• 제목/요약/키워드: $Alq_{3}$

검색결과 524건 처리시간 0.028초

Electronic Charge Transfer at the $Alq_3/Ba$ and $Alq_3/Au$ Interfaces by NEXAFS Spectroscopy

  • Lim, Jong-Tae;Yeom, Geun-Young
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
    • /
    • pp.1457-1460
    • /
    • 2007
  • To understand the electronic charge transfer from cathode to an ETL in the TEOLED, the pristine $Alq_3$ thin film and the interfaces of both $Alq_3/Ba$ and $Alq_3/Au$ were investigated by using the NEXAFS spectroscopy. The unoccupied energy state of each interface using the NEXAFS Analyses at the C and OK-edges was assigned and charge transfer from Ba to ${\pi}^{\ast}$ of $Alq_3$ was investigated in detail.

  • PDF

ITO/$Alq_3$/Al의 유기 발광 소자에서 $Alq_3$의 두께 변화에 따른 임피던스 특성 (Impedance properties with thickness variation of $Alq_3$ in organic light-emitting diodes of ITO/$Alq_3$/Al)

  • 정동희;김상걸;정택균;허성우;이호식;송민종;김태완
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
    • /
    • pp.1098-1101
    • /
    • 2003
  • Complex impedances with frequency and voltage variation were analyzed in ITO/$Alq_3$/Al device structure at thickness 100 nm and 200 nm of $Alq_3$, respectively. At low frequency, complex impedance is mostly expressed by resistive component, and at the high frequency by capacitive component. Also, we have evaluated resistance, capacitance and permittivity.

  • PDF

$Alq_3$의 증착속도에 따른 유기발광소자의 발광특성 (Luminous Properties in Organic Light-Emitting Diodes Depending on the deposition rate of $Alq_3$)

  • 김원종;이영환;양재훈;심낙순;김태완;홍진웅
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
    • /
    • pp.154-156
    • /
    • 2005
  • In the device structure of ITO/tris (8-hydroxyquinoline) aluminum(Alq3)/Al, we investigated the Organic Light-Emitting Diodes (OLEDs) properties as a function of the deposition rate of the $Alq_3$. The deposition rate was from 0.5 to 2.0 $[{\AA}/s]$ in a base pressure of $5{\times}10^{-6}$ [Torr]. It was found that a $Alq_3$ deposition rate of around 1.5 $[{\AA}/s]$ is the optimum for the maximum luminous properties. The optimum deposition rate of $Alq_3$ is 1.5 $[{\AA}/s]$.

  • PDF

ITO/$Alq_3$/Al의 유기 발광 소자에서 $Alq_3$의 두께 변화에 따른 임피던스 특성 (Impedance characteristics with various $Alq_3$ thickness in ITO/$Alq_3$/Al organic light-emitting diodes)

  • 공두원;구자룡;김영관
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
    • /
    • pp.477-478
    • /
    • 2005
  • The devices with a structure of ITO/$Alq_3$/Al were fabricated and their impedance properties were analyzed. It is obtained that an effect of resistance $R_p$ of the device was dominant at the low frequency and the high voltage region, emitting region, and it is ignored at the high frequency region. Capacitance $C_p$ appears intensely in a range of all frequencies of non-emitting region, below turn on voltage.

  • PDF

$Alq_3$-C545T시스템을 이용한 고성능 녹색 유기발광다이오드의 제작과 특성 평가 (Fabrication and Characterization of High Performance Green OLEDs using $Alq_3$-C545T Systems)

  • 장지근;김희원;신세진;강의정;안종명;임용규
    • 마이크로전자및패키징학회지
    • /
    • 제13권1호통권38호
    • /
    • pp.51-55
    • /
    • 2006
  • [ $Alq_3$ ]-C545T 형광 시스템을 이용하여 녹색 발광 고성능 OLED를 제작하고 그 특성을 평가하였다. 소자 제작에서 ITO(Indium Tin Oxide)/glass 위에 정공 주입층으로 2-TNATA [4,4',4'-tris(2-naphthyl-phenyl-phenylamino)-triphenylamine]를, 정공수송층으로 NPB [N,N-bis(1-naphthyl)- N,N'-diphenyl-1,1'-biphenyl-4,4-diamine]를 진공 증착하였다. 녹색 발광층으로는 $Ahq_3$를 호스트로, 545T [10-(2-benzo-thiazolyl)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]/benzopyrano[6,7,8-ij]-quinolizin-11-one]를 도펀트로 사용하였다. 또한, 전자 수송층으로는 $Alq_3$를 전자 주입층으로는 LiF를 사용하여 ITO/2-TNATA/NPB/$Alq_3$:C-545T/$Alq_3$/LiF/Al 구조의 저분자 OLED를 제작하였다. 본 실험에서 제작된 녹색 OLED는 521 nm의 중심 발광 파장을 가지며, CIE(0.29, 0.65)의 색순도, 그리고 12V의 동작전압에서 7.3 lm/W의 최대 전력효율을 나타내었다.

  • PDF

포로히-블루머(Forouhi-Bloomer) 분산식을 이용한 유기발광물질 Alq3의 광학 상수 결정 (Determination of optical constants for organic light emitting material of Alq3 using Forouhi-Bloomer dispersion relations)

  • 정부영;우석훈;이석목;황보창권
    • 한국광학회지
    • /
    • 제14권1호
    • /
    • pp.1-7
    • /
    • 2003
  • 유기발광물질 Alq$_3$ 복소굴절률을 양자역학적 흡수이론인 바탕인 포로히-블루머(Forouhi-Bloomer) 분산식[Phys. Rev. B 34. 7018(1986)]을 이용하여 1.5~6 ev의 영역에서 계산하였다. 분광광도계를 이용하여 측정한 Alq$_3$ 박막의 흡수 스펙트럼에서 흡수 피크의 위치와 폭으로부터 포로히-블루머 분산식의 변수 $A_{i}$ , B$_{i}$, $C_{i}$ 의 초기 근사값을 결정하였다. 기판으로 사용한 비정질실리카(fused silica)의 굴절률은 분광광도계로부터 측정된 투과율과 반사율 스펙트럼으로부터 셀마이어(Sellmeier)분산식을 적용하여 계산하였다. 기판의 굴절률과 분광광토계에서 측정한 Alq$_3$박막의 투과율과 반사율 스펙트럼에 포로히-블루머 분산식을 이용한 비선형 최소자승법 곡선맞춤을 하여 Alq$_3$의 복소굴절률을 계산할 수 있었다.

염료감응형 태양전지의 고효율화를 위한 $Alq_3$가 코팅된 FTO기판 제작 (Optimization of $Alq_3$-coated FTO substrate for high efficient of DSSC)

  • 박아름;박경희;구할본;박복기
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
    • /
    • pp.241-241
    • /
    • 2010
  • Recently high and persistent spontaneous buildup of a surface potential (SP) upon vacuum deposition of tris (8-hydroxyquinolinato) aluminum (III) ($Alq_3$), which is widely used for organic light emitting devices. The removal of the giant surface potential by visible light irradiation has also been reported. In this study, we coated $Alq_3$ on the FTO substrate and raise the capacity for absorbing sun light. The $Alq_3$ which is green light emitting diode emits light at wavelengths between 500 and 550nm. If we apply one's FTO/$Alq_3$ substrate in one's DSSC, we could get higher energy conversion efficiency because the N719 dye that we used for fabricating the DSSC emits light just at near 540nm. The energy conversion efficiency of approximately 4.8 % at the condition of irradiation of AM 1.5 (100 mW/$cm^2$) simulated sunlight, and the $J_{sc}$ is 12.0 mA/$cm^2$, $V_{oc}$ is 0.71 V, FF is 0.56, respectively.

  • PDF

란탄계 금속 착화합물을 이용한 다양한 유기 전기 발광 소자의 연구 (A Study on the Various Organic Electroluminescent Devices Using Lanthanide Chelate Metal Complexes)

  • 표상우;김윤명;이한성;김정수;이승희;김영관
    • 한국전기전자재료학회논문지
    • /
    • 제13권5호
    • /
    • pp.437-443
    • /
    • 2000
  • In this study several lanthanide complexes such as Eu(TTA)$_3$(Phen), Tb(ACAC)$_3$-(Cl-Phen) were synthesized and the white-light electroluminescence(EL) characteristics of their thin films were investigated where the devices having structures of anode/TPD/Tb(ACAC)$_3$(Cl-Phen)/Eu(TTA)$_3$(Phen)/Alq$_3$or Bebq$_2$/cathode and the low work function metal alloy such as Li:Al was used as the electron injecting electrode(cathode). Device structure of glass substrate/ITO/TPD(30nm)/Tb(ACAC)$_3$(Phen)(30nm)/Eu(TTA)$_3$(Phen)(6nm)/DCM doped Alq$_3$(10nm)/Alq$_3$(20nm)/Li:Al(100nm) was also fabricated and their EL characteristics were investigated where Eu(TTA)$_3$(Phen) and DCM doped Alq$_3$were used as red light-emitting materials. It was found that the turn-on voltage of the device with non-doped Alq$_3$was lower than that of the devices with doped Alq$_3$and the blue and red light emission peaks due to TPD and Eu(TTA)$_3$(Phen) with non-doped Alq$_3$were lower than those with DCM doped Alq$_3$Details on the white-light-emitting characteristics of these device structures were explained by the energy and diagrams of various materials used in these structure where the energy levels of new materials such as ionization potential(IP) and electron affinity(EA) were measured by cyclic voltametric method.

  • PDF

$Alq_3$ 유도체를 사용한 유기전기발광소자의 발광 특성 (Luminescent Properties of Organic Light Emitting Diode Using $Alq_3$ Complex)

  • 양기성;김두석;김병상;신훈규;김정균;권영수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2004년도 하계학술대회 논문집 C
    • /
    • pp.1703-1705
    • /
    • 2004
  • New luminescent material, 6.11-dihydoxy-5.12-naphtacene-dione $Alq_3$ complex($Alq_2$-Ncd), 1.4-dihydoxy-5.8-naphtaquinone $Alq_3$ complex ($Al_2Nq_4$) was synthesized. The $Alq_2-$ Ncd and $Al_2Nq_4$ has big molecular weight and many ${\pi}$-electrons more than widely known $Alq_3$. And extended efforts have been made to obtain high-performance electro luminescent(EL) devices. We used hole transfer layer of powdered TPD to improve hole transfer and characteristics of interface in OLED. This study indicates not only the sterical effect but also some other effects that would be responsible for the change of the emission wavelength. improvement of luminance and etc.

  • PDF

TPS Analysis of Various Metal Plates for Belt Source Evaporation in AMOLED Manufacturing

  • Hwang, Chang-Hun
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
    • /
    • pp.1603-1606
    • /
    • 2007
  • The TPS (Temperature Programmed Sublimation) technology has been developed to monitor the plane evaporation of the organic films and introduced in SID2007, P53.[4] The Alq3 organic film is deposited on various metal surface such as Cu, Ti, Invar, STS to sublimate. The TPS signal confirms that the Alq3 film consists of nano scale film phase and bulk phase on all the metal plates. The sublimation temperature of the Alq3 film was much lower ($130^{\circ}C$) than the vapor temperature ($265^{\circ}$) of the Alq3 powder.

  • PDF