• Journal of The Korean Society of Grassland and Forage Science
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• v.11 no.2
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• pp.68-75
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• 1991

A series of tests was carried out to determine the purity and germination of pasture plant and forage crop seeds imported in 1986 and 1987 at the grassland and forage laboratory, College of Agriculture, Seoul National University, Suweon. At the same time, the results obtained were compared with the National Livestook Cooperatives Federation(NLCF1's seed standards as a guide for determining seed quality. 1. The germination percentages of Potomac orchardgrass, Fawn tall fescue, Aquila Ky bluegrass and California ladino clover among grasses and legumes tested were lower than those of the N1,CF's standards, but the germination percentages of forage crops were higher than those of the NLCF's standards. 2. The purity of Potomac orchardgrass and Aquila Ky bluegrass were relatively lower than those of the NLCF's standards. 3. The percentages of other crop seeds in Potomac orchardgrass, Fawn tall fescue, Aquila Ky bluegrass and Cayuse oats were lower than those of the NLCF's standards. 4. Percentage of inert matter in the seeds was lower compared with the NLCF's standards except Akela ' forage rape. 5. The seeds of Potomac orchardgrass, NK 367 sorghum hybrid and sorghum x sudangrass hybrids such as NC+855, G83F and TE Haygrazer were contaminated with one or more weed seeds. Rumex spp. was by far the most common weed in the seeds imported. The other weeds occurred at a low level were Rumex acestosella, Senecio jacobaea, Cirsium arvense and Cuscicta spp. 6. There were many variations in 1,000 seed weight among different species. A thousand seed weight of Aquila Ky bluegrass was 0.263g, but that of Tetrone Italian ryegrass, Akela forage rape and Pioneer 3160 sorghum x sudangrass hybrid was 3.875, 3.476 and 242.4578, respectively. 7. According to the fluorescence test of ryegrass seed, Tetrone Italian ryegrass was known as a true annual type, but an unknown cultivar produced in Cheju was contaminated with 6% of perennial ryegrass seed.

• Journal of Korean Society of Forest Science
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• v.103 no.1
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• pp.37-42
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• 2014

Fine root distribution was investigated in Pinus densiflora stands using soil core sampling and minirhizotrons, and conversion factors and regression equations were developed for converting minirhizotron data into fine root biomass. Fine root biomass was measured by soil core sampling from October, 2012 to September, 2013 once a month except for the winter, and surface area of fine roots was estimated by minirhizotrons from May to August, 2013 once a month. Fine root biomass and surface area were significantly higher in the upper soil layers than in the lower soil layers. Fine root biomass showed seasonal patterns; the mean fine root biomass ($kg{\cdot}ha^{-1}$) in summer (3,762.4) and spring (3,398.0) was significantly higher than that in autumn (2,551.6). Vertical and seasonal patterns of fine root biomass might be related to the soil bulk density, nutrient content and temperature with soil depth, and seasonal changes of soil and air temperature. Conversion factors (CF) between fine root surface area from minirhizotron data and fine root biomass from soil core sampling were developed for the three soil depths. Then a linear regression equation was developed between the predicted fine root biomass using CF and the measured fine root biomass (y = 79.7 + 0.93x, $R^2=0.81$). We expect to estimate the long-term dynamics of fine roots using CF and regression equation for P. densiflora forests in Korea.

• Restorative Dentistry and Endodontics
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• v.34 no.5
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• pp.450-459
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• 2009

The aim of this study was to measure the initial dynamic modulus changes of light cured composites using a custom made rheometer. The custom made rheometer consisted of 3 parts: (1) a measurement unit of parallel plates made of glass rods, (2) an oscillating shear strain generator with a DC motor and a crank mechanism, (3) a stress measurement device using an electromagnetic torque sensor. This instrument could measure a maximum torque of 2Ncm, and the switch of the light-curing unit was synchronized with the rheometer. Six commercial composite resins [Z-100 (Z1), Z-250 (Z2), Z-350 (Z3), DenFil (DF), Tetric Ceram (TC), and Clearfil AP-X (CF)] were investigated. A dynamic oscillating shear test was undertaken with the rheometer. A certain volume ($14.2\;mm^3$) of composite was loaded between the parallel plates, which were made of glass rods (3 mm in diameter). An oscillating shear strain with a frequency of 6 Hz and amplitude of 0.00579 rad was applied to the specimen and the resultant stress was measured. Data acquisition started simultaneously with light curing, and the changes in visco-elasticity of composites were recorded for 10 seconds. The measurements were repeated 5 times for each composite at $25{\pm}0.5^{\circ}C$. Complex shear modulus G*, storage shear modulus G', loss shear modulus G" were calculated from the measured strain-stress curves. Time to reach the complex modulus G* of 10 MPa was determined. The G* and time to reach the G* of 10 MPa of composites were analyzed with One-way ANOVA and Tukey's test ($\alpha$ = 0.05). The results were as follows. 1. The custom made rheometer in this study reliably measured the initial visco-elastic modulus changes of composites during 10 seconds of light curing. 2. In all composites, the development of complex shear modulus G* had a latent period for $1{\sim}2$ seconds immediately after the start of light curing, and then increased rapidly during 10 seconds. 3. In all composites, the storage shear modulus G" increased steeper than the loss shear modulus G" during 10 seconds of light curing. 4. The complex shear modulus of Z1 was the highest, followed by CF, Z2, Z3, TC and DF the lowest. 5. Z1 was the fastest and DF was the slowest in the time to reach the complex shear modulus of 10 MPa.

• Macromolecular Research
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• v.17 no.5
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• pp.301-306
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• 2009

This work has demonstrated that a novel amphiphilic poly(epichlorohydrine)-graft-polystyrene (PECH-g-PS) copolymer at 34:66 wt% was synthesized via atom transfer radical polymerization (ATRP) of styrene using PECH as a macroinitiator. The structure of the graft copolymer was characterized by nuclear magnetic resonance ($^1H$ NMR) and FTIR spectroscopy, demonstrating that the "grafting from" method using ATRP was successful. The self-assembled graft copolymer was used as a template film for the in-situ growth of silver nanoparticles from $AgCF_3SO_3$ precursor under UV irradiation. The in situ formation of silver nanoparticles with 6-8 nm in average size in the solid state template film was confirmed by transmission electron microscopy (TEM), UV-visible spectroscopy and wide angle X-ray scattering (WAXS). Differential scanning calorimetry (DSC) also displayed the selective incorporation and the in situ formation of silver nanoparticles within the hydrophilic PECH domains, probably due to stronger interaction of the silvers with the ether oxygens of PECH backbone than that with hydrophobic PS side chains.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.219.2-219.2
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• 2011

The oxyfluorination effects of electrospun carbon nanofibers (OFACFs) were investigated for $CO_2$ storage. Carbon nanofibers were prepared form poly acrylonitrile / N,N-dimethylformamide solution through electrospinning method and heat treatment. Chemical activation of carbon nanofibers were carried out in order to improve the pore structure. And the surface modification of activated carbon nanofibers was conducted by oxyfluorination to improve the $CO_2$ storage on effect of introduced functional groups. The samples were labeled CF (electrospun carbon nanofiber), ACF (activated carbon nanofibers), OFACF-1 ($F_2:O_2$ = 3:7), OFACF-2 ($F_2:O_2$ = 5:5) and OFACF-3 ($F_2:O_2$ = 7:3). The functional group of OFACFs was investigated by x-ray photoelectron spectroscopy analysis. The specific surface area, pore volume and pore size of OFACFs were calculated and pore shape was estimated by the BET equation. Through the adsorption isotherm, the specific surface area and pore volume significantly decreased by oxyfluorination.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.12
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• pp.1078-1084
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• 2006

Impurity contamination induced by $CF_4\;and\;HBr/Cl_2/O_2$ plasma etching on Si surface was examined by using surface spectroscopes. XPS(x-ray photoelectron spectroscopy) surface analysis showed that F of 0.4 at % exists in the surface layer in the form of Si-F bonding but Br and Cl are below the detection limit $(0.1{\sim}1.0%)$ of the spectroscope. Static-SIMS(secondary ion mass spectrometry) surface analysis showed that the etched Si surface was contaminated with etching gas elements such as H, F, Cl and Br, and they existed to the depth of about $20{\sim}40nm$. The etched Si surface was treated with three different methods that were HF dip, thermal oxidation followed by HF dip and oxygen-plasma oxidation followed by HF dip. They showed an effect in reducing the impurity contamination and the oxygen-plasma oxidation followed by HF dipping method appears to be a little bit more effective.

• Transactions of Materials Processing
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• v.8 no.3
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• pp.309-309
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• 1999

Effects of rare earth metals addition and aging treatment on corrosion resistance and mechanical properties of super duplex stainless steels were investigated using optical/SEM/TEM metallographic examination, an X-ray diffraction test, a potentiodynamic anodic polarization test and a tensile test. The performance of the experimental alloy with 0.32% REM addition was compared with commercial super duplex stainless steel such as SAF 2507 when they were exposed to solution annealing heat treatment and aging treatment. The corrosion resistance in CF environments and mechanical properties of the experimental alloy were found superior to those of the commercial duplex stainless steel. The REM with larger atomic radii than those of Cr, Mo and W may fill vacancies inside the matrix and around the grain boundaries, retarding formation of harmful intermetallic σ and χ phases. In addition, fine REM oxides/oxy-sulfides (1-3㎛) seemed to enhance the retardation effects. With REM additions, strength and ductility increased due to the phase and grain refinement caused by fine REM oxides and oxy-sulfides.

• Journal of the Korean Ceramic Society
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• v.46 no.5
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• pp.441-446
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• 2009

Dense crack-free yttria film with 10 $\mu m$ thickness was prepared on aluminum by aerosol deposition. X-ray diffraction pattern on the film showed that it contained the same crystalline phase as the raw powder. Transmission electron microscopy revealed a nanostructured yttria film with grains smaller than 100 nm. Tensile adhesion strength between the film and aluminum substrate was 57.8 $\pm$ 6.3MPa. According to the etching test with $CF_4-O_2$ plasma, the etching rate of the yttria film was 1/100 that of quartz, 1/10 that of sintered alumina and comparable to that of sintered yttria.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.4
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• pp.157-164
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• 2003

$LaF_{3}$ thin films have been fabricated on Si (100) substrates under the highest possible vacuum condition by pulsed laser deposition (PLD) method. The temperature of the sbustrate varied from $20^{\circ}C$ to $800^{\circ}C$. The films deposited at the higher temperature indicated the sharper peaks in the X-ray diffraction measurement. A highly oriented film was successfully obtained at a substrate temperature of $800^{\circ}C$. The surface observation by the AFM revealed that the many hexagonal structures constructed the film. The XPS analysis revealed that the lacking of F in the film deposited at $600^{\circ}C$ were much more than that in film at $^20{\circ}C$. Adding the adequate amount of $CF_{4}$ gas in the growth chamber can compensate this lacking of F.

• Journal of the Korean Society for Railway
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• v.10 no.1 s.38
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• pp.39-44
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• 2007

This rafer explains a durability test of a large train car body made of carbon/epoxy composite material. The composite car body with the length of 23m was manufactured as a sandwich structure composed of an aluminum honeycomb core and CF1263 woven fabric carbon/epoxy faces. In order to evaluate durability of the composite car body, it was excited by two 500kN capacity hydraulic actuators installed underneath the body bolster. The natural frequency of the composite car body under full weight condition was found to be 4.33Hz. Based on this result, the excitation frequency and displacement of 5Hz and ${\pm}1.0mm$, respectively, were used as inputs for the durability test. The test was conducted for $2{\times}10^6$ cycles. During the test, the nondestructive tests using X-ray radiography and dye penetration method was performed to determine the presence of the cracks. Upon completion of the test, no cracks were found.