• Title/Summary/Keyword: $^7Li$

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Spherical-shaped Zn2SiO4:Mn Phosphor Particles with Gd3+/Li+ Codopant (Gd3+/Li+ 부활성제가 첨가된 구형의 Zn2SiO4:Mn 형광체 입자)

  • Roh, Hyun Sook;Lee, Chang Hee;Yoon, Ho Shin;Kang, Yun Chan;Park, Hee Dong;Park, Seung Bin
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.752-756
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    • 2002
  • Green-emitting $Zn_2SiO_4:Mn$ phosphors for PDP(Plasma Display Panel) application were synthesized by colloidal seed-assisted spray pyrolysis process. The codoping with $Gd^{3+}/Li^+$, which replaces $Si^{4+}$ site in the willemite structure, was performed to improve the luminous properties of the $Zn_2SiO_4:Mn$ phosphors. The particles prepared by spray pyrolysis process using fumed silica colloidal solution had a spherical shape, small particle size, narrow size distribution, and non-aggregation characteristics. The $Gd^{3+}/Li^+$ codoping amount affected the luminous characteristics of $Zn_2SiO_4:Mn$ phosphors. The codoping with proper amounts of $Gd^{3+}/Li^+$ improved both the photoluminescence efficiency and decay time of $Zn_2SiO_4:Mn$ phosphor particles. In spray pyrolysis, the post-treatment temperature is another factor controlling the luminous performance of $Zn_2SiO_4:Mn$ phosphors. The $Zn_{1.9}SiO_4:Mn_{0.1}$ phosphor particles containing 0.1 mol% $Gd^{3+}/Li^+$ co-dopant had a 5% higher PL intensity than the commercial product and 5.7 ms decay time after post-treatment at $1,145^{\circ}C$.

A Study on the Removal of Sulfate in Li2CO3 by Recrystallization (재결정화법을 이용한 탄산리튬 내 황산이온 제거에 관한 연구)

  • Kim, Ki-Hun;Cho, Yeon-Chul;Jang, In-Hwan;Ahn, Jae-Woo
    • Resources Recycling
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    • v.29 no.6
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    • pp.27-34
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    • 2020
  • In order to remove sulfate(SO42-) and purify the Li2CO3, dissolution and recrystallization of crude Li2CO3 using distilled water and HCl solution was performed. When Li2CO3 was dissolved using distilled water, the amount of dissolved Li2CO3(wt.%) increased as the solution temperature decrease and showed about 1.50 wt.% at 2.5℃. In addition, when Na2CO3 was added and the Li2CO3 solution was recrystallized, the recrystallization(%) increased with increasing temperature, resulting in a 49.00 % at 95 ℃. On the other hand, when Li2CO3 was dissolved using HCl solution, there was no effect of reaction temperature. As the concentration of HCl solution increased, the amount of dissolved Li2CO3(wt.%) increased, indicating 7.10 wt.% in 2.0 M HCl solution. When the LiCl solution was recrystallized by adding Na2CO3, it exhibited a recrystallization(%) of 86.10 % at a reaction temperature of 70 ℃, and showed a sulfate ion removal(%) of 96.50 % or more. Finally, more than 99.10 % of Na and more than 99.90 % of sulfate were removed from the recrystallized Li2CO3 powder through water washing, and purified Li2CO3 with a purity of 99.10 % could be recovered.

A Comparative Study of Carbon Absorption Measurement Using Hyperspectral Image and High Density LiDAR Data in Geojedo

  • Choi, Byoung Gil;Na, Young Woo;Shin, Young Seob
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.35 no.4
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    • pp.231-240
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    • 2017
  • This paper aims to study a method to estimate precise carbon absorption by quantification of forest information that uses accurate LiDAR data, hyperspectral image. To estimate precise carbon absorption value by using spatial data, a problem was found out of carbon absorption value estimation method with statistical method, which is already existed method, and then offered optimized carbon absorption estimation method with spatial information by analyzing with methods of compare digital aerial photogrammetry and LiDAR data. It turned out possible Precise classification and quantification in case of using LiDAR and hyperspectral image. Various classification of tree species was possible with use of LiDAR and hyperspectral image. Classification of hyperspectral image was matched in general with field survey and Mahalanobis distance classification method. Precise forest resources could be extracted using high density LiDAR data. Compared with existing method, 19.7% in forest area, 19.2% in total carbon absorption, 0.9% in absorption per unit area of difference created, and improvement was found out to be estimated precisely in international code.

On-line Measurement of $H_2$O/LiBr Concentration using Electric Conductivity (전기 전도도를 이용한 $H_2$O/LiBr 용액의 실시간 농도의 측정)

  • 박찬우;김정환;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.12
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    • pp.1078-1083
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    • 2002
  • The objectives of this paper are to measure the concentration of $H_2$O/LiBr solution by measuring the electrical conductivity and to study the effect of the solution temperature and the concentration on the electrical conductivity of the solution. The solution temperature ranges $20^{\circ},\;40^{\circ},\;and\; 60^{\circ}$ for a fixed concentration during the experiment. The valid ranges of the concentration are two regions, low concentration region (1~20% of LiBr) and high concentration region (55~66% of LiBr). The results show that the conductivity of the solution increases linearly with increasing the solution temperature while it increases without creasing the concentration lower than about 35% of LiBr and decreases with increasing the concentration higher than 35%. This paper proposes experimental correlations for the concentration as functions of the solution temperature and the concentration with error band of $\pm7$% for the low concentration region and $\pm1$% for the high concentration region, respectively. The experimental correlation can be practically used in the on-line measurement without any sampling of solution from the closed system.

전자 주입층 $Li_2CO_3$를 사용한 유기 발광 소자의 특성 변화에 대한 연구

  • Mok, Rang-Kyun;Jang, Kyung-Uk;Lee, Ho-Sik;Chung, Dong-Hoe;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.185-185
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    • 2010
  • 유기 발광 소자에서 $Li_2CO_3$를 전자 주입층으로 사용하여 전류, 전압, 휘도 그리고 수명을 살펴 보았다. 전자 주입층을 사용함으로써 음전극과 전자 수송층 사이의 전자 주입의 에너지 장벽을 낮출 수 있다. 전자 주입층에 Ca, Mg, Li 등과 같은 낮은 일 함수의 금속을 사용하면, 음전극과 유기물층 사이의 효과적인 전자 주입을 도울 수 있다. 소자의 구조는ITO/TPD(40nm)/$Alq_3$(60nm)/$Li_2CO_3$(xnm)/Al(100nm)으로 하였으며, $Li_2CO_3$의 두께를 0.1, 0.2, 0.3, 0.5, 0.7, 0.9, 1.2, l.5nm로 변화시켜 소자를 제작하였다. $Li_2CO_3$의 박막 두께가 0.3nm일 때, 전자 주입층을 사용하지 않은 소자에 비하여 효율은 2.4배 증가하였고, 구동전압은 0.75V 낮아졌다.

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Wet Chemical Preparation of Li-rich LiMn$_2$O$_4$ Spinel by Oxalate Precipitation (Oxalate 침전을 이용한 Li-과량 LiMn$_2$O$_4$ Spinel의 습식합성가 분말 특성)

  • 이병우;김세호
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.698-704
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    • 1999
  • Li rich Li1+xMn2-xO4(x=0.07) spinel powders were prepared by an oxalate precipitation of wet chemical methods at temperature lower than $600^{\circ}C$. The FTIR results showed that the powders prepared at $600^{\circ}C$ had high degree of crystal quality comparing with the spinel powders prepared by solid state reaction at 75$0^{\circ}C$ which was the lowest synthesis temperature of the solid state reaction method. The particle size of powders prepared by the oxalate precipitation at $600^{\circ}C$ was smaller than 0.2${\mu}{\textrm}{m}$ and the specific surface area was 11.01 m2/g A heat treatment over 90$0^{\circ}C$ formed second phase in the precipitates. It was shown that there were phase transitions at temperatures. T1,T2 and T2. The transitions involved weight loss and gain during heating and cooling. The low temperature synthesis below $600^{\circ}C$ avoided the second phase formation and the prepared powders showed improved compositional and physical properties for secondary lithium battery applications.

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Roles of Fundamental and Additional Hardening Precipitates on the Changes of Mechanical Properties and Electrical Resistivity in Al-Li Alloys Containing Cu and Mg (Cu, Mg을 함유한 Al-Li 합금의 기계적 성질과 전기저항 변화에 미치는 기본 및 추가 강화상들의 역할)

  • Chung, D.S.;Song, K.H.;Woo, K.D.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.2
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    • pp.77-87
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    • 1994
  • Roles of fundamental and additional hardening precipitates on the changes of mechanical properties and electrical resistivity during precipitation decomposition in binary Al-Li, ternaty Al-Li-Cu and multi-Li-Cu-Mg-Zr alloys have been investigated by the detailed measurement of electrical resistivity, hardness and tensile strength and the observation of transmission electron micrographs. Peek hardness and tensile strength in multi-component Al-Li-Cu-Mg-Zr Alloy had higher than that of the other alloys and the results of measurement of hardness, strength and electrical resistivity in each alloys aged at 90 and $190^{\circ}C$, precipitation behaviors and mechanical properties in binary, ternary and multi-component Al-Li alloys were contributed to the ${\delta}^{\prime}$ precursory phase of ${\delta}^{\prime}$, $T_1$, G.P.B. zone and S' phases, repectively.

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Optimization of Mg:Ag Cathodes and Effect of LiF Electron Injection Layer on the Characteristics of Top Emission Organic Light Emitting Diodes (전면 유기발광 다이오드 제작시 Mg:Ag 캐소드 최적화 및 LiF 전자주입층 유무에 따른 소자 특성에 관한 연구)

  • Song, Min Seok;Kwon, Sang Jik;Cho, Eou-Sik
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.1
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    • pp.71-74
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    • 2022
  • For the process simplification in the fabrication of organic light emitting diode(OLED), top emission OLED (TEOLED) was fabricated without lithium fluoride(LiF) used as an electron injection layer (EIL). After co-deposition of Mg and Ag with a different process conditions, a cathode material adjacent to EIL was optimized when Mg and Ag have a ratio of 1:9 considering sheet resistance and transmittance. From the energy band diagram of TEOLED, band gap difference between Trisaluminium (Alq3) and Mg:Ag cathode show the difference of 0.4 eV according to the usage of LiF The fabricated TEOLED without LiF showed the improvement of 5.2 % and 2.7 % in the luminance and the current density comparing that with LiF. The results show there is no significant difference in OLED characteristics regardless of LIF layer in the TEOLED structures.

Study of Clinical Research Acupuncture Treatment on Post-stroke Depression (뇌졸중후 우울증 침치료의 임상연구에 대한 고찰)

  • Choi, Ji-Hye;Kim, Lae-Hee;Yun, Jong-Min;Moon, Byung-Soon
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.25 no.6
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    • pp.1119-1128
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    • 2011
  • The aim of this study is to collect and analyze clinical studies on acupuncture therapies of Post-stroke depression, and to suggest a method on study about acupuncture therapies. In this thesis, electronic searches were performed. Also, 6 major journals associated with oriental medicine in Korea were searched manually. Through searching, 27 studies were selected and analyzed. There were 24 controlled studies and 3 non-controlled studies. Treatment methods were acupuncture, electronic-acupuncture, eye-acupuncture, abdominal-acupuncture and pharmaco-puncture. The percentages of these treatment method were 59.2%, 29.6%, 3.7%, 3.7% and 3.7%, respectively. Acupuncture points such as GV20, PC6, ST36, SP6, LV3, GV24, GV26, LI14, LI11, H7, ST40, GB20, GB34 and LI15 were used. In comparison of results before and after acupuncture treatment, there were statistically significant improvement in 26 studies. Based on the results from above, the studies on acupuncture for Post-stroke depression needs to be standardized and more appropriate high-quality study models should be introduced.

Electrolytic Boronzing on TiAl-based Intermetallic Compounds in Fused Salt of Borax, Potassium Chloride and Lithium Chloride Mixture (Na$_2$B$_4$O$_7$-KCl-LiCl 혼합용융욕에서 TiAl계 금속간 화합물의 전해붕화처리)

  • 이두환;김익범;이주호;김수식
    • Journal of the Korean institute of surface engineering
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    • v.31 no.6
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    • pp.359-370
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    • 1998
  • TiAl-based intermetallic compounds were electro-bornizel in the mixture of $Na_2B_4O_7$, KCL and LiCl in the termetature rage between 850 and $1000^{\circ}C$for various times (1-5 hours)under the fixed current density of 0.5 A/$cm^2$. The optimized composition of electrolyte in this work was decided to be 76.9 wt% $Na_2B_4O_7$-19.2 wt.%(0.7KCl-0.3LiCl) -3.9 wt.% al. The samples with boronized layer were investigated by SEM, XRD and EDS. The surface micro-hardness of boronized TiAl was also evaluated using Micro Vickers Hardness Tester. The sample, boronized at $900^{\circ}C$ for 4 hours in the above composition of electrolyte under the current density of 0.5 A/$\textrm{cm}^2$, has about 36$\mu\textrm{m}$ think layer on the surface, and its surface micro-hardness was measured to be 1263 Hv. From the results of SEM, XRD and EDS, the layer consisted of $TiB_2$ sublayer and Al-oxide sub layer. Al-depleted layer below the Al-oxide sudlayer was also detected. The activation energy for formation of boronized layer in this study was calculated as 178 Kcal/moleK.

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