• 제목/요약/키워드: ${\delta}$-phase

Search Result 841, Processing Time 0.027 seconds

무연 Cu-Zn-Sn 청동의 조직과 주조성에 미치는 Bi 및 Sb 첨가의 영향 (Influence of Bismuth and Antimony Additions on the Structures and Casting Properties of Lead-free Cu-Zn-Sn Bronze Castings)

  • 박흥일;박성익;김성규
    • 한국주조공학회지
    • /
    • 제32권2호
    • /
    • pp.91-97
    • /
    • 2012
  • The effects of Bi and Sb additions on the microstructures and casting properties in lead-free Cu-Zn-Sn broze were investigated. (1) When only Bi was added to the bronze, Bi was precipitated on the ${\delta}$ phase of ${\alpha}$ dendrite cell boundary. When Bi and Sb were added together, Bi was precipitated on the ${\delta}_A$ which was the Sb-rich area in the ${\delta}$ phase. (2) The addition of Sb accelerated the formation of ${\delta}$ phase, and when Sb, Bi and Pb were added, Bi and Pb were precipitated as mixed solution in the ${\delta}_A$ phase. (3) The combined addition of Sb and Bi resulted in the suppression of shrinkage due to the complementary effects of the mass feeding of ${\alpha}$-dendrite cluster covered with ${\delta}$ phase and sealing of micro-shrinkage in the ${\delta}$ phase by solidification expansion of Bi.

The Positional Effect of Solute Functional Group among Positional Isomers of Phenylpropanol in Hydroxyl Group-Solvent Specific Interactions in Methanol/Water Mixed Solvents Monitored by HPLC

  • Cheong, Won-Jo;Ko, Joung-Ho;Kang, Gyoung-Won
    • Bulletin of the Korean Chemical Society
    • /
    • 제26권8호
    • /
    • pp.1246-1250
    • /
    • 2005
  • We have evaluated the hydroxyl group-solvent specific interactions by using a Lichrosorb RP18 stationary phase and by measuring the retention data of carefully selected solutes in 50/50, 60/40, 70/30, 80/20, and 90/10(v/v%) methanol/water eluents at 25, 30, 35, 40, 45, and 50 ${^{\circ}C}$. The selected solutes are 3 positional isomers of phenylpropanol, that is, 1-phenyl-1-propanol, 1-phenyl-2-propanol, and 3-phenyl-1-propanol. There exist clear discrepancies in ${\Delta}H^o$ (solute transfer enthalpy from the mobile to the stationary phase) and $T{\Delta}S^o$ (solute transfer entropy) among positional isomers. The difference in ${\Delta}H^o$ and $T{\Delta}S^o$ between secondary alcohols (1-phenyl-1-propanol and 1-phenyl-2-propanol)is negligible compared to the difference between the primary alcohol (1-phenyl-3-propanol) and secondary alcohols. The $T{\Delta}S^o$ values of 3-phenyl-1-propanol are close to those of butylbenzene while the $T{\Delta}S^o$ values of secondary alcohols are close to those of propylbenzene. The difference in ${\Delta}{\Delta}H^o$ (specific solute-mobile phase interaction enthalpy) between the primary alcohol and the secondary alcohol decreases with increase of methanol content in the mobile phase. A unique observation is an extremum for 1-phenyl-3-propanol in the plot of $T{\Delta}{\Delta}S^o$ vs. methanol volume %. The positive sign of $T{\Delta}{\Delta}S^o$ of 3-phenyl-1-propanol implies that the entropy of 3-phenyl-1-propanol is greater than that of the hypothetical alkylbenzene (the same size and shape as phenylpropanol) in the mobile phase.

$La(Ba)Ga(Mg)O_3_\delta$계 Perovskite 산화물의 생성상 및 산소이온전도 (Phase Formation and Oxygen Ion Conduction of $La(Ba)Ga(Mg)O_3_\delta$ Perovskite Oxide System)

  • 이기태;김신;이홍림
    • 한국세라믹학회지
    • /
    • 제36권10호
    • /
    • pp.1056-1061
    • /
    • 1999
  • Phase formation and oxygen ion conduction of La(Ba)Ga(Mg)O3-$\delta$ system was studied, BaLaGa3O7 and BaLaGaO4 formed as a secondary phase above the solubility limit of Ba2+ in La3+ sites. The oxygen ionic conductivity of La(Ba)Ga(Mg)O3-$\delta$ was 0.1 S/cm 80$0^{\circ}C$ The activation energy of the oxygen ion conduction was dependent on temperature. This value was higher at low temperature than at high temperature.

  • PDF

Al-Li-( Cu, Zr) 합금에서 시효에 따른 δ' 상의 형상 및 입자크기분포의 변화 (The Changes of the Shape and Particle Size Distribution of δ' Phase on Ageing in Al-Li-( Cu, Zr) Alloys)

  • 우기도;조현기
    • 열처리공학회지
    • /
    • 제7권2호
    • /
    • pp.96-102
    • /
    • 1994
  • The present work was aimed to examine the changes of the shape and particle size distribution(PSD) of ${\delta}^{\prime}$ particles on ageing in Al-Li-(Cu, Zr) alloys which had low density, high specific strength and stiffness, Increasing ageing time and temperature resulted in particles whose aspect ratio tended toward 1. The aspect ratio of ${\delta}^{\prime}$ particles was not dependent upon the ageing temperature and time in Al-Li-Cu alloy but was dependent upon them in Al-Li-Zr alloy. The PSD of ${\delta}^{\prime}$ particles in Al-Li-Zr alloy skewed to the right hand compared with that in Al-Li-Cu alloy, because $Al_3Zr$ phase in Al-Li-Zr alloy formed before ageing promoted the precipitation and growth of ${\delta}^{\prime}$ phase. Therefore, the PSD of the ${\delta}^{\prime}$ particles was found to be affected by the presence of $Al_3Zr$ particles. The growth rate of ${\delta}^{\prime}$ phase was not affected by the existence of the third transition phase $T_1$ formed by the addition of Cu in Al-Li alloy but was affected by the existence of $Al_3Zr$ formed by the addition of Zr in Al-Li alloy.

  • PDF

유압 서보 모터를 위한 $e-{\Delta}e$ 위상평면을 이용한 이중 퍼지 로직 제어기 설계 (Design of Dual Fuzzy Logic Controller using $e-{\Delta}e$ Phase Plane for Hydraulic Servo Motor)

  • 신위재;문정훈
    • 융합신호처리학회논문지
    • /
    • 제8권3호
    • /
    • pp.222-226
    • /
    • 2007
  • 본 연구에서는 응답의 과도영역에서 특징점의 각 영역과 $e-{\Delta}e$ 위상평면을 이용하여 이중 퍼지룰을 구성하였다. 구성된 퍼지 제어룰은 기본 퍼지제어 룰에 비해 상승시간, 지연시간, 최대오브슈트 등을 줄일 수 있었으며 퍼지 룰의 제안방법은 $e-{\Delta}e$ 위상평면에서 하나의 퍼지룰은 과도영역에서 정상상태오차를 일으키고 다른 퍼지 제어 룰은 정상상태오차를 감소시키고 수렴영역에서 빠르게 수렴하도록 교대로 사용한다. 또한 $e-{\Delta}e$ 위상평면에서의 두 개의 퍼지 룰은 플랜트의 응답 특성에 따라 교체시기를 결정한다. DSP 프로세서를 사용하는 유압서보 모터 제어시스템을 통한 실험의 결과로서 제안된 이중 퍼지 제어 룰은 기본 퍼지 제어 룰에 비해 빠른 상승시간, 정정시간등 양호한 응답을 얻을 수 있음을 확인하였다.

  • PDF

EPLD 로직구현을 통한 델타변조기법에 의한 스위치드 리럭턴스 전동기의 전류제어 (Current Control of Switched Reluctance Motor with Delta Modulation Method on EPLD Logic Design)

  • 윤용호;김재문
    • 전기학회논문지P
    • /
    • 제57권4호
    • /
    • pp.356-361
    • /
    • 2008
  • The conventional drive system of SRM has a current sensor per each phase. The torque demand signal generated by the outer control loop is translated into individual current reference signal for each phase. The torque is controlled by regulating these currents. Using the SRM in a variable-speed control, the phase currents are generally regulated to achieve a square wave. The simplest form of current regulation uses fixed frequency delta modulation of the phase voltages. The aim of this paper is to regulate 3-phases current of SRM by only single current sensor using delta modulation with digital chip. In this paper, the asymmetric bridge converter which is able to control independently phases and be excited simultaneously is used as the driver system for 6/4 poles SRM. And the current sensor is replaced 3 sensors of each phase with only one on bus line of converter so as to detect current of every phase. The proposed delta modulation technique has been implemented in a simple digital logic circuit using EPLD(Electrically Programmable Logic Device). This method is verified through simulation and experiment results.

유압 서보계의 $\delta$연산자를 이용한 모델기준형적응제어 (Model Reference Adaptive Control Using $\delta$-Operator of Hydraulic Servosystem)

  • 김기홍;윤일로;염만오
    • 한국정밀공학회지
    • /
    • 제17권11호
    • /
    • pp.151-157
    • /
    • 2000
  • The MRAC theory has proved to be one of the most popular algorithms in the field of adaptive control, particularly for practical application to devices such as an hydraulic servosystem of which parameters are unknown or varying during operation. For small sampling period, the discrete time system becomes a nonminimal phase system. The $\delta$-MRAC was introduced to obtain the control performance of nonminimal phase system, because the z-MRAC can not control the plant for small sampling period. In this paper, $\delta$-MRAC is applied to the control of an hydraulic servosystem which is composed of servovalve, hydraulic cylinder and inertia load.

  • PDF

微視組織에 敏感한 균열닫힘 현상 (Microstructurally sensitive crack closure)

  • 김정규;황돈영
    • 대한기계학회논문집
    • /
    • 제10권6호
    • /
    • pp.898-905
    • /
    • 1986
  • 본 논문에서는 강의 피로균열진전거동과 미시조직과의 관계를 밝히기 위한 연 구의 일환으로 제이상 마르텐사이트 중에 모상 페라이트가 존재하는 복합조직강을 준 비하여 이들 강의 제이상 경도변화에 따른 피로균열진전저항을 균열휨과 균열닫힘을 통하여 검토하였다.

Fractional-N Frequency Synthesizer with a l-bit High-Order Interpolative ${\sum}{\Delta}$ Modulator for 3G Mobile Phone Application

  • Park, Byeong-Ha
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • 제2권1호
    • /
    • pp.41-48
    • /
    • 2002
  • This paper presents a 18-mW, 2.5-㎓ fractional-N frequency synthesizer with l-bit $4^{th}$-order interpolative delta-sigma ($\Delta{\;}$\sum$)modulator to suppress fractional spurious tones while reducing in-band phase noise. A fractional-N frequency synthesizer with a quadruple prescaler has been designed and implemented in a $0.5-\mu\textrm{m}$ 15-GHz $f_t$ BiCMOS. Synthesizing 2.1 GHzwith less than 200 Hz resolution, it exhibits an in-band phase noise of less than -85 dBc/Hz at 1 KHz offset frequency with a reference spur of -85 dBc and no fractional spurs. The synthesizer also shows phase noise of -139 dBc/Hz at an offset frequency of 1.2 MHz from a 2.1GHz center frequency.

3권선 변압기 순환전류 추정 알고리즘 (Estimation of a circulating current of a three-phase Y-Y-$\Delta$ transformer)

  • 강용철;이미선;이병은;장성일;김용균
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2007년도 제38회 하계학술대회
    • /
    • pp.559-560
    • /
    • 2007
  • In the case of the transformers including the delta winding such as a three-phase Y-Y-$\Delta$ transformer, a delta winding current flows in the delta windings. The delta winding current of a three-phase Y-Y-$\Delta$ transformer is decomposed into a non-circulating current and a circulating current. The former can be estimated directly from the line currents, but the latter can not. This paper proposes an estimation method for a circulating current of a Y-Y-$\Delta$ Transformer. A first order differential equation for the circulating current is derived by applying the Kirchhoff's voltage law on the loop of the delta side. The circulating current can be estimated by solving the differential equation. Various test results indicate the algorithm can estimate the circulating current accurately even under over-excitation and magnetic inrush.

  • PDF