• Bulletin of the Korean Chemical Society
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• 제14권1호
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• pp.137-143
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• 1993

The tetranuclear heterometallic complex CpMo$Os_3(CO)_{10}({\mu]-H)2[{\mu}3-{\eta}^2-C(O)CH_2Tol]\;(1,\;Cp={\eta}^5-C_5H_5,\;Tol=p-C_6H_4Me)$ has been examined by variable-temperature $^{13}$C-NMR spectroscopy and by a full three-dimensional X-ray structual analysis. Complex 1 crystallizes in the orthorhombic space group Pna2$_1$ with a = 12.960(1) ${\AA}$, b = 11.255(l) ${\AA}$, c = 38.569(10)${\AA}$, V = 5626(2) ${\AA}^3$ and ${\rho}$(calcd) = 2.71 gcm$^{-3}$ for Z = 8 and molecular weight 1146.9. Diffraction data were collectedon a CAD4 diffractometer, and the structure was refined to $R_F$ = 9.7% and $R_{W^F}$ = 9.9% for 2530 data (MoK${\alpha}$ radiation). There are two essentially equivalent molecules in the crystallographic asymmetric unit. The tetranuclear molecule contains a triangulated rhomboidal arrangement of metal atoms with Os(2) and Mo at the two bridgehead positions. The metal framework is planar; the dihedral angle between Os(l)-Os(2)-Mo and Os(3)-Os(2)-Mo planes is 180$^{\circ}$. A triply bridging (${\mu}_3,\;{\eta}^2$) acyl ligand lies above the Os(l)-Os(2)-Mo plane; the oxygen atom spans the two bridgehead positions, while the carbon atom spans one bridgehead position and an acute apical position. The molecular architecture is completed by an ${\eta}^5$-cyclopentadienyl ligand and a semi-triply bridging carbonyl ligand on the molybdenum atom, and nine terminal carbonyl ligands-four on Os(3), three on Os(l), and two on Os(2). The two hydride ligands are inferred to occupy the Os(l)-Os(2) and Mo-Os(3) edges from structural and NMR data.

• Archives of Pharmacal Research
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• 제19권4호
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• pp.335-336
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• 1996

• Archives of Pharmacal Research
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• 제7권2호
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• pp.121-126
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• 1984

From the roots of Patrinia scabiosaefolia Valerianaceae), scopoletin (1), esculetin (2), oleanonic acid (3), 3-O-.alpha.-L-rhamnopyranosyl (1.rarw.2)-.alpha.-l-arabinopyranosyl oleanolic acid (4) and 3-O-.alpha.-L- rhamnopyranosyl (1 .rarw. 2)-.alpha.-L-arabinopyranosyl header agenin (5) were isolated and characterized by spectral data.

• 약학회지
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• 제46권6호
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• pp.398-404
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• 2002

A phytochemical study on the root of Cibotium barometz J. Smith led to the isolation of onitin (I), daucosterol (II) and a new compound (III). Compound III was characterized as 2-Ο-(9Z,12Z-octadecadienoyl)-3-Ο-[$\alpha$-D-galactopyranosyl-(1"-6")-Ο-$\beta$-D-galactopyranosyl] glycerol, named shinbarometin by $^1$H-, $^{13}$ C-NMR and LC/MS data. Compound III exerted an induced neuronal regeneration on nogo-A induced neuroblastoma cells.

• Natural Product Sciences
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• 제2권2호
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• pp.102-105
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• 1996

A new glycolipid, 2-hydroxy-3 $(octadecyloxy)-propyl-{\alpha}-D-arabinopyranoside$ (1) has been isolated from Lobophytum microlobulatum and its structure has been elucidated by physical and spectral $(UV,\;IR,\;^1H,\;^{13}C\;NMR,\;FABMS)$ data.

• 생약학회지
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• 제18권3호
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• pp.177-179
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• 1987

From the roots of Rosa rugosa(Rosaceae), (+)-catechin, and a mixture of ${\beta}-sitosterol$ and campesterol glucosides were isolated and characterized by the physicochemical and spectral data.

• Archives of Pharmacal Research
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• 제14권2호
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• pp.114-117
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• 1991

From the leaves of Eucommia ulmoides, quercetin, astragalin, isoquercitrin, quercetin 3-O-$\beta$-D-sambubioside and chlorogenic acid were isolated and characterized by spectral data.

• 생약학회지
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• 제21권1호
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• pp.49-51
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• 1990

From tire root bark of Accnthopanax koreanum a new diterpene glycoside, mp $212{\sim}214^{\circ}$, was isolated. The structure was established as 15(R),16-dihydroxypimar-9(11)-ene-19-oic acid ${\beta}$-D-glucopyranosyl ester (sumogaside) oil the basis of spectroscopic methods and chemical transformation.

• 생약학회지
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• 제21권3호
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• pp.197-200
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• 1990

Quercetin, trifolin and quercitrin were isolated from the leaves of Machilus thunbergii Sieb. et Zucc. (Lauraceae) and characterized by spectral data. These are reported for the first time from this plant.

• Natural Product Sciences
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• 제12권2호
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• pp.101-103
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• 2006

In the course of the continual work on the fresh tubers of Gastrodia elata, a fructoside constituent was isolated from the n-butanol soluble fraction prepared from the methanol extract. The structure of this compound was identified as $n-butyl-{\beta}-D-fructopyranoside$ from various spectroscopic data including $^1H-\;and\;^{13}C-NMR$, HMQC, HMBC, and FABMS.