• Journal of the Korean Ceramic Society
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• v.38 no.11
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• pp.967-972
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• 2001

The crystal and defect structures of U $O_{x}$(x=2.0, 2.03, 2.14, 2.19, 2.20 and 2.26) were analysed by rietveld refinement and the results were compared to the U-O phase diagram. Neutron diffraction data were collected in the temperature range of RT~100$0^{\circ}C$. The specimens of x=2.14, 2.19, and 2.20 consisted of two phase: $UO_{2+x}$(Fm3m, a≒5.4$\AA$) and $U_4$$O_{9}$(I43d, a≒21.8$\AA$). The proportion of the $UO_{2+x}$(Fm3m) phase increased with increasing the temperature. The variation of the proportion of the two phases with temperature in the U $O_{2.2}$ and U $O_{2.18}$ samples showed some deviation from the expected values from the phase diagram especially at the high temperature range. The phase transitions ${\gamma}$longrightarrow$\beta$longrightarrow$\alpha$ of $U_4$$O_{9}$ were discussed in relation with the phase separation.eparation.ion.

• Nuclear Engineering and Technology
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• v.34 no.5
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• pp.517-531
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• 2002

The speciation and solubility of Am, Np, Pu and U have been analyzed by means of the geochemical code MUGREM, under the chemical conditions of domestic deep groundwater, in order to support the preliminary safety assessment for a Korean HLW disposal concept. Under the conditions of groundwaters studied, the stable solid phase is AmOHC $O_3$(s) or Am(OH)$_3$(s), soddyite((U $O_2$)$_2$ $SiO_2$.2$H_2O$) or N $a_2$ $U_2$ $O_{7}$ (c), Np(OH)$_4$(am), and Pu(OH)$_4$(am) for Am, U, Np, and Pu, respectively. The dominating aqueous species are as follows: the complexes of Am(III), Am(OH)$_2$$^{+}$ and Am(C $O_3$)$_2$$^{[-10]}$ , the complexes of U(VI), U $O_2$(OH)$_3$$^{[-10]}$ and U $O_2$(C $O_3$)$_3$$^{4-}$, the complexes of Np(IV), Np(OH)$_4$(aq) and Np(OH)$_3$C $O_3$, and the complexes of Pu(IV), Pu(OH)$_4$(aq) and Pu(OH)$_3$C $O_3$$^{[-10]}$ . The calculated solubilities exist between 1.9E-10 and 1.3E-9 mol/L for Am, between 5.6E-6 and 1.2E-4 mol/L for U, between 3.1E-9 and 1.3E-8 mol/L for Np, and between 6.6E-10 and 2.4E-10 mol/L for Pu, depending on groundwater conditions. The present solubilities of each actinide agree well with the results of other studies obtained under similar conditions.s.

• Economic and Environmental Geology
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• v.36 no.3
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• pp.225-232
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• 2003

Three piston cores. obtained from the northwestern Ulleung Basin of the East Sea, are analyzed to study the tephrostratigraphy of the late Quaternary core sediments and to reveal the comparative characteristics of the tephra layers. The cores consist mainly of the muddy sediments that are partly interbedded with lapilli tephra and ash layers. The muds are further divided into hemipelagic and turbiditic mud facies. The hemipelagic facies is dominated by bioturbated mud and crudely laminated mud, whereas the turbiditic facies includes mainly thinly laminated mud and homogeneous mud, and often alternates with non-turbiditic muds. According to microscopic observation and EDX analysis, three tephra layers of the Ulleung-Oki (U-Oki; ca. 9.3 ka), Aira-Tanzawa (AT: ca. 22~24.7 ka) and Ulleung-Yamato (U-Ym; ca. 25~33 ka) are identified in the study cores. Among these, the U-Oki and U-Ym layers, originating from the Ulleung Island, consist mainly of massive-type glass shards with alkali feldspar. Both of the tephra layers contain a lower content of SiO$_2$ (57~66.5 wt.%) and a higher content of Na$_2$O+K$_2$O (11~16 wt.%) than the AT layer (SiO$_2$=75~78.5 wt.%, Na$_2$O+K$_2$O=6.5~9 wt.%) that consists of typical plane-type and/or bubble-wall glass grains. Compared with that of the U-Ym layer, a sedimentary facies of the U-Oki layer is very thick and contains three stratigraphic units, probably due to relatively large and different supplies of pyroclastic sediments. Thus, the eruption of Ulleung Volcano (ca. 7,300 B.C.) is thought to have had a more powerful effect on depositional environment than the U-Ym eruption.

• Journal of the Korean Ceramic Society
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• v.44 no.9
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• pp.471-476
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• 2007

The hydration mechanism of the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system in the presence of alkali sulfates has been investigated. The early hydration rate of $3CaO{\cdot}Al_2O_3$ was accelerated by the addition of $Na_2SO_4$ and $K_2SO_4$. This is closely related to the formation of syngenite $(CaSO_4{\cdot}K_2SO_4{\cdot}H_2O)$, and the U-phase added $K_2SO_4$ and $Na_SO_4$ in the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, respectively. The formation of the rigid syngenite and U-phase structure led to rapid setting and decreases the sulfate content in the liquid phase of the hydrating cement to the extent that it cannot adequately retard the hydration of $3CaO{\cdot}Al_2O_3$. In case of the alkali sulfate not added to the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, the ettringite was transformed to monosulfoaluminate immediately after the consumption of gypsum. However, when the alkali sulfates were added to this system, the ettringite did not transform to monosulfoaluminate immediately even though the gypsum was completely consumed. There was a stagnation period to transform to the monosufoaluminate after the consumption of gypsum because the syngenite and U-phase remained as the sulfate source.

• Resources Recycling
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• v.22 no.3
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• pp.57-64
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• 2013

Sulfurization reaction characteristics of $Eu_2O_3$, uranium oxides($UO_2$, $U_3O_8$), mixture of $Eu_2O_3$ and uranium oxides, Eu-doped uranium oxides($(U,Eu)O_2$, $(U,Eu)_3O_8$), and phase-separated products prepared by HOX (High temperature OXidation) of $(U,Eu)O_2$ were investigated in the temperature range from 400 to $800^{\circ}C$. Only $Eu_2O_3$ in the mixture of $Eu_2O_3$ and uranium oxides was converted into $Eu_3S_4$ by sulfurization reaction at $450^{\circ}C$ without reaction between them. Sulfurization reaction behavior of $(U,Eu)_3O_8$ and $(U,Eu)O_2$ up to $600^{\circ}C$ was similar to $U_3O_8$ and $UO_2$, respectively, while they were sulfurized into Eu-rich $(U,Eu)S_x$ and ${\alpha}-US_2$ at $800^{\circ}C$. In the sulfurization of RE-rich $(U,Eu)_4O_9$ and $U_3O_8$ prepared by high temperature oxidation, it was confirmed that RE-rich $(U,Eu)S_x$ and UOS phases were formed at $600^{\circ}C$. For Eu-rich $(U,Eu)O_2$ and $UO_2$ prepared by reduction of HOX products, it was identified that Eu-rich (U,Eu)OS was formed at $450^{\circ}C$ by sulfurization of Eu-rich $(U,Eu)O_2$, while $UO_2$ remained unreacted.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.46-51
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• 1996

본 연구는 MDD(modified direct denitration)공정의 주 우라늄염인 암노늄 우라닐 나이트레이트의 화학특성을 밝히고 이들 화합물의 열분해 및 환원반응의 반응기구에 대하여 조사되었다. 암모늄 우라닐 나이트레이트는 제조 조건에 따라 N $H_4$$UO_2$N $O_3$와 (N $H_4$)$_2$$UO_2$(N $O_3$)$_4$.2$H_2O$의 두가지 형태의 복염으로 존재함이 화학 및 원소분석, X산 회절 분석, 그리고 적외선 분광분석에 의하여 확인되었다. 암모늄 우라닐 나이트레이트는 질소분위기에서 N $H_4$$UO_2$(N $O_3$)$_3$$\longrightarrow$ Amorphous $UO_3$$\longrightarrow$ a-$UO_3$$\longrightarrow$ U$_3$ $O_{8}$$\longrightarrow$ $\alpha$-U$_3$ $O_{8}$의 경로를 따라서 열분해 되며, 수소분위기에서는 N $H_4$$UO_2$(N $O_3$)$_3$$\longrightarrow$ $UO_3$$\longrightarrow$ U$_3$ $O_{8}$$\longrightarrow$ U$_4$ $O_{9}$ $\longrightarrow$ $UO_2$의 경로로 환원되었다.

• Proceedings of the Materials Research Society of Korea Conference
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• 2005.05a
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• pp.27-27
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• 2005

• Korean Journal of Mathematics
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• v.24 no.3
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• pp.369-374
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• 2016

In this paper, we study the hereditary convex radius of convex harmonic mapping $f(z)=f_1(z)+{\bar{f_x(z)}}$ under the integral operator $I_f(z)={\int_{o}^{z}}{\frac{f_1(u)}{u}}du+{\bar{{\int_{o}^{z}}{\frac{f_x(u)}{u}}}}$ and obtain the sharp constant ${\frac{{\sqrt[4]{6}}-{\sqrt[]{15}}}{9}}$, which generalized the result corresponding to the class of analytic functions given by Nash.

• Journal of agriculture & life science
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• v.46 no.1
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• pp.163-176
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• 2012

TTo increase productivity of a strong extracellular alkaline protease (BCAP), stable strains of Bacillus clausii I-52 carrying another copy of BCAP gene in the chromosome were developed. Integrative vector, pHPS9-fuBCAP carrying BCAP promoter, ribosome binding site, signal sequence and active protease gene was constructed and transferred into B. clausii I-52, and integration of the constructed plasmid into chromosome was identified by PCR. An investigation was carried out on BCAP production by B. clausii I-52 and transformant C5 showing the highest relative activity of alkaline protease using submerged fermentation. Maximum enzyme activity was produced when cells were grown under the submerged fermentation conditions at $37^{\circ}C$ for 48 h with an aeration rate of 1 vvm and agitation rate of 650 rpm in a optimized medium (soybean meal 2%, wheat flour 1%, sodium citrate 0.5%, $K_2HPO_4$ 0.4%, $Na_2HPO_4$ 0.1%, NaCl 0.4%, $MgSO_47H_2O$ 0.01%, $FeSO_47H_2O$ 0.05%, liquid maltose 2.5%, $Na_2CO_3$ 0.6%). A protease yield of approximately 134,670U/ml was achieved using an optimized media, which show an increase of approximately 1.6-fold compared to that of non-transformant (83,960 U/ml). When the stability of transformant C5 was examined, the integrated plasmid pHPS9-fuBCAP was detected in the transformant after cultivation for 8 days, suggesting that it maintained stably in the chromosomal DNA of transformant C5.

• Proceedings of the Korean Magnestics Society Conference
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• 2011.06a
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• pp.19-19
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• 2011

We studied the effect of Dy content on the magnetic properties of cobalt ferrite single crystal. The $CoFe_{1.9}Dy_{0.1}O_4$ single crystals were grown by the flux method by using $Na_2B_4O_{7.}10H_2O$ (Borax) as a solvent (flux). The black and shiny single crystals were obtained as a product. The X-ray diffraction test at room temperature confirmed the spinel cubic symmetry with lattice constant a = $8.42{\AA}$ of the single crystals. The presences of constitute elements (Co, Fe and Dy) was endorsedby EDAX analysis. The saturation magnetization (Ms) of $CoFe_{1.9}Dy_{0.1}O_4$ single crystals was measured and is found to be 72emu/g or equivalently $3.2{\mu}B$/f.u. at 300 K. The observed Ms and coercivity (Hc) is found to be lower than that of pure $CoFe_2O_4$.