• 제목/요약/키워드: $^{238}U$

검색결과 212건 처리시간 0.022초

지하수와 지표수에서의 라돈 및 우라늄의 실태 조사 (The Study of Radon Activity and Uranium Concentration of Ground Water and Surface Water)

  • 오영미;이종복;신경진;김학철;이재희;황상철;정상기;이상태
    • 한국물환경학회지
    • /
    • 제23권2호
    • /
    • pp.201-205
    • /
    • 2007
  • This paper reports the amount of $^{222}Rn$ and $^{238}U$ in 18 sites of ground water and 30 sites of surface water. The instrument used to count $^{222}Rn$ activity was the liquid scintillation counter (LSC) which could resolute ${\alpha}$ and ${\beta}$ radiations. And $^{238}U$ was analyzed by the inductively coupled plasma (ICP). Radon and Uranium were not detected in raw and treated water which were sampled in a water treatment plant. However, radon ($^{222}Rn$) was high concentration in ground water from Jeon-la, Gang-won. So was uranium ($^{238}U$) in case of ground water from Gang-won, Choong-chung. Radon ($^{222}Rn$) activities were detected less than 15 pCi/L at 5 sampling points, 15~300 pCi/L at 7 sampling points, 300~4000 pCi/L at 6 sampling points. However, Radon ($^{222}Rn$) activities of all ground water samples were less than 4,000 pCi/L, which was bellow American Alternative Maximum Contamination Level (AMCL). Uranium ($^{238}U$) concentrations were less than $0.1{\mu}g/L$ at 5 sampling points, from $0.1{\mu}g/L$ to $20{\mu}g/L$ at 13 sampling points. Uranium was not detected in about 30% of the whole samples, but the concentration ranged from relatively low to high concentrations depending on the sampling point. The minimum detectable activity (MDA) of radon was 15 pCi/L. and the detection limit of uranium was $0.1{\mu}g/L$.

UNS N06690 제1열 시제전열관의 U-굽힘성형에서 형상변화와 표면잔류응력 (Geometric variations and surface residual stresses in U-bending processes of an UNS N06690 row-1 heat exchanger tubes)

  • 김우곤;장진성;국일현;주진원;김성청
    • 대한기계학회논문집A
    • /
    • 제22권1호
    • /
    • pp.238-246
    • /
    • 1998
  • Surface residual stresses as well as wall thickness and ovality changes after U-bending process on UNS N06690 row-1 heat exchanger tubes, were estimated. Surface residual stresses were measured by Hole Drilling Method(HDM), calculating the stresses from relieved strains of 3 rosette strain gages. After bending of the tubes, dimensional tolerances for wall thickness and ovality were satisfied with ASTM requirements. Residual stresses at the extrados were introduced with compressive stress(-) by bending operations, and its maximum value reached-319 MPa in axial direction at ${\phi}=0^{\circ}$ in position. Tensile residual stresses(+) of ${\sigma}_zz=45$ MPa,${\sigma}_zz=25$ MPa were introduced in the intrados surface at position of ${\phi}=0^{\circ}$ Maximum tensile residual stress of 170 MPa was detected on the flank side at position of ,${\phi}=95^{\circ}$i.e., at apex region. It appeared that higher stress gradients were generated at the irregular transition regions. In the trend of residual stress changes with U-bend position, the extrados is related with the changes of ovality and the intrados is related with the changes of wall thickness.

다검출기 유도결합 플라즈마 질량분석기를 이용한 경주 입실, 장항리 단층 파쇄대 충진 탄산염암 맥의 $^{230}Th/^{234}U$ 비평형 연대측정 ($^{230}$ Th/$^{234}$ U disequilibrium dating of fracture-filling carbonate veins from the Ipsil and Janghangri fault zones, Gyeongju, Korea by multiple collector inductively coupled plasma mass spectrometry)

  • 정창식;최만식;김현철;임상복
    • 암석학회지
    • /
    • 제10권3호
    • /
    • pp.148-156
    • /
    • 2001
  • 경북 경주시 인근의 제4기 추정단층 중 입실단층과 장항리단층의 파쇄대를 충진하고 있는 탄산염암맥을 대상으로 다검출기 유도결합 플라즈마 질량분석기를 이용한 $^{230}$ $Th^{234}$ U 비평형 연대를 측정하였다. 완전히 녹인 시료로부터 공침과 이온교환화학을 통해 간편하게 U, Th을 단체분리하였는데 회수율은 Th 80%, U 70% 정도였다. 이 부분으로부터 기기 조건이 최적화된 다검출기 유도결합 플라즈마 질량분석기를 이용하여 $^{234}$ $U^{238}$ $U^{230}$ $Th^{232}$ Th비를 분석하였고 U/Th비는 처리하지 않은 시료로부터 직접 분석하였다. 분석 결과 입실 단층의 탄산염암 맥은 $^{234}$ U-$^{230}$ Th 시차평형에 도달하여 기존의 ESR 연대측정 결과를 지지하였으며 쇄설성 부분이 보정된 장항리단층 탄산염암 맥의 $^{230}$$Th^{234}$ /U 비평형 연대는$ 48\pm$41 ka로서 파쇄대의 최소 형성시기를 지시한다.

  • PDF

Conceptual Core Design of 1300MWe Reactor for Soluble Boron Free Operation Using a New Fuel Concept

  • Kim, Soon-Young;Kim, Jong-Kyung
    • Nuclear Engineering and Technology
    • /
    • 제31권4호
    • /
    • pp.391-400
    • /
    • 1999
  • A conceptual core design of the 1,300MWe KNGR (Korean Next Generation Reactor) without using soluble boron for reactivity control was developed to determine whether it is technically feasible to implement SBF (Soluble Boron Free) operation. Based on the borated KNGR core design, the fuel assembly and control rod configuration were modified for extensive use of burnable poison rods and control rods. A new fuel rod, in which Pu-238 had been substituted for a small amount of U-238 in fuel composition, was introduced to assist the reactivity control by burnable poison rods. Since Pu-238 has a considerably large thermal neutron capture cross section, the new fuel assembly showed good reactivity suppression capability throughout the entire cycle turnup, especially at BOC (Beginning of Cycle). Moreover, relatively uniform control of power distribution was possible since the new fuel assemblies were loaded throughout the core. In this study, core excess reactivity was limited to 2.0 %$\delta$$\rho$ for the minimal use of control rods. The analysis results of the SBF KNGR core showed that axial power distribution control can be achieved by using the simplest zoning scheme of the fuel assembly Furthermore, the sufficient shutdown margin and the stability against axial xenon oscillations were secured in this SBF core. It is, therefore, concluded that a SBF operation is technically feasible for a large sized LWR (Light Water Reactor).

  • PDF

동위원소희석 질량분석법을 이용한 사용후핵연료 중 우라늄 동위원소 정량 (Determination of Uranium Isotopes in Spent Nuclear Fuels by Isotope Dilution Mass Spectrometry)

  • 김정석;전영신;손세철;박순달;김종구;김원호
    • 분석과학
    • /
    • 제16권6호
    • /
    • pp.450-457
    • /
    • 2003
  • 사용후핵연료 내 U 및 동위원소 정량분석을 동위원소 희석 질량분석법 (isotope dilution mass spectrometry, IDMS)으로 수행하였다. 시료는 산화우라늄 사용후핵연료 시료를 $HNO_3$(1+1) 또는 이 용액과 14 M $HNO_3-0.05M$ HF 혼합용액으로 용해한 후 막 거르게 ($1.2{\mu}m$)로 여과하여 준비하였다. 시료 및 스파이크를 첨가한 시료 중의 U은 AG lX8 음이온교환 수지관에서 0.1 M HCl 용액으로 용리하였다. 시료 중의 총 U 량과 성분 동위원소 ($^{234}U$, $^{235}U$, $^{236}U$$^{238}U$)의 조성은 $^{233}U$을 스파이크로 이용하는 동위원소 희석 질량분석법으로 정량하였다. 제조한 U-233 스파이크 용액은 천연 및 감손 U을 이용한 역동위원소 희석 질량분석법 (reverse isotope dilution mass spectrometry, R-IDMS)으로 표정하였다. 동위원소 희석 질량분석법에 의한 핵연료시료 중의 총 U 량 측정결과를 전위차 적정으로 측정한 결과와 비교하였을 때 0.34% 평균 상대오차 범위에서 일치하였다.

Feasibility Study of Isotope Ratio Analysis of Individual Uranium-Plutonium Mixed Oxide Particles with SIMS and ICP-MS

  • Esaka, Fumitaka;Magara, Masaaki;Suzuki, Daisuke;Miyamoto, Yutaka;Lee, Chi-Gyu;Kimura, Takaumi
    • Mass Spectrometry Letters
    • /
    • 제2권4호
    • /
    • pp.80-83
    • /
    • 2011
  • Isotope ratio analysis of nuclear materials in individual particles is of great importance for nuclear safeguards. Although secondary ion mass spectrometry (SIMS) and thermal ionization mass spectrometry (TIMS) are utilized for the analysis of individual uranium particles, few studies were conducted for the analysis of individual uranium-plutonium mixed oxide particles. In this study, we applied SIMS and inductively coupled plasma mass spectrometry (ICP-MS) to the isotope ratio analysis of individual U-Pu mixed oxide particles. In the analysis of individual U-Pu particles prepared from mixed solution of uranium and plutonium standard reference materials, accurate $^{235}U/^{238}U$, $^{240}Pu/^{239}Pu$ and $^{242}Pu/^{239}Pu$ isotope ratios were obtained with both methods. However, accurate analysis of $^{241}Pu/^{239}Pu$ isotope ratio was impossible, due to the interference of the $^{241}Am$ peak to the $^{241}Pu$ peak. In addition, it was indicated that the interference of the $^{238}UH$ peak to the $^{239}Pu$ peak has a possibility to prevent accurate analysis of plutonium isotope ratios. These problems would be avoided by a combination of ICP-MS and chemical separation of uranium, plutonium and americium in individual U-Pu particles.

Sensitivity and uncertainty quantification of neutronic integral data in the TRIGA Mark II research reactor

  • Makhloul, M.;Boukhal, H.;Chakir, E.;El Bardouni, T.;Lahdour, M.;Kaddour, M.;Ahmed, Abdulaziz;Arectout, A.;El Yaakoubi, H.
    • Nuclear Engineering and Technology
    • /
    • 제54권2호
    • /
    • pp.523-531
    • /
    • 2022
  • In order to study the sensitivity and the uncertainty of the Moroccan research reactor TRIGA Mark II, a model of this reactor has been developed in our ERSN laboratory for use with the N-Particle MCNP Monte Carlo transport codes (version 6). In this article, the sensitivities of the effective multiplication factor of this reactor are evaluated using the ENDF/B-VII.0, ENDF/B-VII.1 and JENDL-4.0 libraries and in 44 energy groups, for the cross sections of the fuel (U-235 and U-238) and the moderator (H-1 and O-16). However, the quantification of the uncertainty of the nuclear data is performed using the nuclear code NJOY99 for the generation and processing of covariance matrices. On the one hand, the highest uncertainty deviations, calculated using the ENDFB-VII.1 and JENDL4.0 evaluations, are 2275, 386 and 330 pcm respectively for the reactions U235(n, f), $ U_{235}(n\bar{\nu})$ and H1(n, γ). On the other hand, these differences are very small for the neutron reactions of O-16 and U-238. Regarding the neutron spectra, in CT-mid plane, they are very close for the three evaluations (ENDF/B-VII.0, ENDF/B-VII.1 and JENDL-4.0). These spectra present two peaks (thermal and fission) around the energies 0.05 eV and 1 MeV.

유비쿼터스 센서네트워크 분석을 위한 모니터링 도구 설계 및 구현 (A Design and Implementation of Monitoring Tool for Analysis of Ubiquitous Sensor Network)

  • 한형욱;이정배;안성순
    • 한국정보처리학회:학술대회논문집
    • /
    • 한국정보처리학회 2009년도 추계학술발표대회
    • /
    • pp.237-238
    • /
    • 2009
  • u-City 통합 운영 센터의 목적은 다양한 u-City 서비스들의 정보를 수집, 분석, 통합하여 제공함으로써 삶의 질을 높이고 도시를 효율적으로 관리하는 것이다. 이를 위해서 u-City 통합 플랫폼 구축과 기술 표준화를 위한 연구들이 활발히 진행되고 있으며, u-City 통합 플랫폼은 한 서비스에 종속적이지 않은 독립적인 서비스 플랫폼으로서 기존의 u-City서비스를 제공할 수 있으며 자유롭게 확장 될 수 있어야 한다. 따라서 효율적인 통합 플랫폼 구축을 위해서는 기존의 센서 네트워크 시스템 분석이 필요하며 본 논문에서는 이기종의 센서 네트워크 시스템들의 비교 및 분석을 용이하게 하는 지원도구를 설계 및 구현한다.

Determine the hazards of radioactive elements and radon gas manufacturing processes in an Egyptian fertilizer factory

  • Soad Saad Fares
    • Nuclear Engineering and Technology
    • /
    • 제56권5호
    • /
    • pp.1781-1795
    • /
    • 2024
  • This study investigated the levels of radioactivity in soil surrounding a phosphate fertilizer factory in Egypt, aiming to assess potential risks to the population exposed to radiation. Concentrations of 238U, 226Ra, 232Th, and 40K were measured in soil samples collected from two subsites: one near the factory (subsite 1) and another further away (subsite 2). Two different systems were used for measuring radioactivity, a high-purity gamma ray spectroscopy system with an HPGe detector for gamma-emitting isotopes and a CR-39 solid nuclear track detector for alpha-emitting radon gas. Subsite 1, located close to the factory, displayed significantly elevated levels of 226Ra compared to global background levels (514 and 456 Bq/kg vs. 35 Bq/kg). Additionally, the concentrations of 238U (241.06 Bq/kg vs. global average 35 Bq/kg), 232Th (16.15 Bq/kg vs. global average 30 Bq/kg), and 40K (146.36 Bq/kg vs. global average 400 Bq/kg) were all above global averages. Furthermore, a high concentration of radon gas (337.06 μSv/y) was measured at subsite 1. The strong positive correlation observed between 226Ra and 238U (0.96256) provides further evidence of potentially elevated radioactivity levels near the factory. In contrast, subsite 2, situated farther from the factory, exhibited natural radioactive background levels within international limits. Quantitative analysis revealed that gamma ray absorbed doses for 226Ra and 232Th exceeded global averages in some samples. Specifically, 226Ra doses ranged from 7.8 to 46.26 ppm (exceeding the 20 ppm global average in some cases), and 232Th doses ranged from 1.98 to 9.14 ppm (exceeding the 10 ppm global average in some cases). The concentration of 40K, however, remained within the global range (0.07%-0.69 %). The observed imbalances in the ratios of Th/U (0.17-0.24 Bq/kg and 0.73-0.24 ppm) and U/Ra (0.81-0.73 Bq/kg and 0.73-0.17 ppm), both of which are significantly lower than their respective global averages of 4 and 2.4, point towards the presence of fertilizer-derived contamination. This conclusion is further supported by the high phosphate concentrations detected in the samples. Overall, this study suggests that radioactive contamination near the phosphate fertilizer factory significantly exceeds global background levels and international limits in some cases. This raises concerns about potential risks posed to surrounding agricultural land and crops.