• Journal of Korea Foundry Society
• /
• v.29 no.4
• /
• pp.169-175
• /
• 2009

Effect of iron and manganese contents on die soldering reaction has been studied in Al-9wt.%Si-0.3wt.%Mg alloy. Ternary ${\alpha}_{hcp}-Al_8Fe_2Si$ and ${\alpha}_{bcc}-Al_8Fe_2Si$ intermetallic compounds formed by interaction diffusion between Al-Si-Mg system alloy melt and SKD61 die steel surface. Thickness of soldering reaction layer in die steel surface decreased as Fe and Mn contents of the melts increased : When Fe content of Al-9wt.%Si-0.3wt.%Mg melts at constant 0.5wt%Mn content was 0.15wt.%, 0.45wt.% and 0.6wt.%, thickness of soldered layer of each alloy was $64.5{\mu}m,\;57.3{\mu}m$ and $46.9{\mu}m$ respectively. For Mn content of the alloy melts at constant 0.45wt.%Fe content was 0.30wt.%, 0.50wt.% and 0.70wt.%, thickness of soldered layer of each alloy was $66.1{\mu}m,\;57.3{\mu}m$ and $48.3{\mu}m$ respectively.

• Journal of the Korean Society for Heat Treatment
• /
• v.14 no.3
• /
• pp.160-166
• /
• 2001

The change of ribbon geometry, microstructure and shape recovery with Mn contents, wheel speed and various annealing temperature have been studied in Fe-X%Mn-5Cr-5Co-4Si (X%=15, 20, 24) shape memory alloy (SMA) ribbons rapidly solidfied by single roll chill-block melt-spinning process. The thickness and width of melt-spun ribbons are reduced, results in refining and uniformalizing grains with increasing wheel speed. In the ribbons melt-spun at a wheel speed of 15m/sec, both ${\varepsilon}$ and ${\alpha}^{\prime}$martensites are formed in ribbon 1 (15.5wt%Mn), while only ${\varepsilon}$ martensite is revealed in ribbon 2 (20.2wt%Mn) and ribbon 3 (23.5wt%Mn). The volume fraction of ${\varepsilon}$ martensite is decreased with increasing Mn contents, and those of ${\varepsilon}$ as well ${\alpha}^{\prime}$martensites are increased due to thermal stress relief and grain growth with increasing annealing temperature. Ms temperatures of the ribbons 1, 2 and 3 are fallen with increasing Mn contents. $M_s$ temperatures of the ribbons 1, 2 and 3 annealed at $300^{\circ}C$ for 3 min are risen abruptly, but are nearly constant even at higher annealing temperature, i.e., 400, 500 and $600^{\circ}C$ for 3 min. Shape recovery of the ribbons 1, 2 and 3 increased 30%, 52% and 69% with Mn contents, respectively. Shape recovery of ribbon 1 (15.5wt%Mn) formed ${\varepsilon}$ and ${\alpha}^{\prime}$martensites decreased because of the presence of ${\alpha}^{\prime}$martensite but those of ribbon 2 (20.2wt%Mn) and ribbon 3 (23.5wt%Mn) formed ${\varepsilon}$ martensite increased with increasing annealing temperature.

• Journal of the Korean Society for Heat Treatment
• /
• v.13 no.3
• /
• pp.158-162
• /
• 2000

The high temperature oxidation behavior and the surface defect in Fe-25Mn-1.5A1-0.5C steel was investigated by XRD (X-ray Diffractin) and electron microscopy. The intra- and inter-granular oxides were formed by the selective oxidation of manganese and aluminum, which were identified to MnAl2O4 phase. Aluminum nitride (AlN) was formed in front of these oxides. The ${\gamma}$-matrix was transformed to ${\alpha}$- and ${\varepsilon}$- phases by the selective oxidation of manganese. The surface defect, micro-scab was induced by the difference of the high temperature ductility between the matrix and the inter-granular oxide.

• Journal of the Korean Magnetics Society
• /
• v.3 no.1
• /
• pp.7-12
• /
• 1993

The effects of Mn, Cr or Co addItion on the magnetic properties of Fe-Ni Invar alloys were investigated. The composition range of the three additives is up to 5wt%. In the temperature range of room temperature-$250^{\circ}C$, the variation of specific magnetization with the addition of Mn, Cr or Co in the Fe-Ni alloys except for 5wt% Co shows the phenomenon characteristics of the Invar effect, viz., the specific magnetization decreases very abrubtly with the temperature and the dependence of temperature on the specific magnetization is in the mixed form of $T^{3/2}$ and $T^{2}$. In the room temperature, the amount of increase in the specific magnetization, Curie temperature and coercivity is in order of Co > Cr > Mn. In the case of 5wt% Co an anomalous phenomena were observed due to the occurrance of ferromagnetic $\alpha$ phase which reduces the invar effect.

• Korean Journal of Materials Research
• /
• v.28 no.10
• /
• pp.583-589
• /
• 2018

This study investigates the effect of fatigue stress on the damping capacity in a damaged Fe-22Mn-12Cr-3Ni-2Si-4Co damping alloy under fatigue stress. ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ forms by fatigue stress in the damaged Fe-22Mn-12Cr-3Ni-2Si4-Co damping alloy under fatigue stress. The ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ forms with the specific direction and surface relief, or they cross each other. With an increasing fatigue stress, the volume fraction of ${\alpha}^{\prime}-martensite$ and ${\varepsilon}-martensite$ increases. With an increasing fatigue stress, the damping capacity increases with an increase in the volume fraction of ${\varepsilon}-martensite$. The increase in the damping capacity in the damaged Fe-22Mn-12Cr-3Ni-2Si-4Co alloy under fatigue stress strongly affects the increase of ${\varepsilon}-martensite$ formed by fatigue stress, but the damping capacity of the damaged Fe-22Mn-12Cr-3Ni-2Si-4Co damping alloy under fatigue stress is strongly controlled by a large amount of ${\alpha}^{\prime}-martensite$.

• Korean Journal of Materials Research
• /
• v.12 no.7
• /
• pp.550-554
• /
• 2002

The effect of Mn on cavitation erosion resistance and the sliding wear resistance of Fe-base hardfacing NewAlloy was investigated. Mn is known to decrease stacking fault energy and enhance the formation of $\varepsilon$-martensite. Cavitation erosion resistance for 50 hours and sliding wear resistance for 100 cycles were evaluated by weight loss. Fe-base hardfacing NewAlloy showed more excellent cavitation erosion resistance than Mn-added NewAlloys. $\Upsilon-\alpha$' phase transformation that can enhance erosion resistance by matrix hardening occurred in every specimens. But, only in Mn free Fe-base hardfacing NewAlloy, the hardened matrix could repress the propagation of cracks that was initialed at the matrix-carbides interfaces more effectively than Mn-added NewAlloy The Mn free Fe-base hardfacing NewAlloy showed better sliding wear resistance than Mn-added alloys. Mn-addition up to 5wt.% couldn't increase the sliding wear and cavitation erosion resistance of Fe-base hardfacing alloy because it didn't make $\Upsilon\to\varepsilon$ martensite phase transformation. Therefore, it is considered that the cavitation erosion and the sliding wear resistance can be improved due to $\Upsilon\to\varepsilon$ martensite phase transformation when Mn is added more than 5wt.% in Fe-base hardfacing alloys.

• Journal of Magnetics
• /
• v.18 no.3
• /
• pp.245-249
• /
• 2013

A finite element model was built for MnBi/${\alpha}$-Fe nanocomposite permanent magnets, and the demagnetization curves of the magnets were simulated by micro-magnetic calculation. The microstructure of the cubic model is composed of 64 irregular grains with an average grain size of 20 nm. With the volume fraction of soft magnetic phase (t vol. %) ranged from 5 to 20 vol. %, both isotropic and anisotropic nanocomposite magnets show typical single-phase permanent magnets behavior in their demagnetization curves, illustrating good intergranular exchange coupling effect between soft and hard magnetic phases. With the increase of volume fraction of soft magnetic phase in both isotropic and anisotropic magnets, the coercive force of the magnets decreases monotonically, while the remanence rises at first to a peak value, then decreases. The optimal values of maximum energy products of isotropic and anisotropic magnets are 84 and $200kJ/m^3$, respectively. Our simulation shows that the MnBi/${\alpha}$-Fe nanocomposite permanent magnets own excellent magnetic properties and therefore good potential for practical applications.

• Korean Journal of Materials Research
• /
• v.26 no.9
• /
• pp.493-497
• /
• 2016

This study was carried out to investigate the effect of deformation induced martensite on the damping capacity of Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}$-martensite were formed by cold working, and; deformation induced martensite was formed with according to the specific direction and the surface relief. With an increasing degree of cold rolling, the volume fraction of ${\alpha}^{\prime}$-martensite increased rapidly, while the volume fraction of ${\varepsilon}$-martensite decreased after rising to a maximum value at a specific level of cold rolling. Damping capacity was increased, and then decreased with an increasing of the degree of cold rolling. Damping capacity was influenced greatly by the volume fraction of ${\varepsilon}$-martensite formed by cold working, but the effect of the volume fraction of ${\alpha}^{\prime}$-martensite have a actually on effect on the damping capacity.

• Journal of Power System Engineering
• /
• v.20 no.6
• /
• pp.46-50
• /
• 2016

This study was carried out to investigate the effect of cold working on the tensile strength of Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}$-martensite were formed by cold working, and martensite was formed with the specific direction and surface relief. With the increasing degree of cold rolling, volume fraction of ${\alpha}^{\prime}$-martensite was increased, whereas the volume fraction of ${\varepsilon}$-martensite was decreased after rising to maximum value at specific lever of cold rolling. Tensile strength was linearly increased with an increasing of degree of cold rolling. Tensile strength was strongly affected to the volume fraction of ${\varepsilon}$-martensite formed by cold working, but the effect of volume fraction of ${\varepsilon}$-martensite on the tensile strength was not observed.

• Journal of the Korean Society for Heat Treatment
• /
• v.32 no.2
• /
• pp.61-67
• /
• 2019

This study was carried out to investigate the effect of thermo-mechanical treatment on the tensile properties of Fe-20Mn-12Cr-3Ni-3Si alloy with deformation induced martensite transformation. ${\alpha}^{\prime}$ and ${\varepsilon}$-martensite, dislocation, stacking fault were formed, and grain size was refined by thermo-mechanical treatment. With the increasing cycle number of thermo-mechanical treatment, volume fraction of ${\varepsilon}$ and ${\alpha}^{\prime}$-martensite, dislocation, stacking fault were increased, and grain size decreased. In 5-cycle number thermo-mechanical treated specimens, more than 10% of the volume fraction of ${\varepsilon}$-martensite and less than 3% of the volume fraction of ${\alpha}^{\prime}$-martensite were attained. Tensile strength was increased and elongation was decreased with the increasing cycle number of thermo-mechanical treatment. Tensile properties of thermo-mechanical treated alloy with deformation induced martensite transformation was affected to formation of martensite by thermo-mechanical treatment, but was large affected to increasing of dislocation and grain refining.