• KSBB Journal
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• v.14 no.2
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• pp.205-211
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• 1999

We investigated optimal conditions for the microbial transformation of $\gamma$-butyrobetaine into L-carnitine by using Achromobacter cycloclast ATCC 21921. When the cells were cultivated in the medium containing $\gamma$-butyrobetaine as the sole carbon source for both cell growth and L-carnitine production, the maximum L-carnitine production was 2.9 g/L and the conversion yield from $\gamma$-butyrobetaine to L-carnitine was as low as 30.9 mol%. In order to enhance the L-carnitine production and the conversion yield, various carbon sources were added to the $\gamma$-butyronetaine containing basal medium. In the medium supplemented with glycerol, L-carnitine production was as high as 4.6 g/L and the conversion yield was 88.2 mol%, showing a significant improvement in L-carnitine synthesis compared to those in the medium without glycerol. We also examined the additional effect of quaternary ammonium compounds such as betaine and choline, which are similar in structure to $\gamma$-butyrobetaine and L-carnitien. It was observed that in the presence of those quaternary ammonium compounds, both the L-carnitine production rate and the conversion yield increased. In addition, we found that cell growth was inhibited by a $\gamma$-butyrobetaine concentration of more than 3%, while L-carnitine production was efficient at the $\gamma$-butyrobetaine concentration of 2-3%. By cultivating the cells in the optimal medium containing glycerol and choline, we obtained an L-carnitine concentration of 7.2 g/L with the conversion yield of 98.7 mol% in 4 days.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.420-420
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• 2010

AC PDP에서 유전체 보호막으로 사용되는 MgO 박막은 높은 이차전자방출계수($\gamma$)로 인해 방전전압을 낮춰주는 중요한 역할을 하고 있다. 이러한 MgO 보호막의 이차전자방출계수를 증가시키기 위해 MgO 의 Energy Band Structure 규명이 중요한 연구 주제가 되고 있다. MgO의 이차전자방출계수($\gamma$)는 Auger 중화 이론에 의해 방출 메커니즘이 설명이 되고, 그 원리는 다음과 같다. 고유의 이온화 에너지를 가진 이온이 MgO 표면에 입사 되면, Tunneling Effect에 의해 전자와 이온 사이에 중화가 일어나고, 중화가 되고 남은 에너지가 MgO Valance Band 내의 전자에게 전달되면 이때 남은 에너지(${\Delta}E$)가 MgO의 일함수(Work function) 보다 크게 되면 이차전자로 방출된다. 본 실험 에서는 $\gamma$-FIB System을 이용하여 결정 방향이 (100), (110), (111)을 갖는 Single Crystal MgO에 이온화 에너지가 24.58eV인 He Ion source를 주사 하였을 때 Auger self-convolution을 통해 이차전자의 운동 에너지 분포를 구하고, 이를 통해 MgO 내의 Energy Band Structure를 실험적으로 측정하였다. 이를 통해 MgO Single Crystal의 일함수 및 Defect Level의 분포를 확인하였다.

• Journal of Photoscience
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• v.9 no.1
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• pp.5-7
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• 2002

Direct irradiation of carbonyl compounds such as some aldehydes, ketones and anthraquinone in N,N-dimethylamiline(DMA), without using other solvents, gave $\beta$-hydroxyamines as the major products. Irradiation of anthrone and DMA in methanol afforded ${\gamma}$-hydroxyamine. The structure of the photoproduct was confirmed by treatment with an acid to give a bicyclic compound.

• Communications of the Korean Mathematical Society
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• v.28 no.3
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• pp.481-486
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• 2013

In this note, we show that $\mathcal{M}({\Gamma}_0(N))$ is a weighted polynomial ring if and only if N = 1, 2, 4, where $\mathcal{M}({\Gamma}_0(N))$ is the graded ring of integral-weighted modular forms for the congruence subgroup ${\Gamma}_0(N)$.

• Applied Chemistry for Engineering
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• v.9 no.1
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• pp.101-106
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• 1998

Two types of CoMo/zeolite as well as $NiMo/{\gamma}-Al_2O_3$ were prepared and their activities and selectivities of low-temperature dibenzothiophene(DBT) hydrodesulfurization(HDS) were studied in high pressure fixed bed reactor. The HDS activities of CoMo/zeolites were higher than that of $NiMo/{\gamma}-Al_2O_3$ at temperatures below $225^{\circ}C$ while they were lower than that of $NiMo/{\gamma}-Al_2O_3$ at temperatures higher than $275^{\circ}C$. The main products from $NiMo/{\gamma}-Al_2O_3$ were biphenyl and cyclohexylbenzene. The product distribution of CoMo/zeolite catalysts was different from that of $NiMo/{\gamma}-Al_2O_3$. It is speculated that DBT is converted to alkylcyclohexane over zeolite based catalysts through both alkylation and hydrogenation reactions. The crystal structure of molybdenum was $MoO_3$ in fresh zeolite support while mixtures of $MoO_3$ and $MoS_2$ were observed in the aged catalyst.

• Journal of The Korean Astronomical Society
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• v.37 no.5
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• pp.447-454
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• 2004

During the hierarchical formation of large scale structure in the universe, the progressive collapse and merging of dark matter should inevitably drive shocks into the gas, with nonthermal particle acceleration as a natural consequence. Two topics in this regard are discussed, emphasizing what important things nonthermal phenomena may tell us about the structure formation (SF) process itself. 1. Inverse Compton gamma-rays from large scale SF shocks and non-gravitational effects, and the implications for probing the warm-hot intergalactic medium. We utilize a semi-analytic approach based on Monte Carlo merger trees that treats both merger and accretion shocks self-consistently. 2. Production of $^6Li$ by cosmic rays from SF shocks in the early Galaxy, and the implications for probing Galaxy formation and uncertain physics on sub-Galactic scales. Our new observations of metal-poor halo stars with the Subaru High Dispersion Spectrograph are highlighted.

• Journal of The Korean Astronomical Society
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• v.37 no.5
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• pp.465-470
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• 2004

I address the issue of nonthermal processes in the large scale structure of the universe. After reviewing the properties of cosmic shocks and their role as particle accelerators, I discuss the main observational results, from radio to $\gamma$-ray and describe the processes that are thought be responsible for the observed nonthermal emissions. Finally, I emphasize the important role of $\gamma$-ray astronomy for the progress in the field. Non detections at these photon energies have already allowed us important conclusions. Future observations will tell us more about the physics of the intracluster medium, shocks dissipation and CR acceleration.

• Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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• 2003.10a
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• pp.135.1-135
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• 2003

To elucidate the effect of gamma-irradiation on the molecular properties of hemoglobin, the secondary, tertiary structure, and the molecular weight size of the protein were examined after irradiation at 0.5, 1, 5, and 10 kGy. Gamma-irradiation of hemoglobin solutions caused the disruption of the ordered structure of the protein molecules, as well as degradation, cross-linking, and aggregation of the polypeptide chains. A SDS-PAGE study indicated that irradiation caused initial fragmentation of the proteins and subsequent aggregation due to cross-linking of the protein molecules. The effect of irradiation on the protein was more significant at lower protein concentrations. Ascorbic acid decreased the degradation and aggregation of proteins by scavenging oxygen radicals that were produced by irradiation. A circular dichroism study showed that irradiation decreased the helical content of hemoglobin with a concurrent increase of the aperiodic structure content. Fluorescence spectroscopy indicated that irradiation decreased the emission intensity that was excited at 280 nm.

• Journal of the Korean Ceramic Society
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• v.35 no.10
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• pp.1113-1119
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• 1998

Crystal structure of needle-shaped maghemite(${\gamma}$-{{{{ { {Fe }_{2 }O }_{3 } }}) has been studied by the Rieveld analysis of powder X-ray diffraction patterns. The tetragonal space group P41,.3212 and cubic space group P41,.32 have been have been used for the refinement of X-ray diffraction patterns. The crystal system of maghemite is closed to tetragonal more than cubic. The tetragonal lattice parameters are a=8.3460$\AA$ and c=25.034$\AA$ The standard X-ray diffraction pattern of the tetragonal maghemite analyzed with space group P41,.3212 is proposed.

• Journal of the Korean Ceramic Society
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• v.31 no.11
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• pp.1271-1282
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• 1994

The surface of commercial alumina fibers used for reinforcing the MCFC matrix has been coated with ${\gamma}$-LiAlO2 being the same material as the matrix, by the sol-gel method in order to enhance the corrosion resistivity of alumina fibers. Stable LiAlO2 complex polymeric sols for coating was synthesized by mixing aluminum alkoxide polymeric sols with LiNO3 solution. It was found that the LiAlO2 polymeric sol prepared by adding the mixed chelate of acethylacetone and triethanolamine (the mole ratio of AA/TEA = 0.125/0.75) to the 1 mole of the aluminum alkoxide had the excellent stability and coating behavior. The crystalline structure of the dried gel from the ${\gamma}$-LiAlO2 sol was completely transformed into the ${\gamma}$-LiAlO2 at $600^{\circ}C$. The optimum viscosity of the sol for coating the alumina long fibers was 30~40 cP, while it was 12~20 cP in case of the short fiber coating. The ${\gamma}$-LiAlO2 coated alumina fibers without defects fully densified when heat-treated at 120$0^{\circ}C$.