• Title/Summary/Keyword: $^7Li$

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A Study on the Integrated-Optical Electric-Field Sensor utilizing Ti:LiNbO3 Y-fed Balanced-Bridge Mach-Zehnder Interferometric Modulators (Ti:LiNbO3 Y-fed Balanced-Bridge 마하젠더 간섭 광변조기를 이용한 집적광학 전계센서에 관한 연구)

  • Jung, Hongsik
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.1
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    • pp.29-35
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    • 2016
  • We have demonstrated a $Ti:LiNbO_3$ electro-optic electric-field sensors utilizing a $1{\times}2$ Y-fed balanced-bridge Mach-Zehnder interferometric (YBB-MZI) modulator which uses a 3-dB directional coupler at the output and dipole patch antenna. The operation and design were proved by the BPM simulation. A dc switching voltage of ~16.6 V and an extinction ratio of ~14.7 dB are observed at a wavelength of $1.3{\mu}m$. For a 20 dBm rf power, the minimum detectable electric-fields are ~1.12 V/m and ~3.3 V/m corresponding to a dynamic range of about ~22 dB and ~18 dB at frequencies 10 MHz and 50 MHz, respectively. The sensors exhibit almost linear response for the applied electric-field intensity from 0.29 V/m to 29.8 V/m.

A Study on the Application of Green LiDAR Using Automatic River Water Quality Data (하천 수질자동측정 자료를 활용한 Green LiDAR 적용성 검토)

  • Kim, Chang Sung;Kim, Tae-Jeong;Kim, Ji Sung
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.232-232
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    • 2020
  • 하천기본계획 수립이나 생태하천 조성사업 등 다양한 하천사업에서 하천측량은 대상 하천의 지형 현황과 과거 사업이후의 변화량을 확인할 수 있는 중요한 요소이다. 국내 측량 기준인 공공측량작업규정(국토지리정보원)에서 하천 측량은 육지부에서는 횡단측량을 수부에서는 수심측량을 실시하고 수심측량은 음향측심기 사용을 원칙으로 한다. 국내 대부분의 수심측량은 단빔 음향측심기를 사용하고 있는 실정이며 일부 수심 확보 구간 또는 연구목적으로 멀티빔 음향측심기를 적용한 사례가 일부 보고된 바가 있다. 최근 수심측정이 가능한 항공수심측량(Airbone LiDAR Bathymetry) 장비 중 핵심계측기기인 Green LiDAR 센서 국산화 및 경량화에 관한 연구가 진행중이다. 이에 본 연구는 국내 하천 여건에서 개발 센서가 어느 정도의 활용성을 확보할 수 있는지를 검토하였다. 우선 환경부가 운영중인 수질자동측정망 71개 지점의 정기측정성과 중 탁도에 관한 일자료를 확보가 가능한 45개 지점을 대상으로 G-LiDAR 센서의 SD(Secchi Depth)를 기준으로 가용계측일을 산정해 보았다. 분석기간은 '12. 7.부터 '19.12.까지이며 분석기간중 SD 1.5m(1.94 NTU 추정) 기준을 만족하는 기간은 한강 2.07년, 낙동강 0.64년, 금강 2.21년, 영산강 2.71년으로 나타났다. 또한 지점별 가용기간 분석결과 분석기간인 7.33년 동안 탁도 기준이하인 운영 가능 기간은 연중 평균 80여일(2.74개월)로 나타나 제한적이나마 활용이 가능할 것으로 확인되었다. 향후 현장조사를 통해 공공측량 성과와 대상수계의 탁도 실측자료와의 연계분석을 통해 정확한 활용성 검토를 수행할 예정이다. 향후 적용 센서의 개발 성능목표를 달성한다면 하천내의 다양한 분야에서 활용이 가능할 것으로 기대된다.

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Determination of Acceptor Concentration by Use of Recording Dynamics of Photorefractive Holograms Under Low-Intensity Condition in LiNbO3

  • Rhee, Bum-Ku;Kim, Bong-Gi;Shin, Seung-Ho
    • Journal of the Optical Society of Korea
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    • v.7 no.3
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    • pp.197-201
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    • 2003
  • We investigated recording dynamics of a holographic grating in the photorefractive LiNbO$_3$ crystal under the low-intensity condition of recording beams. New expressions for the space-charge field and the recording time constant were obtained by solving the Kukhtarev equations under the global space -charge field, which is induced in the previous process of recording and erasing. Their validity can be confirmed by considering the limit that the period of the grating goes to infinity both theoretically and experimentally. It was found that the new expression for the recording time constant allows us to determine acceptor concentration to be $1.2${\times}$10^{21}m^{-3}$ for pure LiNbO$_3$ crystal and 2.5${\times}$$10^{21}m^{-3}$ for the 0.1 mol% iron doped LiNbO$_3$ crystal from the measured ratio of the recording time constant under the extremely large grating condition, in which the diffusion effect can be neglected, to that under the small grating condition.

Lithium/Sulfur Secondary Batteries: A Review

  • Zhao, Xiaohui;Cheruvally, Gouri;Kim, Changhyeon;Cho, Kwon-Koo;Ahn, Hyo-Jun;Kim, Ki-Won;Ahn, Jou-Hyeon
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.97-114
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    • 2016
  • Lithium batteries based on elemental sulfur as the cathode-active material capture great attraction due to the high theoretical capacity, easy availability, low cost and non-toxicity of sulfur. Although lithium/sulfur (Li/S) primary cells were known much earlier, the interest in developing Li/S secondary batteries that can deliver high energy and high power was actively pursued since early 1990’s. A lot of technical challenges including the low conductivity of sulfur, dissolution of sulfur-reduction products in the electrolyte leading to their migration away from the cathode, and deposition of solid reaction products on cathode matrix had to be tackled to realize a high and stable performance from rechargeable Li/S cells. This article presents briefly an overview of the studies pertaining to the different aspects of Li/S batteries including those that deal with the sulfur electrode, electrolytes, lithium anode and configuration of the batteries.

Lithium-silicate coating on Lithium Nickel Manganese Oxide (LiNi0.7Mn0.3O2) with a Layered Structure

  • Kim, Dong-jin;Yoon, Da-ye;Kim, Woo-byoung;Lee, Jae-won
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.87-95
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    • 2017
  • Lithium silicate, a lithium-ion conducting ceramic, is coated on a layer-structured lithium nickel manganese oxide ($LiNi_{0.7}Mn_{0.3}O_2$). Residual lithium compounds ($Li_2CO_3$ and LiOH) on the surface of the cathode material and $SiO_2$ derived from tetraethylorthosilicate are used as lithium and silicon sources, respectively. Powder X-ray diffraction and scanning electron microscopy with energy-dispersive spectroscopy analyses show that lithium silicate is coated uniformly on the cathode particles. Charge and discharge tests of the samples show that the coating can enhance the rate capability and cycle life performance. The improvements are attributed to the reduced interfacial resistance originating from suppression of solid-electrolyte interface (SEI) formation and dissolution of Ni and Mn due to the coating. An X-ray photoelectron spectroscopy study of the cycled electrodes shows that nickel oxide and manganese oxide particles are formed on the surface of the electrode and that greater decomposition of the electrolyte occurs for the bare sample, which confirms the assumption that SEI formation and Ni and Mn dissolution can be reduced using the coating process.

Structural and Magnetic Studies on Electrochemically Lithiated $PrBa_2Cu_3O_y$

  • Choy, Jin-Ho;Chun, Sung-Ho;Kang, Seong-Gu
    • Bulletin of the Korean Chemical Society
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    • v.11 no.6
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    • pp.564-567
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    • 1990
  • A lithiated compound $Li_{0.1}Pr^{3+}Ba_2Cu_3O_y$ has been successfully prepared by electrochemical method, which is achieved with a two electrode cell of the type: Metal(Li)/($Li^+\;,\;ClO_4^-$) + propylene carbonate/$PrBa_2Cu_3O_y$. All Pr ions in the lithiated compound are stabilized with a trivalent state as the other rare earths (Ⅲ) substituted in the 90K superconductor lattice ($Y_{1-x}Ln_x^-Ba_2Cu_3O_{7-{\delta}}$). Powder X-ray diffraction analysis shows that both compounds, $PrBa_2Cu_3O_y$ and $Li_{0.1}PrBa_2Cu_3O_y$ are isostructural with the 90 K superconductor, ($YBa_2Cu_3O_{7-{\delta}}$), nevertheless both of them are non-metallic and also non-superconducting down to 10 K. Magnetic susceptibility ${\chi}$ vs. temperature data indicate that Curie contribution from the magnetic ions (Pr and Cu) is weakened on the one hand, but on the other hand temperature-independent part of susceptibility ${\chi}_o$ increases depending upon the rate of lithium intercalation in $PrBa_2Cu_3O_y$ lattice.

2×2 Ti:LiNbO3 optical add/drop multiplexers utilizing tilted film-loaded SAW waveguides (Tilted Film-Leaded SAW 도파로를 이용한 2×2 Ti:LiNbO3 광 삽입/분기 멀티플렉서)

  • 강창민;정흥식
    • Korean Journal of Optics and Photonics
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    • v.14 no.6
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    • pp.657-662
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    • 2003
  • Optimum Hamming apodized acousto-optic 2${\times}$2 add/drop multiplexers, using SiO$_2$ film loaded acoustic waveguide with angular offset to the Ti:LiNbO$_3$ waveguide, were fabricated. The four-port device consists of two input waveguides, a polarization beam splitter (PBS), two polarization conversion/acoustooptic tuning waveguide sections, a second PBS and two output waveguides. Insertion loss <7.1 ㏈ has been obtained and side-lobe of -19 ㏈ for -32 ㎽ RF driving power has been realized. Add/drop performance has been confirmed and a linear tuning rate of 8.1 nm/MHz and a 3 ㏈ spectral width of -1.5 nm were demonstrated.

A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior (리튬이온전지의 유기용매분해에 따른 SEI film 형성과 전기화학적 거동에 관한 연구)

  • Kim, Min-Seong;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.545-549
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    • 2001
  • We have produced electrolyte solution out of 1.15M $LiPF_6$ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M $LiPF_6$ DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M $LiPF_6$ EC/DEC(1/2 by vol%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC,DMC and EMC brought the de-decomposition peak of salt anion of $PF_6$ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. $Li/Li^+$). In addition, a kinetics current peak, in which intercalation of Lt is proceeded at 750mV, 450mV(vs. $Li/Li^+$), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance($R_{ct}$) according to the electric potential of $Li^+$ intercalation at 750mV(vs. $Li/Li^+$), which was the same as the resistance ($R_f$) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance($R_p$) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

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3D Reconstruction of Structure Fusion-Based on UAS and Terrestrial LiDAR (UAS 및 지상 LiDAR 융합기반 건축물의 3D 재현)

  • Han, Seung-Hee;Kang, Joon-Oh;Oh, Seong-Jong;Lee, Yong-Chang
    • Journal of Urban Science
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    • v.7 no.2
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    • pp.53-60
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    • 2018
  • Digital Twin is a technology that creates a photocopy of real-world objects on a computer and analyzes the past and present operational status by fusing the structure, context, and operation of various physical systems with property information, and predicts the future society's countermeasures. In particular, 3D rendering technology (UAS, LiDAR, GNSS, etc.) is a core technology in digital twin. so, the research and application are actively performed in the industry in recent years. However, UAS (Unmanned Aerial System) and LiDAR (Light Detection And Ranging) have to be solved by compensating blind spot which is not reconstructed according to the object shape. In addition, the terrestrial LiDAR can acquire the point cloud of the object more precisely and quickly at a short distance, but a blind spot is generated at the upper part of the object, thereby imposing restrictions on the forward digital twin modeling. The UAS is capable of modeling a specific range of objects with high accuracy by using high resolution images at low altitudes, and has the advantage of generating a high density point group based on SfM (Structure-from-Motion) image analysis technology. However, It is relatively far from the target LiDAR than the terrestrial LiDAR, and it takes time to analyze the image. In particular, it is necessary to reduce the accuracy of the side part and compensate the blind spot. By re-optimizing it after fusion with UAS and Terrestrial LiDAR, the residual error of each modeling method was compensated and the mutual correction result was obtained. The accuracy of fusion-based 3D model is less than 1cm and it is expected to be useful for digital twin construction.

Preparation and characterization of nearly stoichiometric $LiNbO_3$ crystals by VTE method (VTE법에 의한 nearly stoichiometric $LiNbO_3$의 성장 및 특성)

  • 김상수;유동선
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.6-17
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    • 1997
  • Lithium niobate single crystals with various [Li]/[Nb] ratios were grown by the Czochralski method from melts having compositions varing between 48.6 ~ 58.0 mol % $Li_2O$. A vapor transport equilibration technique has been used to improve the homogeneity and adjust the [Li]/[Nb] ratio in small $LiNbO_3$ single crystals grown by the Czochralski method. When equilibrated with a Li-rich powder (65 mol%$Li_2O$), containing a mixture of $LiNbO_3$ and $Li_3NbO_4$, crystals of nearly stoichiometric composition can be obtained. This was established by studying the composition dependence of the following properties; lineshape, intensity and linewidth for the electron paramagnetic resonance (EPR) of $Fe^{3+}$ energy of the fundamental absorption edge and $OH^-$ absorption spectra.

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