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검색결과 210건 처리시간 0.03초

양극산화 처리에 따른 탄소섬유 표면의 페놀릭 하이드록실 관능기 비율의 증가가 에폭시기지 복합재료의 기계적 계면결합 특성에 미치는 영향 (Effects of Increase in Ratio of Phenolic Hydroxyl Function on Carbon Fiber Surfaces by Anodic Oxidation on Mechanical Interfacial Bonding of Carbon Fibers-reinforced Epoxy Matrix Composites)

  • 김동규;김관우;한웅;송범근;오상엽;방윤혁;김병주
    • 공업화학
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    • 제27권5호
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    • pp.472-477
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    • 2016
  • 본 연구에서는 전류밀도 변화에 따른 탄소섬유의 양극산화 처리가 탄소섬유 표면과 탄소섬유 강화 복합재료의 기계적 계면결합력에 미치는 영향을 고찰하였다. 양극산화 처리된 탄소섬유 표면 특성은 원자간력 현미경(Atomic force microscope, AFM)과 전계방사형 주사전자현미경(Field emission-scanning electron microscope, FE-SEM), 적외선 분광법(Fourier transform infrared spectroscopy, FT-IR) 및 X선 광전자 분광법(X-ray Photoelectron Spectroscopy, XPS)으로 분석하였으며, Short beam 전단시험을 통해 표면처리에 따른 탄소섬유 강화 복합재료의 계면 전단강도를 측정하였다. 실험 결과 전류밀도가 증가함에 따라 탄소섬유 표면의 거칠기와 산소관능기의 함량의 증가와, 탄소섬유 강화 복합재료의 층간전단강도(Interlaminar shear strength, ILSS)의 향상 및 페놀릭 하이드록실 그룹과의 비례관계를 확인하였다. CF-2.0 시편의 층간전단강도는 87.9 MPa로 CF-AS 시편에 비해 약 4% 증가하였는데, 이러한 결과는 양극산화 처리가 산소관능기와 탄소섬유 표면 거칠기의 증가를 유도하여 탄소섬유와 수지의 계면 결합력이 증가된 것으로 판단된다. 그중 층간전단강도와 비례관계인 페놀릭 하이드록실 그룹은 탄소섬유 강화 복합재료의 계면결합력을 향상시키는 중요한 요소라 판단된다.

압입과 압축에 의한 광중합형 수복용 복합레진의 기계적 성질 평가 (AN EVALUATION OF MECHANICAL PROPERTIES OF LIGHT-CURED RESTORATIVE COMPOSITES BY INDENTATION AND COMPRESSION TEST)

  • 이용우;유미경;조영곤;배태성;이광원
    • Restorative Dentistry and Endodontics
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    • 제24권3호
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    • pp.511-518
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    • 1999
  • This study was performed to evaluate the mechanical properties of light-cured restorative composites by compression and indentation tests. Five commercially available light-activated composites (Heliomolar : HM, Aelitefil : AF, Amelogen : AG, Clearfil AP-X : CF, Z100 ZH) were used Disc specimens of 12mm in diameter and 1 mm in thickness and Cylindrical specimens of 3mm in diameter and 6mm in length were prepared for the indentation and compressive test, respectively. All specimens were immersed in distilled water at $37^{\circ}C$ for 30 days. An indentation test of 68-degree trigonal diamond pyramid was made under 10 g load for 15 seconds and an Knoop indentation test was made under 50 g load for 15 seconds. Hardness numbers, characteristic indentation depths and permanent deformation were measured during indentation of the 68-degree trigonal diamond pyramid compressive test was carried out at a crosshead speed of 0.5mm/min. The results obtained were summarized as follows, 1. The highest hardness value was obtained in the CF group and the lowest value was obtained in the HM group. Hardness values showed no significant, difference between AG group and HM group but other groups showed the significant differences in each group(p<0.05). 2. Hardness number by Knoop pyramid were higher than those of 68-degree trigonal diamond pyramid. 3. Plastic deformation during the indentation of 68-degree trigonal diamond pyramid was the lowest in the CF group and the largest in the HM group. Results of Tukey test showed the significant difference between CF group and others; also between ZH and AF groups and AG and HM groups(p<0.05) 4. The highest compressive strength was obtained in the CF group and the lowest compressive strength was obtained in the ZH group. Compressive strength values showed no significant difference between CF group and ZH group but other groups showed the significant differences in each group(p<0.05).

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SNR 0104-72.3: A remnant of Type Ia Supernova in a Star-forming region?

  • 이재준;박상욱
    • 천문학회보
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    • 제36권1호
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    • pp.87.2-87.2
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    • 2011
  • We report our 110 ks Chandra observations of the supernova remnant (SNR) 0104-72.3 in the Small Magellanic Cloud (SMC). The X-ray morphology shows two prominent lobes along the northwest-southeast direction and a soft faint arc in the east. Previous low resolution X-ray images attributed the unresolved emission from the southeastern lobe to a Be/X-ray star. Our high resolution Chandra data clearly shows that this emission is diffuse, shock-heated plasma, with negligible X-ray emission from the Be star. The eastern arc is positionally coincident with a filament seen in optical and infrared observations. Its X-ray spectrum is well fit by plasma of normal SMC abundances, suggesting that it is from shocked ambient gas. The X-ray spectra of the lobes show overabundant Fe, which is interpreted as emission from the reverse-shocked Fe-rich ejecta. The overall spectral characteristics of the lobes and the arc are similar to those of Type Ia SNRs, and we propose that SNR 0104-72.3 is the first case for a robust candidate Type Ia SNR in the SMC. On the other hand, the remnant appears to be interacting with dense clouds toward the east and to be associated with a nearby star-forming region. These features are unusual for a standard Type Ia SNR. Our results suggest an intriguing possibility that the progenitor of SNR 0104-72.3 might have been a white dwarf of a relatively young population.

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CT 데이터와 3D 프린팅 기술을 이용한 뼈 모형 X선 팬텀 제작에 관한 연구 (A Study on the Fabrication of bone Model X-ray Phantom Using CT Data and 3D Printing Technology)

  • 윤명성;한동균;김연민;윤준
    • 한국방사선학회논문지
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    • 제12권7호
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    • pp.879-886
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    • 2018
  • 3-dimensional(D) 프린터는 컴퓨터로 모델링 한 데이터를 바탕으로 3차원의 입체 물체를 출력할 수 있는 장비이다. 이러한 특징을 방사선과학 분야와 융합하여, CT 데이터를 이용한 뼈 모형 X선 팬텀제작 등에 활용되고 있다. 본 연구는 기존의 Pelvis팬텀을 CT 스캔하고 얻어진 데이터로 Fused Filament Fabrication(FFF) 3D 프린터의 소재인 PLA, Wood, XT-CF20, Glow fill, Steel 필라멘트를 이용하여, 뼈 모형 팬텀을 제작하였다. 기존의 Pelvis 팬텀과 3D 프린터로 제작된 5가지 재질의 팬텀을 동일한 조건으로 CT 스캔 하고 얻어진 영상에서 Hounsfield Unit(HU)을 측정하였으며, 진단용X선 발생장치를 이용하여 SI, SNR을 측정하여 각 팬텀을 비교 분석하였다. 그 결과 사지 X선 검사 조건 내에서 X선 팬텀은 glow fill 필라멘트가 가장 적합하다는 것을 알 수 있었다. 본 연구의 기반으로 필라멘트의 특성들을 알 수 있었으며, X선 팬텀 제작에 대한 실용성을 확인하였다.

SCR 및 LNT가 적용된 Euro-6 소형 경유차의 실제도로 주행과 인증모드에서의 CO2 및 NOx 배출특성의 비교 (Characteristics of Real-Driving CO2 and NOx Emissions Compared to Test Modes on Euro-6 LDVs Equipped with SCR and LNT)

  • 이종태;김정수;전문수;차준표
    • 한국분무공학회지
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    • 제21권4호
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    • pp.200-206
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    • 2016
  • Recently, the certification procedure for exhaust emission regulation of LDV has tested with the NEDC mode in the laboratory. But the on-road exhaust emissions exceed the standard emission limits. Therefore, it is important to analyze the real-driving emissions (RDE) with a portable emissions measurement system (PEMS). In present study, the on-road emissions were measured with a PEMS and evaluated by moving averaging window (MAW) method. Also, it was compared with the $CO_2$ and $NO_x$ emissions for real-driving and test modes from euro-6 light-duty vehicles equipped with SCR and LNT systems. In results, on-road $NO_x$ emission has been 2.3-10.0 times higher than the standard $NO_x$ emission limit on NEDC mode. The reason was that the test modes did not reflect traffic and various real-driving patterns sufficiently.

유기자원 장기연용에 따른 작물 생산성의 변화 (Changes of Crop Productivity by Long-term Application of Organic Materials in Organic Farming System)

  • 이상민;성좌경;이연;윤홍배;이용환;오진성;김계훈
    • 한국유기농업학회:학술대회논문집
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    • 한국유기농학회 2009년도 하반기 학술대회
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    • pp.298-298
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    • 2009
  • 유기농업 토양에서 합리적인 유기물 관리를 위한 기초자료로 활용하기 위하여 밭토양에서 동일한 유기물을 9년간 연용하면서 옥수수의 건물량의 연차간 변화량을 조사하였다. 처리는 무비구(WF)를 비롯하여 화학비료 단용처리(CF), 화학비료 및 돈분왕겨퇴비 혼용(CF+CPR) 두었으며, 유기자원별로는 돈분왕겨퇴비(CPR), 채종유박(RC), 볏짚퇴비(CRS), 녹비(GM) 등 7처리를 두었고, 작물의 생산성은 줄기와 알곡을 포함한 총 건물량에 대하여 화학비료 단용구를 대조로 하여 상대비교하였다. 옥수수의 생육은 파종후 52일 및 수확기에 볏짚퇴비구와 녹비처리구에서 가장 양호하였다. 9년차 옥수수 총 건물량은 화학비료구 1,226kg/10a 대비 녹비처리구에서 121%로 높았으나 볏짚퇴비구 97%, 채종유박 92% 돈분왕겨퇴비 80%로 낮았으며, 무비구의 경우 24%의 수량을 보였다. 양분의 흡수량은 녹비처리구에서 11.8kg/10a로 화학비료구에 비하여 낮았으나 다른 유기자원 처리구보다 높았다. 질소 이용율은 녹비처리구 61.1%로 화학비료구 61.6%와 동일한 수준을 보였다. 화학비료구에 대한 상대적인 수량은 녹비처리구에서 5년차까지 증가하다가 6년차부터 점차 감소하는 경향(y=$-2.044x^2$+25.302x+51.402, $R^2$=0.8571)이었으며, 볏짚퇴비구도 7년차까지는 수량이 증가하다가 8년차부터 감소하는 경향(y=$-1.0621x^2$+13.091x+63.59, $R^2$=0.6643)을 보였다. 유기질비료구와 돈분왕겨퇴비구는 완만한 감소경향을 보였으나 무비구는 급격히 감소하는 경향이지만 점차 감소폭이 좁아지는 경향(y=$0.4584x^2$-9.5544x+69.221, $R^2$=0.8777)을 보였다.

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ON THE SPACING PATTERN OF PLANETS AND SATELLITES

  • La, Daile
    • 천문학회지
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    • 제25권2호
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    • pp.105-109
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    • 1992
  • We show that spacing patterns of planets and satellites in the solar system are formulatable in a single form. It is suggested that a possible explanation for the rule might be the orbital resonance effect, which has existed at an earlier epoch of the solar (planet) system. By extrapolating the formulated spacing patterns beyond the sun-Pluto distance, we find the sun-Planet X distance falls in a range ($46{\sim}79$) A. U..

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Effect of Raw Fish-Based Moist Pellet (MP) and Commercial Red Sea Bream Feed (CF) on Growth and Body Composition of Sunshine Bass (M. saxatilis male X M. chrysops female) Reared at Various Salinity During the Winter Season

  • Cho Sung Hwoan;Lee Jong Kwan
    • Fisheries and Aquatic Sciences
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    • 제5권3호
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    • pp.229-234
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    • 2002
  • Possibility of raising sunshine bass during the winter season in Korea was investigated. Also, the effect of feed on growth and body composition of sunshine bass was compared at the various salinity. Twenty sunshine bass $(Mean\;weight\;\pm S.D.\: :\;53.9 \pm 0.24 g)$ were stocked into the eighteen circular flow-through tanks. A 2 (feed) $\times$ 3 (salinity) factorial design with triplicate was used for this study. Feed was prepared into the 2 groups: the raw fish-based me>ist pellet (MP) containing $59.5\%$ crude protein and $9.4\%$ crude lipid, and commercial sinking red sea bream feed (CF) containing $49.9\%$ crude protein and $9.4\%$ crude lipid, respectively. And salinity was prepared into the 3 groups: freshwater $(0\%)$, brackishwater $(15\%)$, and seawater $(32\%)$. Fish were fed to satiation twice daily for 6 days a week. Fish were all survived at the end of the 8-week feeding trial. Weight gain (WG) and specific growth rate (SGR) of sunshine bass were significantly (P<0.05) affected by both feed and salinity. WG and SGR of sunshine bass fed the MP were significantly (P<0.05) higher than those of fish fed the CF in the same salinity. Amount of dry feed fed was significantly (P<0.05) affected by both feed and salinity. Feed consumption by sunshine bass fed on the MP was significantly (P<0,05) higher than by fish fed on the CF in the same salinity. Feed efficiency ratio (FER) was significantly (P<0,05) affected by salinity, but not by feed. Protein efficiency ratio (PER) was significantly (P<0.05) affected by both feed and salinity. Moisture and protein content of the whole-body of fish was not significantly (P>0.05) affected by either feed or salinity. However, lipid and ash content of the whole-body of fish was significantly (P<0.05) affected by salinity, but not by feed. In conclusion, the MP was superior to CF for growth of sunshine bass during the winter season in Korea and no mortality occurred. And sunshine bass seemed to grow better in freshwater $(0\%)$ and brac-kishwater $(15\%)$ than seawater $(32\%)$ under these experimental conditions, in terms of improvement in FER and PER in freshwater or brackishwater.

Co/Ni 복합실리사이드의 메탈 콘택 건식식각 안정성 연구 (Stability of Co/Ni Silicide in Metal Contact Dry Etch)

  • 송오성;범성진;김득중
    • 한국재료학회지
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    • 제14권8호
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    • pp.573-578
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    • 2004
  • Newly developed silicide materials for ULSI should have the appropriate electrical property of low resistant as well as process compatibility in conventional CMOS process. We prepared $NiCoSi_x$ silicides from 15 nm-Co/15 nm-Ni/Si structure and performed contact dry etch process to confirm the dry etch stability and compatibility of $NiCoSi_x$ layers. We dry etched the photoresist/SiO/silicide/silicon patterns with $CF_4\;and\;CHF_3$ gases with varying powers from 100 to 200 W, and pressures from 45 to 65 mTorr, respectively. Polysilicon and silicon active layers without silicide were etched $0\sim316{\AA}$ during over etch time of 3min, while silicon layers with proposed $NiCoSi_x$ silicide were not etched and showed stable surfaces. Our result implies that new $NiCoSi_x$ silicides may replace the conventional silicides due to contact etch process compatibility.

Base-Promoted, Ketene-Forming Elimination Reactions. Mechanistic Borderline between E2 and E1cb Mechanisms

  • Pyun, Sang-Yong;Cho, Bong-Rae
    • Bulletin of the Korean Chemical Society
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    • 제26권7호
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    • pp.1017-1024
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    • 2005
  • Elimination reactions of $XC_6H_4CH_2CO_2C_6H_3-2-Y-4-NO_2$ have been studied under various conditions. When X was moderately electron-withdrawing, Y = H, and base-solvent was $R_2$NH-MeCN, the reaction proceeded by the E2 mechanism via an E1cb-like transition state. Concave downward curve was noted in the Hammett plots. When X = 4-$NO_2$, Y = Cl, $CF_3,\;NO_2$, and the base-solvent was ${R_2NH/R_2NH_2}^+$ in 70 mol % MeCN(aq), the reaction proceeded by the E2 mechanism. The mechanism changed to a competing E2 and E1cb when X = 4-$NO_2$ and Y = H, MeO, and to the E1cb when X = 2,4-($NO_2)_2$, and Y = $NO_2$. From these results, a plausible pathway of the change of the mechanism from E2 to the E1cb extreme is proposed.