• Title/Summary/Keyword: $10^{\circ}C$ law

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Flash Point Determination of Binary Liquid Solution Containing Nonflammable Component (비가연성 성분을 포함한 이성분계 액상 용액의 인화점 결정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.23 no.3
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    • pp.40-45
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    • 2019
  • Flash point is the important flammability indicator characterizing the risk of fire and explosion of flammable liquid mixture. In this study, flash points of water+formic acid and water+acrylic acid were measured by Seta flash apparatus. The flash points estimated by the methods based on empirical equation and Raoult's law were compared with experimental flash points. Absolute average errors of the results estimated by Raoult's law are $10.7^{\circ}C$ and $4.8^{\circ}C$ for water+formic acid and water+acrylic acid, respectively. Absolute average errors of the results estimated by empirical equation are $1.0^{\circ}C$ and $0.5^{\circ}C$ for water+formic acid and water+acrylic acid, respectively. In conclusion, the estimated values by empirical equation simulated the measured values better than those calculated by Raoult's law.

Effect of Temperature Change on the Respiration Characteristics of Vegetables

  • Kawagoe, Yoshinori;Seo, Yasuhisa;Oshita, Sei-Ichi;Sagara, Yasuyuki
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1996.06c
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    • pp.947-952
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    • 1996
  • The effect of fluctuating temperature on the respiration of vegetables has been investigated. Spinach was selected as the experimental material because of its high respiratory activity and kept under the condition that temperature changed alternately at low and high levels every 4 hours. The low-high level temperature combination was set in $1-10^{\circ}C,{\;}1-20^{\circ}C{\;}and{\;}1-30^{\circ}C$. Respiration was evaluated in terms of quantity of $CO_2$ evolved from spinach. The evolution rate of $CO_2$ was determined by a change in its concentration. The evaluation rate of $CO_2$ followed closely the temperature change. In the temperature combinations at $1-10^{\circ}C{\;}and{\;}1-20^{\circ}C$, the relationship between $CO_2$ evolution rate and temperature was found to be able to express by Arrhenius law, while at $1-30^{\circ}C$, it did not obey the law.

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Study on failure and subsidence law of frozen soil layer in coal mine influenced by physical conditions

  • Zhang, Yaning;Cheng, Zhanbo;Lv, Huayong
    • Geomechanics and Engineering
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    • v.18 no.1
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    • pp.97-109
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    • 2019
  • Physical conditions play vital role on the mechanical properties of frozen soil, especially for the temperature and moisture content of frozen soil. Subsequently, they influence the subsidence and stress law of permafrost layer. Taking Jiangcang No. 1 Coal Mine as engineering background, combined with laboratory experiment, field measurements and empirical formula to obtain the mechanical parameters of frozen soil, the thick plate mechanical model of permafrost was established to evaluate the safety of permafrost roof. At the same time, $FLAC^{3D}$ was used to study the influence of temperature and moisture content on the deformation and stress law of frozen soil layer. The results show that the failure tensile stress of frozen soil is larger than the maximum tensile stress of permafrost roof occurring in the process of mining. It indicates that the permafrost roof cannot collapse under the conditions of moisture content in the range from 20% to 27% as well as temperature in the range from $-35^{\circ}C$ to $-15^{\circ}C$. Moreover, the maximum subsidence of the upper and lower boundary of the overlying permafrost layer decreases with the increase of moisture content in the range of 15% to 27% or the decrease of temperature in the range of $-35^{\circ}C$ to $-15^{\circ}C$ if the temperature or moisture content keeps consistent with $-25^{\circ}C$ or 20%, respectively.

Dew Point Prediction by Lower Flash Points of Binary Mixtures (이성분계 혼합물의 하부 인화점에 의한 이슬점 예측)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Society of Safety
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    • v.32 no.6
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    • pp.34-39
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    • 2017
  • Vapor-liquid equilibrium calculation is required to properly design and operation of distillation process. The general calculation method is to use binary interaction parameter. Lower flash points of cyclohexanol+aniline and cyclohexanol+cyclohexanone were measured by using Seta-flash closed cup apparatus. The measured flash points were compared with those calculated by the method based on Raoult's law and the optimization method using Wilson equation. The absolute average errors(A.A.E.) of the results calculated by Raout's law are $0.25^{\circ}C$ and $1.07^{\circ}C$ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. The absolute average errors of the results calculated by the optimization method are $0.22^{\circ}C$ and $0.65^{\circ}C$ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. As can be seen from A.A.E., the calculated values based on the optimization method were found to be better than those based on the Raoult's law. The binary interaction parameters calculated by the optimization method are used to predict the dew points of cyclohexanol+aniline and cyclohexanol+cyclohexanone. The A.A.E. for these mixtures show that there is an acceptable agreement between experimental and calculated dew poins.

The Calculation of Flash Point for n-Nonane+n-Decane+n-Tridecane System by Raoult's Law and Multiple Regression Analysis (라울의 법칙과 다중회귀분석법에 의한 n-Nonane+n-Decane+n-Tridecane 계의 인화점 계산)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.52-58
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    • 2018
  • The flash point is one of the most important properties to characterize fire and explosion hazard of flammable liquid mixture. In this paper, the flash points of ternary liquid mixture, n-nonane+n-decane+n-tridecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and multiple regression analysis. The absolute average errors(AAE) of the results calculated by Raoult's law is $0.6^{\circ}C$. The absolute average errors of the results calculated by multiple regression analysis is $0.4^{\circ}C$. As can be seen from AAE, the calculated values based on multiple regresstion analysis were found to be better than those based on Raoult's law.

Effect of Temperature on the Growth of the Water Strider, Gerris paludum insularis (Gerridae, Heteroptera)

  • Park, Sang-Ock
    • The Korean Journal of Ecology
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    • v.27 no.6 s.122
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    • pp.369-373
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    • 2004
  • The water strider, Gerris paludum insularis, was reared in a growth cabinet at two constant temperatures and ${\approx}20^{\circ}C$ under a 16:8 (L:D) photoperiod. Differences in head width among three temperatures of ${\approx}20^{\circ}C,\;25^{\circ}C\;and\;30^{\circ}C$ in G. paludum insularis, were compared. Temperature affected growth of head width of G. paludum insularis. There were highly significant differences among head width for three temperature regimes and the immature stages. It was found that head width is greater in $30^{\circ}C$ than $25^{\circ}C\;and\;{\approx}20^{\circ}C$. The growth quantity of the head width in ${\approx}20^{\circ}C$ shows the slowest increase, and $25^{\circ}C\;and\;30^{\circ}C$ were gradually increased in that order. The maximum ratio of growth quantity by each stage is in the first instar in all regimes. The growth rates of all regimes show an increase pattern.

The Study Intervertebral Foramen Image for the Cervical spine of Posterior Anterio Oblique for the Angle (목뼈 척추사이 공간 관찰을 위한 후·전 사방향 촬영 각도에 관한 연구)

  • Ahn, Byung Ju
    • Journal of the Korean Society of Radiology
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    • v.9 no.4
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    • pp.197-203
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    • 2015
  • The Study on the patient is in a clinical researcher is not necessarily pose before after before after dwichim (Pronation) pose with neck-in-law (RAO, LAO) to chwalyoungbeop subjective evaluation experiment looked at objectively. Overview evaluation is a result of measuring the angle of the space between the vertebrae in PACS image $C_2{\sim}C_3$, $C_3{\sim}C_4$, $C_4{\sim}C_5$, $C_5{\sim}C_6$, $C_6{\sim}C_7$, in the angle of the $C_7{\sim}T_1$ $47.4^{\circ}{\pm}3.3$, $50.5^{\circ}{\pm}2.3$, $52.7^{\circ}{\pm}4.2$, $53.2^{\circ}{\pm}1.9$, $53.2^{\circ}{\pm}2.3$, $55.2^{\circ}{\pm}2.3$ was found to show increasing the angle between the ball and the median nerve in the lower neck sagittal grows. In a comparison of the measured angles in foraminal image was not significantly different (P>0.01). Subjective evaluation Recever Operation characteristic to the top, the upper neck hole (foramen) C2 ~ C3-up than conventional $45^{\circ}$ angle of the lower neck, $C_3{\sim}C_4$, were observed in the well $50^{\circ}$ $C_5{\sim}C_6$, $C_6{\sim}C_7$, the $C_7{\sim}T_1$ was observed at $55^{\circ}$ well observed experimental results video recession neck vertebrae son-in-law, son-in-law taken place in an objective evaluation, subjective evaluation of the upper neck after case could be observed at $50^{\circ}$, well in the lower neck $55^{\circ}$.

Investigations of Temperature Effect on the Conduction Mechanism of Electrical Conductivity of Copolymer/Carbon Black Composite

  • El Hasnaoui, M.;Kreit, L.;Costa, L.C.;Achour, M.E.
    • Applied Microscopy
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    • v.47 no.3
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    • pp.121-125
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    • 2017
  • This study deals the prediction of temperature effect on low-frequency dispersion of alternating current (AC) conductivity spectra of composite materials based on copolymer reinforced with carbon black (CB) particles. A sample of ethylene butylacrylate loaded with 13% of CB particles were prepared and investigated using the impedance spectroscopy representation in the frequency range from 40 Hz to 0.1 MHz and temperature range from $20^{\circ}C$ to $125^{\circ}C$. The dielectric constant, ${\varepsilon}^{\prime}$, and dielectric losses, ${\varepsilon}^{{\prime}{\prime}}$, were found to decrease with increasing frequency. The frequency dependence of the AC conductivity follows the universal power law with a large deviation in the high frequency region, the positive temperature coefficient in resistivity effect has been observed below the melting temperature which makes this composite potentially remarkable for industrial applications.

Estimation of the Flash Point for n-Pentanol + n-Propanol and n-Pentanol + n-Heptanol Systems by Multiple Regression Analysis (다중회귀분석법을 이용한 n-Pentanol + n-Propanol계 및 n-Pentanol + n-Heptanol계의 인화점 예측)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.31-36
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    • 2016
  • The flash point is one of the most important properties for characterizing the fire and explosion hazard of liquid solutions. In this study, the flash points of two flammable binary mixtures, n-pentanol + n-propanol and n-pentanol + n-heptanol systems were measured using a Seta flash closed cup tester. The flash point was estimated using the methods based on Raoult's law and multiple regression analysis. The measured flash points were also compared with the predicted flash points. The absolute average errors (AAE) of the results calculated by Raout's law were $1.3^{\circ}C$ and $1.3^{\circ}C$ for the n-pentanol + n-propanol and n-pentanol + n-heptanol mixtures, respectively. The absolute average errors of the results calculated by multiple regression analysis were $0.4^{\circ}C$ and $0.3^{\circ}C$ for the n-pentanol + n-propanol and n-pentanol + n-heptanol mixtures, respectively. According to the AAE, the calculated values based on multiple regression analysis were better than those based on Raoult's law.

Statistical Analysis on Microcrack Length Distribution in Tertiary Crystalline Tuff (제3기 결정질 응회암에서 발달하는 미세균열의 길이 분포에 대한 통계적 분석)

  • Park, Deok-Won
    • The Journal of the Petrological Society of Korea
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    • v.20 no.1
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    • pp.23-37
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    • 2011
  • The scaling properties on the length distribution of microcrack populations from Tertiary crystalline tuff are investigated. From the distribution charts showing length range with 15 directional angles and five groups(I~V), a systematic variation appears in the mean length with microcrack orientation. The distribution charts are distinguished by the bilaterally symmetrical pattern to nearly N-S direction. The whole domain of the length-cumulative frequency diagram for microcrack populations can be divided into three sections in terms of phases of the distribution of related curves. Especially, the linear middle section of each diagram of five groups represents a power-law distribution. The frequency ratio of linear middle sections of five groups ranges from 46.6% to 67.8%. Meanwhile, the slope of linear middle section of each group shows the order: group V($N60{\sim}90^{\circ}E$, -2.02) > group IV($N20{\sim}60^{\circ}E$, -1.55) > group I($N60{\sim}90^{\circ}W$, -1.48), group II($N10{\sim}60^{\circ}W$, -1.48) > group III($N10^{\circ}W{\sim}N20^{\circ}E$, -1.06). Five sub-populations(five groups) that closely follow the power-law length distribution show a wide range in exponents( -1.06 - -2.02). These differences in exponent among live groups emphasizes the importance of orientation effect. In addition, breaks in slope in the lower parts of the related curves represent the abrupt development of longer lengths, which is reflected in the decrease in the power-law exponent. Especially, such a distribution pattern can be seen from the diagram with $N10{\sim}20^{\circ}E,\;N10{\sim}20^{\circ}W$ and $N60{\sim}70^{\circ}W$ directional angles. These three directional angles correspond with main directions of faults developed around the study area. The distribution chart showing the individual characteristics of the length-cumulative frequency diagrams for 15 directional angles were made. By arraying above diagrams according to the categories of three groups(A, B and C), the differences in length-frequency distributions among these groups can be easily derived. The distribution chart illustrates the importance of analysing microcrack sets separately. From the related chart, the occurrence frequency of shorter microcracks shows the order: group A > group B > group C. These three types of distribution patterns could reveal important information on the processes occurred during microcrack growth.