• Title/Summary/Keyword: ${\alpha}$-Fe/oxide

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Corrosion Control in Water Distribution System using Lime and Carbon Dioxide(II) - Evaluation on the Characteristics of Corrosion as a Function of Pipe Material (소석회와 CO2를 이용한 상수관로의 부식제어(II) - 관종별 부식특성 평가)

  • Lee, Doo-Jin;Kim, Young-Il;Song, Young-Il;Park, Hyun-A
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.379-387
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    • 2008
  • The pH & alkalinity adjustment method by lime and carbon dioxide($CO_2$) for corrosion control in water distribution system was investigated to evaluate the corrosion characteristics of metal pipes, such as galvanized iron, copper, stainless steel, and carbon steel. When the pH in sand filtered and ozone+GAC treated water was increased with lime and $CO_2$ from 7.5 to 8.0, the concentration of residual chlorine decreased at higher pH and longer reaction time; the concentration of trihalomethane increased. The corrosion rate of coupons with corrosion control using lime and carbon dioxide was showed much smaller than those without corrosion control using pilot-scale simulated distribution system. The galvanized iron was corroded much faster than carbon steel, copper, and stainless steel. Especially, copper and stainless steel coupons were hardly corroded. The galvanized iron and carbon steel coupons with corrosion control were produced the corrosion products less than those without corrosion control by the results of environmental scanning electron microscope(ESEM) and energy dispersive x-ray spectroscopy(EDS) analyses. The galvanized iron coupon with pH and alkalinity adjustment by lime and carbon dioxide was detected about 30 percent of zinc, when the carbon steel was detected about 30 percent of calcium by calcium carbonate products formation. For the results of X-ray diffraction(XRD) analyses, the goethite(${\alpha}$-FeOOH) was identified as primary corrosion product of galvanized iron without corrosion control, while the Zinc oxide(ZnO) was found on corrosion products of galvanized iron coupon with corrosion control as the results of EDS analyses. However, the carbon steel corrosion products regardless of corrosion control were composed predominantly of maghemite(${\gamma}-Fe_2O_3$) and hematite(${\alpha}-Fe_2O_3$).

Biological Activities of Polysaccharide Extracted from the Fruit Body and Cultured Mycelia of Phellinus linteus IY001 (목질진흙버섯 자실체와 배양 균사체 유래 ${\beta}-Glucan$성 다당류의 생리활성)

  • Lee, June-Woo;Baek, Sung-Jin;Bang, Kwang-Woong;Kang, Shin-Wook;Kang, Sang-Mo;Kim, Byung-Yong;Ha, Ick-Su
    • Korean Journal of Food Science and Technology
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    • v.32 no.3
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    • pp.726-735
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    • 2000
  • This study was conducted to investigate the biological activities of polysaccharide extracted from the fruit body and cultured mycelia of Phellinus linteus IY001. All fractions were extracted by hot water, in the next, Fr. I, Fr. II, Fr. III and Fr. IV were polysaccharide obtained by ethanol precipitation or ultrafiltration. The highest antitumor activity against sarcoma 180 in ICR mice was observed in Fr. III and Fr. IV at the level 85%, but the antitumor activity had no connection with their anticomplementary activity in vitro, it might probably be due to extraction of hot water. All fractions promoted the production of nitric oxide and $TNF-{\alpha}$ in macrophage, addition of Fr. I and Fr. II resulted in production of nitric oxide$3(5.9{\sim}37.6\;{\mu}M)$ and of the $TNF-{\alpha}$ production($8,696.2{\sim}9,420pg/ml)$. All fractions inhibited the lipid peroxidation induced by $AsA/Fe^{2+}$, $ADP/NADPH/Fe^{3+}\;and\;CCl_4/NADPH$ in rat liver microsomes, and Fr. III showed the electron donating ability stronger than tocopherol in assay system using DPPH. From these results, it is suggested that all fractions contain immunoregulatory components which may protect cellular materials from the oxidative damages by their radical scavenging activities.

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Properties of Oxide Systems for NTC Thermistors (산화물계 NTC 서미스터의 특성)

  • Lee, Sung-Kwan;Lee, Hae-Yon;Lee, Sean-Hag;Her, Jeong-Seob;Kim, Hyun-Sik;Oh, Young-Woo
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1855-1857
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    • 1999
  • $Mn_{1-x}Fe_{2+x}O_4$, $Mg_{1-x}Fe_{2+x}O_4$ (x=0.0, 0.025, 0.1, 0.2) for negative temperature coefficient (NTC) thermistor were prepared by calcining at $800^{\circ}C$ and sintering from 1100 to $1250^{\circ}C$ with $50^{\circ}C$ intervals. The best linear property was obtained in the Mn-based sample sintered at $1200^{\circ}C$ with x=0.0 composition. Temperature coefficient of resistance, $\alpha$, was -3.0 %/$^{\circ}C$ in the Mg-based sample at $25^{\circ}C$. Thermistor parameter, B, was in the range of 2500 [K] $\sim$7400 [K]. The results show the possibility that Mn-Ni-Co based thermistor could be substituted by the composition used in this study.

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Dispersion Stability of Pigments in Aqueous Solution of Anionic Oligo-Type Surfactants(Parts 2) - Dispersion of Red Iron Oxide or Titanium Dioxide - (올리고머형 음이온성 계면활성제 수용액에서 안료의 분산안정성(제2보) - 산화철이나 산화티티늄의 분산 -)

  • Lee, Hyang Woo;Lee, Jin Hee;Park, Heung Joe;Nam, Ki Dae
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.1-5
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    • 1999
  • The dispersing performance of oligomer-type anionic surfactants ($C_mD-Na$), cooligomers of diethylester maleate and alkylvinylether of different alkyl chain lengths or polymerization degree were studied on the aqueous suspension of iron dxide or titanium dioxide particles which are hydrophilic pigments. The dispersion behavior of oligomer-type surfactants for these dispersoids, although anion charges on the surface of pigments particles showed different dispersing properties, was dependent upon the side alkyl chain length. Oligomer-type surfactants having more than $C_8$ side alkyl chain exhibited large dispersing action for relatively hydrophobic ${\alpha}-Fe_2O_3$ and Anatase $TiO_2$ in the concentration range of more than 0.1% oligomer-type surfactant solutions.

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Al-hot Dipping Followed by High-Temperature Corrosion of Carbon Steels in Air and Ar-0.2%SO2 Gas

  • Abro, Muhammad Ali;Jung, Seung Boo;Lee, Dong Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.128-129
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    • 2015
  • Al-rich coatings were prepared on hot rolled low carbon steel by hot dipping method in molten Al-bath to investigate the corrosion resistance with the possible outcomes and defects of aluminized coatings in air and $Ar-0.2%SO_2$ mixed gases. Coating microstructure was composed of an inner Al-Fe intermetallic layer and outer Al-rich layer. Aluminum oxidized preferentially to the thin, outer, protective ${\alpha}-Al_2O_3$ layer, without forming the nonprotective iron/sulfur-oxide layer after heating at $800^{\circ}C$ for 20 h, in both the gases and provided the resistance against corrosion.

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Al-hot Dipping Followed by High-Temperature Corrosion of Carbon Steels in Air and Ar-0.2%SO2 Gas

  • Kim, Min-Jeong;abro, Muhammad Ali;Park, Sang-Hwan;Ji, Gwon-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.122-122
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    • 2015
  • Al-rich coatings were prepared on hot rolled low carbon steel by hot dipping method in molten Al-bath to investigate the corrosion resistance with the possible outcomes and defects of aluminized coatings in air and $Ar-0.2%SO_2$ mixed gases. Coating microstructure was composed of an inner Al-Fe intermetallic layer and outer Al-rich layer. Aluminum oxidized preferentially to the thin, outer, protective ${\alpha}-Al_2O_3$ layer, without forming the nonprotective iron/sulfur-oxide layer after heating at $800^{\circ}C$ for 20h, in both the gases and provided the resistance against corrosion.

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Surface Characteristics of Anodized Ti-3wt%, 20wt%, and 40wt%Nb Alloys

  • Ko, Y.M.;Choe, H.C.;Jang, S.H.;Kim, T.H.
    • Corrosion Science and Technology
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    • v.8 no.4
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    • pp.143-147
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    • 2009
  • In biomedical implants and dental fields, titanium has been widely utilized for excellent corrosion resistance and biocompatibility. However, Ti and its alloys are nonbioactive after being implanted in bone. In this study, for the purpose of improvement in biocompatibility the anodic $TiO_2$ layer on Ti-xNb alloys were fabricated by electrochemical method in phosphate solution, and the effect of Nb content on the pore size, the morphology and crystallinity of Ti oxide layer formed by the anodic oxidation method was investigated. The Ti containing Nb up to 3 wt%, 20 wt% and 40 wt% were melted by using a vacuum furnace. The sample were cut, polished, and homogenized for 24 hr at $1050^{\circ}C$ for surface roughness test and anodizing. Titanium anodic layer was formed on the specimen surface in an electrolytic solution of 1 M phosphoric acid at constant current densities ($30mA/cm^2$) by anodizing method. Microstructural morphology, crystallinity, composition, and surface roughness of oxide layer were observed by FE-SEM, XRD, EDS, and roughness tester, respectively. The structure of alloy was changed from $\alpha$-phase to $\beta$-phase with increase of Nb content. From XRD results, the structure of $TiO_2$ formed on the Ti-xNb surface was anatase, and no peaks of $Nb_2O_5$ or other Nb oxide were detected suggesting that Nb atoms are dispersed in $TiO_2$-based solid solution. Surface roughness test and SEM results, pore size formed on surface and surface roughness decreased as Nb content increased. From the line analysis results, intensity of Ti peak was high in the center of pore, whereas, intensity of O peak was high in the outside of pore center.

Microstructural Investigations of $Al_2O_3$ Scale Formed on FeCrAl Steel during High Temperature Oxidation in $SO_2$

  • Homa, M.;Zurek, Z.;Morgiel, B.;Zieba, P.;Wojewoda, J.
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.139-144
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    • 2008
  • The results of microstructure observations of the $Al_2O_3$ scale formed on a Fe-Cr-Al steel during high temperature oxidation in the $SO_2$ atmosphere are presented. Morphology of the scale has been studied by SEM and TEM techniques. Phase and chemical compositions have been studied by EDX and XRD techniques. The alumina oxide is a primary component of the scale. TEM observations showed that the scale was multilayer. The entire surface of the scale is covered with "whiskers", which look like very thin platelets and have random orientation. The cross section of a sample shows, that the "whiskers" are approximately $2{\mu}m$ high, however the compact scale layer on which they reside is $0.2{\mu}m$ thick. The scale layer was composed mainly of small equiaxial grains and a residual amount of small columnar grains. EDX analysis of the scale surface showed that the any sulfides were found in the formed outer and thin inner scale layer. A phase analysis of the scale formed revealed that it is composed mainly of the $\theta-Al_2O_3$ phase and a residual amount of $\alpha-Al_2O_3$.

Recovery of $\alpha$-iron from converter dust in a steel making factory -Utilization of the converter dust in a steel making factory- (제장소 전노 dust로부터 $\alpha$-장분말 회수에 관한 연구(II) -전노 dust의 이용에 관한 연구-)

  • Kim, Mi-Sung;Kim, Mahn;Cho, Moung-Ho;Oh, Jae-Hyun;Kim, Tae-Dong;Kim, Sung-Wan
    • Resources Recycling
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    • v.3 no.2
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    • pp.9-16
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    • 1994
  • In this study, the grinding and wet cyclone process of the dust for the effective separation of high purity iron powder and iron oxide were investigated. The results obtained in this study can be summarized as follows: 1. By applying the wet cyclone technique for the iron powder(+200 mesh) produced from EC dust of the Kwangyang 2nd steel making factory, the iron powder of high content more than 99.76% of Fe was obtained with 47.66% yield at grinding time of 5 minutes by attritor. 2. The particle size distribution of the iron powder recovered from converter dust is quite simillar with the iron powder of sweden Hoganas Co.(W40.24, W40.29, W40.37, W40.37OX). 3. By using iron powder, copper ions are all adsorbed and removed in any concentration ranges of copper sulfate solution(Cu:100, 200, 300, 600 ppm).

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Effect of a Combined Extract of Orostachys japonicus with Medicinal Plants on the Lipid Composition of the Liver and Kidney from Streptozotocin-induced Diabetic Rats (와송과 생약재 복합물이 Streptozotocin 유발 당뇨쥐의 간장 및 신장 조직의 지질성분에 미치는 영향)

  • Shin, Jung-Hye;Lee, Soo-Jung;Seo, Jong-Kwon;Lee, Hyun-Ju;Ju, Jong-Chan;Sung, Nak-Ju
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.4
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    • pp.510-518
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    • 2012
  • This study examined the biological activity and synergistic effects of an extract of Wa-song ($Orostachys$ $japonicus$, OE), a medicinal plant mixture (MPE) and a combination of both at different ratios (1:1, OMPE-1 and 3:1, OMPE-3). Extracts of the medicinal plants mixture were comprised of Baekbokyung, Changchul and Sa-in at the same ratio. The antioxidant activity of the extracts and their complex were tested $in$ $vitro$. The $in$ $vivo$ antioxidant activity was also analyzed by examining the lipid composition in the liver and kidney of streptozotocin (STZ)-induced diabetes rats. The nitric oxide radical scavenging activity was more than 50% in OMPE-3 at a 1,000 ${\mu}g$/mL concentration. Regarding metal ions, such as $Fe^{2+}$ and $Cu^{2+}$, the antioxidant activity of OMPE-1 and OMPE-3 was higher than that of OE and MPE. OMPE-1 and 3 had higher activity on $Cu^{2+}$ ions than $Fe^{2+}$ ions. The ${\alpha}$-glucosidase inhibition activity of the OE extract was higher than that of MPE and OMPE-1 but the relative activity of OMPE-3 was significantly higher than the others. Freeze-dried MPE, OMPE-1 and OMPE-3 were added to the diet at a level of 1% given to STZ induced diabetes rats for 4 weeks. The OMPE-1 and OMPE-3 administered groups showed significant decreases in the total lipid, total cholesterol and triglyceride levels in the liver and kidney. In these groups, the glycogen accumulation level of the liver was increased significantly. The content of thiobarbituric acid reactive substances (TBARS) in the liver and kidney was decreased but the DPPH radical scavenging activity was increased. These results suggest that Wa-song extract exhibits antioxidant and antidiabetic activity, which are enhanced by a complex with a medical plants extract.