• Title/Summary/Keyword: $BaTiO_{3}$

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Geochemical and Nd-Sr Isotope Studies for Foliated Granitoids and Mylonitized Gneisses from the Myeongho Area in Northeast Yecheon Shear Zone (예천전단대 북동부 명호지역 엽리상 화강암류와 압쇄 편마암류에 대한 지구화학 및 Nd-Sr 동위원소 연구)

  • Kim, Sung-Won;Lee, Chang-Yun;Ryu, In-Chang
    • Economic and Environmental Geology
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    • v.41 no.3
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    • pp.299-314
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    • 2008
  • The NE-trending Honam shear zone is a broad, dextral strike-slip fault zone between the southern margin of the Okcheon Belt and the Precambrian Yeongnam Massif in South Korea and is parallel to the trend of Sinian deformation that is conspicuous in Far East Asia. In this paper, we report geochemical and isotopic(Sr and Nd) data of mylonitic quartz-muscovite Precambrian gneisses and surrounding foliated hornblende-biotite granitoids near the Myeongho area in the Yecheon Shear Zone, a representative segment of the Honam Shear Zone. Foliated hornblende-biotite granitoids commonly plot in the granodiorite field($SiO_2=61.9-67.1\;wt%$ and $Na_2O+K_2O=5.21-6.99\;wt%$) on $SiO_2$ vs. $Na_2O+K_2O$ discrimination diagram, whereas quartz-muscovite Precambrian orthogneisses plot in the granite field. The foliated hornblende-biotite granitoids are mostly calcic and calc-alkalic and are dominantly magnesian in a modified alkali-lime index(MALI) and Fe# [$=FeO_{total}(FeO_{total}+MgO)$] versus $SiO_2$ diagrams, which correspond with geochemical characteristics of Cordilleran Mesozoic batholiths. The foliated hornblende-biotite granitoids have molar ratios of $Al_2O_3/(CaO+Na_2O+K_2O)$ ranging from 0.89 to 1.10 and are metaluminous to weakly peraluminous, indicating I type. In contrast, Paleoproterozoic orthogneisses have peraluminous compositions, with molar ratios of $Al_2O_3/(CaO+Na_2O+K_2O)$ ranging from 1.11 to 1.22. On trace element spider diagrams normalized to the primitive mantle, the large ion lithophile element(LILE) enrichments(Rb, Ba, Th and U) and negative Ta-Nb-P-Ti anomalies of foliated hornblende-biotite granitoids and mylonitized quartz-muscovite gneisses in the Yecheon Shear Zone are features common to subduction-related granitoids and are also found in granitoids from a crustal source derived from the arc crust of active continental margin. ${\varepsilon}_{Nd}(T)$ and initial Sr-ratio ratios of foliated hornblende-biotite granitoids with suggest the involvement of upper crust-derived melts in granitoid petrogenesis. Foliated hornblende-biotite granitoids in the study area, together with the Yeongju Batholith, show not changing contents of specific elements(Ti, P, Zr, V and Y) from shear zone to the area near the shear zone. These results suggest that no volume changes and geochemical alterations in fluid-rich foliated hornblende-biotite granitoids may occur during deformation, which mass transfer by fluid flow into the shear zone is equal to the mass transfer out of the shear zone.

Microwave Properties of Tunable Phase Shifter Using High Temperature Superconducting Thin Film (고온초전도 박막을 이용한 튜너블 이상기의 마이크로파 특성)

  • Kwak Min Hwan;Kim Young Tae;Moon Seong Eon;Ryu Han Cheol;Lee Su Jae;Kang Kwang Yong
    • Progress in Superconductivity and Cryogenics
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    • v.7 no.1
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    • pp.13-16
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    • 2005
  • High temperature superconductor, $\YBa_2Cu_3O_{7-x}$ (YBCO) and ferroelectric, $\Ba_{0.1}Sr_{0.9}TiO_{3}$ (BST) multilayer thin films were deposited using on MgO(100) substrates pulsed laser deposition. The thin films exhibited only (001) peaks of YBCO and 1357 The HTS thin films demonstrated excellent zero resistance temperature of 92.5 K. We designed and fabricated HTS ferroelectric phase shifter using high frequency system simulator and standard photolithography method, respectively The HTS phase shifter shows a low insertion loss (2.97 dB) and large phase change ($\162^{circ}$) with 40 V do bias at 10 GHz. The HTS phase shifter shows 54 of figure of merit. These results can be applicable to phased anay antenna system for satellite communication services.

Design and Fabrication of Thin Microwave Absorbers of ITO/Dielectric Structures Used for Mobile Telecommunication Frequency Bands (ITO박막/세라믹유전체 구조의 이동통신 주파수대역용 박형 전파흡수체의 설계 및 제조)

  • Yoon, Yeo-Choon;Kim, Sung-Soo
    • Korean Journal of Materials Research
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    • v.13 no.4
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    • pp.259-265
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    • 2003
  • For the aim of thin microwave absorbers used in mobile telecommunication frequency band, this study proposed a high permittivity dielectrics(λ/4 spacer) coated with ITO thin films of 377 $\Omega$/sq(impedance transformer). High frequency dielectric properties of ferroelectric ceramics, electrical properties of ITO thin films and microwave absorbing properties of ITO/dielectrics were investigated. Ferroelectric materials including $BaTiO_3$(BT), 0.9Pb($Mg_{1}$3/Nb$_{2}$3/)$O_3$-0.1 $PbTiO_3$(PMN-PT), 0.8 Pb (Mg$_{1}$3/$Nb_{2}$3/)$O_3$-0.2 Pb($Zn_{1}$3$_Nb{2}$3/)$O_3$(PMN-PZN) were prepared by ceramic processing for high permittivity dielectrics,. The ferroelectric materials show high dielectric constant and dielectric loss in the microwave frequency range. The microwave absorbance (at 2 ㎓) of BT, 0.9PMN-0.1PT, and 0.8PMN-0.2PZN were found to be 60%(at a thickness of 3.5 mm), 20% (2.5 mm), and 30% (2.5 mm), respectively. By coating the ITO thin films on the ferroelectric substrates with λ/4 thickness, the microwave absorbance is greatly improved. Particularly, when the surface resistance of ITO films is closed of 377 $\Omega$/sq, the reflection loss is reduced to -20 ㏈(99% absorbance). This is attributed to the wave impedance matching controlled by ITO thin films at a given thickness of high permittivity dielectrics of λ/4 (3.5 mm for BT, 2.5 mm for PMN-PT and PMN-PZN at 2 ㎓). It is, therefore, successfully proposed that the ITO/ferroelectric materials with controlled surface resistance and high dielectric constant can be useful as a thin microwave absorbers in mobile telecommunication frequency band.

Characterization of Surface Properties of $BaTiO_3$ Powder by XPS

  • Chun, Myoung-Pyo;Cho, Jung-Ho;Kim, Byung-Ik
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.678-679
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    • 2006
  • The effects of particle size on the surface properties of hydro-thermally synthesized barium titanate powders were investigated by means of particle size analysis, specific surface area, SEM, zeta potential and XPS. Particle sizes were measured by laser light scattering and are in the range of 150 to 1100nm. Zeta potential increased with increasing particle size and it was large minus value in the range of particle size from 500 to 900nm, which seems to be related with the dissolution of $Ba^{2+}$ ion in these particle sizes from the analysis of surface properties by XPS.

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Chemical Speciations of Elements in the Fe-Mn Crusts by Sequential Extraction (단계별 추출법을 이용한 망간각 구성 원소의 존재 형태)

  • Kim, Jong-Uk;Moon, Jai-Woon;Chi, Sang-Bum;Ko, Young-Tak;Lee, Hyun-Bok
    • Ocean and Polar Research
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    • v.26 no.2
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    • pp.231-243
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    • 2004
  • Sequential extraction was carried out on twenty two subsamples of three ferromanganese crusts from three seamounts (Lemkein, Lomilik, and Litakpooki) near the Marshall Islands in the western Pacific. The extraction was designed to fractionate Fe-Mn crust forming elements into low defined groups: (1) exchangeable and carbornate, (2) Mn-oxide, (3) Fe-oxyhyd.oxide, and (4) residual fraction. X-ray diffraction result shows that target material were well removed by each extraction step except for CFA in phosphatized crusts generation. According to chemical analysis of each leachate, most of elements in the Fe-Mn crusts are bound with two major phases. Mn, Ba, Co, Ni, Zn, (Fe, Sr, Cu, and V) are strongly bounded with Mn-oxide $({\delta}-MnO_2)$ phase, whereas Fe, Ti, Zr, Mo, Pb, Al, Cu,(V, P, and Zn) show chemical affinity with Fe-oxyhydroxide phase. This result indicates that significant amount of Al, Ti, and Zr can not be explained by detrital origin. Ca, Mg, K, and Sr mainly occur as exchangeable elements and/or carbonate phase. Outermost layer 1 and inner layer 2 which are both young crusts generations are similar in chemical speciations of elements. However, some of Fe-oxyhydroxide bounded elements (Pb, Y, Mo, Ba, Al, and V) in phosphatized innermost layer 3 are released during phosphatization and incorporated into phosphate (Pb, Y, Mo, and Ba) or Mn-oxide phase (Al and V). Our sequential extraction results reveal that chemical speciations of elements in the hydrogenetic crusts are more or less different from interelemental relationship calculated by statistical method based on bulk chemistry.

Fabrication of Piezoelectric Cantilever with Microcone Tip for Sensing Local Stiffness of Biological Tissue (생체 조직의 국소 강도 측정을 위한 마이크로 콘 팁을 가진 압전 캔틸레버 제작)

  • Roh, Hee Chang;Yang, Dasom;Ryu, WonHyoung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.11
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    • pp.743-748
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    • 2017
  • For diseases that are difficult to detect by conventional imaging techniques, the development of a diagnostic method that allows sensors to be inserted into the human body to aid the diagnosis of local spots of the target tissue, is highly desirable. In particular, it is extremely difficult to determine whether vulnerable plaque can later develop into atherosclerosis using only imaging techniques. However, vulnerable plaques are expected to have slightly different mechanical properties than healthy tissue. In this study, we aim to develop a piezoelectric cantilever-type sensor that can be inserted into the human body and can detect the local mechanical properties of the target tissue. A piezoelectric polymer composite based on $BaTiO_3$ nanoparticles was optimized for fabrication of a piezoelectric cantilever. Next, a micro-cone tip was fabricated at the end of the piezoelectric cantilever by thermal drawing. Finally, stiffness of biological tissue samples was measured with the piezoelectric cantilever sensor for verifying its functionality.

Effect of heating temperature to remove NOx by sludge pellet (Sludge Pellet의 NOx제거특성에 미치는 온도의 영향)

  • Kim, Young-Ju;Park, Jae-Yoon;Park, Hong-Jae;Song, Won-Seob;Park, Sang-Hyun;Bae, Myung-Whan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.922-926
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    • 2002
  • In this paper, in order to investigate the catalytic effect of the sludge exhausted from waterworks as heating temperature for NOx removal, we measure NO, $NO_2$ concentration as increasing temperature of sludge pellets and applying high voltage to sludge pellets in a quartz-glass reactor at the same time. NO initial concentration is 100ppm balanced with air gas in a mixing chamber. The gas flow is 5[l/min] and the heating temperature of sludge pellets in a quartz-glass reactor is adjusted from $200[^{\circ}C]$ $400[^{\circ}C]$ to investigate the effect of sludge pellets for removal NOx$(NO+NO_2)$ as increasing temperature. $BaTiO_3$ pellets is filled in a packed-bed reactor for corona discharge to measure how much NOx$(NO+NO_2)$ is removed after generating $NO_2$ from the packed-bed reactor. AC[60Hz] voltage is supplied to the reactor for discharge. In the result, $NO_2$ concentration is decreased by sludge pellets without heating temperature for sludge pellets in case of sludge pellets done heat treatment, however NO concentration is almost the same to be compared NO initial concentration. As increasing heating temperature for sludge pellets, $NO_2$ adsorbed on the sludge surface done heat treatment is converted to NO by the thermal energy, so NO concentration is extremely increased by reduction decomposition of $NO_2$. Finally, We think the sludge is possible to use for reduction catalysts, however we need to study more about the possibility and endurance of sludge as catalysts for NOx removal.

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A Study on Protective Control System for Electrical Fire using Characteristics of SCR and Multilayer-Type PTC Thermistor (SCR과 적층형 PTC 서미스터의 전기적 특성을 이용한 전기화재 보호제어시스템에 관한 연구)

  • Kwak Dong-Kurl
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.1 s.38
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    • pp.31-35
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    • 2006
  • This paper is studied on a protective control system for electrical fire used electrical characteristics of SCR and multilayer-type PTC thermistor. The PTC thermistor has characteristic or positive resistivity temperature coefficient according to the temperature variation, which is construction of a regular square and cube demarcation with $BaTiO_{3_}$Ceramics of positive temperature coefficient. Also PTC shows the phenomenon which is rapidly increased in the resistivity if the temperature is increased over Curie temperature point. This paper is proposed on a protective control system used multilayer-type PTC which is protected from electrical fire due to electric short circuit faults or overload faults. Some experimental results of the proposed apparatus is confirmed to the validity of the analytical results.

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Development on Electrical Fire Prevention System of Small Size and High Speed by using PTC Thermistor (PTC 서미스터를 이용한 소형 고속응성의 전기화재 방재시스템 개발)

  • Kwak, Dong-Kurl
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.1
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    • pp.51-58
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    • 2008
  • This paper is studied on a prevention system for electrical fire and electrical faults by using electrical temperature characteristic of PTC thermistor. The PTC thermistor has characteristic of positive resistivity temperature coefficient according to the temperature variation, which is construction of a regular square and cube demarcation with $BaTiO_3$ ceramics of positive temperature coefficient. Also PTC shows the phenomenon which is rapidly increased in the resistivity if the temperature is increased over Curie temperature point. This paper is proposed on a protective control system used with temperature sensor of PTC thermistor. The proposed prevention system will prevent electrical fires due to electric short circuit faults or overload faults. And the prevention system will solve the problems that circuit breakers to be commonly used at existing are happened frequently electrical fires and electrical disasters due to incapable operation, weak reliability and low speed response. Some experimental results of the proposed apparatus are confirmed to the validity of the analytical results.

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