• Title/Summary/Keyword: ${Mg_2}{SiO_4}$: Dy

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A Study on The Fabrication of The Sintering Process and The Thermoluminescence Properties of UV Dose about The Mg2SiO4 Thermoluminescent Phosphors (Mg2SiO4 열형광체의 소결공정과 자외선 선량에 대한 TL 특성에 관한 연구)

  • Kim, Young-KooK;Shon, In-Ho;Kim, Il-Hong;Song, Jae-Heung;Doh, Sih-Hong;Kang, Hee-Dong
    • Korean Journal of Materials Research
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    • v.12 no.11
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    • pp.870-874
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    • 2002
  • $Mg_2$$SiO_4$: Dy, Tb pellets were made by using a sintering process, including pressing and heat treatment. In the present study, the optimum parameters of the sintering for the $Mg_2$$SiO_4$: Dy, Tb pellets obtained such as the pressing pressure, the sintering temperature and the sintering time were in terms of thermoluminescence. Experimental results showed that the main peak of the glow curve for $Mg_2$$SiO_4$: Dy, Tb thermoluminescence dosimeter was clearly correlated with the energy of the UV and with the grain size. The intensity of the TL glow curve increased and its main peak position shifted to lower temperature with increasing UV irradiation time.

Synthesis and Luminescent Characterization of Eu2+/Dy3+-Doped Sr2MgSi2O7 Powders (Eu2+/Dy3+ 이온이 도핑된 Sr2MgSi2O7 분말 합성 및 발광 특성)

  • Park, Jaehan;Kim, Young Jin
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.658-662
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    • 2014
  • $Eu^{2+}/Dy^{3+}$-doped $Sr_2MgSi_2O_7$ powders were synthesized using a solid-state reaction method with flux ($NH_4Cl$). The broad photoluminescence (PL) excitation spectra of $Sr_2MgSi_2O_7:Eu^{2+}$ were assigned to the $4f^7-4f^65d$ transition of the $Eu^{2+}$ ions, showing strong intensities in the range of 375 to 425 nm. A single emission band was observed at 470 nm, which was the result of two overlapping subbands at 468 and 507 nm owing to Eu(I) and Eu(II) sites. The strongest emission intensity of $Sr_2MgSi_2O_7:Eu^{2+}$ was obtained at the Eu concentration of 3 mol%. This concentration quenching mechanism was attributable to dipole-dipole interaction. The $Ba^{2+}$ substitution for $Sr^{2+}$ caused a blue-shift of the emission band; this behavior was discussed by considering the differences in ionic size and covalence between $Ba^{2+}$ and $Sr^{2+}$. The effects of the Eu/Dy ratios on the phosphorescence of $Sr_2MgSi_2O_7:Eu^{2+}/Dy^{3+}$ were investigated by measuring the decay time; the longest afterglow was obtained for $0.01Eu^{2+}/0.03Dy^{3+}$.

A Study on the Characteristics and Fabrication of $\textrm{Mg}_{2}\textrm{SiO}_{4}$ Phosphors ($\textrm{Mg}_{2}\textrm{SiO}_{4}$ 열형광체의 제작 및 특성에 관한 연구)

  • Kim, Yeong-Guk;Son, In-Ho;Chae, Geon-Sik;Lee, Su-Dae;Seol, Gyeong-Sik;No, Gyeong-Seok;Song, Jae-Heung;Lee, Sang-Yun;Do, Si-Heung
    • Korean Journal of Materials Research
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    • v.8 no.2
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    • pp.179-185
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    • 1998
  • Mg2SiO4 열형광체에 란탄계 금속 Tb, Tm, La, Ho, Dy 및 Nd를 활성체로 첨가하여 열형광체를 제작했으며, Peak shape법으로 활성화에너지를 계산한 결과 0.53-1.77eV였으며, 발광과정의 차수는 전부 2차였다. 저 에너지 X-선에 대해 매우 높은 감도를 나타내었으므로 방사선 센서 소자로 개발하기 위한 기초 자료가 될 것이다.

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The Effect of Rare-Earth Additives on Dielectric Properties of X7R MLCC Composition (X7R용 적층 칩 세라믹 캐패시터 조성의 희토류 첨가에 따른 유전 특성)

  • 이석원;윤중락
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12
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    • pp.1080-1086
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    • 2003
  • Effects of E$_2$O$_3$. HO$_2$O$_3$ and Dy$_2$O$_3$ addition on dielectric properties of non-reducible BaTiO$_3$ based X7R dielectrics with Ni electrode have been studied in a reduced atmosphere. As the content of rare-earth with E$_2$O$_3$. HO$_2$O$_3$, Dy$_2$O$_3$ was less than 3wt%, The TCC(Temperature Capacitance Change) and insulation resistance characteristics were improved by compensate the oxygen vacancies due to occupy either the Ba or Ti site. We developed the composition of X7R (EIA standard) for higher capacitance MLCC which had high reliability electric properties by the addition of Er ion into BaTiO$_3$ + MgO + Y2O$_3$ + MnO + (Ba$\sub$0.4/Ca$\sub$0.6/)SiO$_3$ composition.