• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.217-217
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• 2003

초전도체 선재를 제작하기위해 YBa$_2$Cu$_3$$O_{7-x}$ (YBCO) 와 Ni substrates사이의 계면 문제를 해결하기 위한 buffer layer로써 CaRuO$_3$ (CRO) thu film이 제안되었는데, 이런 buffer layer의 조건으로는Ni metal과 YBCO superconductor사이의 화학적 반응이 없어야 하고 metal component가 YBCO로 diffusion되는 것을 막아주어야 하며 substrates의 산화를 막아주어야 한다. 이런 조건을 만족시키는 것 중에서 CRO thin film이 가장 적절하였지만, CRO의 orthorhombic구조의 distortion에 의만 lattice mismatch 문제가 발생하였다. 이러한 문제를 해결하기 위해 이론적인 구조 분석을 통한 CRO의superconductor buffer layer로써의 가능성을 검토해 보는 것이 목적이다.

• Journal of the Korean Ceramic Society
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• v.25 no.2
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• pp.154-160
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• 1988

Almost single phase of Y1Ba2Cu3Ox, which exhibits the onset of superconducting transition at 90K, has been prepared via a conventional ceramic processing route followed by an anneal for a period of 10 hours at 45$0^{\circ}C$ in an atmosphere of 100% O2. The mean value for the oxygen content has been determined as x=6.85$\pm$0.02 by an iodometric titration technique. X-ray photoemission spectra are found to be consistent with a mixture of the d8(Cu3+) and d9(Cu2+) as the ground state and reveals that the local concentration of Cu3+ decreases with depth from the surface where x corresponds to 7.0. This is explained as being associated with the intercalation of oxygen during cooling from the annealing temperature.

• Journal of the Korean Ceramic Society
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• v.28 no.1
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• pp.37-45
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• 1991

The critical current density, electrical conductivity, critical magnetic field, Meissner effect, apparent density, and microstructure of YBa2Cu3O7-x ceramic superconductor prepared by polymeric precursor, while varing calcining and sintering conditions, were investigated. The best superconducting properties could be obtained from the body sintered at 93$0^{\circ}C$ for 10h after calcining at 90$0^{\circ}C$ for 10h, which gave 383A/$\textrm{cm}^2$ of critical current density(Jc), 96K of onset temperature(Tonset), 94. 8K of zero temperature (Tzero) 225 Oe of critical magnetic field (Hc1), 72.8% of superconducting volume fraction measured by Meissner effect and 6.28g/㎤ of apparent density.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.115-118
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• 2001

High-temperature superconductor films of YBa$_2$Cu$_3$$O_{7-x}$ were fabricated by electrophoretic deposition (EPD) from alcohol-based suspension. Maximum stability is observed for the suspension containing iso-alcohol as the dispersion medium. However, for the formation of a dense and adherent coating of YBCO on a silver substrate by EPD, the best results were obtained in mix PrOH and BuOH suspension. The superconducting critical current density (J$_{c}$) was 1200 A/cm$^2$ for a films deposited in 30% iso-PrOH and 70 % iso-BuOH suspension.ion.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.7
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• pp.450-455
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• 2015

For the practical application of a YBCO superconductor bulk, the superconductor bulk magnet with high magnetic field on a large area surface should be fabricated. To make this, YBCO single crystal bulks with fine $Y_2BaCuO_5$(Y211) particles have been prepared by the top-seed melt growth(TSMG) method with $YBa_2Cu_3O_x$, $Y_2O_3$, and $CeO_2$ mixing precursor. By using $Y_2O_3$ instead of $Y_2BaCuO_5$ as precursor, the manufacturing process became simpler and more economical. The microstructures, trapped field and critical current density of the various conditioned YBCO bulks have been observed, analyzed and measured. The different characteristic values of the several samples have been analyzed from the viewpoint of their microstructures. We have developed a $8{\times}12cm$ size superconductor bulk magnet, up to 3 T class, by using the 4 T class-high field superconducting magnetizer and confirmed the applicability of the transmission level circuit breakers by measuring the strength and speed of the superconductor bulk magnet actuator.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.169-169
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• 2012

The high-temperature superconductor YBa2Cu3O7-x (YBCO) have attached attentions because of a high superconducting transition temperature, low surface resistance, high superconducting critical current density (Jc), and superior superconducting capability under magnetic field. Moreover, the Jc of YBCO superconductors can be enhanced by adding impurities to the YBCO films for vortex-pinning. Understanding and controlling pinning centers are key factors to realize high Jc superconductors. We synthesized vertically-aligned ZnO nanorods on SrTiO3 (STO) substrates by catalyst-free metal-organic chemical vapor deposition (MOCVD), and subsequently, deposited YBCO films on the ZnO nanorods/STO templates using pulsed laser deposition (PLD). The various techniques were used to analyze the structural and interfacial properties of the YBCO/ZnO nanorods/STO hybrid structures. SEM, TEM, and XRD measurements demonstrated that YBCO films on ZnO nanorods/STO were well crystallized with the (001) orientation. EXAFS measurements from YBCO/ZnO nanorods/STO at Cu K edge demonstrated that the local structural properties around Cu atoms in YBCO were quite similar to those of YBCO/STO.

• Journal of the Korean Society for Nondestructive Testing
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• v.35 no.5
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• pp.314-320
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• 2015

The present study investigates the thermal characteristics of a nanoscale superconductor material. A thin-film of $YBa_2Cu_3O_7-x$ was deposited on a $SrTiO_3$ substrate by using a pulsed-laser deposition technique and characterized using an ultrafast laser system. In order to extract a thermal conductivity value, a numerical solution for a transient one-dimensional heat conduction equation was obtained using a finite-difference method. The curve-fit shows a value 1.2 W/mK, which is relatively lower than those of bulk materials. This research provides a material property of superconductor thin-film required for the thermal design of micro or nanodevices.

• Journal of the Korean Institute of Telematics and Electronics
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• v.27 no.5
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• pp.724-728
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• 1990

The X-ray diffraction pattern, electrical resistance, density and critical temperature of a series of YBa2(Cu3-xNix)O7-\ulcornersamples (0\ulcorner\ulcorner.5) were investigated with the increase of the Ni content. The samples show a principal 1.2.3-like phase with well resolved orthorhombic peaks. The final pattern of the x=0.1 sample appears to be well reacted orthorhombic YBa2(Cu,Ni)3O7-\ulcornerwith minor impurities and an appreciable amorphous fraction. From the above results, we conclude that Ni does not play an important role for the superconductivity in the Y-Ba-Cu-O system.

• Bulletin of the Korean Chemical Society
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• v.11 no.6
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• pp.564-567
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• 1990

A lithiated compound $Li_{0.1}Pr^{3+}Ba_2Cu_3O_y$ has been successfully prepared by electrochemical method, which is achieved with a two electrode cell of the type: Metal(Li)/($Li^+\;,\;ClO_4^-$) + propylene carbonate/$PrBa_2Cu_3O_y$. All Pr ions in the lithiated compound are stabilized with a trivalent state as the other rare earths (Ⅲ) substituted in the 90K superconductor lattice ($Y_{1-x}Ln_x^-Ba_2Cu_3O_{7-{\delta}}$). Powder X-ray diffraction analysis shows that both compounds, $PrBa_2Cu_3O_y$ and $Li_{0.1}PrBa_2Cu_3O_y$ are isostructural with the 90 K superconductor, ($YBa_2Cu_3O_{7-{\delta}}$), nevertheless both of them are non-metallic and also non-superconducting down to 10 K. Magnetic susceptibility ${\chi}$ vs. temperature data indicate that Curie contribution from the magnetic ions (Pr and Cu) is weakened on the one hand, but on the other hand temperature-independent part of susceptibility ${\chi}_o$ increases depending upon the rate of lithium intercalation in $PrBa_2Cu_3O_y$ lattice.

• Bulletin of the Korean Chemical Society
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• v.10 no.1
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• pp.5-8
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• 1989

Conventional ceramic method has been used to prepare the green phase, $Y_2BaCuO_5$, commonly observed in 90-K superconductor $YBa_2Cu_3O_P{7-{\delta}}$as an impurity phase. The powder X-ray diffraction analysis indicates that $Y_2BaCuO_5$ has an orthorhombic symmetry with lattice parameter of a = 12.2 $\AA$, b = 5.61 $\AA$, and c = 7.14 $\AA.$ The average g-value 2.13 observed in ESR spectrum is attributable to Cu2+ stabilized in $C_{4v}$ field. From the magnetic susceptibility ($\mu$eff = 2.29 BM) and the ESR measurements, it is confirmed that Cu(II) $3d^9$ electrons in $Y_2BaCuO_5$ are localized and can be characterized by Curie-Weiss behavior. Optical reflectance spectrum shows a broad absorption peak around 680 nm due to dxy ${\rightarrow}$ $dx^2-y^2$ eletronic transition.