• Title/Summary/Keyword: $BaTiO_{3}$

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Microwave Dielectric Properties of La2O3-B2O3-TiO2 Glass-Ceramic and BaNd2Ti5O14Ceramic System for LTCC Application (저온동시소성(LTCC)을 위한 결정화 유리(La2O3-B2O3-TiO2계)와 BaNd2Ti5O14 세라믹을 이용한 마이크로파 유전체 특성)

  • 황성진;김유진;김형순
    • Journal of the Korean Ceramic Society
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    • v.41 no.8
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    • pp.599-604
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    • 2004
  • The LTCCs (Low-Temperature Co-fired Ceramics) are very important for electronic industry to build smaller RF modules and to fulfill the necessity for miniaturization of devices in wireless communication industry. The dielectric materials with sintering temperature $T_{sint}$<90$0^{\circ}C$ are required. In this study, BaO-N $d_2$ $O_3$-Ti $O_2$ (BNT : 20∼40 wt%) for ceramic materials and L $a_2$ $O_3$- $B_2$ $O_3$-Ti $O_2$ (LBT : 80∼60 wt%) for crystallizable glasses were used. The glass/ceramic composites were investigated for sintering behavior, phase evaluation, densities, interface reaction and microwave dielectric properties. It was found that the addition LBT glass frist significantly lowered the sintering temperature to below 90$0^{\circ}C$ and the densification with increasing addition LBT glass frist developed rapidly which was meant to be namely 90% of relative density. The sintered bodies ekhibited applicable dielectric properties, namely 15 for $\varepsilon$$_{r}$,, 10000 GHz for Q* $f_{0}$. The results suggest that the composites have good potential as a new candidate for LTCC materials.

Preparation and Characteristics of $Fe_3O_4$-Encapsulated $BaTiO_3$ Powder by Ultrasound-Enhanced Ferrite Plating (초음파 여기 페라이트 플레이팅 법에 의한 $Fe_3O_4/BaTiO_3$ 복합 분말의 제조 및 특성)

  • 최성현;오재희
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.98-99
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    • 2002
  • 페라이트 플레이팅(ferrite plating)법은 10$0^{\circ}C$ 이하의 낮은 온도에서 박막을 제작할 수 있기 때문에 비 내열성 물질(플라스틱, GaAs, 종이류 등)을 기판으로 사용 가능하고, 일종의 무전해 도금법으로서 피도금체의 형상에 관계없이 균일한 두께의 페라이트 막이 얻어지며, PVD 및 CVD방법에 비하여 복잡한 장치를 필요로 하지 않기 때문에 특히 경제적인 측면에서 제작비용을 낮게 할 수 있다는 장점이 있다[1]. (중략)

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Properties of ba-ferrite Particles Synthesized by Molten Salt Method (용융염법으로 합성한 Ba-ferrite 입자의 특성)

  • 오영우
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.545-550
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    • 2000
  • In order to synthesize Ba-ferrite particles by molten salt method KCl and NaCl were added to basic composition to 50% by weight. X was varied from 0.0 to 1.0 to control the magnetic properties in $BaFe_{12-2x}$/ $Co_{x}$ / $Ti_{x}$ / $O_{19}$ and 1 mol% of $SiO_2$was added to control the aspect ratio of hexagonal platelets. And the effects of reaction temperatures were examined by varying the temperature from 85$0^{\circ}C$ to 120$0^{\circ}C$ with 5$0^{\circ}C$ intervals. Eutectic composition of NaCl and KCl lowered the crystallizing temperature of Ba-ferrite in molten salts than using KCl and NaCl separatly. The morphology of resulting Ba-ferrite particles was clearly hexagonal-shaped plates. $H_{c}$ and $M_{r}$ were decreased when F $e^{3+}$ was substitued with $Co^{2+}$ and $Ti^{4+}$ from x=0 to x=1.0 in $BaFe_{12-2x}$/ $Co_{x}$ / $Ti_{x}$ / $O_{19}$ . Adding 1mol% $SiO_2$in molten salt method increased the size but shortened c-axis of the hexagonal ferrites and this result is an opposite phenomenon compared with the result in solid-statge reaction.n.ion.n.

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Effects of Nb2O5 and MnO2 on the PTCR behavior of Lead-free Ba0.99(Bi1/2Na1/2)0.01TiO3 Ceramics (무연 Ba0.99(Bi1/2Na1/2)0.01TiO3 세라믹의 PTCR 특성에 미치는 Nb2O5와 MnO2의 효과)

  • Park, Yong-Jun;Nahm, Sahn;Lee, Young-Jin;Jeong, Young-Hun;Paik, Jong-Hoo;Kim, Dae-Joon;Lee, Woo-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.7
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    • pp.638-644
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    • 2008
  • The effects of $Nb_2O_5$ and $MnO_2$ on the positive temperature coefficient of resistivity (PTCR) behavior of lead-free $Ba_{0.99}(Bi_{1/2}Na_{1/2})_{0.01}TiO_3$ (BaBiNT) ceramics were investigated in order to fabricate a PTC thermistor available at high temperature of > $120^{\circ}C$. In particular, 0.05 mol% $Nb_2O_5$ added BaBiNT ceramic, which has significantly increased Curie temperature (Tc) of $160^{\circ}C$, showed good PTCR behavior; low resistivity at room temperature $(\rho_r)$ of $80.1{\Omega}{\cdot}cm$, a high $\rho_{max}/\rho_{min}$ ratio of $5.65{\times}10^3$ and a large resistivity temperature factor (a) of 18.5%/$^{\circ}C$. Furthermore, the improved $\rho_{max}/\rho_{min}$ of $6.48{\times}10^4$ and a of 25.4%/$^{\circ}C$ along with higher $T_c$ of $167^{\circ}C$ despite slightly increased $\rho_r$ of $569{\Omega}{\cdot}cm$, could be obtained for the BaBiNT + 0.05 mol% $Nb_2O_5$ + 0.02 wt% $MnO_2$ ceramic cooled down at a rate of $200^{\circ}C/h$.

Effects of $SiO_2$ and Seed on Ba-ferrite Synthesized by Molten Salt (용융염법으로 합성한 Ba-ferrite의 $SiO_2$ 및 Seed 첨가 효과)

  • 김영근;이승관;김현식;오영우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.326-329
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    • 1996
  • In order to synthesize Ba-ferrite fine particles by molten salt method and inhibit the abnormal grain growth of sintered specimen, KCI anti NaCl were added to basic composition to 50% by weight, and added 1 male% of $SiO_2$ to control the shape of Ba-ferrite particles. $H_{c}$ and $M_{r}$ were decreased when F $e^{3+}$ was substituted with $Co_{2+}$ and $Ti_{4+}$ from x=0 to x=1.0 in $BaFe_{12-2x}$ $Ti_{x}$ $Co_{x}$ $O_{19}$ , and 1 mole% $SiO_2$ increased the size but shortened c-axis of hexagonal ferrite. Seeds added in Ba-ferrite particle effected inhibition of abnormal grain growth during sintering.ing.g.

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A study on Dielectric and Electrical Properties Using PMN-PT-BT Ceramics(II) (PMN-PT-BT계 세라믹스의 유전 및 전기적 특성(II))

  • Ji, S.H.;Lee, N.H.;Lee, H.K.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.196-198
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    • 1994
  • The dielectric and electrical properties of $Pb(Mg_{1/3}Nb_{2\3})O_3-PbTiO_3-BaTiO_3$ have been investigated. Perovskite crystalline phase of the specimens are confirmed by XRD at $1270^{\circ}C$. The curie temperature is around $40^{\circ}C$ with the amount of $BaTiO_3$ and $PbTiO_3$. Every specimens shows the slim loop hysteresis curves which is electrostrictive characteristic. The strain vs. applied voltage characteristics exhibits nonlinear relationship, and the specimen of 0.85PMN-0.125PT-0.025BT shows the largest strain.

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Optical Properties of Opal Glass on the Various Contents of Chemical Composition

  • Nguyen, Tuan Dung;N., Bramhe Sachin;Kim, Ji Ho;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.23 no.1
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    • pp.59-66
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    • 2013
  • Opal glass samples having different chemical compositions were synthesized and transparent glass was obtained after melting. The effects of $TiO_2$, $BaF_2$, and $CeO_2$ content on the color of the opal glass were studied by observing images of the opal samples and analyzing the results via ultraviolet visible spectroscopy and color spectrometry. The aesthetic properties of the opal glass were determined by studying the transmittance of visible light in the 400 nm to 700 nm range. The basic chemical composition of opal glass was $SiO_2$ 52.9 wt%, $Al_2O_3$ 12.35 wt%, $Na_2CO_3$ 15.08 wt%, $K_2CO_3$ 10.35 wt%, $Ca_3(PO)_4$ 4.41 wt%, $MgCO_3$ 1.844 wt%, $LiCO_3$ 2.184 wt%, and $TiO_2$ 0.882 wt%. The glass samples were prepared by varying the weight percentage of $TiO_2$, $BaF_2$, and $CeO_2$. The transmittance of visible light was decreased from 95 % to 75 % in the glass samples in which $TiO_2$ content was increased from 0 to 3.882 wt%. In the blue spectrum region, as the content of $TiO_2$ increased, the reflectance value was observed to become higher. This implies that $TiO_2$ content induces more crystal formation and has an important effect on the optical properties of the glass. The opalescence of opal samples that contained $CeO_2$ or $BaF_2$ is stronger than that in the samples containing $TiO_2$. Opal glass samples comprising $TiO_2$ had tetragonal lattice structures; samples including $CeO_2$ as an additive had cubic lattice structures (FCC, $CeO_2$).