• 한국진공학회지
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• 제7권s1호
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• pp.179-182
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• 1998

Boron carbide coating has some very attractive properties for nuclear and semiconductor industry. The potential of atmosheric plasma spray as manufacturing methods for $B_4C$ coating was discussed. In this work, the boron carbide coating with low porosity, high microhardness and good life of thermal shock resistance was deposited by the control of spraying distance. The relationship between the properties of $B_4C$ coatings and their spraying distance was studied.

• 한국세라믹학회지
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• 제40권8호
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• pp.777-783
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• 2003

B$_4$C/Al 복합체의 기계적 물성은 제조 과정에서 B$_4$C와 Al의 반응에 의한 반응생성물의 종류와 양에 의해서 결정되므로, 강하고 경량 소재로서의 특성이 요구되는 복합체를 만들려면 반응생성물을 조절할 필요가 있다. TiB$_2$는 알루미늄과 반응성이 거의 없고 B$_4$C보다 낮은 접촉각(100$0^{\circ}C$에서 85$^{\circ}$)을 가지고 있다. 그러므로 B$_4$C를 TiB$_2$로 코팅하면 B$_4$C/Al복합체를 함침법으로 제조하는 경우 알루미늄의 함침 온도를 낮출 수 있다. 본 연구에서는 TiB$_2$가 B$_4$C/Al 복합체의 미세구조와 기계적 특성에 미치는 영향을 조사하였다. TiB$_2$를 코팅한 B$_4$C 분말을 졸겔법을 이용하여 준비하였다. B$_4$C 입자에 코팅된 TiB$_2$ 입자 크기는 20-50 nm이었다. TiB$_2$를 코팅하고 제작한 B$_4$C/Al 복합체에는 l7wt%의 미반응 알루미늄이 남아있었고, 코팅하지 않고 제작한 것에는 l4 wt%가 남았다. 결과적으로 코팅하고 제작한 복합체는 코팅하지 않고 제작한 것보다 파괴인성은 높고 경도는 낮았으며, 이러한 결과에서 TiB$_2$가 알루미늄의 함침 온도를 낮추고 B$_4$C와 Al이 반응하는 것을 억제하고 있다는 것을 알 수 있었다.

• Corrosion Science and Technology
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• 제7권4호
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• pp.233-236
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• 2008

Halide-activated pack cementation was utilized to deposit B-doped silicide coating. The pack powders were consisted of $3Wt.c/oNH_4Cl$, 7Wt.c/oSi, $90Wt.c/oAl_2O_3+TiB_2$. B-doped silicide coating was consisted of two layers, an outer layer of $NbSi_2$ and an inner layer of $Nb_5Si_3$. Isothermal oxidation resistance of B-doped silicide coating was tested at $1250^{\circ}C$ in static air. B-doped silicide coating had excellent oxidation resistance, because continuous $SiO_2$ scale which serves as obstacle of oxygen diffusion was formed after oxidation.

• 한국농공학회논문집
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• 제46권4호
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• pp.39-46
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• 2004

This experiment was carried out to study on the effect of surface coating on thermal insulation of farm structures to improve thermal resistance and reflective effect of solar radiation. Nine different types of experimental specimen were compared in the temperature variations of inside and outside; A, B, C, D. E and F types are box container and G, H and I types are drum container. The size of these containers is $1,500{\times}2,000{\times}2,500$ mm and ${\varphi}$ $280{\times}330$ mm, respectively. Specimen of 3-type box(A, B, C) is galvanized steel sheet of thickness 0.45 mm. D, E and F types are sandwich panel of the thickness 50 mm inserted with urethane, glass wool and polystyrene form, respectively. G, H and I types are paint pot using in general. The surface of A. D, E, F and I types didn't any treatment, B, C and G types were treated with thermal insulation coating on the outside surface(B, G) or the inside and outside surface(C). And H type was treated with water paint coating on the only outside surface. In general, the experimental results showed the following tendencies; In case of A, B and C types. it was found that the thermal insulation effect of types coated with thermal insulation coating was improved remarkably than that of no treatment. And the thermal insulation effect between steel sheet and sandwich panel type was nearly similar There was not a significant difference of thermal insulation effect between thermal insulation coating and water paint coating. In time of drum container filled with rough rice, The difference of heat transfer tendency and temperature variation among surface treatments was nearly similar that of box types of galvanized steel sheet. And there was time lag about 6 hours between the temperature of middle part of rice and that of inside or outside surface.

• 한국분말재료학회지
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• 제16권2호
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• pp.110-114
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• 2009

Mechanical coating process was applied to form 89 %-hydrolyzed poly vinyl alcohol (PVA) onto boron carbide ($B_4C$) nanopowder using one step high energy ball mill method. The polymer layer coated on the surface of B4C was changed to glass-like phase. The average particle size of core/shell structured $B_4C$/PVA was about 50 nm. The core/shell structured $B_4C$/PVA was formed by dry milling. However, the hydrolyzed PVA of $98{\sim}99%$ with high glass transition temperature ($T_g$) was rarely coated on the powder. The $T_g$ of polymer materials was one of keys for guest polymer coating on to the host powder by solvent free milling.

• KSBB Journal
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• 제19권3호
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• pp.221-225
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• 2004

Bacillus sp. 유래의 Bacillus polyfermenticus SCD를 Bisroo $t^{ⓡ}$라고 부르고, 이것은 생균제로서 산업적으로 매우 유용하다. 본 연구에서는 B. polyfermenticus SCD를 산업적으로 활용성을 증대시키기 위해 three layer coating법을 사용하여 인공위액의 pH 변화에 대한 안정성과 열안정성, glucose 농도에 따른 안정성을 연구하였다. 그 결과 코팅한 B. polyfermenticus SCD가 인공위액에 대한 내성에서는 배양 4시간을 기준으로 pH 2는 30%, pH 4는 20%, pH 6은 14% 상승효과가 있었음을 알 수 있었고, 온도변화에 대한 안정성에서는 코팅한 B. polyfermenticus SCD가 8$0^{\circ}C$에서 2시간 기준으로 안정성이 약 40% 증진됨을 확인할 수 있었다. 고농도 (30%)의 glucose에서 코팅한 B. polyfermenticus SCD는 안정하였으며, 코팅하지 않은 것보다 약 50% 안정성이 증대됨을 확인할 수 있었다. 그리고 pH 4.0에서는 코팅한 B. polyfermenticus SCD는 코팅을 하지 않은 B polyfermenticus SCD보다 전체적으로 생존율이 40% 이상, pH 6.0에서는 생존율이 42% 이상 증진됨을 알 수 있었다.

• Composites Research
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• 제33권5호
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• pp.235-240
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• 2020

본 연구에서는 B₄C tile 삽입 B₄C_p/Al7075 하이브리드 복합재의 내충격성을 향상시키기 위하여 B₄C/Al7075 계면의 제어법을 개발하고 제어된 계면의 특성에 관하여 분석하였다. 이를 위해 B₄C 타일 표면에 B₂O₃, Ni, 그리고 Si을 각각 열산화, 무전해도금, 그리고 플라즈마 용사법을 이용하여 코팅하였다. 이후 코팅된 B₄C 타일을 액상 가압법을 이용하여 B₄C/Al7075 복합재 내부에 삽입하여 B₄C tile 삽입 B₄C_p/Al7075 하이브리드 복합재를 제작하였다. 코팅의 효과를 체계적으로 분석하기 위해 계면에너지, 접합 강도, 그리고 내충격성을 측정하였다. 모든 코팅이 계면에너지, 계면강도, 내충격성을 증가시켰으며 특히 B₂O₃ 코팅 시 내충격성이 86.8% 증가하였다. 본 연구는 차세대 경량 장갑, 방탄소재로 주목받고 있는 B₄C/Al 계열 복합재의 성능을 향상시키는 핵심적인 표면처리법을 개발, 분석한 것에 의의가 있다.

• 한국결정성장학회지
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• 제16권6호
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• pp.278-285
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• 2006

발전소의 탈황설비에 적용하기 위한 B-H 코팅조성물을 탄소강에 코팅하여 $65^{\circ}C{\sim}80^{\circ}C$에서 경화시켰다. 이들 시편을 $100^{\circ}C$와 $120^{\circ}C$의 70 wt% $H_2SO_4$ 용액에 접촉시킨 후 코팅조성물의 조성, 비이커스 경도, SEM에 의한 미세구조 등을 분석하였다. 황산에 대한 내산성은 내산성 시험후 코팅 조성물의 $SO_3$양과 관련이 있었다. 경화온도가 높을수록, 경화시간이 짧을수록 내산성이 좋았으나 고온일 경우에는 균열이 더 많이 발생하여 내산성을 떨어뜨렸다 B-H 코팅 조성물의 고온 내산성을 향상시키기 위한 조건은 경화온도 $65^{\circ}C$이상, 경화시간 12시간 이상이었다.

• 한국표면공학회지
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• 제44권2호
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• pp.60-67
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• 2011

Ternary B-C-N coatings were deposited on Si(100) wafer substrate from $B_4C$ target by RF magnetron sputtering technique in $Ar+N_2+CH_4$ gas mixture. In this work, the effect of reactant gas ratio, $CH_4/(N_2+CH_4)$ on the composition, kinds and amounts of bonding states comprising B-C-N coatings were investigated using two different bias power sources of continuous and unipolar DCs. In addition, the tribological properties of coatings were studied with the composition and bonding state of coating. It was found that the substrate bias power had an effect on chemical composition, and all of the obtained coatings were nearly amorphous. Main bonding states of coatings were revealed from FTIR analyses to be h-BN, C-C, C-N, and B-C. The amount of C-C bonging mainly increased with increase of the reactant gas ratio. From our studies, both C-C and h-BN bonding states improved the tribological properties but B-C one was found to be harmful on those. The best coating from tribological points of view was found to be $BC_{1.9}N_{2.3}$ composition.

• 전기학회논문지
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• 제61권4호
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• pp.585-589
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• 2012

The characteristics of interface layer and the effect of mole fraction of inlet gas mixture($B_2H_6/H_2/N_2/TiCl_4$) on the microstructure of Ti(B,N) films were studied by microwave plasma hot filament CVD process. Ti(B,N) films were deposited on a substrate(STD-61) to develop a high performance of resistance wear coating tool. Ti(B,N) films were obtained at a gas pressure of 1 torr, bias voltage of 300 V and substrate temperature of $480^{\circ}C$ in $B_2H_6/H_2/N_2/TiCl_4$gas system. It was found that TiN, $TiB_2$, TiB and hexagonal boron nitride(h-BN) phases exist in thin layer on the STD-61.