• Title/Summary/Keyword: $BaTiO_{3}$

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Enhanced Piezoelectric Properties of (1-x)[0.675BiFeO3-0.325BaTiO3]-xLiTaO3 Ternary System by Air-Quenching

  • Akram, Fazli;Malik, Rizwan Ahmed;Lee, Soonil;Pasha, Riffat Asim;Kim, Myong Ho
    • Korean Journal of Materials Research
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    • v.28 no.9
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    • pp.489-494
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    • 2018
  • Lead free $(1-x)(0.675BiFeO_3-0.325BaTiO_3)-xLiTaO_3$ (BFBTLT, x = 0, 0.01, 0.02, and 0.03, with 0.6 mol% $MnO_2$ and 0.4 mol% CuO) were prepared by a solid state reaction method, followed by air quenching and their crystalline phase, morphology, dielectric, ferroelectric and piezoelectric properties were explored. An X-ray diffraction study indicates that lithium (Li) and tantalum (Ta) were fully incorporated in the BFBT materials with the absence of any secondary phases. Dense ceramic samples (> 92 %) with a wide range of grain sizes from $3.70{\mu}m$ to $1.82{\mu}m$ were obtained in the selected compositions ($0{\leq}x{\leq}0.03$) of BFBTLT system. The maximum temperatures ($T_{max}$) were mostly higher than $420^{\circ}C$ in the studied composition range. The maximum values of maximum polarization ($P_{max}{\approx}31.01{\mu}C/cm^2$), remnant polarization ($P_{rem}{\approx}22.82{\mu}C/cm^2$) and static piezoelectric constant ($d_{33}{\approx}145pC/N$) were obtained at BFBT-0.01LT composition with 0.6 mol% $MnO_2$ and 0.4 mol% CuO. This study demonstrates that the high $T_{max}$ and $d_{33}$ for BFBTLT ceramics are favorable for industrial applications.

Grain growth of the PTC thermistor according to the soaking temperature (PTC 서어미스타 소자의 소성온도에 따른 Grain의 성장상태)

  • 박창엽;이영희
    • 전기의세계
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    • v.31 no.6
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    • pp.437-444
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    • 1982
  • Although several kinds of conduction mechanism of PTC thermistor have been reported, there were few satisfying results. In this paper, the reported conduction mechanism theories were scrutinized and analyzed by using the experimental results. PTC thermistors for this study were manufactured by adding Sb$\_$2/O$\_$3/, AI$\_$2/O$\_$3/, TiO$\_$2/, and SiO$\_$2/ to BaTiO$\_$3/, and by sintering it at different temperatures. In order to analyze the conduction mechanism, R-T characteristics and its frequency dependence of specimens were measured. And also, the structures of specimens were studied. Especially this paper emphasized the explanation of the resistivity characteristics as the grain growth state of PTC thermistor specimens with respect to soaking temperature. According to the results, the resistivity of PTC thermistor whose grain was formed by semiconducting, was independent to the grain size at room temperature. For small and uniform grain size, the slope of the resistivity near the Curie temperature and the resistivity above the Curie temperature became greater and PTCR effect was improved.

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Characteristics of Flow Sensor Using PTC Thermistor (PTC 써어미스터를 이용한 유속센서의 특성)

  • Kwon, Hyuk-Joo;Lee, Yang-Hyun
    • Journal of Sensor Science and Technology
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    • v.3 no.3
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    • pp.3-8
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    • 1994
  • Flow sensor was fabricated with PTC thermistor usually operating as thermostats. The PTC thermistor was manufactured with $(Ba_{0.7}Sr_{0.3})TiO_{3}$ powder and its resistivity as a function of flow velocity was investigated. The resistivity changed from 4.45 $k{\Omega}{\cdot}cm$ to 3.95 $k{\Omega}{\cdot}cm$ as flow velocity varied 0 cm/s to 5 cm/s The sensitivities of the PTC thermistor were -204 (${\Omega}{\cdot}cm$)/(cm/s) and -24 (${\Omega}{\cdot}cm$)/(cm/s) at the flow velocity of 1 cm/s and 5 cm/s, respectively.

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A Study on the Dielectric, Electrical Properties of the PZN-BT-PT Ceramics (Y2O3가 첨가된 PZN-BT-PT 세라믹의 유전 및 전기적 특성에 관한 연구)

  • 유주현;이두희;홍재일;강원구;박창엽
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.3
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    • pp.253-260
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    • 1992
  • In this study, the dielectric, structural and electrical properties of Pb(ZnS11/3TNbS12/3T)OS13T-BaTiOS13T-PbTiOS13T system ceramics were investigated with respect to the variation of YS12TOS13T addition amount. As the YS12TOS13T addition amount is increased, the resistivity at 100$^{\circ}C$ and the resonant/antiresonant frequencies and the frequency constant are slowly increased, and the grain growth is restrained until 0.4 wt% YS12TOS13T addition amount but continuously increased with the addition amount more than 0.4 wt% YS12TOS13T. As the YS12TOS13T addition amount is increased, the density, the diffuseness of dielectric constant and the induced polarization are increased until 0.4 wt% YS12TOS13T addition.

Red-emissive Y2SiO5:Eu3+ Phosphor-based Electroluminescence Device (Y2SiO5:Eu3+ 형광체 기반 적색 전계 발광 소자)

  • Hyunjee Jung;Sunho Park;Jong Su Kim;Hoon Heo
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.1
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    • pp.83-87
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    • 2023
  • Y2SiO5 Powder based on silicon and yttrium is well known as powder phosphors due to their excellent sustainability and efficiency. A new electroluminescence device was fabricated with Y2SiO5:Eu3+ powder phosphors though a simple screen printing method. The powder-dispersed electroluminescence device consisted of the Y2SiO5:Eu3+ powder-dispersed phosphor layer and BaTiO3-dispersed dielectric layer. The annealing temperature of the phosphor for the best powder electroluminescence performance was optimized to high temperature in ambient atmosphere though a solid-state reaction. The Eu3+ concentration for the best device performance was also investigated and furthermore, the thermal dependence of the electroluminescence intensity was investigated at the operating voltage at 100℃, which is the Curie temperature of the BaTiO3 layer. And the intensity was exponentially increased with voltage and increased linearly with frequency.

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Effective of $Li_2CO_3$ and ZnBO for low temperature sintered $(Ba_{0.5},Sr_{0.5})TiO_3$ ceramics (BST 세라믹 저온소결에 $Li_2CO_3$와 ZnBO가 미치는 영향)

  • Kim, Se-Ho;You, Hee-Wook;Koo, Sang-Mo;Ha, Jae-Geun;Lee, Young-Hie;Koh, Jung-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.297-297
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    • 2007
  • The $(B_{0.5},Sr_{0.5})TiO_3$ ceramics, which added with low sintering materials $Li_2CO_3$ and ZnBO, was investigated for LTCC(low temperature co-fired ceramic) applications. To compare sintering temperature of $(B_{0.5},Sr_{0.5})TiO_3$ respectively, we added 1, 2, 3, 4, and 5wt% of $Li_2CO_3$ and ZnBO to $(B_{0.5},Sr_{0.5})TiO_3$. For confirming the sintering temperature, the respective specimens were sintered from $750^{\circ}C$ to $1200^{\circ}C$ by $50^{\circ}C$. The case of $Li_2CO_3$ greatly lowered the sintering temperature of $(B_{0.5},Sr_{0.5})TiO_3$ ($1350^{\circ}C$) below $900^{\circ}C$. The addition of ZnBO improved the loss tangent of $(B_{0.5},Sr_{0.5})TiO_3$. The crystalline structure of $LiCO_3$ doped $(B_{0.5},Sr_{0.5})TiO_3$ and ZnBO doped $(B_{0.5},Sr_{0.5})TiO_3$ was analyzed with the X-ray diffraction (XRD) analysis. The dielectric permittivity and loss tangent of $Li_2CO_3$ doped BST and ZnBO doped BST were measured with the HP 4284A precision. From the electrical characterization, we respectively obtained the dielectric permittivity 1361, loss tangent $6.94{\times}10^{-3}$ at $Li_2CO_3$ doped $(B_{0.5},Sr_{0.5})TiO_3$ (3wt%) and the dielectric constant 1180, loss tangent $3.70{\times}10^{-3}$ at ZnBO doped $(B_{0.5},Sr_{0.5})TiO_3$(5wt%).

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A study on the characteristics of electrostrictive ceramics for micro displacement control (미소변위 제어용 전왜세라믹스의 특성에 관한 연구)

  • 윤광희;윤석진;홍재일;유주현;박창엽
    • Electrical & Electronic Materials
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    • v.3 no.4
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    • pp.339-346
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    • 1990
  • 미소변위소자에 적합한 전왜세라믹스를 제조하기 위하여 0.85Pb(Zn$_{1}$3-x/MgxNb$_{2}$3/) $O_{3}$-0.10BaTi $O_{3}$-0.05PbTi $O_{3}$조성으로 Mg(mol%)를 변화시키면서 시편을 제조하고 구조적, 유전적, 전기적 특성 및 온도 안정성을 관찰하였다. 큐리온도는 Mg(mol%)가 증가함에 따라 감소하였고 Mg(mol%)가 0.15일 때 유전상수가 가장 높았으며 완만도는 -3.9, 산만도.DELTA.Tc는 21로 가장 컸다. 전계에 따른 유전상수는 감소하였고 Mg(mol%)가 증가할수록 압전정수 d$_{31}$은 감소하였으나 0.05, 0.10, 0.15일 때는 거의 일정하였다. Mg(mol%)가 0.15까지 증가함에 따라 전왜정수 Q$_{31}$은 감소하였고 그 이상에서는 Mg(mol%)가 1/3일때 가장 컸으며 ES-1시편에서의 AC 60(Hz), 11(kV/cm) 전계(electric field)에 의한 왜형을 253*$10^{-6}$을 나타냈다.

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