protein spots varied among the four strains of Bacillus. Over 123 spots of extracellular proteins were visualized on the gel for B. subtilis CH 97, 68 spots for B. subtilis 3-5, 230 spots for B. amyloliquefaciens CH 51, and 60 spotsfor B. amyloliquefaciens 86-1. 2D gel electrophoresis images of the four Bacillus strains showed significantly different protein profiles. Consistent with the 2D gel electrophoretic analysis, most of the B. subtilis proteins differed from the proteases secreted by the B. amyloliquefaciensstrains. Among the proteins identified from B. subtilis, approximately 50% were cytoplasmic and 30% were canonically extracellular proteins. The secreted protein profiles for B. subtilis CH 97 and B. subtilis 3-5 were quite different, as were the profiles for B. amyloliquefaciens CH 51 and 86-1. The four proteomes also differed in the major protein composition. The B. subtilis CH 97 and B. amyloliquefaciens CH 51 proteomes both contained large amounts of secreted hydrolytic enzymes. Among the four strains, B. subtilis 3-5 secreted the least number of proteins. Therefore, even closely related bacteria in terms of genomic sequences can still have significant differences in their physiology and proteome layout.

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