• Title/Summary/Keyword: ${\gamma}'$ phase

Search Result 688, Processing Time 0.027 seconds

Purification and Properties of HPS (Halitosis Prevention Substance) Isolated from Cumin (Cuminum cyminum L.) Seed

  • Kang, Eun-Ju;Ryu, Il-Hwan;Lee, Kap-Sang
    • Food Science and Biotechnology
    • /
    • v.14 no.5
    • /
    • pp.621-627
    • /
    • 2005
  • Halitosis is mainly caused by the presence of volatile sulfur-containing compounds (VSC's) produced by proteolytic periodontopathic bacteria in the oral cavity. Various mouth-rinses have been offered on the market as solutions to reduce halitosis. The aim of this study was to find a potent substance for the prevention of halitosis. The halitosis prevention substance (HPS) from cumin seed powder was purified by solvent extraction, silica gel column chromatography and preparative TLC to yield an oil phase (0.98%). Instrumental analysis such as FT-IR, $^1H$-NMR and $^{13}C$-NMR showed that HPS contained an -OH group, -HC=CH-, -COO-, and long chain acyl group. HPS was therefore determined to be 2-hydroxyethyl-${\beta}$-undecenate. HPS inhibited the growth of Fusobacterium nucleatum and Porphyromonas gingivalis, by 72.44% and 64.37% at $1{\times}10^{-2}\;M$, and by 99.85% and 91.62% at $5\;{\times}\;10^{-2}\;M$, respectively. It also inhibited the activity of L-methionine-${\alpha}$-deamino-${\gamma}$-mercaptomethane-lyase (METase), which was produced by oral microbes. Furthermore, the VSC production by oral microbes in the human mouth air decreased with increasing HPS concentration. These results suggested that HPS from cumin seed is an efficient halitosis prevention agent.

Changes in Microstructure and Texture during Annealing of 0.015% C-1.5% Mn-0~0.5% Mo Steels (0.015% C-1.5% Mn-0~0.5% Mo 강의 어닐링과정에서 미세조직과 집합조직의 변화)

  • Jeong, Woo Chang
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.24 no.5
    • /
    • pp.251-261
    • /
    • 2011
  • The changes in microstructure and texture during annealing were examined in a series of 0.015% C-1.5% Mn cold-rolled sheet steels with 0~0.5% Mo. Orientation distribution function data were calculated from the (110), (200), (211) pole figures determined on the rolled plane of cold-rolled and annealed steel sheets. Regardless of Mo content and annealing conditions, martensite volume fraction was less than 1.0%, not affecting the texture evolution. Textural change at the cooling stage after heating at $820^{\circ}C$ for 67 sec was not observed. Increasing the Mo content and annealing temperature markedly strengthened the intensities of ${\gamma}$-fiber texture, resulting in the increase in $r_m$ value. The desirable texture evolution for deep drawability in the 0.5% Mo steel may be mainly caused by the grain refining effect of Mo carbide in the hot-rolled steel sheet.

Scanning Electron Micrographic Study on the Etched Surface of Base Metal Alloys for Dental Restorations (치과용 비귀금속합금의 식각표면에 대한 주사전자현미경적 연구)

  • Chung, Hun-Young;Lee, Sun-Hyung
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.23 no.1
    • /
    • pp.83-95
    • /
    • 1985
  • The purpose of this study was to evaluate microstructures on the etched surface of 11 base metal alloys for dental restorations and to observe the relationship between the etching pattern and beryllium. For this purpose, the following experiments were done; 11 base metal alloys were etched in (1) 10% $H_2SO_4$, (2) 10% $H_2SO_4$, 9 parts+methanol 1 part (3) Conc. $HNO_3$ 25%+glacial acetic acid 25%+$H_2O$ 50% (4) Conc. $HNO_3$ 5% (5) 2% glacial acetic acid added to Conc. $HNO_3$ 1% solution, with their etching conditions varied. Etched surface of alloys were examined under the scanning electron microscope. Results were as follows; 1. Almost all of Ni-Cr-Be alloys showed gooed etchd surface in $H_2SO_4$, solution, while some of those alloys which contains no beryllium showed good etched surface in $HNO_3$ solution. 2. Main components of etching solution can vary etching pattern of alloys. 3. Gamma prime phase relief, which can be found in all Ni-Cr-Be alloys, can't be found in any alloy that contains no beryllium.

  • PDF

Pharmacokinetics and Tissue Distribution of UTI in the Rat (랫드에서의 UTI의 약물동태학 및 조직 분포)

  • 정요찬;윤효인;조명행;박병권;발일현;김복환;송동호
    • Biomolecules & Therapeutics
    • /
    • v.4 no.3
    • /
    • pp.265-270
    • /
    • 1996
  • The purpose of this study was to determine pharmacokinetic parameters and tissue distribution patters of urinary trypsin inhibitor(UTI) in Sprague-Dawley rats. $Na^{125}$I was conjugated to UTI to make $^{125}I-UTI$ and the concentrations were determined by $\gamma$-counter. With the aid of nonlinear least-square regression analysis for i.v bolus injection of 1,000 unit UTI including $^{125}I-UTI$, the temporal concentration curves were best fitted by 2-compartment open model. The distribution phase half-life was 0.39$\pm$0.02 hours whereas the elimination half-life was 12.99$\pm$1.05 hours in male rats. The volume of distribution and total body clearance in male rats were 0.28$\pm$0.01 1/kg and 83.16$\pm$1.15 ml/kg/h, respectively. We could not find any difference of pharmacokinetic parameters of UTI between male and female rats. UTI were distributed widely in rat organs. In both male and female rats, the kidney was the highest distributed organ. Amount of UTI in 24 hour cumulative urine in male rats was 36.22$\pm$8.74% and that in 48 hours was 43.32$\pm$10.55%. Excretion via feces was very scanty, with the 24 hours cumulative amount being only 2.76$\pm$0.97%. This data suggest the main excretion route of UTI is urine.

  • PDF

Effect of Intercritical Annealing on the Dynamic Strain Aging(DSA) and Toughness of SA106 Gr.C Piping Steel

  • Lee, Joo-Suk;Kim, In-Sup;Park, Chi-Yong;Kim, Jin-Weon
    • Nuclear Engineering and Technology
    • /
    • v.32 no.1
    • /
    • pp.77-87
    • /
    • 2000
  • It is reported that the toughness and safety margins of the SA106 Gr.C main steam line piping steel is reduced due to dynamic strain aging (DSA) at the reactor operating temperature for Leak-Before-Break (LBB) application. In this study, intercritical annealing in two-phase ($\alpha$+${\gamma}$)region was performed to investigate the possibility of improving the toughness and reducing DSA susceptibility. The manifestations of DSA were still observed in the tensile tests of the annealed specimens. However, the ductility loss caused by DSA was smaller than that in the as-received material. Furthermore, the intercritical annealing was able to increase the Charpy impact toughness by 1.5 times compared to as-received. With the heat treatment, we could obtain microstructural changes such as the cleaner retained ferrite, increased ferrite content and somewhat finer grain size. It is considered that the reduced DSA was induced by cleaner retained ferrite, which in turn resulted in higher impact toughness in addition to the general toughening due to finer grain sizes and increased ferrite content.

  • PDF

The Characteristics of the Oxide Layer Produced on the Plasma Nitrocarburized Compound Layer of SCM435 Steel by Plasma Oxidation (플라즈마 산질화처리된 SCM435강의 표면경화층의 미세조직과 특성)

  • Jeon Eun-Kab;Park Ik-Min;Lee Insup
    • Korean Journal of Materials Research
    • /
    • v.14 no.4
    • /
    • pp.265-269
    • /
    • 2004
  • Plasma nitrocarburising and post oxidation were performed on SCM435 steel by a pulsed plasma ion nitriding system. Plasma oxidation resulted in the formation of a very thin ferritic oxide layer 1-2 $\mu\textrm{m}$ thick on top of a 15~25 $\mu\textrm{m}$ $\varepsilon$-F $e_{2-3}$(N,C) nitrocarburized compound layer. The growth rate of oxide layer increased with the treatment temperature and time. However, the oxide layer was easily spalled from the compound layer either for both oxidation temperatures above $450^{\circ}C$, or for oxidation time more than 2 hrs at oxidation temperature $400^{\circ}C$. It was confirmed that the relative amount of $Fe_2$$O_3$, compared with $e_3$$O_4$, increased rapidly with the oxidation temperature. The amounts of ${\gamma}$'-$Fe_4$(N,C) and $\theta$-$Fe_3$C, generated from dissociation from $\varepsilon$-$Fe_{2-3}$ /(N,C) phase during $O_2$ plasma sputtering, were also increased with the oxidation temperature.e.

Study on the development of simultaneous-rapid screening methods for residues pesticides in livestock products (수입 축산식품에서의 잔류농약 동시분석법 개발에 관한 연구)

  • Kim, Jong-shu;Kim, Gon-sup;Hah, Dae-sik
    • Korean Journal of Veterinary Research
    • /
    • v.37 no.1
    • /
    • pp.213-220
    • /
    • 1997
  • A simple and rapid method known as matrix solid phase dispersion(MSPD) for simultaneous determination of 11 pesticide(2,4,5,6-tetrachlor m-xylene, ${\alpha}$-BHC, ${\gamma}$-BHC, ${\delta}$-BHC, aldrin, chlorfulazuron, heptachloroepoxide, dieldrine, endrin, endosulfan sulfate, and tetradifon) in beef fat was estabilished. Beef fat(0.5g) was fortified by adding the 11 pesticides and dibutylchlorendate as internal standard, and blended with 2g bulk $C_{18}$ in pestle and motar. Pesticides were eluted from an extraction column composed of $C_{18}$/ fat matrix blend and 2g activated Florisil by addition of 8ml acetonitrile. Then $2{\mu}l$ portion of the acetonitrile elute was directly analyzed by gaschromatography with electron capture detection. Unfortified blank control were treated similarly. Recovery rate were ranged from $83{\pm}5.4%$ to $94.2{\pm}7.6%$, intra-assay variability and inter-assay variability were ranged from 2.3% to 7.4%(n=5 for each insecticides) and from $6{\pm}1%$ to $12{\pm}3%$(n=10 for each insecticides), respectively. These results indicated that the MSPD methodology is aceptable for the extraction, determination and screening of residues 11 chroniated pesticides in beef fat.

  • PDF

The Effect of pH and temperature on the Morphology of Aluminum Hydroxides formed by Hydrolysis Reaction (알루미늄의 수화 반응시 pH와 온도에 따른 형상 변화)

  • 오영화;이근회;박중학;이창규;김흥회;김도향
    • Journal of Powder Materials
    • /
    • v.11 no.2
    • /
    • pp.118-123
    • /
    • 2004
  • A formation of aluminum hydroxide by hydrolysis reaction in the water has been studied by using nano aluminum powder fabricated by pulsed wire evaporation(PWE) method. The hydroxide type and morphology depending on temperature and pH were examined by structural analysis. The Boehmite($Al_2O_3$.$H_2O$ or AIO(OH)) was predominantly formed in high temperature region over 4$0^{\circ}C$, while the Bayerite($Al_2O_3$.$H_2O$ or $Al(OH)_3$) below $30^{\circ}C$ of hydrolysis temperature. The Boehmite formation was preferred to the Bayerite in acidic solution in the same hydrolysis temperature. The slowly formed Bayerite phase showed facet crystalline structure, while the fast formed Boehmite was fine fiber with a large aspect ratio of several nm in diameter and several hundred nm in length, and with much larger specific surface area(SSA) than that of Bayerite. The highest SSA was about $420m^2$/g.

Observation of early photons of Gamma-ray bursts from UFFO/Lomonosov

  • Jeong, Soomin;Park, I.H.
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.41 no.1
    • /
    • pp.64.4-65
    • /
    • 2016
  • Observations of the early photons from evolution of optical afterglows or internal shock provides the crucial clues on the nature of the bursts and environments. Hundreds of GRBs afterglow observations in multi-wavelength region have been made mainly thanks to the fast (~ 60 seconds after the trigger) localisation GRB by Swift and its fast alert to the ground telescope. It helps to improve our understandings tremendously, however many enigmas still remain, such as burst mechanism, transition prompt emission to the afterglow, early optical flash, rise phase of the early optical light curve and some missing afterglows. They could be addressed by fast slewing and multi colour and IR follow-up by future telescopes. The primary aim of UFFO/Lomonosov is to follow up optical fast ever, within a couple of seconds after trigger by onboard X-ray telescope. Its optical FOV is $30{\times}30degrees$. As a key instrument, the Slewing Mirror to redirect the optical beam from GRBs rapidly to the Ritchey-Chretien telescope. The status and launch schedule of the UFFO/Lomonosov and its test performance will be reported and prospects for the next missions will be discussed.

  • PDF

PARTICLE ACCELERATION IN SUPERNOVA REMNANTS

  • KANG, HYESUNG
    • Publications of The Korean Astronomical Society
    • /
    • v.30 no.2
    • /
    • pp.545-548
    • /
    • 2015
  • Most high energy cosmic rays (CRs) are thought to be produced by diffusive shock acceleration (DSA) in supernova remnants (SNRs) within the Galaxy. Plasma and MHD simulations have shown that the self-excitation of MHD waves and amplification of magnetic fields via plasma instabilities are an integral part of DSA for strong collisionless shocks. In this study we explore how plasma processes such as plasma instabilities and wave-particle interactions can affect the energy spectra of CR protons and electrons, using time-dependent DSA simulations of SNR shocks. We demonstrate that the time-dependent evolution of the shock dynamics, the self-amplified magnetic fields and $Alfv{\acute{e}nic$ drift govern the highest energy end of the CR energy spectra. As a result, the spectral cutoffs in nonthermal X-ray and ${\gamma}$-ray radiation spectra are regulated by the evolution of the highest energy particles, which are injected at the early phase of SNRs. We also find that the maximum energy of CR protons can be boosted significantly only if the scale height of the magnetic field precursor is long enough to contain the diffusion lengths of the particles of interests. Thus, detailed understandings of nonlinear wave-particle interactions and time-dependent DSA simulations are crucial for understanding the nonthermal radiation from CR acceleration sources.