• 콘크리트학회논문집
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• 제16권4호
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• pp.549-555
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• 2004

Cement of three alkalinities (equivalent alkalinities of 0.36,0.52 and 0.97) was employed in fabricating a set of classical G109 type specimens. To-date, these have been subjected to a one week wet-one week dry cyclic pending using 15 w/o NaCl solution. At the end of the dry period, potential and macro-cell current were measured to indicate whether the top reinforcing steel was in the passive or active state. Once this bar became active, the specimen was autopsied and the extent of corrosion was documented. Subsequent to visual inspection, concrete powder samples were collected from the upper region of the top rebar trace; and at a certain times concrete cores were taken from non-reinforced specimens. Using these, determinations were made of (1) critical chloride concentration for corrosion initiation ($Cl_{th}^-$), (2) effective chloride diffusion coefficient ($D_e$), and (3) pore water alkalinity ($[OH^-]$). The pore water alkalinity was strongly related to the alkali content of cement that was used in the mix. The chloride concentration, ($Cl^-$), was greater at active than at passive sites, presumably as a consequence of electro migration and accumulation of these species at active site subsequent to corrosion initiation. Accordingly, ($Cl^-$) at passive sites was considered indicative of the threshold concentration fur corrosion initiation. The $Cl_{th}^-$ was increased with increasing Time-to-corrosion ($T_i$). Consequently, the HA(High Alkalinity) specimens exhibited the highest $Cl_{th}^-$ and the NA(Normal Alkalinity) was the least. This range exceeds what has previously been reported in North America. In addition, the effective diffusion coefficient, $D_e$, was about 40 percent lower for concrete prepared with the HA cement compared to the NA and LA(Low Alkalinity) ones.

• 대한치과교정학회지
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• 제46권2호
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• pp.87-95
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• 2016

Objective: We evaluated the effects of tooth displacement on frictional force when conventional ligating lingual brackets (CL-LBs), CL-LBs with a narrow bracket width, and self-ligating lingual brackets (SL-LBs) were used with initial leveling and alignment wires. Methods: CL-LBs (7th Generation), CL-LBs with a narrow bracket width (STb), and SL-LBs (In-Ovation L) were tested under three tooth displacement conditions: no displacement (control); a 2-mm palatal displacement (PD) of the maxillary right lateral incisor (MXLI); and a 2-mm gingival displacement (GD) of the maxillary right canine (MXC) (nine groups, n = 7 per group). A stereolithographic typodont system and artificial saliva were used. Static and kinetic frictional forces (SFF and KFF, respectively) were measured while drawing a 0.013-inch copper-nickel-titanium archwire through brackets at 0.5 mm/min for 5 minutes at $36.5^{\circ}C$. Results: The In-Ovation L exhibited lower SFF under control conditions and lower KFF under all displacement conditions than the 7th Generation and STb (all p < 0.001). No significant difference in SFF existed between the In-Ovation L and STb for a 2-mm GD of the MXC and 2-mm PD of the MXLI. A 2-mm GD of the MXC produced higher SFF and KFF than a 2-mm PD of the MXLI in all brackets (all p < 0.001). Conclusions: CL-LBs with narrow bracket widths exhibited higher KFF than SL-LBs under tooth displacement conditions. CL-LBs and ligation methods should be developed to produce SFF and KFF as low as those in SL-LBs during the initial and leveling stage.

• Journal of Preventive Medicine and Public Health
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• 제21권2호
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• pp.295-306
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• 1988

Dose-response relationship among blood cadmium concentrations, catalase and superoxide dismutase activities were studied with acutely intoxicated rats by cadmium. The Sprague-Dawley male rats to which single dose of $1{\sim}32mg/kg\;CdCl_2$ were administered into peritoneal cavity were sacrificed by decapitation at $3{\sim}36$ hours after the administration. Cadmium concentrations in blood increased significantly with dose of $CdCl_2$ administered and reached peak level at 3 hours later. Catalase activities in rats' testes were not correlated with esposure time elapsed after the administration in rats to which $1{\sim}2mg/kg\;of\;CdCl_2$ were administered, but they showed linear relationship with time in groups to which $4{\sim}32mg/kg\;of\;CdCl_2$ were administered. Cu, Zn-SOD activities in testes of acutely intoxicated rats by cadmium were not altered either by dosage or by time elapsed after the administration. Mn-SOD activities in the testes were also not influenced by dosage of $1{\sim}2mg/kg\;CdCl_2$, but remarkably inactivated by dosage of $4{\sim}32mg/kg\;CdCl_2$ with time elapsed after the administration. Neither catalase, Cu, Zn-SOD nor Mn-SOD activities of testes were correlated with blood cadmium concentrations in acutely intoxicated rats by cadmium.

• 대한수의학회지
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• 제36권1호
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• pp.75-82
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• 1996

Erythrocyte sedimentation rate is influenced by plasma protein, red cell itself and physiological conditions and it is clear that the measurement of erythrocyte sedimentation rate varies with technique and various environmental factors. The effect of temperature, angle of test tube, and osmobility with different percent of NaCl solution on erythrocyte sedimentation rate on sheep was determined by modified Westergren method. In sheep, as the angle of Westergren tube was decreased from $90^{\circ}$ to $45^{\circ}$, erythrocyte sedimentation rate was increased in both diluted plasma and NaCl solutions. As temperature was increased from $4^{\circ}C$ to $20^{\circ}C$ at $45^{\circ}$ angle. erythrocyte sedimentation rate was increased. In ruminants, this modified Westergren methods, erythrocyte 1 : plasma 9 instead of erythrocyte 4 : plasma 6(whole blood), enable them to have meanings as dog therefor, using this method, clinical can determine the erythrocyte sedimentation rate of ruminants for diagnosis. Because erythrocyte sedimentation rate was changed according to the angle of Westergren tube, temperature as erythrocyte diluted with NaCl, this study detected that the change of temperature, the angle of Westergren tube could change erythrocyte sedimentation rate by effecting red cell itself. The increase of osmobility owing to change of NaCl percent resulted in the decrease of rapid erythrocyte sedimentation rate. So this fact indicate that deformibility and the change of red cell volume have meaning in the change of erythrocyte sedimentation rate.

• 대한화학회지
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• 제36권1호
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• pp.44-50
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• 1992

착물들의 자기성과 스펙트라의 성질은 d 궤도 함수의 퇴화에 대한 분열과 자외선 가시 분광학적 방법으로 비수용액 속에서 조사하였다. 10Dq의 에너지 크기는 착물들의 스펙트라와 결합에너지 그리고 스핀상태로부터 얻어졌다. 전기화학적 거동은 순환전압 전류법에 의해 측정하였다. 이들의 환원 피크는 Ag/AgCl 전극으로 20mV/s에서 $[(C_6H_5)3_P]_2Pd(II)(CH_3COO)_2$는 $E_{pc1} = -1.32 V,\;E_{pc2} = -1.56 V$이고, 그리고 $[(C_6H_5)_3Pd]_2Pd(II)Cl_2$에서는 $E_{pc1} = -1.74 V,\;E_{pc2} = -1.88 V$로 일전자 비가역적인 과정이었다. 그러나 $Ni^{2+}$ 착물에서는 환원성으로 되지 않았다.

• 대한화학회지
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• 제36권6호
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• pp.906-913
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• 1992

실온에서 $WCl_6$와 $WNaNO_2$ 및 산성화시킨 $WFeSO_4$의 환원성 니트로실화 반응을 통해 다핵 화합물인 [{$W(NO)_2Cl_2$}$_n$]을 합성하였다. 이 [{$W(NO)_2Cl_2$}$_n$]와 한자리 및 두자리 리간드를 반응시켜 비교적 높은 수득률(70$\sim$90%)로 중성의 단핵 화합물인 [$W(NO)_2Cl_2L_2$(or L-L)]을 얻었다. 배위 리간드로는 3,5-lutidine, ${\gamma}$-cyanopyridine, 1,2-phenylenediamine, 1,10-phenanthroline, sym-diphenylethylenediamine, 9,10-phenanthrenequinone, 1,3-bis(diphenylphosphino)propane, 1,1'-bis(diphenylphosphino)ferrocene 및 8-hydroxyquinoline을 사용하였다. 합성한 디니트로실텡스텐 착물은 원소분석과 적외선, 핵자기 공명 및 전자 흡수 스펙트럼 등을 이용해서 그 특성을 조사하였으며 이들 분광학적 결과로써 모든 화합물의 기하학적 구조가 $C_{2v}$ 대칭인 cis-dinitrosyl-trans-dichloro-cis-$L_2$의 구조임을 확인하였다.

• Membrane and Water Treatment
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• 제3권1호
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• pp.25-34
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• 2012

Carboxylated polysulfone (CPS), poly (1,4-phenylene ether ethersulfone) (PPEES), membranes were prepared and used for the separation of NaCl and $CaCl_2$, in efficient way with less energy consumption. In this work, nanofiltration and reverse osmosis membranes were employed to the salt rejection behavior of the different salt solutions. The influence of applied pressure (1-12 bar), on the membrane performance was assessed. In CM series of membranes, $CM_1$ showed maximum of 97% water uptake and 36% water swelling, whereas, $CM_4$ showed 75% water uptake and 28% water swelling. In RCM series, $RCM_1$ showed 85% water uptake and 32% water swelling whereas, in $RCM_4$ it was 68% for water uptake and 20% for water swelling. Conclusively reverse osmosis membranes gave better rejection whereas nanofiltration membrane showed enhanced flux. CM1 showed 58% of rejection with 12 L/($m^2$ h) flux and $RCM_1$ showed 55% of rejection with 15 L/($m^2$ h) flux for 0.1 wt.% NaCl solution. Whereas, in 0.1 wt.% $CaCl_2$ solution, membrane $CM_1$ showed 78% of rejection with 12 L/($m^2$ h) flux and $RCM_1$ showed 63% rejection with flux of 9 L/($m^2$ h).

• 대한화학회지
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• 제36권6호
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• pp.872-878
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• 1992

VCl3${\cdot}$3MeCN과 리간드를 반응시켜 새로운 바나듐(III) 착물을 합성하였으며 원소분석과 적외선, 핵자기 공명 및 전자 흡수스펙트럼 등을 이용하여 그 특성을 조사하였다. 사용한 리간드는 3,5-lutidine(lutd), 8-hydroxyquinoline(oxine), 1,2-phenylenediamine(phda), ethylenediamine(en), and sym-diphenylethylenediamine(dpen)이다. lutidine 착물의 V-Cl 신축진동이 418$cm^{-1}$에서 나타나고, 다른 착물들(oxine, phda, en, dpen)은 337∼347 $cm^{-1}$에서 나타난다. 이러한 사실로 전자의 착물은 삼각 이중뿔 구조이며 후자의 착물들은 팔면체 구조로 추정된다. oxine과 phda 착물에서 acetonitrile의 C${\equiv}$N 신축진동은 자유 리간드(2260$cm^{-1}$) 보다 약 70$cm^{-1}$ 증가한 위치에서 나타나며, 또한 C${\equiv}$N 굽힘진동도 자유 리간드(377$cm^{-1}$)보다 약 60$cm^{-1}$ 증가한 위치에서 나타난다. 이러한 결과에 따라 [$VCl_3(lutd)_2$], [$VCl(oxine)_2$MeCN]$Cl_2$, [$VCl(phda)_2$MeCN]$Cl_2$, [$VCl_2(en)_2$]Cl, [$VCl_2(dpen)_2$]Cl와 같은 바나듐(III) 착물임을 알 수 있었다.

• 한국수산과학회지
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• 제16권3호
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• pp.291-297
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• 1983

고온${\cdot}$고염수인 대마난류는 동해에서 하계에 염분 최대층을 형성한다. 또 이 염분최대층의 용존산소($4.0{\sim}5.5\;ml/l$)는 고산소인 동해고유수 ($6.0{\sim}8.5\;ml/l$)에 비해 적은 값을 보이고 있는 것이 특징이다. 하계 동해에서 대마난류가 변동함에 따른 용존산소의 분포특성과 그 변동을 파악하기 위하여, 용존산소의 연직구조에 따라 그 분포역을 구분하고 염분 최대층에서 용존산소를 조사하여 연직단면구조의 변화를 검토하였다. 그 결과는 다음과 같다. 용존산소의 분포역은 해에 따라 다소 변동은 있으나 크게 셋으로 구분되었다. 즉 쿠로시오의 성질을 거의 그대로 보이는 $36^{\circ}N$ 이남해역, 동해 고유수의 성질을 보이는 해역($40^{\circ}N$ 이북해역) 및 그 중간해역인 대마난류역($36^{\circ}N{\sim}40^{\circ}N$)이었다. 염분최대치가 나타나는 층에서의 용존산소 및 ${\delta}_T$(thermosteric anomaly)의 범위는 대체로 $4.9{\sim}6.5\;ml/l,\;210{\sim}240\;cl/t$ 이었으나, 그 최대빈도는 각각 $5.5{\sim}5.7ml/l,\;230{\sim}240\;cl/t$ 이었다. 대마난류가 한국 동해안쪽으로 치우쳐 북상한 해의 경우에는 냉수와의 경계역에서 사행이 심하나 일본 연안쪽으로 주류가 북상한 해의 경우는 냉수와의 경계역이 매우 남하해 있고 비교적 전자에 비해 사행도 적었으며, PM 선상의 단면도로 볼 때 주축이 외해쪽으로 좀 더 이동해 있는 것으로 나타났다. 한편 용존산소의 분포상태로써 대마난류의 복상한계를 파악할 수가 있었다.

• Current Research on Agriculture and Life Sciences
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• 제4권
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• pp.87-94
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• 1986

본(本) 연구(硏究)에서는 주요(主要) 항만(港灣)에서 채취(採取)한 해성점토(海性粘土)에 대(對)하여 각종(各種) 공학력(工學力) 성질(性質)들을 측정(測定)하여 이들의 상호관계(相互關係)를 분석(分析) 고찰(考察)하였는바 그 결과(結果)를 요약(要約)하면 다음과 같다. 1. 본(本) 시험지구(試驗地區)의 흙은 대구분(大部分)이 CH, CL, ML로 구성(構成)되어 있으며 초기압밀(初期壓密)이 진행중(進行中)인 것으로 사료(思料)된다. 2. 압축지수(壓縮指數)와 액성한계(液性限界)의 관계식(關係式)은 다음과 같다. CH : $C_c=0.0137$ (LL-22.6) CL : $C_c=0.0123$ (LL-14.64) 3. 압축지수(壓縮指數)와 초기간극비(初期間隙比)의 관계(關係)는 소성(塑性)이 높은 흙 일수록 기울기가 완만하였으며 그 관계식(關係式)은 다음과 같다. CH : $C_c=0.431$ ($e_o-0.504$) CH : $C_c=0.471$ ( $e_o-0.235$) ML : $C_c=0.641$ ($e_o-0.393$) 4. 압축지수(壓縮指數)와 자연함수비(自然含水比)의 관계식(關係式)은 다음과 같다. CH : $C_c=0.0133$ ($W_n-28.27$) CL : $C_c=0.0225$ ($W_n-23.56$) ML : $C_c=0.0106$ ($W_n-16.42$) 5. 초기간극비(初期間隙比) 및 자연함수비(自然含水比)와 압축지수(壓縮指數)의 관계(關係)는 높은 정(正)의 상관(相關)으로 그 관계식(關係式)은 다음과 같다. CH : $C_c=0.301$ ($e_o+0.017W_n-1.05$) CL : $C_c=0.141$ ($e_o+0.0567W_n-1.054$) ML : $C_c=0.421$ ($e_o+0.0214W_n-1.121$) 6. 초기간극비(初期間隙比) 및 액성한계(液性限界)와 압축지수(壓縮指數)의 관계식(關係式)은 다음과 같다. CH : $C_c=0.36$ ($e_o+0.08LL-0.819$) CL : $C_c=0.269$ ($e_o+0.026LL-0.929$) 7. 해성점토(海性粘土)의 점착력(粘着力)은 심도(深度)와 상관성(相關性)이 없으며 일축압축강도(一軸壓縮强度)와의 관계식(關係式)은 다음과 같다. CH : qu=1.896C+0.0107 CL : qu=1.849C+0.04.