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Investigated properties of Low temperature curing Ag Paste for Silicon Hetero-junction Solar Cell

  • Oh, Donghyun;Jeon, Minhan;Kang, Jiwoon;Shim, Gyeongbae;Park, Cheolmin;Lee, Youngseok;Kim, Hyunhoo;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.160-160
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    • 2016
  • In this study, we applied the low temperature curing Ag paste to replace PVD System. The electrode formation of low temperature curing Ag paste for silicon Hetero-junction solar cells is important for improving device characteristics such as adhesion, contact resistance, fill factor and conversion efficiency. The low temperature curing Ag paste is composed various additives such as solvent, various organic materials, polymer, and binder. it depends on the curing temperature conditions. The adhesion of the low temperature curing Ag paste was decided by scratch test. The specific contact resistance was measured using the transmission line method. All of the Ag electrodes were experimented at various curing temperatures within the temperature range of $160^{\circ}C-240^{\circ}C$, at $20^{\circ}C$ intervals. The curing time was also changed by varying the conditions of 10-50min. In the optimum curing temperature $200^{\circ}C$ and for 20 min, the measured contact resistance is $19.61m{\Omega}cm^2$. Over temperature $240^{\circ}C$, confirmed bad contact characteristic. We obtained photovoltaic parameter of the industrial size such as Fill Factor (FF), current density (Jsc), open-circuit voltage (Voc) and convert efficiency of up to 76.2%, 38.1 mA/cm2, 646 mV and 18.3%, respectively.

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Improved performance in flexible organic solar cells via optimization of highly transparent silver grid/graphene electrodes

  • Cha, Myoung Joo;Kim, Sung Man;Kang, Ju Hwan;Kang, Seong Jun;Seo, Jung Hwa;Walker, Bright
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.152-152
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    • 2016
  • We studied the effect of the silver grid size on graphene transparent conducting films for flexible organic solar cells (OSCs). The silver grid was used an assistant layer of the graphene to reduce the sheet resistance of substrates. Silver grid with various graphene sizes for optimizing transmittance and sheet resistance of substrates were fabricated on polyethylene terephthalate (PET) substrates to form the hybrid films. The optimized grid geometry on the single layer graphene (SLG) was the grid dimension $200{\mu}m{\times}200{\mu}m{\times}50nm{\times}2{\mu}m$ (length ${\times}$ width ${\times}$ height ${\times}$ linewidth), where the sheet resistance was $55.73{\Omega}/square$ with the average transmittance of ~ 92.83 % at 550 nm. The properties of the OSCs fabricated using SLG with optimized silver grids on PET substrates show a short circuit current of $10.9mA/cm^2$, an open circuit voltage of 0.58 V, a fill factor of 60.8 %, and a power conversion efficiency (PCE) of 3.9 %. The PCE was improved about 91% than that of the OSCs using the SLG without the silver grid. These results demonstrate that the optimized grid geometry to the based on the graphene transparent electrodes contribute to improving the performance of OSCs.

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In situ viscoelastic properties of insoluble and porous polysaccharide biopolymer dextran produced by Leuconostoc mesenteroides using particle-tracking microrheology

  • Jeon, Min-Kyung;Kwon, Tae-Hyuk;Park, Jin-Sung;Shin, Jennifer H.
    • Geomechanics and Engineering
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    • v.12 no.5
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    • pp.849-862
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    • 2017
  • With growing interests in using bacterial biopolymers in geotechnical practices, identifying mechanical properties of soft gel-like biopolymers is important in predicting their efficacy in soil modification and treatment. As one of the promising candidates, dextran was found to be produced by Leuconostoc mesenteroides. The model bacteria utilize sucrose as working material and synthesize both soluble and insoluble dextran which forms a complex and inhomogeneous polymer network. However, the traditional rheometer has a limitation to capture in situ properties of inherently porous and inhomogeneous biopolymers. Therefore, we used the particle tracking microrheology to characterize the material properties of the dextran polymer. TEM images revealed a range of pore size mostly less than $20{\mu}m$, showing large pores > $2{\mu}m$ and small pores within the solid matrix whose sizes are less than $1{\mu}m$. Microrheology data showed two distinct regimes in the bacterial dextran, purely viscous pore region of soluble dextran and viscoelastic region of the solid part of insoluble dextran matrix. Diffusive beads represented the soluble dextran dissolved in an aqueous phase, of which viscosity was three times higher than the growth medium viscosity. The local properties of the insoluble dextran were extracted from the results of the minimally moving beads embedded in the dextran matrix or trapped in small pores. At high frequency (${\omega}>0.2Hz$), the insoluble dextran showed the elastic behavior with the storage modulus of ~0.1 Pa. As frequency decreased, the insoluble dextran matrix exhibited the viscoelastic behavior with the decreasing storage modulus in the range of ${\sim}0.1-10^{-3}Pa$ and the increasing loss modulus in the range of ${\sim}10^{-4}-1\;Pa$. The obtained results provide a compilation of frequency-dependent rheological or viscoelastic properties of soft gel-like porous biopolymers at the particular conditions where soil bacteria produce bacterial biopolymers in subsurface.

Bidirectional Current Triggering in Two-Terminal Planar Device Based on Vanadium Dioxide Thin Film Using 1550nm Laser Diode (1550nm 레이저 다이오드를 이용한 바나듐 이산화물 박막 기반 2단자 평면형 소자에서의 양방향 전류 트리거링)

  • Lee, Yong Wook
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.4
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    • pp.11-17
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    • 2015
  • While most switching devices are based on PN junctions, a single layer can realize a switching device in the case of vanadium dioxide($VO_2$) thin films. In this paper, bidirectional current triggering(switching) is demonstrated in a two-terminal planar device based on a $VO_2$ thin film by illuminating the film with an infrared laser at 1550nm. To begin with, a two-terminal planar device, which had a $30{\mu}m$-wide $VO_2$ conducting layer and an electrode separation of $10{\mu}m$, was fabricated. A specific bias voltage range for stable bidirectional laser triggering was experimentally obtained by measuring the current-voltage characteristics of the fabricated device in a current-controlled mode. Then, by constructing a test circuit composed of the device, a standard resistor, and a DC voltage source, connected in series, the transient response of laser-triggered current and its response time were investigated with a DC bias voltage, included in the above specific bias voltage range, applied to the device. In the test circuit with a DC voltage source of 3.35V and a $10{\Omega}$ resistor, bidirectional laser triggering could be realized with a maximum on-state current of 15mA and a switching contrast of ~78.95.

Organic photovoltaic cells using low sheet resistance of ITO for large-area applications

  • Kim, Do-Geun;Gang, Jae-Uk;Kim, Jong-Guk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.5.1-5.1
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    • 2009
  • Organic photovoltaic (OPV)cells have attracted considerable attention due to their potential for flexible, lightweight, and low-cost application of solar energy conversion. Since a 1% power conversion efficiency (PCE) OPV based on a single donor-acceptor heterojunction was reported by Tang, the PCE has steadily improved around 5%. It is well known that a high parallel (shunt)resistance and a low series resistance are required simultaneously to achieve ideal photovoltaic devices. The device should be free of leakage current through the device to maximize the parallel resistance. The series resistance is attributed to the ohmic loss in the whole device, which includes the bulk resistance and the contact resistance. The bulk resistance originated from the bulk resistance of the organic layer and the electrodes; the contact resistance comes from the interface between the electrodes and the active layer. Furthermore, it has been reported that the bulk resistance of the indium tin oxide (ITO) of the devices dominates the series resistance of OPVs for a large area more than $0.01\;cm^2$. Therefore, in practical application, the large area of ITO may significantly reduce the device performance. In this work, we investigated the effect of sheet resistance ($R_{sh}$) of deposited ITO on the performance of OPVs. It was found that the device performance of polythiophene-fullerene (P3HT:PCBM) bulk heterojunction OPVs was critically dependent on Rsh of the ITO electrode. With decreasing $R_{sh}$ of the ITO from 39 to $8.5\;{\Omega}/{\square}$, the fill factor (FF) of OPVs was dramatically improved from 0.407 to 0.580, resulting in improvement of PCE from $1.63{\pm}0.2$ to $2.5{\pm}0.1%$ underan AM1.5 simulated solar intensity of $100\;mW/cm^2$.

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$TiO_2$가 도핑된 ZnO박막의 전기적 광학적 특성

  • Seo, Seong-Bo;Yun, Hyeong-O;Ji, Seung-Hun;Kim, Mi-Seon;Bae, Gang;Kim, Hwa-Min
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.42-43
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    • 2009
  • 본 연구에서는 고주파 마그네트론 스퍼터링방법을 사용하여 ITO박막을 대체할 수 있는 새로운 TCO박막으로서 $TiO_2$가 도핑된 ZnO(TZO) 박막을 성막하였다. 이때, $TiO_2$의 도핑량을 1wt.%에서 5wt.%까지 변화를 주었으며 제작된 TZO 박막에 대해서 전기적 특성과 광학적 특성들의 조성비와 박막두께의 할수로서 조사하였다. 그 결과, $TiO_2$가 2wt.% 도핑된 박막에서 가장 낮은 $1\times10^{-3}\Omega{\cdot}cm$의 비저항이 얻어졌으며, $TiO_2$의 도핑량이 증가함에 따라 비저항은 점점 증가하는 것으로 나타났다. 이와같은 비저항의 변화는 $TiO_2$도핑량이 다른 TZO박막의 홀이동도(Hall mobility)에 비례하며, 이동도는 결국 TZO박막을 형성하고 있는 결정립의 크기에 의존하는 것이 X선 회절 패턴으로부터 확인되었다. XRD 패턴에서 ZnO(002) 방향의 결정성이 가장 큰 것으로 나타났으며, 도핑량이 증가할수록(002)피크의 크기가 점점 감소하는 것을 볼 수 있다. 이는 결정성의 크기가 2wt.%일 때 가장 크며 도핑량이 증가할수록 결정성의 크기가 감소하는 것으로 나타났다. 결정립의 크기변화는 TZO박막의 전기적 이동도에 영향을 주는 것으로 나타난다. 즉, 2wt.%일 때 이동도가 가장 크며 도핑량이 증가할수록, 이동도가 감소하였으며 이결과는 TZO박막의 Hall effect 측정으로부터 확인된다. 따라서, $TiO_2$도핑량에 따른 TZO 박막의 비저항을 도핑량이 2wt.%일 때 가장 낮으며 이는 TZO 박막의 결정성이 가장 우수하였으며 그결과 이동도가 증가했기 때문인 것으로 확인되었다.

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Fabrication and Charactreistics of MOCVD Cu Thin Films Using (hfac)Cu(VTMOS) ((hfac)Cu(VTMOS)를 이용한 Thermal CVD Cu 박막의 제조 및 그 특성)

  • 이현종;최시영
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.3
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    • pp.59-65
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    • 1999
  • In this paper, we had studied the possibility of application as Cu thin films from (hfac)Cu(VTMOS) which is very stable. Cu thin films had been studied as a function of deposition temperature. Substrates used in the experiment were PVD TiN on Si wafer. Deposition conditions were as follow : deposition temperature $50^{\circ}C$. Cu thin films were analyzed by AES, four point probe, XRD and SEM. All of deposited films were very pure and some favoring of <111> planes perpendicular to the substrate surface were observed. Cu thin films had two distinct growth rates at various deposition temperature. One is the surface reaction limited region below $200^{\circ}C$, and the other is the mass transport limited region above $200^{\circ}C$. The resistivity of deposited Cu thin films under the optimum deposition condition is $2.5mu\Omega.cm$ Thus, properties of deposited Cu thin films using (hfac)Cu(VTMOS) didn't show difference with Cu thin films from other precursors.

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Bandwidth-Improved Design of Shielded Printed Spiral Coil Probes for Radio-Frequency Interference Measurement (무선주파수 간섭 측정용 차폐된 Printed Spiral Coil(PSC) 프로브의 대역폭 개선 설계)

  • Kim, Kyungmin;Song, Eakhwan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.29 no.5
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    • pp.359-365
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    • 2018
  • Herein, electromagnetic shielding structures to reduce the external noise coupling to printed spiral coils (PSCs) and a design method for improving the bandwidth of shielded PSCs have been proposed. It has been demonstrated that the bandwidth of shielded PSCs is limited due to the parasitic capacitance between the coils and the shielding structures and is confirmed by the transfer function simulation of the shielded PSCs with a transmission line as the radio-frequency interference noise source. A design method for the bandwidth improvement of the shielded PSCs has been proposed based on the equivalent circuit model analysis and the case studies depending on PSC designs with a three-dimensional field simulation. With the design method, an optimized shielded PSC design has been presented and successfully confirmed by experimental verification in that the optimized design results in a significant bandwidth improvement.

Relaxing Effects of Acanthopanacis Cortex through NO Production and PDE-5 Inhibition in Corpus Cavernosum (오가피의 NO 생성과 PDE-5 억제를 통한 음경해면체 이완효과)

  • Kim, Ho Hyun;Park, Sun Young
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.31 no.1
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    • pp.52-58
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    • 2017
  • This study was aimed to examine relaxing effects of Acanthopanacis cortex(AC) through nitric oxide(NO) production and phosphodiesterase type 5(PDE-5) inhibition in corpus cavernosum. In order to define the relaxation effects of AC extract, rabbit corpus cavernous tissues were prepared in $2{\times}2{\times}8mm$ sized strip. AC extract ($0.01-3.0mg/m{\ell}$) were treated in contracted strips induced by phenylephrine(PE) and $N{\omega}$-nitro-L-arginine (L-NNA) was treated before AC extract-treated. And calcium chloride($Ca^{2+}$) 1 mM was infused into precontracted strips after pretreatment of AC extract in $Ca^{2+}-free$ krebs-ringer solution. When AC extract was applied to human umbilical vein endothelial cell(HUVEC), cell viability was measured by MTT assay, and NO concentration was measured by Griess reagent system. Ratio of smooth muscles to collagen fibers and eNOS, PDE-5 positive reaction were measured by histochemical and immunohistochemical process on mice corpus cavernosum. AC extract significantly affected relaxion of the cavernous strips, and the pretreatment of L-NNA inhibited AC extract-induced relaxation. Contraction induced by the addition of $Ca^{2+}$ was inhibited by treatment with the AC extract in $Ca^{2+}-free$ solution. In AC group, NO concentration, ratio of smooth muscle to collagen fibers, and eNOS positive reaction were increased, PDE-5 positive reaction was decreased compared to PE group. As a result of the above experiment, it was thought that AC extract inhibits the inflow of extracellular $Ca^{2+}$ by activating cGMP through the increase of eNOS / NO and the decrease of PDE-5 which inhibits cGMP activity, in the corpus cavernosum.

Improved Conductivities of SWCNT Transparent Conducting Films on PET by Spontaneous Reduction

  • Min, Hyeong-Seop;Kim, Sang-Sik;Lee, Jeon-Guk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.43.2-43.2
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    • 2011
  • Single-walled carbon nanotubes (SWCNT) are transparent in the visible and show conductivity comparable to copper, and are environmentally stable. SWCNT films have high flexibility, conductivity and transparency approaching that indium tin oxide (ITO), and can be prepared inexpensively without vacuum equipment. Transparent conducting Films (TCF) of SWCNTs has the potential to replace conventional transparent conducting oxides (TCO, e.g. ITO) in a wide variety of optoelectronic devices, energy conversion and photovoltaic industry. However, the sheet resistance of SWCNT films is still higher than ITO films. A decreased in the resistivity of SWCNT-TCFs would be beneficial for such an application. We fabricated SWCNT sheet with $KAuBr_4$ on PET substrate. Arc-discharge SWCNTs were dispersed in deionized water by adding sodum dodecyl sulfate (SDS) as surfactant and sonicated, followed by the centrifugation. The dispersed SWCNT was spray-coated on PET substrate and dried on a hotplate at $100^{\circ}C$. When the spray process was terminated, the TCF was immersed into deionized water to remove the surfactant and then it was dried on hotplate. The TCF film was then treated with AuBr4-, rinsed with deionized water and dried. The surface morphology of TCF was characterized by field emission scanning electron microscopy. The sheet resistance and optical transmission properties of the TCF were measured with a four-point probe method and a UV-visible spectrometry, respectively. $HNO_3$ treated SWCNT films with Au nano-particles have the lowest 61 ${\Omega}$/< sheet resistance in the 80% transmittance. Sheet resistance was decreased due to the increase of the hole concentration at the washed SWCNT surface by p-type doping of $AuBr_4{^-}$.

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