• Title/Summary/Keyword: ${\omega}-3$

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Preparation of Novel Ionic Liquids and Their Applications in Brominating Reaction (새로운 이온용액의 제조 및 브롬화반응 응용)

  • Li, Hua;Liu, Juan;Zhu, Jiang;Wang, Hongkai
    • Journal of the Korean Chemical Society
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    • v.55 no.4
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    • pp.685-690
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    • 2011
  • Novel acidic ionic liquids, 1-(${\omega}$-sulfonicacid)propyl-3-methylimidazolium bromide ([$HSO_3$pmim]Br)and 1-(${\omega}$-sulfonicacid)butyl-3-methylimidazolium bromide ([$HSO_3$bmim]Br), were prepared and used as brominating agents, catalysts and solvents in the synthesis of 1,7-dibromoheptane, respectively. 1,7-dibromoheptan with a yield of 95% was obtained at $100^{\circ}C$ for 2 h by simple phase separation. The acidic ionic liquid [$HSO_3$pmim]Br was recycled for 5 times and the yield of 1,7-dibromoheptane did not decrease remarkably, which indicates that catalysts still maintain good selectivity and activity after recycling. The structure of the acidic ionic liquid [$HSO_3$pmim]Br was characterized with IR, and it was found that [$HSO_3$pmim]Br had stronger acidity than other ionic liquid.

The Application of Standard in According to Ground and Electrical Continuity Testing of Lightning Protection Equipment in Field (피뢰설비현장의 접지 및 전기적 연속성 시험에 따른 표준적용)

  • Song, Gil-Mok;Koo, Kyung-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.63 no.4
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    • pp.583-588
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    • 2014
  • In this study, there are examined to the grounding of lightning protection system and electrical continuity tests in the field. The standard for lightning protection system is different design or construction according to the characteristics of the structure. Ground is measured and compared at least four locations. According to the measured results in the field, the sampled values of the ground resistance are measured $5{\Omega}$ or less and the difference between each value is suitable as $0.2{\Omega}$ or less. The values of the electrical continuity test between ground and metal bodies are measured 3 groups such as isolated portion, the mechanical contacted portion, and the electrical continuity portion measuring $0.2{\Omega}$ or less. It is measured to be less than $0.2{\Omega}$ at all in metal bodies of underground. A metal body installed inside the structure is not isolated, but the resistance values are higher than $0.2{\Omega}$. Therefore, It must be carried out the structure having lightning protection system confirm the LPL(lightning protection level) and design the strategy.

Coregulation of lux Genes and Riboflavin Genes in Bioluminescent Bacteria of Photobacterium phosphoreum

  • Sung, Nack-Do;Lee, ChanYong
    • Journal of Microbiology
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    • v.42 no.3
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    • pp.194-199
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    • 2004
  • Investigation of the expression of the riboflavin (rib) genes, which are found immediately downstream of luxG in the lux operon in Photobacterium phosphoreum, provides more information relevant to the evolution of bioluminescence, as well as to the regulation of supply of flavin substrate for bacterial bioluminescence reactions. In order to answer the question of whether or not the transcriptions of lux and rib genes are integrated, a transcriptional termination assay was performed with P. phoxphoreum DNA, containing the possible stem-loop structures, located in the intergenic region of luxF and luxE ($\Omega$$\_$A/), of luxG and ribE ($\Omega$$\_$B/), and downstream of ribA ($\Omega$$\_$c/). The expression of the CAT (Chloram-phenicol Acetyl Transferase) reporter gene was remarkably decreased upon the insertion of the stem-loop structure ($\Omega$$\_$c/) into the strong lux promoter and the reporter gene. However, the insertion of the structure ($\Omega$$\_$B/) into the intergenic region of the lux and the rib genes caused no significant change in expression from the CAT gene. In addition, the single stranded DNA in the same region was protected by the P. phosphoreum mRNA from the Sl nuclease protection assay. These results suggest that lux genes and rib genes are part of the same operon in P. phosphoreum.

Combination resonances in forced vibration of spar-type floating substructure with nonlinear coupled system in heave and pitch motion

  • Choi, Eung-Young;Jeong, Weui-Bong;Cho, Jin-Rae
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.8 no.3
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    • pp.252-261
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    • 2016
  • A spar-type floating substructure that is being widely used for offshore wind power generation is vulnerable to resonance in the heave direction because of its small water plane area. For this reason, the stable dynamic response of this floating structure should be ensured by accurately identifying the resonance characteristics. The purpose of this study is to analyze the characteristics of the combination resonance between the excitation frequency of a regular wave and natural frequencies of the floating substructure. First, the nonlinear equations of motion with two degrees of freedom are derived by assuming that the floating substructure is a rigid body, where the heaving motion and pitching motions are coupled. Moreover, to identify the characteristics of the combination resonance, the nonlinear term in the nonlinear equations is approximated up to the second order using the Taylor series expansion. Furthermore, the validity of the approximate model is confirmed through a comparison with the results of a numerical analysis which is made by applying the commercial software ANSYS AQWA to the full model. The result indicates that the combination resonance occurs at the frequencies of ${\omega}{\pm}{\omega}_5$ and $2{\omega}_{n5}$ between the excitation frequency (${\omega}$) of a regular wave and the natural frequency of the pitching motion (${\omega}_{n5}$) of the floating substructure.

A Study on the Ignition Hazard of Flammable Mixtures by Radio-Frequency Spark (고주파 스파크에 의한 가연성 혼합가스의 점화위험성에 관한 연구)

  • Choi, Sang-Won;Lee, Gwan-Hyung;Moon, Jung-Gi
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1913-1916
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    • 1996
  • With a progress of electrical and electronic technology, radio-frequency circuits including high frequency components are widely applied to various industrial installations. Some of them are used in hazardous locations where explosive or flammable gases exist. As a result, ignition of such gases may be induced by a spark discharge when the radio frequency circuits are switched on or off. The purpose of this study is to investigate the ignition hazards of acetylene-air and ethylen-air mixtures experimentally based on the IEC 79-3 publication. In this experiment, we used a high frequency resistive circuit which consists of a co-axial cable, a $10{\Omega}$, $20{\Omega}$, $30{\Omega}$, $40{\Omega}$ or $50{\Omega}$ resistor and a power amplifier with frequency range up to almost 1 MHz. Experimental results show that the ignition of the acetylene-air and ethylen-air mixtures due to spark discharge depends primarily on the frequency of the power source in the resistive circuit: the minimum ignition voltage increases gradually with the increase of the frequency.

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Domains of Attraction of a Forced Beam with Internal Resonance (내부공진을 가진 보의 흡인영역)

  • 이원경;강명란
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.9
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    • pp.1711-1721
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    • 1992
  • A nonlinear dissipative dynamical system can often have multiple attractors. In this case, it is important to study the global behavior of the system by determining the global domain of attraction of each attractor. In this paper we study the global behavior of a forced beam with two mode interaction. The governing equation of motion is reduced to two second-order nonlinear nonautonomous ordinary differential equations. When .omega. /=3.omega.$_{1}$ and .ohm.=.omega $_{1}$, the system can have two asymptotically stable steady-state periodic solutions, where .omega./ sub 1/, .omega.$_{2}$ and .ohm. denote natural frequencies of the first and second modes and the excitation frequency, respectively. Both solutions have the same period as the excitation period. Therefore each of them shows up as a period-1 solution in Poincare map. We show how interpolated mapping method can be used to determine the two four-dimensional domains of attraction of the two solutions in a very effective way. The results are compared with the ones obtained by direct numerical integration.

Raman Spectroscopic Deconvolution of Strain and Charge Doping Effects in Graphene on SiO2/Si Substrate

  • Lee, Ji-Eun;Kim, Seon-Ho;Gang, Seong-Gyu;Yang, Seong-Ik;Lee, Yeong-Sik;Ryu, Sun-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.155-155
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    • 2011
  • 그래핀(graphene)은 모든 탄소 원자가 표면에 존재하는 이차원 결정이기 때문에 다른 고체 표면에 고착될 때 인장 및 압축 변형(tensile & compressive strain)과 전하 도핑(charge doping)에 취약하다고 알려져 있다. 본 연구에서는 산화실리콘(SiO2/Si) 기판 위에 기계적으로 박리된 그래핀에 혼재되어 나타나는 기계적 변형과 전하 도핑 현상을 분석할 수 있는 라만 분광법 기술을 개발하고자 하였다. 대부분의 시료에서 기계적 변형으로 인해 라만 G-band와 2D-band의 진동수(${\omega}$)가 특별한 상관관계(${\Delta}{\omega}2D/{\Delta}{\omega}G$ = 2.0 ${\pm}$ 0.2)를 가진다는 사실을 확인하였다. 전자 친화도가 큰 F4-TCNQ (tetrafluorotetracianoquinodimethane)를 증착하여 화학적으로 p-형 전하 도핑을 유도한 그래핀에서는 기계적 변형과는 분명히 구별되는 상관관계(${\Delta}{\omega}2D/{\Delta}{\omega}G$ = 1.0 ${\pm}$ 0.3)가 관찰되었다. 본 연구는 라만 분광법을 통해 그래핀의 기계적 변형과 전하 도핑 정도를 정량적으로 분리해서 분석할 수 있는 방법을 제시해 준다.

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LFC 태양전지에서 접촉 면적 가변을 통한 전지 효율 변화 분석

  • Lee, Won-Baek;Lee, Yong-U;Jeong, Seong-Uk;Jang, Gyeong-Su;Park, Hyeong-Sik;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.300-300
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    • 2010
  • 후면 패시베이션, back contact의 가변, 후면 접촉면적의 가변 등으로 Laser Fired Contact 태양전지의 효율을 증가 시킬 수 있다. 이 중 spacing의 가변으로 후면 접촉 면적을 가변 할 수 있으며, 이로 인하여 LFC 태양 전지의 효율을 높일 수 있을 것으로 전망된다. 본 연구에서는 후면 접촉 면적을 가변하였으며 이에 따른 효과를 확인하였다. series resistance가 작고, open circuit voltage 가 높은 최적의 조건을 찾는 것에 그 목적을 두었다. 실험 순서는 texturing 후, 후면에 SiNx를 10nm 증착하였으며, drive-in 방법으로 $POCl_3$을 도핑하였다. ARC후, spacing 조건 가변으로 접촉 면적을 가변시키면서 소자의 특성 변화를 비교하였다. 접촉 면적 및 spacing 조건은 5개의 set에 대하여 reference, 50%의 접촉 면적을 가지는 $150{\mu}m$ line, 10%의 접촉 면적을 가지는 $700{\mu}m$ line, 1%의 접촉 면적을 가지는 $700{\mu}m$ dot, 그리고 0.2%의 접촉 면적을 가지는 $1500{\mu}m$ dot으로 하였다. 각각의 경우에 대한 short circuit current density, fill factor, seris resistance, sheet resistance, open circuit voltage를 측정하였으며, 특히 series resistance는 각각의 경우에 대하여 $6.1m{\Omega}$, $5.1m{\Omega}$, $7.8m{\Omega}$, $10.1m{\Omega}$, 그리고 $15.7m{\Omega}$으로 측정되었다. wafer의 외각 테두리를 접촉 면적이 증가함에 따라서 sheet resistance가 증가하는 것을 확인 할 수 있었다.

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The Effect of Annealing Temperature and Zn contents on Transparent Conducting Indium Zinc Tin Oxide Thin Films

  • Lee, Seon-Yeong;Denny, Yus Rama;Park, Su-Jeong;Gang, Hui-Jae;Heo, Seong;Jeong, Jae-Gwan;Lee, Jae-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.227-227
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    • 2012
  • 본 연구에서는 RF스퍼터링법에 의하여 glass substrate에 In-Zn-Sn-O (IZTO)를 Zn 성분에 변화를 주면서 $350{\AA}$ 만큼 증착시키고, 1시간 동안 $350^{\circ}C$로 열처리 하였다. In:Zn:Sn의 성분 비율은 20:48:32 (IZTO1), 13:60:27 (IZTO2)이다. 박막의 전자적, 광학적 특성은 XPS (X-ray Photoelectron Spectroscopy), REELS(Reflection Electron Energy Loss Spectroscopy), UV-Spectrometer를 이용하여 연구하였고, 박막의 전기적 특성은 van der Pauw 법을 이용하여 측정하였다. XPS측정결과, IZTO박막은 In-O, Sn-O and Zn-O의 결합을 가진다. REELS를 이용해 Ep=1,500 eV에서의 밴드갭을 얻어보면, $350^{\circ}C$로 열처리 한 박막은 열처리를 하지 않은 것에 비해 밴드갭이 IZTO1는 3.36 eV에서 3.54 eV로, IZTO2는 3.15 eV에서 3.31 eV로 증가하였다. 반면에 Zn 함량이 증가할수록 밴드갭이 감소하는 것을 확인할 수 있었다. 이 값은 UV-Spectrometer를 이용한 광학적 밴드갭과 일치하였다. 또한 van der Pauw method를 이용한 전기적 특성 분석 결과, 열처리를 하기 전에 비하여 carrier concentration이 IZTO1는 $-4.4822{\times}10^{18}cm^{-3}$에서 $-2.714{\times}10^{19}cm^{-3}$로, IZTO2는 $-3.6931{\times}10^{17}cm^{-3}$에서 $-1.7679{\times}10^{19}cm^{-3}$로 증가하였다. 반면에 Resistivity는 IZTO1의 경우 $1.7122{\times}10^{-1}{\Omega}{\cdot}cm$에서 $5.5496{\times}10^{-3}{\Omega}{\cdot}cm$로, IZTO2는 $1.3290 {\Omega}{\cdot}cm$에서 $1.3395{\times}10^{-2}{\Omega}{\cdot}cm$로 감소하였다. 그리고 UV-Spectrometer를 이용한 광학적 특성을 측정해본 결과, 가시광선영역인 380~780 nm에서의 투과율이 83%이상으로 투명전자소자로의 응용이 가능하다는 것을 보여주었다.

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