• Title/Summary/Keyword: ${\alpha}-chlorosulfoxide$

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Synthetic Studies Related to Antibiotics Containing Higher-carbon Sugars

  • Kim, Kwan-Soo
    • Korean Journal of Pharmacognosy
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    • v.16 no.4
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    • pp.239-242
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    • 1985
  • The anion of $6-benzenesulfonyl-3-O-benzyl-6-deoxy-1,2-O-isopropylidene-{\alpha}-d-glucofuranose$ was stable and reacted with carbon electrophiles to give higher-carbon sugars. Reactions of uridine 5'-aldehyde with phosphoranes afforded heptofuranose nucleosides.

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