• Title/Summary/Keyword: ${CO_2}^*$ background

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Applicability of the Multi-Channel Surface-soil CO2-concentration Monitoring (SCM) System as a Surface Soil CO2 Monitoring Tool (다채널 지표토양 CO2 농도 모니터링(SCM) 시스템 개발 및 적용성 평가 연구)

  • Sung, Ki-Sung;Yu, Soonyoung;Choi, Byoung-Young;Park, Jinyoung;Han, Raehee;Kim, Jeong-Chan;Park, Kwon Gyu;Chae, Gitak
    • Journal of Soil and Groundwater Environment
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    • v.20 no.1
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    • pp.41-55
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    • 2015
  • Monitoring of $CO_2$ release through the ground surface is essential to confirm the safety of carbon storage projects. We conducted a feasibility study of the multi-channel surface-soil $CO_2$-concentration monitoring (SCM) system as a soil $CO_2$ monitoring tool with a small scale injection test. The background concentrations showed the distinct diurnal variation. The negative relation of $CO_2$ with temperature and the low $CO_2$ concentrations during the day imply that surface-soil $CO_2$ depends on photosynthesis and respiration. After 4.2 kg of $CO_2$ injection (1 m depth for 29 minutes), surface-soil $CO_2$ concentrations increased in the all five chambers, which were located less than 2.8 m of distance from each other. The $CO_2$ concentrations seem to be recovered to the background around 4 hours after the injection ended. To determine the leakage, the data from Chamber 2 and 5 with low increase rates were used for statistical analyses. Coefficient of variation for 30 minutes ($CV_{30min}$.) is efficient to determine a leakage signal, with reflecting the fast change in $CO_2$ concentrations. Consequently, SCM and $CV_{30min}$ could be applied for an efficient monitoring tool to detect $CO_2$ release through the ground surface. Also, this study provides ideas for establishing action steps after leakage detection.

Analysis of Lead in Blood using SR(self-reversal) and $D_2$ Arc Background Correction Methods (SR 바탕보정법과 $D_2$ 바탕보정법에 의한 혈액 중 Pb 분석)

  • Lee, Seokki;Kim, Poongzag
    • Analytical Science and Technology
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    • v.7 no.4
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    • pp.427-434
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    • 1994
  • For the analysis of the relatively volatile lead in blood by GFAAS(graphite furnace atomic absorption spectrophotometer), one can not raise the ashing temperature beyond certain degree due to the elevation of the baseline. Previous investigations showed that background is stabilized when the ashing temperature is raised to $700^{\circ}C$ using a matrix modifier. In this study, same result was obtained at the ashing temperature of around $550^{\circ}C$ even when the matrix modifier is not used and only Triton X-100 is used as a diluent, on an instrument which is equipped with both temperature and current controller(Shimadzu, AA-6501S) and thus the temperature control is fast and accurate. Background correction methods of $D_2$ arc and SR(self reversal) were reviewed. The results show that the absorbance is higher for the $D_2$ arc method, but the background correction is higher for the SR method.

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Distribution of CO2 produced from fossil fuel by accelerator mass spectrometry: in Daejeon (가속기 질량분석법에 의한 화석연료 기원 이산화탄소의 농도 분포: 대전지역을 중심으로)

  • Park, Junghun;Hong, Wan;Park, Ji Youn;Sung, Ki Seok;Eum, Chul-Hun
    • Analytical Science and Technology
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    • v.21 no.1
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    • pp.9-13
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    • 2008
  • We have collected a batch of leaf samples at several main crossroads in Daejeon and a background site to obtain distribution of $CO_2$ (greenhouse gas) due to fossil fuel combustion. The leaf samples were treated with AAA method and ${\Delta}^{14}C$ values of them were measured using AMS. ${\Delta}^{14}C$ values of downtown sites were found to be lower by 27-102 ‰ than that of the background site, and the ratio of $CO_2$ originated from fossil fuel combustion in the atmosphere of Daejeon could be calculated from the differences of ${\Delta}^{14}C$ values. The average ${\Delta}^{14}C$ of the background site, around Kyeryong mountain, was measured to be $35{\pm}8$ ‰, and this value is lower than 66.3 ‰, which have been known as the backgdound values in USA.

Revision of 22-year Records of Atmospheric Baseline CO2 in South Korea: Application of the WMO X2019 CO2 Scale and a New Baseline Selection Method (NIMS Filter) (지난 22년간 한반도 이산화탄소 배경농도 재산정 연구 - WMO/GAW 척도 변경과 NIMS 온실가스 배경농도 산출기법을 중심으로 -)

  • Seo, Wonick;Lee, Haeyoung;Kim, Yeon-Hee
    • Atmosphere
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    • v.31 no.5
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    • pp.593-606
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    • 2021
  • The Korea Meteorological Administration/National Institute of Meteorological Sciences (KMA/NIMS) has monitored atmospheric CO2 at Anmyeondo (AMY) World Meteorological Organization (WMO) Global Atmosphere Watch Programme (GAW) regional station since 1999, and expanded its observations at Jeju Gosan Suwolbong station (JGS) in the South and at Ulleungdo-Dokdo stations in the East (ULD and DOK) since 2012. Due to a recent WMO CO2 scale update and a new filter (NIMS) to select baseline levels at each station, the 22 years of CO2 data are recalculated. After correction for the new CO2 scale, we confirmed that those corrected records are reasonable within the compatibility goal (±0.1 ppm of CO2) between KMA/NIMS and National Oceanic and Atmosphereic Administration (NOAA) flask-air measurements with the new scale. With the new NIMS filter, CO2 baseline levels are now more representative of the large-scale background compared to previous values, which contained large CO2 enhancements. Atmospheric CO2 observed in South Korea is 4 to 8 ppm greater than the global average while the amplitude of seasonal variation is similar (10~13 ppm) to the amplitude averaged over a comparable latitude zone (30°N-60°N). Variations in CO2 growth rate are also similar, increasing and decreasing similar to global values, as it reflects the net balance between terrestrial respiration and photosynthesis. In 2020, atmospheric CO2 continued increasing despite the COVID-19 pandemic. Even though fossil emission was reduced (around -7% globally), we still emitted large amounts of anthropogenic CO2. Overall, since CO2 has large natural variations and its source was derived from not only fossil fuel but also biomass burning, the small fossil emission reduction could not affect the atmospheric level directly.

Optimization of $CO_2$ Direct Absorption Method for the Determination of Carbon-14 in Environmental Samples (환경시료중의 방사성탄소 측정을 위한 $CO_2$ 직접흡수법의 최적화 연구)

  • Cho, Soo-Young;Woo, Hyung-Joo;Chun, Sang-Ki
    • Journal of Radiation Protection and Research
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    • v.23 no.4
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    • pp.237-242
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    • 1998
  • The goal of this work was to optimize the liquid scintillation counting techniques for the determination of C-14 in environmental samples such as biological and air samples. Carbon-14 activities in most environmental samples were measured with direct $CO_2$ absorption method. The highest figure of merit was found through the variation of Carbosorb $E^{TM}$ and Permatluor $V^{TM}$ ratio, in the measurement windows. The best condition was 1:1 volume ratio. Average 2.35 g of $CO_2$ was reproducibly absorbed in the 20 ml mixture within 40 min. The counting efficiency determined by repeated analysis of NIST oxalic acid standard and the background count rate were measured to be $58.8{\pm}1.4%$ and $1.88{\pm}0.06\;cpm$, respectively in case of saturated solution. The correction curves of counting efficiency for partially saturated solutions and for saturated solutions with quenching were prepared, respectively. The overall uncertainty of the sample specific activity for near background levels was estimated to be about 7 % for 4 hours counting at 95 % confidence level. The long-term stability of samples has been checked for all the counting techniques over a two week periods, and no apparent change in counting efficiency and background level was found at that time.

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Simulation of Atmospheric CO2 Over Coastal Basin Urban Areas Using Meteorology-Vegetation Model (기상-식생 모델을 이용한 연안 분지 도시 지역의 대기 중 CO2 시뮬레이션)

  • Park, Changhyoun;Lee, Hwa Woon
    • Journal of Environmental Science International
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    • v.26 no.6
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    • pp.729-739
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    • 2017
  • The Weather Research and Forecasting (WRF) model and Vegetation Photosynthesis and Respiration Model (VPRM) were coupled to simulate atmospheric $CO_2$ concentrations. The performance of the WRF-VPRM to simulate regional scale $CO_2$ concentration was estimated over coastal basin areas. Either Hestia 2011(HST) or Vulcan 2002(VUL) anthropogenic $CO_2$ emission data were used in two numerical experiments for the study regions. Simulated meteorological variables were validated with ground and background $CO_2$ measurement data, and the results show that the model captured temporal variations of $CO_2$ concentration on a daily basis. $CO_2$ directional analysis revealed that the dominant $CO_2$ emission sources are located S and SW. The simulated Net Ecosystem Exchange (NEE) agreed relatively well with measured $CO_2$ fluxes at each vegetation class site, showing approximately 40% at max improvement at shrub areas.

AKARI/IRC spectroscopic survey for interstellar ice study

  • Kim, Jaeyeong;Lee, Jeong-Eun;Kim, Il-Seok;Aikawa, Yuri;Jeong, Woong-Seob;Lee, Ho-Gyu;Noble, Jennifer A.;Dunham, Michael M.
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.41.3-41.3
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    • 2019
  • Ices in interstellar environments are well traced mostly by their absorption features in the near- to mid-infrared spectrum. The infrared camera (IRC) aboard AKARI provides us the near-infrared spectroscopic data which cover $2.5-5.0{\mu}m$ with a spectral resolution of R ~ 120. Our AKARI spectroscopic survey of young stellar objects (YSOs), including low-luminosity protostars and background stars, revealed the absorption features of $H_2O$, $CO_2$, CO, and XCN ice components. We present near-infrared spectra of the observed targets and compare their ice abundances with those previously derived from various YSOs and the background stars behind dense molecular clouds and cores. In addition, we suggest possible science cases for SPHEREx, NASA's new near-infrared space observatory, based on the results from our AKARI IRC spectroscopic study.

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Comparative genetic analyses of Korean bat coronaviruses with SARS-CoV and the newly emerged SARS-CoV-2

  • Na, Eun-Jee;Lee, Sook-Young;Kim, Hak Jun;Oem, Jae-Ku
    • Journal of Veterinary Science
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    • v.22 no.1
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    • pp.12.1-12.11
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    • 2021
  • Background: Bats have been considered natural reservoirs for several pathogenic human coronaviruses (CoVs) in the last two decades. Recently, a bat CoV was detected in the Republic of Korea; its entire genome was sequenced and reported to be genetically similar to that of the severe acute respiratory syndrome CoV (SARS-CoV). Objectives: The objective of this study was to compare the genetic sequences of SARS-CoV, SARS-CoV-2, and the two Korean bat CoV strains 16BO133 and B15-21, to estimate the likelihood of an interaction between the Korean bat CoVs and the human angiotensin-converting enzyme 2 (ACE2) receptor. Methods: The phylogenetic analysis was conducted with the maximum-likelihood (ML) method using MEGA 7 software. The Korean bat CoVs receptor binding domain (RBD) of the spike protein was analyzed by comparative homology modeling using the SWISS-MODEL server. The binding energies of the complexes were calculated using PRODIGY and MM/GBGA. Results: Phylogenetic analyses of the entire RNA-dependent RNA polymerase, spike regions, and the complete genome revealed that the Korean CoVs, along with SARS-CoV and SARS-CoV-2, belong to the subgenus Sarbecovirus, within BetaCoVs. However, the two Korean CoVs were distinct from SARS-CoV-2. Specifically, the spike gene of the Korean CoVs, which is involved in host infection, differed from that of SARS-CoV-2, showing only 66.8%-67.0% nucleotide homology and presented deletions within the RBD, particularly within regions critical for cross-species transmission and that mediate interaction with ACE2. Binding free energy calculation revealed that the binding affinity of Korean bat CoV RBD to hACE2 was drastically lower than that of SARS-CoV and SARS-CoV-2. Conclusions: These results suggest that Korean bat CoVs are unlikely to bind to the human ACE2 receptor.

The Nondestructive Analysis of the Pigments on the Korean 12-fold scheen, Haehakbando-do (해학반도도 채색안료에 대한 비파괴 특성 분석)

  • Kim, Gyu-ho;Song, Yuo-na;Lim, Duck-su;Song, Jeong-ju
    • 보존과학연구
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    • s.28
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    • pp.121-147
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    • 2007
  • A large variety of mineral pigments has been used for Korean paintings and it has known that organic pigments have been used together on the Buddhist painting and the portrait. Haehakbando-do, which is from Honolulu Academy Museum in the United States, 12-fold screen was commissioned by Court of the late Joseon Dynasty in order to pray for the King's longevity. Therefore, it seems that all material used including pigments were selected very carefully and a great deal of technical effort was gone into its process. The purposes of this research were to estimate the pigments and the contributory elements of each color used on Haehakbando-do, in accordance with the conservation treatment carried out by Gochang Conservation Institute throughout last year. Without extracting sample, property of pigment was measured by nondestructive method, X-ray spectral analysis, and by comparing with the data about ancient pigments. In spite of the limited range of pigment analysis by nondestructive method, it should be noted that this method would not cause damage to the cultural properites. White pigment was found in all colored parts except the background, so it can be suggested that white color was used as a grounding of other color pigments. This would be flake white[$2PbCO_3{\cdot}Pb(OH)_2$] as Pb was found. Pb was the only element could be found in yellow, however, it can be organic pigment like Gamboge as same as background. Red would be Cinnabar (HgS) as hydrargyrum (Hg) was detected. For the light purple in cloud, organic pigments were probably used since any element is not detected except for Pb, which is used for background. It is possible that green color is the mixture of Malachite[$CuCO_3{\cdot}Cu(OH)_2$] and Azurite [$2CuCO_3{\cdot}Cu(OH)_2$], which share Cu as their main element. Azurite[$2CuCO_3{\cdot}Cu(OH)_2$] was used for bluish pigments. Black is carbon compound. For gold, solid gold (Au) was detected. It shows that gold was gilded on the flake white background. Red painted on the frame of screen was identified as Cinnabar (HgS) and the gold pattern was solid gold (Au). The supporting leg of folding screen was made of brass because both copper and zinc were detected. In conclusion, white pigment was used as grounding of all colors of Haehakbando-do, and specific pigments were used for each color. Additionally, result from the analysis of several pigments shows that mineral pigment and organic pigment, or different mineral pigments were mixed to make various colors.

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Seamless and Robust Vehicular MIPv6: VMIPv6 for Vehicular Ad hoc Network (자동차 무선 네트워크 환경에서 연속적이고 견고한 IPv6기반의 이동성 프로토콜)

  • Oh, Ha-Young;Kim, Chong-Kwon
    • Journal of KIISE:Information Networking
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    • v.37 no.2
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    • pp.122-134
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    • 2010
  • With the rapidly increasing demand of traffic applications, the need to support seamless and robust multimedia services in the Vehicular Ad hoc Network is growing. Fast handover for the MIPv6 (FMIPv6) developed to solve the MIPv6's problem as well as Mobile IPv6 (MIPv6) for basic mobility protocol have been developed to support seamless handover in mobile environment. However, MIPv6 and FMIPv6 are useless for Quality-of-Service (QoS) services such as multimedia applications due to the long handover latency and the packet loss problem. In this paper, we propose a seamless and robust handover scheme that supports multimedia services in Vehicular Ad hoc Network using oCoA and background DAD. Through performance evaluation, we show that the proposed scheme is more proper for Vehicular Ad hoc Network than other schemes.